*2021/11/22 15:02:46.81 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/08/24 15:54:39.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 2 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 1504D62B NUMBER OF CHANNELS : 47 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 170 171 2 Bottle_Number n/a 1 2 3 Bottle:Firing_Sequence n/a 1 2 4 Pressure decibar 5.5 49.9 5 Temperature:Primary 'deg C (ITS90)' 9.0356 17.1903 6 Transmissivity %/metre 55.1 61.7 7 Salinity:T0:C0 PSS-78 31.9773 32.3342 8 Oxygen:Dissolved:SBE mL/L 5.72 6.16 9 Oxygen:Dissolved:SBE umol/kg 249.6 268.3 10 Number_of_bin_records n/a 121 121 11 Salinity:Bottle PSS-78 31.9874 31.9874 12 Flag:Salinity:Bottle n/a 13 Nitrate_plus_Nitrite umol/L 0 9.4 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 4.4 13.1 16 Flag:Silicate n/a 17 Phosphate umol/L 0.29 0.99 18 Flag:Phosphate n/a 19 Chlorophyll:Extracted mg/m^3 0.24 0.32 20 Flag:Chlorophyll:Extracted n/a 21 Phaeo-Pigment:Extracted mg/m^3 0.9E-01 0.32 22 HPLC:Chl-c3 mg/m^3 0.12E-01 0.53E-01 23 HPLC:Chlide-a mg/m^3 0 0 24 HPLC:MgDVP mg/m^3 0 0.2E-02 25 HPLC:Chl-c2 mg/m^3 0.23E-01 0.33E-01 26 HPLC:Chl-c1 mg/m^3 0 0 27 HPLC:Me-chlide mg/m^3 0 0 28 HPLC:Peri mg/m^3 0 0.12E-01 29 HPLC:Pheide-a mg/m^3 0 0 30 HPLC:But-fuco mg/m^3 0.17E-01 0.32E-01 31 HPLC:Fuco mg/m^3 0.16E-01 0.84E-01 32 HPLC:Neo mg/m^3 0 0 33 HPLC:Pras mg/m^3 0 0 34 HPLC:Viola mg/m^3 0 0.2E-02 35 HPLC:Hex-fuco mg/m^3 0.46E-01 0.64E-01 36 HPLC:Diadino mg/m^3 0.5E-02 0.24E-01 37 HPLC:Allo mg/m^3 0 0 38 HPLC:Diato mg/m^3 0 0.4E-02 39 HPLC:Zea mg/m^3 0 0.11E-01 40 HPLC:Lut mg/m^3 0 0 41 HPLC:Chl-b mg/m^3 0.11E-01 0.25E-01 42 HPLC:DVChl-a mg/m^3 0 0 43 HPLC:Chl-a mg/m^3 0.19 0.256 44 HPLC:Phe mg/m^3 0 0 45 HPLC:B-Car mg/m^3 0 0.3E-02 46 HPLC:TChl-a mg/m^3 0.19 0.256 47 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 6 F R4 1 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 8 F R4 3 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-18 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P10 EVENT NUMBER : 25 LATITUDE : 48 53.55000 N ! (deg min) LONGITUDE : 129 39.93000 W ! (deg min) WATER DEPTH : 2642 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2668 Conductivity:2 ' ' 2754 Fluorometer:Seapoint ' ' 2228 'Oxygen:SBE 43' ' ' 0997 'Transmissometer:WET Labs C-Star' ' ' 1396 Altimeter ' ' 1204 PAR/Irradiance:Biospherical/Licor ' ' 4615 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.3 2014/03/10 16:00:56 242 242 CLEAN 5.1 2014/03/10 16:02:03 ? ? ADDSAMP 3.6 2014/03/10 16:12:36 242 242 BINAVE 4.1.1 2014/03/10 16:12:53 242 2 MERGE 3.5 2014/03/10 16:25:43 2 2 CLEAN 5.1 2014/03/20 09:06:36 2 2 CALIB 11.8 2014/03/20 17:37:50 2 2 SORT 3.6 2014/03/20 17:38:11 2 2 REMOVECH 8.2 2014/03/20 17:38:42 2 2 CHGUNITS 3.1 2014/03/20 17:40:45 2 2 CHGUNITS 3.1 2014/03/20 17:41:07 2 2 REORDER 1.3 2014/03/20 17:41:23 ? ? HDREDIT2 2.6 2014/04/07 14:13:31 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:44 2 2 HDREDIT2 3.0.2 2016/05/03 08:18:13 ? ? HDREDIT2 3.0.2 2016/07/14 15:10:34 ? ? SORT 3.6 2020/08/26 21:18:17 2 2 REORDER 1.3.1 2021/11/22 15:00:43 ? ? MERGE 3.5.1 2021/11/22 15:01:18 2 2 SORT 3.6 2021/11/22 15:01:26 2 2 CLEAN 5.2.4 2021/11/22 15:01:34 2 2 HDREDIT2 3.2 2021/11/22 15:02:03 ? ? HDREDIT2 3.2 2021/11/22 15:02:46 ? ? $END $REMARKS -CLEAN functions: 2014/03/10 16:01:59 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-18\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/03/10 16:25:43 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-18\Processing\hydro\2013-18-0025.samavg Secondary file: P:\Cruise_Data_Processing\2013-18\Processing\hydro\2013-18-0025.mrgcln1s -SORT parameters: 2014/03/06 16:16:53 Sorted in ascending order of channel Bottle_Number [ ] -CLEAN functions: 2014/03/20 09:06:35 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/03/20 17:37:50 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-18\Processing\doc\2013-18-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.1230000E-01 0.1052800E+01 -SORT parameters: 2014/03/20 17:38:11 Sorted in ascending order of channel Pressure* -REMOVECH 2014/03/20 17:38:42 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Fluorescence:URU:Seapoint [mg/m^3] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Sal* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Sal* - No units changed -HEADER EDITS: 2014/04/07 14:13:31 Applied edit header: P:\Cruise_Data_Processing\2013-18\Processing\doc\HYDRO\2013-18-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 