*2021/11/22 15:49:28.38 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/09/12 09:33:48.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 2CA7899B NUMBER OF CHANNELS : 53 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 432 454 2 Bottle_Number n/a 1 23 3 Bottle:Firing_Sequence n/a 1 23 4 Pressure decibar 4.6 2001 5 Temperature:Primary 'deg C (ITS90)' 1.9855 16.3769 6 Transmissivity %/metre 44.6 64.9 7 Salinity:T0:C0 PSS-78 31.8382 34.5797 8 Oxygen:Dissolved:SBE mL/L 0.23 6.16 9 Oxygen:Dissolved:SBE umol/kg 10.2 268.7 10 Number_of_bin_records n/a 58 121 11 Temperature:Draw 'deg C (ITS90)' 3.6 17 12 Salinity:Bottle PSS-78 31.8472 34.58 13 Flag:Salinity:Bottle n/a 14 Oxygen:Dissolved mL/L 0.254 6.108 15 Oxygen:Dissolved umol/kg 11 266.5 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 0 45.9 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 10.1 171.3 20 Flag:Silicate n/a 21 Phosphate umol/L 0.33 3.3 22 Flag:Phosphate n/a 23 Ammonium umol/L 0.8E-01 1.68 24 Flag:Ammonium n/a 25 Chlorophyll:Extracted mg/m^3 1.03 1.61 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.57 0.91 28 HPLC:Chl-c3 mg/m^3 0.66E-01 0.66E-01 29 HPLC:Chlide-a mg/m^3 0 0 30 HPLC:MgDVP mg/m^3 0.12E-01 0.12E-01 31 HPLC:Chl-c2 mg/m^3 0.105 0.105 32 HPLC:Chl-c1 mg/m^3 0 0 33 HPLC:Me-chlide mg/m^3 0 0 34 HPLC:Peri mg/m^3 0.37E-01 0.37E-01 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0.86E-01 0.86E-01 37 HPLC:Fuco mg/m^3 0.188 0.188 38 HPLC:Neo mg/m^3 0.13E-01 0.13E-01 39 HPLC:Pras mg/m^3 0.35E-01 0.35E-01 40 HPLC:Viola mg/m^3 0.24E-01 0.24E-01 41 HPLC:Hex-fuco mg/m^3 0.99E-01 0.99E-01 42 HPLC:Diadino mg/m^3 0.87E-01 0.87E-01 43 HPLC:Allo mg/m^3 0.23E-01 0.23E-01 44 HPLC:Diato mg/m^3 0.9E-02 0.9E-02 45 HPLC:Zea mg/m^3 0.197 0.197 46 HPLC:Lut mg/m^3 0 0 47 HPLC:Chl-b mg/m^3 0.185 0.185 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 1.013 1.013 50 HPLC:Phe mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0.41E-01 0.41E-01 52 HPLC:TChl-a mg/m^3 1.013 1.013 53 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 5 I I 0 11 -99 ' ' 6 F R4 1 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-58 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : CS00 EVENT NUMBER : 109 LATITUDE : 50 27.65000 N ! (deg min) LONGITUDE : 129 55.07000 W ! (deg min) WATER DEPTH : 2174 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2668 Conductivity:2 ' ' 2754 Fluorometer:Seapoint ' ' 2228 'Oxygen:SBE 43' ' ' 0997 'Transmissometer:WET Labs C-Star' ' ' 1396DR Altimeter ' ' 1204 PAR/Irradiance:Biospherical/Licor ' ' 4615 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.3 2014/03/17 16:38:27 2633 2633 CLEAN 5.1 2014/03/17 16:38:50 ? ? ADDSAMP 3.6 2014/03/17 17:37:03 2633 2633 BINAVE 4.1.1 2014/03/17 17:40:03 2633 23 MERGE 3.5 2014/03/19 08:54:31 23 23 CLEAN 5.1 2014/03/19 08:54:36 23 23 CALIB 11.8 2014/04/01 15:37:15 23 23 SORT 3.6 2014/04/01 16:55:04 23 23 REMOVECH 8.2 2014/04/01 16:56:48 23 23 CHGUNITS 3.1 2014/04/01 16:57:35 23 23 CHGUNITS 3.1 2014/04/01 16:58:10 23 23 REORDER 1.3 2014/04/01 17:00:40 ? ? HDREDIT2 2.6 2014/04/01 17:11:52 ? ? REMOVECH 8.2 2014/06/13 13:59:37 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:58:50 23 23 SORT 3.6 2020/08/20 19:45:49 23 23 REORDER 1.3.1 2021/11/22 15:39:01 ? ? MERGE 3.5.1 2021/11/22 15:43:23 23 23 SORT 3.6 2021/11/22 15:43:32 23 23 CLEAN 5.2.4 2021/11/22 15:47:37 23 23 HDREDIT2 3.2 2021/11/22 15:49:05 ? ? HDREDIT2 3.2 2021/11/22 15:49:28 ? ? $END $REMARKS -CLEAN functions: 2014/03/17 16:38:35 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-58\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/03/19 08:54:31 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-58\Processing\hydro\2013-58-0109.samavg Secondary file: P:\Cruise_Data_Processing\2013-58\Processing\hydro\2013-58-0109.mrgcln1s -CLEAN functions: 2014/03/18 12:51:56 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2014/03/18 