*2021/11/25 14:55:16.92 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/06/11 06:54:13.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : B2D4F859 NUMBER OF CHANNELS : 52 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 253 275 2 Bottle_Number n/a 1 23 3 Bottle:Firing_Sequence n/a 1 23 4 Pressure decibar 5.2 2000 5 Temperature:Secondary 'deg C (ITS90)' 1.9251 13.3078 6 Transmissivity %/metre 51 67.9 7 Fluorescence:URU:Seapoint mg/m^3 0.49E-01 2.87 8 Salinity:T1:C1 PSS-78 32.1203 34.5911 9 Oxygen:Dissolved:SBE mL/L 0.24 6.52 10 Oxygen:Dissolved:SBE umol/kg 10.6 284 11 Number_of_bin_records n/a 142 241 12 Temperature:Draw 'deg C (ITS90)' 3.9 13.4 13 Salinity:Bottle PSS-78 32.1258 34.5932 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 0.224 6.499 16 Oxygen:Dissolved umol/kg 9.7 283.1 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 0.9 47.1 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 5.58 174.81 21 Flag:Silicate n/a 22 Phosphate umol/L 0.513 3.311 23 Flag:Phosphate n/a 24 Chlorophyll:Extracted mg/m^3 0.5E-01 0.78 25 Flag:Chlorophyll:Extracted n/a 26 Phaeo-Pigment:Extracted mg/m^3 0.12 0.37 27 HPLC:Chl-c3 mg/m^3 0.5E-01 0.75E-01 28 HPLC:Chlide-a mg/m^3 0 0 29 HPLC:MgDVP mg/m^3 0 0.5E-02 30 HPLC:Chl-c2 mg/m^3 0.27E-01 0.86E-01 31 HPLC:Chl-c1 mg/m^3 0 0 32 HPLC:Me-chlide mg/m^3 0 0 33 HPLC:Peri mg/m^3 0 0 34 HPLC:Pheide-a mg/m^3 0 0 35 HPLC:But-fuco mg/m^3 0.34E-01 0.65E-01 36 HPLC:Fuco mg/m^3 0.59E-01 0.101 37 HPLC:Neo mg/m^3 0.3E-02 0.4E-02 38 HPLC:Pras mg/m^3 0 0.2E-02 39 HPLC:Viola mg/m^3 0.2E-02 0.15E-01 40 HPLC:Hex-fuco mg/m^3 0.54E-01 0.302 41 HPLC:Diadino mg/m^3 0.5E-02 0.62E-01 42 HPLC:Allo mg/m^3 0.6E-02 0.14E-01 43 HPLC:Diato mg/m^3 0 0.3E-02 44 HPLC:Zea mg/m^3 0 0.24E-01 45 HPLC:Lut mg/m^3 0 0.1E-01 46 HPLC:Chl-b mg/m^3 0.29E-01 0.58E-01 47 HPLC:DVChl-a mg/m^3 0 0 48 HPLC:Chl-a mg/m^3 0.256 0.523 49 HPLC:Phe mg/m^3 0 0 50 HPLC:B-Car mg/m^3 0 0.7E-02 51 HPLC:TChl-a mg/m^3 0.256 0.523 52 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F ' ' 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 6 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 8 F R4 3 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-18 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P8 EVENT NUMBER : 26 LATITUDE : 48 49.00000 N ! (deg min) LONGITUDE : 128 40.06000 W ! (deg min) WATER DEPTH : 2521 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4700 Conductivity:2 ' ' 3321 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3642 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/08/07 16:16:22 5377 5377 CLEAN 5.1 2014/08/07 16:17:03 ? ? ADDSAMP 3.6 2014/08/11 16:39:11 5377 5377 BINAVE 4.1.1 2014/08/11 16:39:44 5377 23 MERGE 3.5 2014/08/27 14:28:23 23 23 CLEAN 5.1 2014/08/27 14:28:31 23 23 CALIB 11.8 2014/09/03 10:48:24 23 23 SORT 3.6 2014/09/03 12:13:45 23 23 REMOVECH 8.2 2014/09/03 12:14:52 23 23 CHGUNITS 3.1 2014/09/03 13:06:01 23 23 CHGUNITS 3.1 2014/09/03 13:06:46 23 23 REORDER 1.3 2014/09/03 13:07:42 ? ? HDREDIT2 2.6 2014/09/03 13:10:32 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:42 23 23 SORT 3.6 2020/08/03 10:06:12 23 23 REORDER 1.3.1 2021/11/25 13:33:17 ? ? MERGE 3.5.1 2021/11/25 13:33:25 23 23 SORT 3.6 2021/11/25 13:33:32 23 23 CLEAN 5.2.4 2021/11/25 13:35:19 23 23 HDREDIT2 3.2 2021/11/25 14:54:30 ? ? HDREDIT2 3.2 2021/11/25 14:55:16 ? ? $END $REMARKS -CLEAN functions: 2014/08/07 16:16:50 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-18\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/08/27 14:28:23 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-18\Processing\hydro\2014-18-0026.samavg Secondary file: P:\Cruise_Data_Processing\2014-18\Processing\hydro\2014-18-0026.mrgcln1s -SORT parameters: 2014/08/27 14:26:38 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/08/27 14:28:30 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/09/03 10:48:24 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-18\Processing\doc\2014-18-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Salinity:T1:C1 PSS-78 10 -0.5300000E-02 0.1000000E+01 14 Oxygen:Dissolved:SBE mL/L 10 -0.2890000E-01 0.1041700E+01 -SORT parameters: 2014/09/03 12:13:45 Sorted in ascending order of channel Pressure* -REMOVECH 2014/09/03 12:14:52 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Sec* Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/09/03 13:10:32 Applied edit header: P:\Cruise_Data_Processing\2014-18\Processing\doc\HYDRO\2014-18-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 20: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 21: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Silicate [umol/L] Units: ==> umol/L Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Phosphate [umol/L] Units: ==> umol/L Channel 26: Flag:Phosphate [n/a] Units: ==> n/a -SORT parameters: 2020/08/03 10:06:12 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 13:33:25 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-018_Nov2021\Processing\ IOS\2014-018-0026.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-018_Nov2021\Processing\ IOS\2014-018-0026.hplc -SORT parameters: 2021/11/25 13:33:32 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 13:35:19 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 14:54:30 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_018\Processing\IOS\ 2014-018-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 20: Silicate [umol/L] Format: F7.2 ==> F6.2 Channel 27: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 14:55:16 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_018\Processing\IOS\ 2014-018-bot-hdr2.txt $END *COMMENTS Sample_Number 253: OXY: Slight Niskin vent leak prior to sampling. Sample_Number 255: OXY: Niskin vent leak prior to sampling. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship during the cruise or at IOS in Room 1310 about 6 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-18CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~5 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2014-018_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-18OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 23 to 39 days after collection. For details including a duplicate analysis, see document QF2014-18SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-18nuts*.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2014-18 DMS report.doc and for data see "DMS summary (2014-18 data)*.xls." References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2014-18_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-018_Nov2021\Processing\IOS\2014-018-0026. hplc --------------------------------------------------------------------------- Sample_Number 274: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.53E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.289E-01 1.0417) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- --12- ---13--- 14 ---15-- --16- 17 --18- 19 --20- 21 ---22-- 23 --24-- 25 --26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- 52 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silic Fl Phospha Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag ate ag te ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec Draw tt lved lv Nitri ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le ed te te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ----- -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 