11: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 12: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 17: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 18: Silicate [umol/L] Units: ==> umol/L Channel 19: Flag:Silicate [n/a] Units: ==> n/a Channel 20: Phosphate [umol/L] Units: ==> umol/L Channel 21: Flag:Phosphate [n/a] Units: ==> n/a -HEADER EDITS: 2016/05/03 08:18:13 - none. -HEADER EDITS: 2016/07/14 15:10:34 Applied edit header: P:\Cruise_Data_Processing\2013-FL\2013-HDR-FL.TXT -SORT parameters: 2020/08/26 21:18:17 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/22 15:01:18 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-018_Nov2021\Processing\ IOS\2013-018-0025.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-018_Nov2021\Processing\ IOS\2013-018-0025.hplc -SORT parameters: 2021/11/22 15:01:26 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/22 15:01:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/22 15:02:03 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-018\2013-018-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 22: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 23: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/22 15:02:46 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-018\2013-018-bot- hdr2.txt $END *COMMENTS Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2013-18CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~5 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2013-018_HPLC*.xlsx. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-18OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 58 to 76 days after collection. Full details including a duplicate analysis are in file QF2013-18SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see file QF2013-18nuts*.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2013-18 DMS Report.doc and for data see "DMS summary (2013-18 data)*.xls." References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For events #1-39 channel Fluorescence:URU:SeaPoint was removed due to a malfunction. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of SBE Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. Based on a precision study run by the Dissolved Oxygen post-cruise analyst, the titrated values of dissolved oxygen are only reported with 2 decimal places. The two CTD salinity channels differed by about 0.006 with one reading lower than bottles and the other higher. Delay in analysis likely caused some evaporation of samples, so the two salinity channels are likely reading higher than the comparison suggests. The little information available suggests that there has been little calibration drift in the primary salinity. For details on the processing see the report: 2013-18_Processing_Report.doc. --------------------------------------------------------------------------------- WARNING: SeaPoint Fluorometer #2228 malfunctioned during the latter half of 2013. There were large values at great depth that got steadily higher through the year until it was removed from service. The data have been left in the file so researchers can see the shape of the profile. Comparison with extracted chlorophyll is recommended. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.123E-01 1.0528) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7---- --8--- --9-- -10- ---11--- 12 --13- 14 --15- 16 --17-- 18 --19-- 20 --21-- ---22-- ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- 47 !Samp Bott Bott Pressu Temperat Trans Salinity Oxygen Oxyge Numb Salinity Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi :T0:C0 : n: er_o :Bottle ag te_ ag ate ag ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity Dissol Disso ~bin ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ ved: lved: _rec tt Nitri ri ca ha ted ct Extrac HP ! ence SBE SBE ords le te te te te ed ted LC !---- ---- ---- ------ -------- ----- -------- ------ ----- ---- -------- -- ----- -- ----- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 171 2 2 5.5 17.1903 55.1 31.9773 5.72 249.6 121 31.9874 0 0.0 0 4.4 0 0.29 0 0.24 6 0.09 0.012 0.000 0.000 0.023 0.000 0.000 0.012 0.000 0.032 0.016 0.000 0.000 0.002 0.046 0.024 0.000 0.004 0.011 0.000 0.011 0.000 0.190 0.000 0.003 0.190 6 170 1 1 49.9 9.0356 61.7 32.3342 6.16 268.3 121 -99.0000 0 9.4 0 13.1 0 0.99 0 0.32 6 0.32 0.053 0.000 0.002 0.033 0.000 0.000 0.000 0.000 0.017 0.084 0.000 0.000 0.000 0.064 0.005 0.000 0.000 0.000 0.000 0.025 0.000 0.256 0.000 0.000 0.256 6