*2014/11/20 09:46:42.01 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2014/06/09 04:34:47.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 21 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : FBA68483 NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 22 2 Bottle_Number n/a 1 21 3 Pressure decibar 1.327 230.126 4 Temperature:Secondary 'deg C (ITS90)' 8.0432 13.3469 5 Transmissivity %/metre 29.5 50.4 6 Fluorescence:URU:Seapoint mg/m^3 0.166 5.636 7 PAR uE/m^2/sec 0 0.17 8 Salinity:T1:C1 PSS-78 25.3138 32.8079 9 Oxygen:Dissolved:SBE mL/L 2.994 7.117 10 Oxygen:Dissolved:SBE umol/kg 130.3 311.8 11 Number_of_bin_records n/a 51 241 12 Sample_Number n/a 1 21 13 Temperature:Draw 'deg C (ITS90)' 8.4 13 14 Oxygen:Dissolved mL/L 2.994 6.854 15 Oxygen:Dissolved umol/kg 130.3456 300.3048 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 7.4 31.3 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 36.41 45.31 20 Flag:Silicate n/a 21 Phosphate umol/L 0.76 2.311 22 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-18 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : HARO59 EVENT NUMBER : 1 LATITUDE : 48 36.87000 N ! (deg min) LONGITUDE : 123 14.89000 W ! (deg min) WATER DEPTH : 238 ALTIMETER (M) : 8.79 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4700 Conductivity:2 ' ' 3321 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3642 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/08/07 16:16:07 1023 1023 CLEAN 5.1 2014/08/07 16:16:50 ? ? JOIN 2.4.2 2014/08/07 16:51:46 4570 4570 ADDSAMP 3.6 2014/08/11 16:38:57 4570 4570 BINAVE 4.1.1 2014/08/11 16:39:37 4570 22 MERGE 3.5 2014/08/27 16:39:02 21 21 CLEAN 5.1 2014/08/27 16:39:09 21 21 CALIB 11.8 2014/09/03 10:48:23 21 21 SORT 3.6 2014/09/03 12:13:44 21 21 REMOVECH 8.2 2014/09/03 12:14:39 21 21 CHGUNITS 3.1 2014/09/03 13:06:00 21 21 CHGUNITS 3.1 2014/09/03 13:06:45 21 21 REORDER 1.3 2014/09/03 13:07:41 ? ? HDREDIT2 2.6 2014/09/03 13:10:31 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:42 21 21 $END $REMARKS -CLEAN functions: 2014/08/07 16:16:50 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-18\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/08/27 16:39:02 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-18\Processing\hydro\2014-18-0001.samavg Secondary file: P:\Cruise_Data_Processing\2014-18\Processing\hydro\2014-18-0001.mrgcln1s -SORT parameters: 2014/08/27 14:26:38 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/08/27 16:39:09 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/09/03 10:48:23 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-18\Processing\doc\2014-18-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Salinity:T1:C1 PSS-78 10 -0.5300000E-02 0.1000000E+01 14 Oxygen:Dissolved:SBE mL/L 10 -0.2890000E-01 0.1041700E+01 -SORT parameters: 2014/09/03 12:13:44 Sorted in ascending order of channel Pressure* -REMOVECH 2014/09/03 12:14:39 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Sec* Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/09/03 13:10:31 Applied edit header: P:\Cruise_Data_Processing\2014-18\Processing\doc\HYDRO\2014-18-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 17: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 18: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 19: Silicate [umol/L] Units: ==> umol/L Channel 20: Flag:Silicate [n/a] Units: ==> n/a Channel 21: Phosphate [umol/L] Units: ==> umol/L Channel 22: Flag:Phosphate [n/a] Units: ==> n/a $END *COMMENTS Sample_Number 4: OXY: Bubble in titrant line. Flushed after sample run. Sample_Number 5: OXY: Problems with both replicate titrations. Titrations jumped up to plateau. Values not trusted Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship during the cruise or at IOS in Room 1310 about 6 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-18CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-18OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 23 to 39 days after collection. For details including a duplicate analysis, see document QF2014-18SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-18nuts*.