*2021/11/22 15:28:51.46 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/06/03 23:03:40.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 28CB8B89 NUMBER OF CHANNELS : 54 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 314 333 2 Bottle_Number n/a 1 20 3 Bottle:Firing_Sequence n/a 1 20 4 Pressure decibar 5.1 1910.2 5 Temperature:Primary 'deg C (ITS90)' 1.9454 11.3213 6 Transmissivity %/metre 43.9 65.5 7 Fluorescence:URU:Seapoint mg/m^3 0.341 1.517 8 Salinity:T0:C0 PSS-78 32.0125 34.5871 9 Oxygen:Dissolved:SBE mL/L 0.26 6.85 10 Oxygen:Dissolved:SBE umol/kg 11.2 298.6 11 Number_of_bin_records n/a 241 241 12 Temperature:Draw 'deg C (ITS90)' 4.5 11.5 13 Salinity:Bottle PSS-78 34.087 34.5014 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 0.27 6.87 16 Oxygen:Dissolved umol/kg 11.7 299.3 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 2.6 46 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 5.5 176.5 21 Flag:Silicate n/a 22 Phosphate umol/L 0.6 3.31 23 Flag:Phosphate n/a 24 Ammonium umol/L 0.7E-01 0.12 25 Flag:Ammonium n/a 26 Chlorophyll:Extracted mg/m^3 0.47 0.86 27 Flag:Chlorophyll:Extracted n/a 28 Phaeo-Pigment:Extracted mg/m^3 0.24 0.38 29 HPLC:Chl-c3 mg/m^3 0.79E-01 0.97E-01 30 HPLC:Chlide-a mg/m^3 0 0 31 HPLC:MgDVP mg/m^3 0.7E-02 0.12E-01 32 HPLC:Chl-c2 mg/m^3 0.87E-01 0.114 33 HPLC:Chl-c1 mg/m^3 0 0 34 HPLC:Me-chlide mg/m^3 0 0 35 HPLC:Peri mg/m^3 0 0 36 HPLC:Pheide-a mg/m^3 0 0 37 HPLC:But-fuco mg/m^3 0.59E-01 0.61E-01 38 HPLC:Fuco mg/m^3 0.85E-01 0.133 39 HPLC:Neo mg/m^3 0.16E-01 0.19E-01 40 HPLC:Pras mg/m^3 0.9E-02 0.13E-01 41 HPLC:Viola mg/m^3 0.12E-01 0.18E-01 42 HPLC:Hex-fuco mg/m^3 0.24 0.241 43 HPLC:Diadino mg/m^3 0.24E-01 0.16 44 HPLC:Allo mg/m^3 0.13E-01 0.73E-01 45 HPLC:Diato mg/m^3 0.2E-02 0.26E-01 46 HPLC:Zea mg/m^3 0.65E-01 0.7E-01 47 HPLC:Lut mg/m^3 0.33E-01 0.5E-01 48 HPLC:Chl-b mg/m^3 0.181 0.204 49 HPLC:DVChl-a mg/m^3 0 0 50 HPLC:Chl-a mg/m^3 0.615 0.916 51 HPLC:Phe mg/m^3 0 0 52 HPLC:B-Car mg/m^3 0.1E-01 0.24E-01 53 HPLC:TChl-a mg/m^3 0.615 0.916 54 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 6 F R4 1 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-38 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : CS02 EVENT NUMBER : 106 LATITUDE : 50 41.24000 N ! (deg min) LONGITUDE : 129 28.03000 W ! (deg min) WATER DEPTH : 1902 ALTIMETER (M) : 9.4 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2668 Conductivity:2 ' ' 2754 Fluorometer:Seapoint ' ' 2228 'Oxygen:SBE 43' ' ' 0997 'Transmissometer:WET Labs C-Star' ' ' 1396 Altimeter ' ' 1204 PAR/Irradiance:Biospherical/Licor ' ' 4601 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.2 2013/10/09 16:16:05 4820 4820 CLEAN 5.1 2013/10/09 16:16:41 4820 4820 ADDSAMP 3.5 2013/10/09 17:44:22 4820 4820 BINAVE 4.1.1 2013/10/09 17:44:43 4820 20 MERGE 3.5 2013/10/12 14:54:11 20 20 CLEAN 5.1 2013/10/12 14:54:16 20 20 CALIB 11.7 2013/10/12 15:42:13 20 20 SORT 3.6 2013/10/25 10:00:03 20 20 REMOVECH 8.1.1 2013/10/25 10:01:18 20 20 CHGUNITS 3.0 2013/10/25 10:02:33 20 20 CHGUNITS 3.0 2013/10/25 10:02:55 20 20 REORDER 1.3 2013/10/25 10:03:52 ? ? HDREDIT2 2.6 2013/10/25 10:06:03 ? ? HDREDIT2 2.6 2013/12/23 08:35:02 ? ? MERGE 3.5 2014/01/14 09:01:52 20 20 REORDER 1.3 2014/01/14 09:09:51 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:32 20 20 HDREDIT2 3.0.2 2016/07/14 15:10:57 ? ? SORT 3.6 2020/08/20 18:31:35 20 20 REORDER 1.3.1 2021/11/22 15:26:31 ? ? MERGE 3.5.1 2021/11/22 15:26:47 20 20 SORT 3.6 2021/11/22 15:27:46 20 20 CLEAN 5.2.4 2021/11/22 15:27:58 20 20 HDREDIT2 3.2 2021/11/22 15:28:27 ? ? HDREDIT2 3.2 2021/11/22 15:28:51 ? ? $END $REMARKS -CLEAN functions: 2013/10/09 16:16:12 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-38\Processing\HYDRO\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2013/10/12 14:54:11 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-38\Processing\hydro\2013-38-0106.samavg Secondary file: P:\Cruise_Data_Processing\2013-38\Processing\hydro\2013-38-0106.mrgcln1s -CLEAN functions: 2013/10/09 17:35:26 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2013/10/09 17:35:31 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2013/10/12 