*2021/11/22 15:28:51.19 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/06/02 01:57:09.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 2D1380E8 NUMBER OF CHANNELS : 53 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 226 242 2 Bottle_Number n/a 1 17 3 Bottle:Firing_Sequence n/a 1 17 4 Pressure decibar 4.8 986.7 5 Temperature:Primary 'deg C (ITS90)' 3.7878 11.2665 6 Transmissivity %/metre 49.9 65.4 7 Fluorescence:URU:Seapoint mg/m^3 0.268 0.964 8 PAR uE/m^2/sec 0 48.1 9 Salinity:T0:C0 PSS-78 32.0404 34.3565 10 Oxygen:Dissolved:SBE mL/L 0.22 6.76 11 Oxygen:Dissolved:SBE umol/kg 9.6 294.4 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 5.5 11.2 14 Oxygen:Dissolved mL/L 0.22 6.762 15 Oxygen:Dissolved umol/kg 9.6 294.7 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 1.7 44.9 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 8.2 124.3 20 Flag:Silicate n/a 21 Phosphate umol/L 0.54 3.3 22 Flag:Phosphate n/a 23 Ammonium umol/L 0.1E-01 0.2E-01 24 Flag:Ammonium n/a 25 Chlorophyll:Extracted mg/m^3 0.53 0.81 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.23 0.27 28 HPLC:Chl-c3 mg/m^3 0.51E-01 0.51E-01 29 HPLC:Chlide-a mg/m^3 0 0 30 HPLC:MgDVP mg/m^3 0.7E-02 0.7E-02 31 HPLC:Chl-c2 mg/m^3 0.89E-01 0.89E-01 32 HPLC:Chl-c1 mg/m^3 0 0 33 HPLC:Me-chlide mg/m^3 0 0 34 HPLC:Peri mg/m^3 0.2E-01 0.2E-01 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0.41E-01 0.41E-01 37 HPLC:Fuco mg/m^3 0.59E-01 0.59E-01 38 HPLC:Neo mg/m^3 0.7E-02 0.7E-02 39 HPLC:Pras mg/m^3 0.3E-02 0.3E-02 40 HPLC:Viola mg/m^3 0.6E-02 0.6E-02 41 HPLC:Hex-fuco mg/m^3 0.21 0.21 42 HPLC:Diadino mg/m^3 0.8E-01 0.8E-01 43 HPLC:Allo mg/m^3 0.61E-01 0.61E-01 44 HPLC:Diato mg/m^3 0.14E-01 0.14E-01 45 HPLC:Zea mg/m^3 0.87E-01 0.87E-01 46 HPLC:Lut mg/m^3 0 0 47 HPLC:Chl-b mg/m^3 0.4E-01 0.4E-01 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 0.649 0.649 50 HPLC:Phe mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0.16E-01 0.16E-01 52 HPLC:TChl-a mg/m^3 0.649 0.649 53 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-38 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LG06 EVENT NUMBER : 78 LATITUDE : 49 3.52000 N ! (deg min) LONGITUDE : 127 1.23000 W ! (deg min) WATER DEPTH : 968 ALTIMETER (M) : 9.6 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2668 Conductivity:2 ' ' 2754 Fluorometer:Seapoint ' ' 2228 'Oxygen:SBE 43' ' ' 0997 'Transmissometer:WET Labs C-Star' ' ' 1396 Altimeter ' ' 1204 PAR/Irradiance:Biospherical/Licor ' ' 4601 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.2 2013/10/09 16:15:56 4097 4097 CLEAN 5.1 2013/10/09 16:16:33 4097 4097 ADDSAMP 3.5 2013/10/09 17:44:14 4097 4097 BINAVE 4.1.1 2013/10/09 17:44:39 4097 17 MERGE 3.5 2013/10/12 14:54:11 17 17 CLEAN 5.1 2013/10/12 14:54:16 17 17 CALIB 11.7 2013/10/12 15:42:12 17 17 SORT 3.6 2013/10/25 10:00:03 17 17 REMOVECH 8.1.1 2013/10/25 10:01:03 17 17 CHGUNITS 3.0 2013/10/25 10:02:32 17 17 CHGUNITS 3.0 2013/10/25 10:02:55 17 17 REORDER 1.3 2013/10/25 10:03:52 ? ? HDREDIT2 2.6 2013/10/25 10:06:03 ? ? HDREDIT2 2.6 2013/12/23 08:35:02 ? ? MERGE 3.5 2014/01/14 09:01:51 17 17 REORDER 1.3 2014/01/14 09:13:23 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:32 17 17 HDREDIT2 3.0.2 2016/07/14 15:10:57 ? ? SORT 3.6 2020/08/20 18:31:35 17 17 REORDER 1.3.1 2021/11/22 15:26:31 ? ? MERGE 3.5.1 2021/11/22 15:26:46 17 17 SORT 3.6 2021/11/22 15:27:46 17 17 CLEAN 5.2.4 2021/11/22 15:27:58 17 17 HDREDIT2 3.2 2021/11/22 15:28:26 ? ? HDREDIT2 3.2 2021/11/22 15:28:51 ? ? $END $REMARKS -CLEAN functions: 2013/10/09 16:16:12 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-38\Processing\HYDRO\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2013/10/12 14:54:11 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-38\Processing\hydro\2013-38-0078.samavg Secondary file: