*2021/11/25 14:59:07.17 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/08/21 17:10:17.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : E0B27323 NUMBER OF CHANNELS : 53 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 93 109 2 Bottle_Number n/a 1 17 3 Bottle:Firing_Sequence n/a 1 17 4 Pressure decibar 1.2 300.6 5 Temperature:Primary 'deg C (ITS90)' 6.2853 14.8435 6 Transmissivity %/metre 40.6 66.4 7 Fluorescence:URU:Seapoint mg/m^3 0.78E-01 3.479 8 PAR uE/m^2/sec 0 947.3 9 Salinity:T0:C0 PSS-78 32.0277 33.9661 10 Oxygen:Dissolved:SBE mL/L 1.81 6.32 11 Oxygen:Dissolved:SBE umol/kg 78.8 275.7 12 Number_of_bin_records n/a 194 241 13 Nitrate_plus_Nitrite umol/L 0.15 36.8 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 7.04 56.73 16 Flag:Silicate n/a 17 Phosphate umol/L 0.448 2.584 18 Flag:Phosphate n/a 19 Dimethyl_Sulphide nmol/L 0 1.36 20 Flag:Dimethyl_Sulphide n/a 21 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 22 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 23 Dimethylsulfoniopropionate_Total nmol/L -99 -99 24 Flag:Dimethylsulfoniopropionate_Total ' ' 25 Chlorophyll:Extracted mg/m^3 0.3E-01 1.89 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.17 0.82 28 HPLC:Chl-c3 mg/m^3 0.65E-01 0.238 29 HPLC:Chlide-a mg/m^3 0 0 30 HPLC:MgDVP mg/m^3 0.4E-02 0.29E-01 31 HPLC:Chl-c2 mg/m^3 0.44E-01 0.234 32 HPLC:Chl-c1 mg/m^3 0 0.2E-02 33 HPLC:Me-chlide mg/m^3 0 0.21E-01 34 HPLC:Peri mg/m^3 0.22E-01 0.42E-01 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0.18E-01 0.145 37 HPLC:Fuco mg/m^3 0.113 0.482 38 HPLC:Neo mg/m^3 0.9E-02 0.32E-01 39 HPLC:Pras mg/m^3 0.5E-02 0.37E-01 40 HPLC:Viola mg/m^3 0 0.21E-01 41 HPLC:Hex-fuco mg/m^3 0.71E-01 0.442 42 HPLC:Diadino mg/m^3 0.1E-01 0.167 43 HPLC:Allo mg/m^3 0.5E-02 0.21E-01 44 HPLC:Diato mg/m^3 0 0.28E-01 45 HPLC:Zea mg/m^3 0.6E-02 0.155 46 HPLC:Lut mg/m^3 0 0.16E-01 47 HPLC:Chl-b mg/m^3 0.12 0.204 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 0.346 1.377 50 HPLC:Phe mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0.2E-02 0.37E-01 52 HPLC:TChl-a mg/m^3 0.346 1.398 53 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 7 F R4 2 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-19 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 20 LATITUDE : 48 38.98000 N ! (deg min) LONGITUDE : 126 39.97000 W ! (deg min) WATER DEPTH : 1325 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2663 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3642 'Transmissometer:WET Labs C-Star' ' ' 1396DR PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/12/17 17:39:01 4041 4041 CLEAN 5.2.1 2014/12/17 17:39:56 ? ? ADDSAMP 3.6 2014/12/18 09:38:09 4041 4041 BINAVE 4.2 2014/12/18 11:15:57 4041 17 MERGE 3.5 2015/01/29 11:27:26 17 17 CLEAN 5.2.1 2015/01/29 11:27:31 17 17 CALIB 11.8.1 2015/01/29 13:40:43 17 17 CALIB 11.8.1 2015/01/29 13:40:53 17 17 SORT 3.6 2015/03/30 10:49:03 17 17 REMOVECH 8.2 2015/03/30 11:16:55 17 17 CHGUNITS 3.1 2015/03/30 11:17:41 17 17 CHGUNITS 3.1 2015/03/30 11:17:58 17 17 REORDER 1.3.1 2015/03/30 11:18:05 ? ? HDREDIT2 3.0.2 2015/03/30 11:18:20 ? ? SORT 3.6 2019/11/26 16:53:06 17 17 HDREDIT2 3.1.1 2019/11/26 16:53:43 ? ? MERGE 3.5 2019/11/26 16:53:57 17 17 SORT 3.6 2019/11/26 16:54:36 17 17 HDREDIT2 3.1.1 2019/11/26 16:59:53 ? ? SORT 3.6 2020/08/03 15:06:50 17 17 REORDER 1.3.1 2021/11/25 13:45:40 ? ? MERGE 3.5.1 2021/11/25 13:45:52 17 17 SORT 3.6 2021/11/25 13:46:03 17 17 CLEAN 5.2.4 2021/11/25 13:46:10 17 17 HDREDIT2 3.2 2021/11/25 14:58:20 ? ? HDREDIT2 3.2 2021/11/25 14:59:07 ? ? $END $REMARKS -CLEAN functions: 2014/12/17 17:39:51 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-19\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/01/29 11:27:26 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-19\Processing\hydro\2014-19-0020.samavg Secondary file: P:\Cruise_Data_Processing\2014-19\Processing\hydro\2014-19-0020.mrgcln1s -SORT parameters: 2015/01/29 11:27:18 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/01/29 11:27:31 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2015/01/29 13:40:43 Calibration type = Correct Mode: HEAD - calibration specs from header only. Calibration file = P:\Cruise_Data_Processing\2014-19\Processing\doc\2014-19-recal1.CCF WARNING: No calibration done on file P:\Cruise_Data_Processing\2014-19\Processing\hydro\2014-19- 0020.mrgcor1 -CALIB parameters: 2015/01/29 13:40:53 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-19\Processing\doc\2014-19-recal2-che.