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2014-18 DMS report.doc and for data see "DMS summary (2014-18 data)*.xls." References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2014-18_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.53E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.289E-01 1.0417) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- -12- --13- ---14-- --15- 16 --17- 18 --19-- 20 ---21-- 22 !Bo Bo Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Samp Tempe Oxygen: Oxyge Fl Nitra Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: :T1:C1 : n: er_o le_ ratur Dissolv n: ag te_ ag te ag te ag !~u ~u Secondar vity URU: Dissol Disso ~bin Numb e: ed Disso ~o plus_ ~t ~i ~p !en mb y Seapoin ved: lved: _rec er Draw lved lv Nitri ri ca ha !ce er t SBE SBE ords ed te te te te !-- -- ------ -------- ----- ------- ------ -------- ------ ----- ---- ---- ----- ------- ----- -- ----- -- ------ -- ------- -- *END OF HEADER 20 15 1.3 13.3442 29.5 5.620 0.2 25.3159 7.11 311.7 128 15 13.0 6.854 300.3 0 7.4 0 36.41 0 0.760 0 22 21 1.3 13.3410 29.6 5.600 0.2 25.3178 7.12 311.8 241 21 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 21 20 1.3 13.3469 29.5 5.636 0.2 25.3138 7.12 311.8 54 20 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 19 14 5.4 12.2403 45.5 1.156 0.0 26.3382 6.06 265.2 241 14 12.0 5.995 262.4 6 12.4 0 37.29 0 1.094 0 18 13 10.1 11.3893 47.1 0.902 0.0 27.5948 5.52 241.5 241 13 11.3 5.499 240.4 0 15.7 0 38.31 0 1.356 0 17 12 20.1 10.5948 49.5 0.330 0.0 28.7799 5.08 221.9 241 12 10.3 4.934 215.5 0 20.1 0 39.76 0 1.715 0 16 11 30.5 9.5304 49.8 0.212 0.0 30.5523 4.39 191.6 241 11 9.5 4.363 190.3 0 24.0 0 41.34 0 1.952 0 15 10 40.0 9.3382 50.3 0.264 0.0 30.9597 4.20 182.9 241 10 9.4 4.190 182.7 0 25.0 0 41.84 0 2.022 0 14 9 50.1 9.2318 50.4 0.245 0.0 31.1313 4.11 179.0 241 9 9.2 4.072 177.5 0 25.8 0 42.19 0 2.027 0 13 8 60.3 9.1042 49.8 0.211 0.0 31.3020 4.01 175.0 241 8 9.1 3.946 172.0 0 26.6 0 42.54 0 2.068 0 12 7 80.1 8.7872 49.2 0.190 0.0 31.8018 3.74 162.9 241 7 8.9 3.698 161.1 0 27.9 6 43.18 6 2.130 6 10 18 100.5 8.6102 49.5 0.188 0.0 32.0788 3.56 155.0 51 18 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 9 6 100.5 8.6104 49.5 0.186 0.0 32.0784 3.55 154.8 181 6 8.7 3.494 152.2 0 28.9 0 43.71 0 2.178 0 11 19 100.5 8.6079 49.7 0.189 0.0 32.0820 3.56 154.9 241 19 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 8 5 125.2 8.3008 47.0 0.172 0.0 32.4855 3.27 142.2 241 5 8.5 -99.000 -99.0 5 30.0 0 44.48 0 2.248 0 7 4 149.8 8.1666 45.8 0.167 0.0 32.6563 3.13 136.4 241 4 8.4 3.125 136.1 3 30.5 0 44.83 0 2.257 0 5 3 174.9 8.1770 44.9 0.170 0.0 32.6430 3.14 136.8 241 3 8.5 3.132 136.4 0 30.5 0 44.88 0 2.243 0 4 2 200.6 8.1508 43.9 0.167 0.0 32.6784 3.11 135.5 241 2 8.4 3.097 134.8 0 30.6 0 44.96 0 2.278 0 1 1 229.9 8.0432 37.4 0.170 0.0 32.8079 2.99 130.3 196 1 8.8 2.994 130.3 0 31.3 0 45.31 0 2.311 0 2 16 230.0 8.0455 38.2 0.166 0.0 32.8050 3.00 130.5 104 16 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 3 17 230.1 8.0558 40.1 0.169 0.0 32.7937 3.01 131.1 241 17 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0