*2023/03/19 10:46:49.77 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/07/07 01:29:50.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 11 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : D6A310CE NUMBER OF CHANNELS : 20 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 11 2 Bottle_Number n/a 1 11 3 Pressure decibar 2.1 65.1 4 Temperature:Secondary 'deg C (ITS90)' 9.1011 17.4124 5 Transmissivity %/metre 18.1 60 6 Fluorescence:URU:Seapoint mg/m^3 0.186 8.716 7 PAR uE/m^2/sec 0 1014.9 8 PAR:Reference uE/m^2/sec 1718.8 1958.8 9 pH:SBE:Nominal n/a 8.213 9.126 10 Salinity:T1:C1 PSS-78 23.74 28.4534 11 Oxygen:Dissolved:SBE mL/L 2.42 7.79 12 Oxygen:Dissolved:SBE umol/kg 105.7 342 13 Number_of_bin_records n/a 121 121 14 Sample_Number n/a 205 214 15 Nitrate_plus_Nitrite umol/L 3.2 14.6 16 Flag:Nitrate_plus_Nitrite n/a 17 Phosphate umol/L 0.6 3.22 18 Flag:Phosphate n/a 19 Silicate umol/L 27.89129 69.6 20 Silicate:Flag n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-55 AGENCY : 'WVL, Marine Environment and Habitat Science,' CONTINUED : ' Vancouver, B.C.' COUNTRY : Canada PROJECT : Aquaculture Environmental Studies SCIENTIST : Sutherland T. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia STATION : MAL 55 EVENT NUMBER : 108 LATITUDE : 50 3.42000 N ! (deg min) LONGITUDE : 124 43.09000 W ! (deg min) WATER DEPTH : 69 ALTIMETER (M) : 3.27 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 3321 'Pressure:Digiquartz with TC' ' ' 77511 Temperature:2 ' ' 4700 Conductivity:2 ' ' 1766 Fluorometer:Seapoint ' ' 2356 'Oxygen:SBE 43' ' ' 0047 'Transmissometer:WET Labs C-Star' ' ' 1185DDR Altimeter ' ' ' ' pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4601 Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! --------------------- ------ ---------- -------- --------- --------- SBE_IOS 3.3 2014/02/07 14:27:03 1331 1331 CLEAN 5.1 2014/02/07 14:47:34 1331 1331 ADDSAMP 3.6 2014/02/10 12:22:52 1331 1331 BINAVE 4.1.1 2014/02/10 12:23:06 1331 11 MERGE 3.5 2014/04/25 16:43:46 11 11 CLEAN 5.1 2014/04/25 16:44:21 11 11 CALIB 11.8 2014/04/26 15:35:28 11 11 SORT 3.6 2014/05/01 08:52:57 11 11 REMOVECH 8.2 2014/05/01 08:53:31 11 11 CHGUNITS 3.1 2014/05/01 09:14:19 11 11 CHGUNITS 3.1 2014/05/01 09:14:40 11 11 REORDER 1.3 2014/05/01 09:17:15 ? ? HDREDIT2 2.6 2014/05/01 09:17:19 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:52 11 11 Silicate_Correction 1.0 2018/02/20 14:45:57 11 11 Silicate_Modification 1.2 2023/03/19 10:46:49 11 11 $END $REMARKS -CLEAN functions: 2014/02/07 14:47:22 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-55\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/04/25 16:43:46 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-55\Processing\hydro\2013-55-0108.samavg Secondary file: P:\Cruise_Data_Processing\2013-55\Processing\hydro\2013-55-0108.mrgcln1s -SORT parameters: 2014/04/25 16:42:43 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/04/25 16:44:20 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/04/26 15:35:28 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-55\Processing\doc\2013-55-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1067200E+01 -SORT parameters: 2014/05/01 08:52:57 Sorted in ascending order of channel Pressure* -REMOVECH 2014/05/01 08:53:31 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Sal* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Sal* - No units changed -HEADER EDITS: 