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Oxygen:Dissolved:SBE mL/L 10 -0.3600000E-02 0.1024500E+01 -SORT parameters: 2015/03/30 10:49:03 Sorted in ascending order of channel Pressure* -REMOVECH 2015/03/30 11:16:55 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T1:C1 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2015/03/30 11:18:20 Applied edit header: P:\Cruise_Data_Processing\Temp\2014-19 temp\hydro\2014-19-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 17: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 18: Silicate [umol/L] Units: ==> umol/L Channel 19: Flag:Silicate [n/a] Units: ==> n/a Channel 20: Phosphate [umol/L] Units: ==> umol/L Channel 21: Flag:Phosphate [n/a] Units: ==> n/a Channel 22: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L Channel 23: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -SORT parameters: 2019/11/26 16:53:06 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2019/11/26 16:53:43 -The following MERGE parameters were used: 2019/11/26 16:53:57 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\2014-019\Processing\Bottle\2014-019-0020.rem Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2014-019\Processing\Bottle\2014-019-0020. dmsp -SORT parameters: 2019/11/26 16:54:36 Sorted in ascending order of channel pressure -HEADER EDITS: 2019/11/26 16:59:53 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2014-019\Processing\DOC\2014-019-dmsp- hdr.txt -SORT parameters: 2020/08/03 15:06:50 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 13:45:52 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-019_Nov2021\Processing\ IOS\2014-019-0020.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-019_Nov2021\Processing\ IOS\2014-019-0020.hplc -SORT parameters: 2021/11/25 13:46:03 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 13:46:10 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 14:58:20 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_019\Processing\IOS\ 2014-019-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 14:59:07 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_019\Processing\IOS\ 2014-019-bot-hdr2.txt $END *COMMENTS Sample_Number 107: CHL: CV%>15% Sample_Number 102: DMS: There is a wide difference between the two dups averaged here. Alth uncommon to see wide differences in dms between dups within the same niskin the sample is nonetheless flagged as a precautionary measure. Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2014-019\Processing\Bottle\2014-019-0020.dmsp --------------------------------------------------------------------------- Sample_Number 94: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 95: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 96: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 102: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 105: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 106: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship during the cruise or at IOS in Room 1409 about 7 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-19CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~4-5 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2014-019HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-19OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Ltd. and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 4 to 19 days after collection. For details including a duplicate analysis, see document QF2014-19SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-19nuts*.xls. DMS samples were analyzed at sea. For details on the collection and analysis of the DMS data see file 2014-19 DMS report.doc and for data see "DMS summary (2014-19 data)*.xls." The minimum detectable level for DMS is 0.10 nMol/L, so “0” values should be interpreted as <0.10nmol/L. DMSP-D: 20-75mL of seawater was allowed to flow directly from the niskin into a magnetic filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMPS-T: 3.5mL of seawater was collected directly from the niskin into a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. For details on analysis and raw data, see document "QF 2014-019 dmsp*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Post-cruise calibration reports indicate that the primary temperature and conductivity sensors had insignificant drifts. