*2015/03/30 11:18:19.93 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2014/08/20 16:52:04.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 15 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 4A9C2933 NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 15 2 Bottle:Firing_Sequence n/a 1 15 3 Pressure decibar 1.78 226.35 4 Temperature:Primary 'deg C (ITS90)' 8.8987 12.4764 5 Transmissivity %/metre 43 56.5 6 Fluorescence:URU:Seapoint mg/m^3 0.174 2.405 7 PAR uE/m^2/sec 0.2E-01 238.326 8 Salinity:T0:C0 PSS-78 28.8937 32.4759 9 Oxygen:Dissolved:SBE mL/L 2.726 4.582 10 Oxygen:Dissolved:SBE umol/kg 118.7 200.2 11 Number_of_bin_records n/a 241 241 12 Sample_Number n/a 1 15 13 Temperature:Draw 'deg C (ITS90)' 10.8 13.2 14 Oxygen:Dissolved mL/L 2.748 4.559 15 Oxygen:Dissolved umol/kg 119.7134 199.2177 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 18.85 29.9 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 42.83 47.08 20 Flag:Silicate n/a 21 Phosphate umol/L 1.729 2.335 22 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-19 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : Haro59 EVENT NUMBER : 3 LATITUDE : 48 36.78000 N ! (deg min) LONGITUDE : 123 14.86000 W ! (deg min) WATER DEPTH : 237 ALTIMETER (M) : 10.92 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2038 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 4883 Conductivity:2 ' ' 3394 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1438 Fluorometer:Seapoint ' ' 3641 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/12/06 15:54:30 3615 3615 CLEAN 5.2 2014/12/06 15:56:37 ? ? ADDSAMP 3.6 2014/12/18 09:38:04 3615 3615 BINAVE 4.2 2014/12/18 11:15:54 3615 15 MERGE 3.5 2015/01/29 11:27:26 15 15 CLEAN 5.2.1 2015/01/29 11:27:31 15 15 CALIB 11.8.1 2015/01/29 13:40:42 15 15 CALIB 11.8.1 2015/01/29 13:40:52 15 15 SORT 3.6 2015/03/30 10:49:03 15 15 REMOVECH 8.2 2015/03/30 11:16:55 15 15 CHGUNITS 3.1 2015/03/30 11:17:40 15 15 CHGUNITS 3.1 2015/03/30 11:17:58 15 15 REORDER 1.3.1 2015/03/30 11:18:05 ? ? HDREDIT2 3.0.2 2015/03/30 11:18:19 ? ? $END $REMARKS -CLEAN functions: 2014/12/06 15:56:37 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-19\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/01/29 11:27:26 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-19\Processing\hydro\2014-19-0003.samavg Secondary file: P:\Cruise_Data_Processing\2014-19\Processing\hydro\2014-19-0003.mrgcln1s -SORT parameters: 2015/01/29 11:27:18 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/01/29 11:27:31 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2015/01/29 13:40:42 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-19\Processing\doc\2014-19-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure decibar 10 0.1250000E+01 0.1000000E+01 -CALIB parameters: 2015/01/29 13:40:52 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-19\Processing\doc\2014-19-recal2-che.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1029600E+01 -SORT parameters: 2015/03/30 10:49:03 Sorted in ascending order of channel Pressure* -REMOVECH 2015/03/30 11:16:55 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T1:C1 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2015/03/30 11:18:19 Applied edit header: P:\Cruise_Data_Processing\Temp\2014-19 temp\hydro\2014-19-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 17: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 18: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 19: Silicate [umol/L] Units: ==> umol/L Channel 20: Flag:Silicate [n/a] Units: ==> n/a Channel 21: Phosphate [umol/L] Units: ==> umol/L Channel 22: Flag:Phosphate [n/a] Units: ==> n/a $END *COMMENTS