P:\Cruise_Data_Processing\2013-38\Processing\hydro\2013-38-0078.mrgcln1s -CLEAN functions: 2013/10/09 17:35:26 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2013/10/09 17:35:31 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2013/10/12 14:54:14 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2013/10/12 15:42:12 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-38\Processing\doc\2013-38-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.1720000E-01 0.1047100E+01 -SORT parameters: 2013/10/25 10:00:03 Sorted in ascending order of channel Pressure* -REMOVECH 2013/10/25 10:01:03 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2013/10/25 10:06:03 Applied edit header: P:\Cruise_Data_Processing\2013-38\Processing\doc\HYDRO\2013-38-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T0:C0 [PSS-78] Name: Salinity:T0:C0 ==> Salinity:Practical:T0:C0 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F5.1 Channel 14: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 17: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 18: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 19: Silicate [umol/L] Units: ==> umol/L Channel 20: Flag:Silicate [n/a] Units: ==> n/a Channel 21: Phosphate [umol/L] Units: ==> umol/L Channel 22: Flag:Phosphate [n/a] Units: ==> n/a Channel 24: Flag:Ammonium [n/a] Units: ==> n/a -HEADER EDITS: 2013/12/23 08:35:02 Channel 8: Salinity:T0:C0 [PSS-78] Name: Salinity:Practical:T0:C0 ==> Salinity:T0:C0 -The following MERGE parameters were used: 2014/01/14 09:01:51 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted Primary file : P:\Cruise_Data_Processing\2013-38\bottle\2013-38-0078.che Secondary file: P:\Cruise_Data_Processing\2013-38\bottle\2013-38-0078.chl -HEADER EDITS: 2016/07/14 15:10:57 Applied edit header: P:\Cruise_Data_Processing\2013-FL\2013-HDR-FL.TXT -SORT parameters: 2020/08/20 18:31:35 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/22 15:26:46 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038_Nov2021\Processing\ IOS\2013-038-0078.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038_Nov2021\Processing\ IOS\2013-038-0078.hplc -SORT parameters: 2021/11/22 15:27:46 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/22 15:27:57 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/22 15:28:26 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038\2013-038-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 13: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/22 15:28:51 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-038\2013-038-bot- hdr2.txt $END *COMMENTS Sample_Number 232: OXY: Slow leak from Niskin spigot Sample_Number 242: OXY: Niskin top cap was not sealed properly. Spigot leaking as a result. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Phaeopigment data are provided for information only. Flags and comments apply to chlorophyll values only. No flags are assigned for Phaeo-Pigment values. For details see worksheet “Precision” in file QF2013-38CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2013-038_HPLC*.xlsx. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 765 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-38OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 13 to 24 days after collection. Full details including a duplicate analysis are in file QF2013-38SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples were collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) were collected and stored at 4C in the dark. All samples were returned to IOS for analysis. THey were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see worksheet QF2013-38nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2013-38NH4*.xls. References*: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. For further processing details see the processing report 2013-38-proc.doc. Comments from secondary file: P:\Cruise_Data_Processing\2013-38\bottle\2013-38-0078.chl --------------------------------------------------------- Sample_Number 241: CHL: variability of reps >15% WARNING: SeaPoint Fluorometer #2228 malfunctioned during the latter half of 2013. There were large values at great depth that got steadily higher through the year until it was removed from service. The data have been left in the file so researchers can see the shape of the profile. Comparison with extracted chlorophyll is recommended. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.172E-01 1.0471) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14-- --15- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T0:C0 : n: er_o ratur Dissolv n: ag te_ ag ate ag ate ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: Dissol Disso ~bin e: ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Draw lved lv Nitri ri ca ha ni ted ct Extrac HP ! ence t SBE SBE ords ed te te te te um ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- ------- ----- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 242 17 17 4.8 11.2665 50.0 0.880 48.1 32.0459 6.72 292.8 241 11.2 6.719 292.8 3 1.8 0 9.3 0 0.55 0 0.01 6 0.71 6 0.23 0.051 0.000 0.007 0.089 0.000 0.000 0.020 0.000 0.041 0.059 0.007 0.003 0.006 0.210 0.080 0.061 0.014 0.087 0.000 0.040 0.000 0.649 0.000 0.016 0.649 6 241 16 16 9.6 11.0118 49.9 0.964 23.7 32.0404 6.76 294.4 241 10.9 6.762 294.7 0 1.7 0 9.0 0 0.54 0 0.01 6 0.81 36 0.27 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 240 15 15 20.2 10.3808 53.6 0.844 7.8 32.0510 6.75 294.0 241 10.3 6.750 294.1 0 1.9 0 8.2 0 0.56 0 0.02 6 0.53 6 0.26 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 239 14 14 30.1 9.6812 56.0 0.876 3.1 32.1250 6.67 290.7 241 9.5 6.665 290.3 6 4.7 0 10.1 0 0.74 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 238 13 13 50.0 7.6455 62.2 0.608 0.8 32.5310 6.16 268.3 241 7.9 6.165 268.4 0 12.9 0 16.5 0 1.21 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 237 12 12 74.8 7.2652 64.1 0.329 0.2 33.2342 4.64 202.0 241 7.6 4.662 202.9 0 21.8 0 26.6 0 1.69 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 236 11 11 99.9 7.3944 64.3 0.298 0.0 33.6098 3.73 162.4 241 7.7 3.660 159.2 0 26.4 0 33.4 0 1.92 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 235 10 10 125.3 7.3501 64.5 0.293 0.0 33.8102 3.10 134.7 241 7.7 3.091 134.4 0 29.3 0 38.6 0 2.08 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 234 9 9 149.8 7.0531 64.4 0.293 0.0 33.8748 3.00 130.3 241 7.4 2.980 129.6 0 30.3 6 42.3 6 2.16 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 233 8 8 175.6 6.7369 64.4 0.294 0.0 33.9000 2.73 118.5 241 7.2 2.677 116.4 0 32.2 0 47.4 0 2.28 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 232 7 7 200.1 6.4887 64.6 0.297 0.0 33.9106 2.50 108.6 241 7.0 2.488 108.2 3 33.4 0 51.0 0 2.38 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 231 6 6 250.5 6.0512 64.9 0.297 0.0 33.9272 2.15 93.4 241 6.8 2.145 93.3 0 35.4 0 57.1 0 2.51 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 230 5 5 300.3 5.7138 64.6 0.300 0.0 33.9491 1.79 77.7 241 6.5 1.765 76.7 0 37.8 0 63.9 0 2.66 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 229 4 4 400.9 5.2767 64.5 0.300 0.0 34.0322 1.04 45.0 241 6.3 1.027 44.7 0 41.1 0 77.1 0 2.91 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 228 3 3 501.0 4.8358 65.4 0.284 0.0 34.1139 0.58 25.1 241 6.1 0.581 25.3 6 43.2 0 89.8 0 3.11 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 227 2 2 750.9 4.3108 64.3 0.270 0.0 34.2512 0.28 12.0 241 5.8 0.284 12.3 0 44.4 6 108.5 6 3.26 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 226 1 1 986.7 3.7878 64.8 0.268 0.0 34.3565 0.22 9.6 241 5.5 0.220 9.6 0 44.9 0 124.3 0 3.30 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0