*2014/11/20 09:46:43.11 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2014/06/13 23:06:35.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : F9A0547B NUMBER OF CHANNELS : 23 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 24 2 Bottle_Number n/a 1 24 3 Pressure decibar 5.462 3684.161 4 Temperature:Secondary 'deg C (ITS90)' 1.5679 11.9673 5 Transmissivity %/metre 50.3 68.1 6 Fluorescence:URU:Seapoint mg/m^3 0.37E-01 2.415 7 Salinity:T1:C1 PSS-78 32.3532 34.6668 8 Oxygen:Dissolved:SBE mL/L 0.335 6.637 9 Oxygen:Dissolved:SBE umol/kg 14.6 289.1 10 Number_of_bin_records n/a 39 241 11 Sample_Number n/a 428 451 12 Temperature:Draw 'deg C (ITS90)' 2.8 12 13 Salinity:Bottle PSS-78 32.3556 34.6661 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 0.339 6.658 16 Oxygen:Dissolved umol/kg 14.73111 289.9933 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 4.2 47.5 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 8.94 177.3 21 Flag:Silicate n/a 22 Phosphate umol/L 0.692 3.243 23 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 ' ' ' ' 5 I I 0 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F ' ' 1 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 8 F R4 3 23 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-18 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P16 EVENT NUMBER : 45 LATITUDE : 49 17.02000 N ! (deg min) LONGITUDE : 134 39.90000 W ! (deg min) WATER DEPTH : 3624 ALTIMETER (M) : 9.67 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4700 Conductivity:2 ' ' 3321 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3642 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/08/07 16:16:32 5582 5582 CLEAN 5.1 2014/08/07 16:17:11 ? ? ADDSAMP 3.6 2014/08/11 16:39:20 5582 5582 BINAVE 4.1.1 2014/08/11 16:39:49 5582 24 MERGE 3.5 2014/08/27 14:28:25 24 24 CLEAN 5.1 2014/08/27 14:28:32 24 24 CALIB 11.8 2014/09/03 10:48:25 24 24 SORT 3.6 2014/09/03 12:13:45 24 24 REMOVECH 8.2 2014/09/03 12:14:52 24 24 CHGUNITS 3.1 2014/09/03 13:06:01 24 24 CHGUNITS 3.1 2014/09/03 13:06:47 24 24 REORDER 1.3 2014/09/03 13:07:43 ? ? HDREDIT2 2.6 2014/09/03 13:10:33 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:43 24 24 $END $REMARKS -CLEAN functions: 2014/08/07 16:16:50 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-18\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/08/27 14:28:25 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-18\Processing\hydro\2014-18-0045.samavg Secondary file: P:\Cruise_Data_Processing\2014-18\Processing\hydro\2014-18-0045.mrgcln1s -SORT parameters: 2014/08/27 14:26:38 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/08/27 14:28:30 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/09/03 10:48:25 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-18\Processing\doc\2014-18-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Salinity:T1:C1 PSS-78 10 -0.5300000E-02 0.1000000E+01 14 Oxygen:Dissolved:SBE mL/L 10 -0.2890000E-01 0.1041700E+01 -SORT parameters: 2014/09/03 12:13:45 Sorted in ascending order of channel Pressure* -REMOVECH 2014/09/03 12:14:52 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Sec* Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/09/03 13:10:33 Applied edit header: P:\Cruise_Data_Processing\2014-18\Processing\doc\HYDRO\2014-18-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 17: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 18: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 19: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 20: Silicate [umol/L] Units: ==> umol/L Channel 21: Flag:Silicate [n/a] Units: ==> n/a Channel 22: Phosphate [umol/L] Units: ==> umol/L Channel 23: Flag:Phosphate [n/a] Units: ==> n/a $END *COMMENTS Sample_Number 436: OXY: OXY: Slow Niskin spigot leak. Endpoint before 85% transmissivity. Significant outlier in comparison to CTD DO. Sample_Number 443: OXY: Duplicate not reported. OXY-2 endpoint overshot. Titration quickly jumped to plateau portion of the curve. Sample_Number 447: OXY: Replicate outliers. Both titrations were not ideal. Sample_Number 449: OXY: Leaky Niskin vent prior to sampling. Sample_Number 450: OXY: Endpoint is overshot. Titration quickly jumped to plateau portion of the curve. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship during the cruise or at IOS in Room 1310 about 6 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-18CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-18OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 23 to 39 days after collection. For details including a duplicate analysis, see document QF2014-18SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-18nuts*.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2014-18 DMS report.doc and for data see "DMS summary (2014-18 data)*.xls." References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2014-18_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.53E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.289E-01 1.0417) $END !1- 2- --3--- ---4---- --5-- ---6--- ---7---- --8--- --9-- -10- -11- --12- ---13--- 14 ---15-- --16- 17 --18- 19 --20-- 21 ---22-- 23 !Bo Bo Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Samp Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: :T1:C1 : n: er_o le_ ratur :Bottle ag Dissolv n: ag te_ ag te ag te ag !~u ~u Secondar vity URU: Dissol Disso ~bin Numb e: ~o ed Disso ~o plus_ ~t ~i ~p !en mb y Seapoin ved: lved: _rec er Draw tt lved lv Nitri ri ca ha !ce er t SBE SBE ords le ed te te te te !-- -- ------ -------- ----- ------- -------- ------ ----- ---- ---- ----- -------- -- ------- ----- -- ----- -- ------ -- ------- -- *END OF HEADER 24 24 5.5 11.9673 50.3 2.336 32.3532 6.51 283.8 241 451 12.0 32.3556 0 6.521 284.1 0 4.2 0 8.98 0 0.692 0 23 23 10.7 11.9666 50.5 2.298 32.3534 6.52 284.1 241 450 12.0 -99.0000 0 6.519 284.1 4 4.2 0 8.98 0 0.696 0 22 22 25.5 11.8317 52.0 2.415 32.3571 6.54 285.0 241 449 11.9 -99.0000 0 6.542 285.1 3 4.3 0 8.94 0 0.706 0 21 21 50.4 9.3890 62.5 1.193 32.4082 6.64 289.1 241 448 9.8 -99.0000 0 6.658 290.0 0 7.3 6 9.62 6 0.868 6 20 20 74.6 8.4830 65.3 0.705 32.4279 6.57 286.2 241 447 9.0 -99.0000 0 6.586 286.8 36 9.7 0 11.89 0 1.028 0 19 19 100.1 6.6949 67.0 0.232 32.6393 6.35 276.3 241 446 7.6 -99.0000 0 6.351 276.5 0 16.6 0 20.24 0 1.393 0 18 18 125.4 6.0530 67.4 0.073 32.9795 5.95 258.7 241 445 7.1 -99.0000 0 5.957 259.2 0 20.2 0 25.96 0 1.562 0 17 17 150.6 5.9443 67.2 0.048 33.5248 4.83 210.1 241 444 6.9 -99.0000 0 4.838 210.5 0 25.9 0 36.73 0 1.850 0 16 16 175.3 5.7135 67.1 0.049 33.7205 4.21 183.0 241 443 6.8 -99.0000 0 4.229 183.9 2 29.4 0 44.41 0 2.017 0 15 15 200.5 5.3480 67.0 0.049 33.7680 3.68 159.8 241 442 6.5 -99.0000 0 3.696 160.7 0 32.2 0 52.23 0 2.231 0 14 14 251.0 4.8827 67.1 0.049 33.7985 3.06 132.9 241 441 6.1 -99.0000 0 3.065 133.3 0 35.4 0 61.94 0 2.457 0 13 13 300.2 4.5352 67.3 0.049 33.8595 2.29 99.5 241 440 5.9 -99.0000 0 2.302 100.1 6 39.0 0 72.87 0 2.682 0 12 12 400.9 4.2660 67.5 0.049 33.9687 1.51 65.6 241 439 5.7 -99.0000 0 1.540 67.0 0 42.0 0 87.16 0 2.897 0 11 11 601.1 3.8651 67.9 0.049 34.1699 0.64 27.7 241 438 5.3 -99.0000 0 0.648 28.2 0 45.1 0 111.14 0 3.114 0 10 10 799.9 3.4629 67.8 0.049 34.2756 0.42 18.1 241 437 5.1 -99.0000 0 0.398 17.3 0 46.6 0 127.29 0 3.206 0 9 9 999.9 3.0040 67.8 0.049 34.3740 0.34 14.6 241 436 4.4 34.3743 6 -99.000 -99.0 5 47.4 0 142.96 0 3.237 0 8 8 1250.4 2.6618 67.9 0.049 34.4446 0.38 16.5 241 435 4.0 34.4444 0 0.339 14.7 0 47.5 6 154.71 6 3.243 6 7 7 1501.1 2.3359 67.9 0.049 34.5061 0.63 27.5 241 434 3.8 34.5067 0 0.593 25.8 0 46.9 0 163.86 0 3.185 0 6 6 2000.8 1.9244 68.0 0.045 34.5892 1.38 60.1 241 433 3.4 34.5896 6 1.324 57.5 6 45.0 0 172.61 0 3.051 0 5 5 2500.4 1.7234 68.1 0.038 34.6300 1.99 86.3 241 432 3.1 34.6298 0 1.945 84.5 0 43.3 0 174.35 0 2.907 0 4 4 3001.2 1.6013 68.0 0.037 34.6528 2.42 105.0 241 431 3.0 34.6533 6 2.442 106.1 0 41.9 0 174.28 0 2.811 0 2 2 3500.7 1.5679 67.6 0.037 34.6653 2.63 114.1 39 429 3.0 34.6647 0 2.713 117.9 0 41.1 0 176.29 0 2.762 0 3 3 3500.9 1.5682 67.6 0.037 34.6651 2.63 114.1 241 430 2.8 34.6661 0 2.719 118.1 0 41.1 0 176.26 0 2.737 0 1 1 3684.2 1.5759 66.7 0.047 34.6668 2.63 114.4 241 428 3.1 -99.0000 0 2.736 118.9 0 41.2 0 177.30 0 2.738 0