12:52:10 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/03/19 08:54:34 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/04/01 15:37:15 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-58\Processing\doc\2013-58-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.2140000E-01 0.1056000E+01 -SORT parameters: 2014/04/01 16:55:04 Sorted in ascending order of channel Pressure* -REMOVECH 2014/04/01 16:56:48 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Sal* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Sal* 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/04/01 17:11:52 Applied edit header: P:\Cruise_Data_Processing\2013-58\Processing\doc\HYDRO\2013-58-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 20: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 21: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Silicate [umol/L] Units: ==> umol/L Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Phosphate [umol/L] Units: ==> umol/L Channel 26: Flag:Phosphate [n/a] Units: ==> n/a Channel 28: Flag:Ammonium [n/a] Units: ==> n/a -REMOVECH 2014/06/13 13:59:37 The following CHANNEL(S) were removed: Fluorescence:URU:Seapoint [mg/m^3] -SORT parameters: 2020/08/20 19:45:49 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/22 15:43:23 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-058_Nov2021\Processing\ IOS\2013-058-0109.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-058_Nov2021\Processing\ IOS\2013-058-0109.hplc -SORT parameters: 2021/11/22 15:43:32 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/22 15:47:36 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/22 15:49:05 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-058\2013-058-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/22 15:49:28 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-058\2013-058-bot- hdr2.txt $END *COMMENTS Sample_Number 436: OXY: Niskin spigot was leaking prior to sampling Sample_Number 439: OXY: Sample redrawn due to bubbles from bottle top dispenser. Sample_Number 443: OXY: Niskin spigot was open prior to sampling. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2013-58CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2013-058_HPLC*.xlsx. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-58OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 56 to 68 days after collection. For details including a duplicate analysis see file QF2013-58SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see file QF2013-58nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2013-58NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminot, A., Kerouel, R., Hooker, B.A., and Peterson, B.J. (1999) A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". The two CTD salinity channels differed by about 0.005 with one reading slightly lower than bottles and the other higher. Delay in analysis likely caused some evaporation of samples, so the CTD salinity channels are likely reading higher than the comparison suggests. The little information available suggests that there has been minimal calibration drift in the primary salinity. The draw temperature is considered less reliable than usual. Several thermometers were used and they did not agree well. The fluorometer malfunctioned so fluorescence data were removed. For details on the processing see the report: 2013-58_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-058_Nov2021\Processing\IOS\2013-058-0109. hplc --------------------------------------------------------------------------- Sample_Number 451: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.214E-01 1.056) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7---- --8--- --9-- -10- --11- ---12--- 13 ---14-- --15- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 !Samp Bott Bott Pressu Temperat Trans Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi :T0:C0 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag ate ag ate ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ ved: lved: _rec Draw tt lved lv Nitri ri ca ha ni ted ct Extrac HP ! ence SBE SBE ords le ed te te te te um ed ted LC !