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except offsets in the fit are allowed. For details on the processing see document: 2014-19_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-019_Nov2021\Processing\IOS\2014-019-0020. hplc --------------------------------------------------------------------------- Sample_Number 108: HPLC: >10%CV for TChl-a Sample_Number 109: HPLC: only single rep available *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.36E-02 1.0245) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13-- 14 --15-- 16 ---17-- 18 --19-- 20 --21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T0:C0 : n: er_o e_ ag te ag te ag yl_ ag ylsulf ag ylsulf ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Nitrit ri ca ha de hi te_Dis lv ionate ot ted ct Extrac HP ! ence t SBE SBE ords e te te te de solved ed _Total al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 106 14 17 1.2 14.8435 43.9 0.721 947.3 32.0320 6.25 272.5 241 0.19 0 7.07 0 0.449 0 1.22 0 -99.00 1 -99.00 1 1.36 0 0.38 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 109 17 16 4.9 14.8095 43.9 0.956 451.4 32.0311 6.25 272.6 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 0.99 6 0.26 0.094 0.000 0.016 0.114 0.000 0.000 0.023 0.000 0.109 0.145 0.015 0.026 0.011 0.223 0.167 0.019 0.028 0.112 0.016 0.123 0.000 0.845 0.000 0.024 0.845 2 105 13 15 5.0 14.7766 43.6 1.013 483.8 32.0308 6.25 272.7 194 0.15 0 7.04 0 0.448 0 1.36 0 -99.00 1 -99.00 1 1.05 0 0.26 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 104 12 14 9.9 14.2680 41.3 2.509 179.1 32.0280 6.32 275.7 241 0.50 6 7.35 6 0.479 6 0.81 0 -99.00 0 -99.00 0 1.80 0 0.60 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 103 11 12 15.0 13.9902 40.6 3.449 73.8 32.0277 6.30 274.6 241 0.85 0 7.48 0 0.487 0 1.18 0 -99.00 0 -99.00 0 1.73 0 0.59 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 108 16 13 15.0 13.9910 40.7 3.479 71.7 32.0278 6.30 274.6 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 1.71 6 0.54 0.238 0.000 0.029 0.234 0.002 0.021 0.042 0.000 0.145 0.482 0.032 0.037 0.021 0.442 0.070 0.021 0.005 0.155 0.000 0.204 0.000 1.377 0.000 0.037 1.398 36 102 10 11 20.0 13.6190 44.8 2.647 25.0 32.0608 6.22 271.0 241 2.48 0 7.75 0 0.597 0 1.05 36 -99.00 1 -99.00 1 1.89 0 0.82 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 101 9 10 25.1 11.3736 60.4 0.989 13.3 32.2312 6.04 263.2 241 7.15 0 10.43 0 0.938 0 0.33 0 -99.00 0 -99.00 0 0.76 0 0.52 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 100 8 8 30.0 10.2416 63.7 0.597 7.4 32.3061 6.01 261.8 232 9.21 0 11.44 0 1.050 0 0.32 0 -99.00 0 -99.00 0 0.46 0 0.42 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 107 15 9 30.0 10.2399 63.6 0.598 7.5 32.3057 6.01 261.7 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 0.46 36 0.33 0.065 0.000 0.004 0.044 0.000 0.000 0.022 0.000 0.018 0.113 0.009 0.005 0.000 0.071 0.010 0.005 0.000 0.006 0.000 0.120 0.000 0.346 0.000 0.002 0.346 6 99 7 7 40.0 9.4040 64.4 0.404 2.0 32.3682 6.03 262.7 241 11.10 0 12.37 0 1.147 0 0.21 0 -99.00 0 -99.00 0 0.40 0 0.37 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 98 6 6 50.1 8.6391 65.4 0.314 1.3 32.4383 6.09 265.0 241 12.22 0 13.67 0 1.190 0 0.00 0 -99.00 0 -99.00 0 0.24 6 0.27 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 97 5 5 75.0 7.3908 65.8 0.135 0.2 32.7060 5.53 240.7 241 18.20 0 21.81 0 1.519 0 0.00 0 -99.00 0 -99.00 0 0.08 0 0.23 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 96 4 4 99.9 7.1722 66.2 0.103 0.1 33.0086 5.00 217.5 241 21.22 0 25.40 0 1.673 0 0.00 0 -99.00 1 -99.00 1 0.03 0 0.17 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 95 3 3 175.0 7.3280 66.4 0.080 0.0 33.8657 2.67 116.0 241 31.26 0 41.19 0 2.227 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 94 2 2 200.3 7.0855 66.3 0.078 0.0 33.8952 2.42 105.1 241 33.06 0 45.18 0 2.329 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 93 1 1 300.6 6.2853 66.4 0.078 0.0 33.9661 1.81 78.8 241 36.80 0 56.73 0 2.584 0 0.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0