14:54:14 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2013/10/12 15:42:13 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-38\Processing\doc\2013-38-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.1720000E-01 0.1047100E+01 -SORT parameters: 2013/10/25 10:00:03 Sorted in ascending order of channel Pressure* -REMOVECH 2013/10/25 10:01:18 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2013/10/25 10:06:03 Applied edit header: P:\Cruise_Data_Processing\2013-38\Processing\doc\HYDRO\2013-38-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: Salinity:Practical:T0:C0 [PSS-78] Name: Salinity:T0:C0 ==> Salinity:Practical:T0:C0 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F5.1 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 17: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 18: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 19: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 20: Silicate [umol/L] Units: ==> umol/L Channel 21: Flag:Silicate [n/a] Units: ==> n/a Channel 22: Phosphate [umol/L] Units: ==> umol/L Channel 23: Flag:Phosphate [n/a] Units: ==> n/a Channel 25: Flag:Ammonium [n/a] Units: ==> n/a -HEADER EDITS: 2013/12/23 08:35:02 Channel 7: Salinity:T0:C0 [PSS-78] Name: Salinity:Practical:T0:C0 ==> Salinity:T0:C0 -The following MERGE parameters were used: 2014/01/14 09:01:52 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted Primary file : P:\Cruise_Data_Processing\2013-38\bottle\2013-38-0106.che Secondary file: P:\Cruise_Data_Processing\2013-38\bottle\2013-38-0106.chl -HEADER EDITS: 2016/07/14 15:10:57 Applied edit header: P:\Cruise_Data_Processing\2013-FL\2013-HDR-FL.TXT -SORT parameters: 2020/08/20 18:31:35 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/22 15:26:47 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038_Nov2021\Processing\ IOS\2013-038-0106.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038_Nov2021\Processing\ IOS\2013-038-0106.hplc -SORT parameters: 2021/11/22 15:27:46 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/22 15:27:57 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/22 15:28:27 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038\2013-038-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 12: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 Channel 29: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/22 15:28:51 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038\2013-038-bot- hdr2.txt $END *COMMENTS Sample_Number 314: OXY: Dosimat serial port dropped. Titration just a flat line. Sample lost Sample_Number 321: OXY: Niskin spigot leaking Sample_Number 322: OXY: Niskin spigot leaking Sample_Number 324: OXY: Niskin spigot leaking Sample_Number 325: OXY: Niskin spigot leaking Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Phaeopigment data are provided for information only. Flags and comments apply to chlorophyll values only. No flags are assigned for Phaeo-Pigment values. For details see worksheet “Precision” in file QF2013-38CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2013-038_HPLC*.xlsx. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 765 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-38OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 13 to 24 days after collection. Full details including a duplicate analysis are in file QF2013-38SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples were collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) were collected and stored at 4C in the dark. All samples were returned to IOS for analysis. THey were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see worksheet QF2013-38nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2013-38NH4*.xls. References*: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. For further processing details see the processing report 2013-38-proc.doc. WARNING: SeaPoint Fluorometer #2228 malfunctioned during the latter half of 2013. There were large values at great depth that got steadily higher through the year until it was removed from service. The data have been left in the file so researchers can see the shape of the profile. Comparison with extracted chlorophyll is recommended. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.172E-01 1.0471) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- --12- ---13--- 14 ---15-- --16- 17 --18- 19 --20- 21 --22-- 23 --24-- 25 --26-- 27 --28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- 54 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T0:C0 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag ate ag ate ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Draw tt lved lv Nitri ri ca ha ni ted ct Extrac HP ! ence t SBE SBE ords le ed te te te te um ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 333 20 20 5.1 11.3213 44.8 1.017 32.0125 6.78 295.6 241 11.5 -99.0000 0 6.798 296.3 0 2.6 0 5.5 0 0.60 0 0.12 6 0.86 6 0.28 0.079 0.000 0.012 0.114 0.000 0.000 0.000 0.000 0.059 0.133 0.019 0.013 0.018 0.240 0.160 0.073 0.026 0.070 0.050 0.181 0.000 0.916 0.000 0.024 0.916 6 332 19 19 10.1 11.0370 43.9 1.414 32.0446 6.79 296.0 241 11.1 -99.0000 0 6.803 296.5 0 3.0 0 5.9 0 0.65 0 0.07 6 0.82 6 0.26 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 331 18 18 20.0 9.6983 52.4 1.517 32.2123 6.85 298.6 241 9.9 -99.0000 0 6.870 299.3 0 4.3 0 9.5 0 0.76 0 0.07 6 0.47 6 0.24 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 330 17 17 30.3 9.3585 55.2 1.458 32.2029 6.75 293.8 241 9.5 -99.0000 0 6.764 294.6 0 4.3 0 9.5 0 0.76 0 -99.00 0 0.51 6 0.38 0.097 0.000 0.007 0.087 0.000 0.000 0.000 0.000 0.061 0.085 0.016 0.009 0.012 0.241 0.024 0.013 0.002 0.065 0.033 0.204 0.000 0.615 0.000 0.010 0.615 6 329 16 16 50.0 7.3704 62.0 0.639 32.5153 6.52 283.9 241 7.7 -99.0000 0 6.544 284.9 0 13.1 0 18.0 0 1.24 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 328 15 15 75.2 6.8200 63.9 0.382 32.7213 6.36 276.7 241 7.3 -99.0000 0 6.327 275.4 0 15.8 0 21.3 0 1.39 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 327 14 14 100.4 6.7523 64.2 0.354 33.1411 5.25 228.5 241 7.3 -99.0000 0 5.205 226.5 0 21.2 0 24.3 0 1.66 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 326 13 13 125.1 6.9546 64.2 0.345 33.5877 4.06 176.6 241 7.6 -99.0000 0 4.088 177.8 3 25.9 0 34.8 0 1.89 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 325 12 12 150.4 7.0231 64.2 0.341 33.7922 3.47 150.7 241 7.5 -99.0000 0 3.446 149.9 36 28.7 0 39.4 0 2.03 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 324 11 11 175.2 6.8211 64.4 0.342 33.8613 3.20 139.1 241 7.4 -99.0000 0 3.208 139.5 3 30.2 0 43.6 0 2.12 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 323 10 10 200.2 6.3680 64.5 0.342 33.8760 3.11 135.2 241 7.1 -99.0000 0 3.128 136.0 3 31.3 6 48.5 6 2.21 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 322 9 9 249.7 5.7370 64.8 0.344 33.8928 2.65 115.4 241 6.7 -99.0000 0 2.667 116.0 0 34.6 0 57.6 0 2.42 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 321 8 8 300.1 5.2499 65.0 0.348 33.9137 2.14 93.2 241 6.3 -99.0000 0 2.151 93.5 3 37.4 0 66.8 0 2.62 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 320 7 7 400.3 4.9133 65.3 0.348 34.0027 1.25 54.3 241 6.2 -99.0000 0 1.227 53.4 0 41.3 0 80.0 0 2.91 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 319 6 6 500.5 4.5598 65.5 0.351 34.0848 0.76 33.1 241 5.9 34.0870 0 0.764 33.2 0 43.4 0 92.0 0 3.08 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 318 5 5 749.7 3.9819 65.4 0.353 34.2517 0.29 12.6 241 5.7 34.2508 0 0.296 12.9 6 45.4 0 114.4 0 3.25 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 317 4 4 1000.4 3.5006 65.0 0.352 34.3781 0.26 11.2 241 5.4 34.3791 0 0.270 11.7 0 45.9 0 131.7 0 3.31 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 316 3 3 1250.5 2.9536 65.1 0.354 34.4480 0.39 16.7 241 5.1 34.4494 0 0.389 16.9 0 46.0 0 147.1 0 3.25 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 315 2 2 1500.6 2.4823 65.5 0.351 34.5009 0.61 26.5 241 4.6 34.5014 6 0.609 26.5 0 45.8 6 160.0 6 3.19 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 314 1 1 1910.2 1.9454 64.2 0.349 34.5871 1.29 56.1 241 4.5 -99.0000 0 -99.000 -99.0 5 43.6 0 176.5 0 3.09 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0