---- ---- ---- ------ -------- ----- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 451 20 20 4.6 16.3738 45.3 31.8382 6.08 265.2 79 17.0 31.8472 0 6.108 266.5 0 0.0 0 10.1 0 0.33 0 0.08 6 1.03 6 0.57 0.066 0.000 0.012 0.105 0.000 0.000 0.037 0.000 0.086 0.188 0.013 0.035 0.024 0.099 0.087 0.023 0.009 0.197 0.000 0.185 0.000 1.013 0.000 0.041 1.013 36 454 23 23 4.8 16.3769 45.3 31.8385 6.09 265.6 121 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 452 21 21 4.9 16.3756 45.3 31.8383 6.07 264.8 58 -99.0 -99.0000 0 -99.000 -99.0 0 0.1 0 10.1 0 0.33 0 -99.00 0 1.11 6 0.65 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 453 22 22 5.1 16.3753 45.2 31.8385 6.07 264.6 76 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 450 19 19 10.4 15.1992 44.6 31.8500 6.16 268.7 121 16.0 31.8607 0 6.087 265.5 6 1.8 0 12.1 0 0.47 0 0.34 6 1.61 6 0.91 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 449 18 18 19.7 12.9801 55.4 31.9990 5.03 219.1 121 13.3 32.0046 0 5.071 221.1 0 9.9 0 20.4 0 1.10 0 1.68 6 1.09 6 0.70 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 448 17 17 29.8 10.5884 60.4 32.2648 3.98 173.4 121 11.1 32.2539 0 4.014 174.9 0 19.4 0 31.6 0 1.74 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 447 16 16 50.1 8.9937 61.3 32.5744 3.55 154.4 121 9.5 32.5794 0 3.541 154.2 0 25.3 6 37.0 6 1.99 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 446 15 15 75.1 7.5399 62.7 32.8546 4.31 187.8 121 8.3 32.8676 0 4.099 178.4 0 24.2 0 34.2 0 1.90 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 445 14 14 100.4 7.3623 63.0 33.3535 3.31 143.8 121 8.1 33.3529 0 3.321 144.5 0 27.8 0 37.7 0 2.03 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 444 13 13 124.9 7.3222 63.9 33.7174 3.33 144.9 121 8.1 33.7140 0 3.346 145.6 6 27.9 0 36.6 0 1.98 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 443 12 12 150.0 7.1532 64.3 33.8452 3.13 136.2 121 7.9 33.8465 0 3.126 136.0 3 29.4 0 40.7 0 2.02 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 442 11 11 174.7 6.8164 64.3 33.8955 2.80 121.7 121 7.6 33.8959 0 2.831 123.1 0 31.4 0 46.1 0 2.18 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 441 10 10 199.9 6.5053 64.2 33.9156 2.44 105.9 121 7.4 33.9150 0 2.462 107.1 0 33.4 0 51.2 0 2.30 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 440 9 9 250.0 6.0325 64.3 33.9525 1.85 80.3 121 7.0 33.9552 0 1.851 80.5 0 36.6 0 59.9 0 2.55 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 439 8 8 300.2 5.7239 64.5 33.9680 1.60 69.4 121 6.7 33.9711 0 1.606 69.8 2 38.3 0 65.6 0 2.69 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 438 7 7 400.5 5.3420 63.9 34.0529 0.90 39.3 121 6.4 34.0528 0 0.933 40.6 0 41.3 6 78.3 6 2.99 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 437 6 6 500.2 4.8725 64.5 34.1096 0.58 25.4 121 6.1 34.1094 0 0.596 25.9 0 43.0 0 89.0 0 3.12 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 436 5 5 749.9 4.0915 64.8 34.2432 0.29 12.4 121 5.6 34.2440 0 0.295 12.8 36 44.8 0 111.7 0 3.26 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 435 4 4 1001.0 3.4951 64.8 34.3689 0.23 10.2 121 4.9 34.3655 0 0.254 11.0 0 45.8 0 130.9 0 3.30 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 434 3 3 1249.4 2.9964 64.9 34.4386 0.33 14.5 121 4.4 34.4398 0 0.361 15.7 0 45.9 0 145.5 0 3.28 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 433 2 2 1500.3 2.5195 64.9 34.4991 0.60 26.1 121 4.0 34.4970 6 0.609 26.5 0 45.0 0 159.1 0 3.21 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 432 1 1 2001.0 1.9855 64.9 34.5797 1.25 54.5 121 3.6 34.5800 0 1.278 55.5 0 43.8 0 171.3 0 3.08 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0