2014/05/01 09:17:19 Applied edit header: P:\Cruise_Data_Processing\2013-55\Processing\doc\HYDRO\2013-55-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 16: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 17: Silicate [umol/L] Units: ==> umol/L Channel 18: Flag:Silicate [n/a] Units: ==> n/a Channel 19: Phosphate [umol/L] Units: ==> umol/L Channel 20: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: MAL 55, Sample Number: 214, Silicate corrected using CTD salinity. ===================================================================================== Sample_Number 213: Nut: Sample tube Empty Analysis methods: ----------------- Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-55OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 9 to 16 days after collection. For full details see file QF2013-55SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All samples are returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see document QF2013-55nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, Fluorescence, pH:SBE, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. The Oxygen:Dissolved:SBE data are considered, very roughly, to be: ±0.5 mL/L from 0 to 15db ±0.15 mL/L from 15 to 75db ±0.05 mL/L below 75db Salinity has not been recalibrated, but there may be a significant error. Incomplete flushing of Niskin bottles makes interpretation of the bottle comparison uncertain. If only bottles below 50db are included both salinity channels appeared to be close to bottles. There was a large change in at least one of the conductivity sensor calibrations between this cruise and the one that followed, so the post-cruise calibration cannot be applied to these data. Salinity is considered ±0.004. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2013-55-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0672) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9--- ---10--- --11-- --12- -13- -14- --15- 16 --17-- 18 --19- 20 !Bo Bo Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Samp Nitra Fl Phosph Fl Silic Si !tt tt re ure: missi cence: Refere Nominal :T1:C1 : n: er_o le_ te_ ag ate ag ate li !~u ~u Secondar vity URU: nce Dissol Disso ~bin Numb plus_ ~t ~p ~: !en mb y Seapoin ved: lved: _rec er Nitri ri ha Fl !ce er t SBE SBE ords te te te ag !-- -- ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ---- ----- -- ------ -- ----- -- *END OF HEADER 11 11 2.1 17.4124 18.2 5.669 1014.9 1922.2 9.126 23.7400 7.79 342.0 121 214 3.2 0 0.60 0 27.9 0 10 10 5.2 15.8511 18.1 8.716 206.2 1933.8 9.059 24.7856 7.35 322.4 121 213 -99.0 9 -99.00 9 -99.0 9 9 9 5.4 14.7450 24.0 5.762 162.1 1869.0 8.914 25.3443 6.16 270.2 121 -99 -99.0 0 -99.00 0 -99.0 0 8 8 10.1 13.9303 46.4 1.590 17.0 1903.6 8.794 25.8399 5.36 235.0 121 212 7.8 6 1.06 6 31.8 6 7 7 20.2 12.8245 56.2 0.462 1.6 1915.0 8.671 26.6501 4.84 212.0 121 211 10.7 0 1.38 0 34.9 0 6 6 30.1 12.3312 58.1 0.380 0.4 1915.2 8.631 26.9298 4.71 206.1 121 210 12.2 0 1.53 0 37.7 0 5 5 40.0 11.5949 57.0 0.327 0.2 1958.8 8.588 27.3712 4.62 201.9 121 209 13.4 0 1.71 0 40.4 0 4 4 50.1 9.9418 60.0 0.186 0.1 1933.5 8.411 28.1777 3.87 169.2 121 208 14.3 0 2.48 0 54.1 0 3 3 61.0 9.2568 59.1 0.199 0.0 1872.5 8.263 28.3943 2.83 123.8 121 207 14.6 0 3.12 0 66.4 0 2 2 63.3 9.1865 58.4 0.298 0.0 1859.4 8.215 28.4193 2.50 109.4 121 206 14.2 0 3.21 0 65.8 0 1 1 65.1 9.1011 57.3 0.206 0.1 1718.8 8.213 28.4534 2.42 105.7 121 205 14.2 0 3.22 0 69.6 0