Sample_Number 1: OXY: Slow drip from Niskin spigot Sample_Number 5: OXY-2: Titration very short and only to 90% transmissivity. Endpoint likely overshot. Sample_Number 6: OXY: Bubble in flask. Value was also a significant outlier when compared to to the CTD DO sensor (Diff ~0.4mL/L.) Sample_Number 10: OXY: Bubble in flask Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship during the cruise or at IOS in Room 1409 about 7 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-19CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-19OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Ltd. and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 4 to 19 days after collection. For details including a duplicate analysis, see document QF2014-19SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-19nuts*.xls. DMS samples were analyzed at sea. For details on the collection and analysis of the DMS data see file 2014-19 DMS report.doc and for data see "DMS summary (2014-19 data)*.xls." The minimum detectable level for DMS is 0.10 nMol/L, so “0” values should be interpreted as <0.10nmol/L. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Post-cruise calibration reports indicate that the primary temperature and conductivity sensors had insignificant drifts. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except offsets in the fit are allowed. For details on the processing see document: 2014-19_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure decibar 10 -99 () (1.25 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0296) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- -12- --13- ---14-- --15- 16 --17-- 18 --19-- 20 ---21-- 22 !Bo Bo Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Samp Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: :T0:C0 : n: er_o le_ ratur Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity URU: Dissol Disso ~bin Numb e: ed Disso ~o plus_ ~t ~i ~p !mb en Seapoin ved: lved: _rec er Draw lved lv Nitrit ri ca ha !er ce t SBE SBE ords ed e te te te !-- -- ------ -------- ----- ------- ------ -------- ------ ----- ---- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 15 15 1.8 12.4764 43.0 1.641 238.3 28.8937 4.58 200.2 241 15 13.2 4.559 199.2 0 18.85 0 42.83 0 1.729 0 14 14 6.0 12.3140 43.5 2.405 59.6 29.0484 4.37 190.9 241 14 13.1 4.400 192.2 6 19.20 0 43.11 0 1.754 0 13 13 11.2 12.1206 45.7 2.014 14.1 29.2382 4.25 185.7 241 13 12.9 4.237 185.1 0 20.08 0 43.57 0 1.802 0 12 12 21.2 11.2853 52.5 0.855 1.5 30.1679 3.80 165.8 241 12 12.3 3.758 164.0 0 22.88 0 45.28 0 1.985 0 11 11 31.4 11.1766 53.9 0.749 0.3 30.2450 3.74 163.4 241 11 12.4 3.727 162.7 0 22.41 0 44.16 0 1.944 0 10 10 41.2 11.1621 53.9 0.734 0.1 30.2561 3.73 162.9 241 10 12.3 3.854 168.2 3 23.37 0 45.38 0 2.015 0 9 9 51.4 11.0617 54.3 0.654 0.0 30.3521 3.69 160.9 241 9 12.4 3.590 156.7 0 24.08 0 45.66 0 2.055 0 8 8 61.4 10.4524 55.7 0.402 0.0 30.9944 3.41 148.6 241 8 11.9 3.355 146.3 0 25.52 0 46.14 0 2.137 0 7 7 81.4 10.0966 56.5 0.308 0.0 31.3657 3.25 141.5 241 7 11.6 3.260 142.1 0 26.37 6 46.16 6 2.176 6 6 6 101.5 10.0582 56.2 0.317 0.0 31.4040 3.23 140.7 241 6 11.7 3.652 159.2 4 26.59 0 46.24 0 2.188 0 5 5 127.0 9.4369 55.6 0.211 0.0 31.9914 2.95 128.3 241 5 11.3 2.990 130.3 46 27.98 0 46.60 0 2.257 0 4 4 151.3 9.0203 52.9 0.179 0.0 32.3624 2.77 120.6 241 4 10.8 2.783 121.2 0 29.22 0 47.01 0 2.321 0 3 3 177.3 8.9721 49.7 0.187 0.0 32.4070 2.75 119.7 241 3 10.8 2.762 120.3 0 29.34 0 46.99 0 2.333 0 2 2 203.8 8.9317 52.4 0.174 0.0 32.4447 2.74 119.1 241 2 11.1 2.748 119.7 0 29.90 0 47.07 0 2.333 0 1 1 226.3 8.8987 50.8 0.177 0.0 32.4759 2.73 118.7 241 1 11.5 2.777 121.0 3 29.82 0 47.08 0 2.335 0