271 19 21 5.2 13.2373 51.2 1.914 32.1209 6.44 280.6 209 13.4 32.1258 0 6.431 280.3 0 0.9 0 6.20 0 0.513 0 0.65 0 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 275 23 23 5.2 13.3078 51.2 1.897 32.1214 6.43 280.2 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 274 22 22 5.3 13.2653 51.0 1.883 32.1203 6.43 280.4 142 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 0.62 6 0.13 0.075 0.000 0.003 0.086 0.000 0.000 0.000 0.000 0.065 0.101 0.003 0.000 0.003 0.302 0.037 0.010 0.000 0.000 0.005 0.029 0.000 0.497 0.000 0.000 0.497 36 270 18 20 10.1 12.9853 51.3 2.403 32.1665 6.45 281.3 241 13.2 -99.0000 0 6.452 281.2 0 0.9 0 6.26 0 0.517 0 0.71 0 0.22 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 273 21 19 20.1 12.8101 54.6 2.642 32.2760 6.39 278.5 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 0.76 6 0.26 0.052 0.000 0.000 0.070 0.000 0.000 0.000 0.000 0.044 0.086 0.004 0.000 0.015 0.212 0.062 0.014 0.003 0.024 0.010 0.058 0.000 0.523 0.000 0.007 0.523 6 269 17 18 25.0 12.5957 54.0 2.870 32.2766 6.42 279.7 241 12.9 -99.0000 0 6.402 279.0 6 1.1 0 5.58 0 0.581 0 0.78 0 0.23 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 272 20 17 50.2 8.8927 64.2 0.477 32.3664 6.52 283.8 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 0.29 6 0.37 0.050 0.000 0.005 0.027 0.000 0.000 0.000 0.000 0.034 0.059 0.004 0.002 0.002 0.054 0.005 0.006 0.000 0.009 0.000 0.040 0.000 0.256 0.000 0.005 0.256 6 268 16 16 50.3 8.8975 64.2 0.478 32.3677 6.52 284.0 206 9.5 -99.0000 0 6.499 283.1 0 8.8 0 12.07 0 0.995 0 0.26 0 0.34 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 267 15 15 75.4 7.9835 64.5 0.275 32.5730 5.65 245.9 241 8.8 -99.0000 0 5.693 247.9 0 15.3 0 18.38 0 1.320 0 0.12 0 0.18 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 266 14 14 100.2 7.1314 66.5 0.090 32.9753 5.19 226.0 241 8.1 -99.0000 0 5.156 224.4 0 21.1 0 25.86 0 1.652 0 0.05 0 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 265 13 13 125.4 7.6831 66.1 0.052 33.5006 3.41 148.4 241 8.5 -99.0000 0 3.434 149.4 0 28.1 0 35.58 0 2.072 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 264 12 12 150.1 7.7708 66.0 0.050 33.7347 2.65 115.3 241 8.5 -99.0000 0 2.668 116.1 0 31.3 6 40.15 6 2.262 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 263 11 11 175.4 7.5861 66.3 0.049 33.8371 2.40 104.2 241 8.3 -99.0000 0 2.403 104.5 0 32.9 0 42.68 0 2.349 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 262 10 10 200.4 7.3817 66.3 0.050 33.8888 2.26 98.1 241 8.2 -99.0000 0 2.272 98.8 0 33.8 0 44.86 0 2.381 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 261 9 9 250.3 6.6135 66.9 0.049 33.9240 2.38 103.5 241 7.6 -99.0000 0 2.392 104.0 6 34.7 0 50.86 0 2.405 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 260 8 8 300.4 5.9150 67.1 0.050 33.9187 2.40 104.3 241 7.1 -99.0000 0 2.355 102.4 0 36.1 0 58.23 0 2.482 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 259 7 7 400.3 5.3797 67.4 0.050 34.0035 1.28 55.8 241 6.7 -99.0000 0 1.278 55.6 0 41.0 0 72.98 0 2.854 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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-99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 255 3 3 1250.4 2.9297 67.9 0.050 34.4535 0.39 17.1 241 4.6 34.4540 0 0.384 16.7 3 47.0 6 148.36 6 3.264 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 254 2 2 1499.9 2.4662 67.7 0.049 34.5120 0.69 29.9 241 4.2 34.5142 0 0.681 29.6 0 46.2 0 161.21 0 3.197 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 253 1 1 2000.0 1.9251 67.9 0.049 34.5911 1.37 59.7 241 3.9 34.5932 6 1.416 61.5 36 44.4 0 174.81 0 3.046 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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