*2014/11/20 09:58:42.42 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2013/09/29 01:37:10.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 12 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 7B433211 NUMBER OF CHANNELS : 25 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 12 2 Bottle_Number n/a 1 12 3 Pressure decibar 1.724 165.957 4 Temperature:Primary 'deg C (ITS90)' 8.6257 11.2321 5 Transmissivity %/metre 32 58.7 6 Fluorescence:URU:Seapoint mg/m^3 0.95E-01 0.76 7 PAR uE/m^2/sec 0 7.276 8 PAR:Reference uE/m^2/sec 29.837 60.953 9 pH:SBE:Nominal n/a 8.519 8.796 10 Salinity:T0:C0 PSS-78 28.9488 30.8871 11 Oxygen:Dissolved:SBE mL/L 2.441 4.589 12 Oxygen:Dissolved:SBE umol/kg 106.4 200.4 13 Number_of_bin_records n/a 121 121 14 Sample_Number n/a 196 207 15 Salinity:Bottle PSS-78 30.7742 30.7742 16 Flag:Salinity:Bottle n/a 17 Chlorophyll:Extracted mg/m^3 0.59 0.64 18 Flag:Chlorophyll:Extracted n/a 19 Phaeo-Pigment:Extracted mg/m^3 0.41 0.49 20 Nitrate_plus_Nitrite umol/L 21.7 32.1 21 Flag:Nitrate_plus_Nitrite n/a 22 Silicate umol/L 46.5 84.3 23 Flag:Silicate n/a 24 Phosphate umol/L 2 3.99 25 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 9 F R4 4 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 6 F R4 1 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 6 F R4 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-14 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Juan de Fuca Strait / Strait of Georgia STATION : 9 EVENT NUMBER : 54 LATITUDE : 49 35.51000 N ! (deg min) LONGITUDE : 124 38.26000 W ! (deg min) WATER DEPTH : 169 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 3321 'Pressure:Digiquartz with TC' ' ' 77511 Temperature:2 ' ' 4700 Conductivity:2 ' ' 1766 Fluorometer:Seapoint ' ' 2356 'Oxygen:SBE 43' ' ' 0047 'Transmissometer:WET Labs C-Star' ' ' 1185DDR Altimeter ' ' ' ' pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4601 Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.3 2014/02/05 16:41:40 1452 1452 CLEAN 5.1 2014/02/05 16:42:00 ? ? ADDSAMP 3.6 2014/02/10 16:23:05 1452 1452 BINAVE 4.1.1 2014/02/10 16:23:16 1452 12 MERGE 3.5 2014/02/10 17:07:35 12 12 CLEAN 5.1 2014/02/10 17:07:37 12 12 CALIB 11.8 2014/02/14 16:59:14 12 12 SORT 3.6 2014/02/17 16:14:03 12 12 REMOVECH 8.2 2014/02/17 16:14:25 12 12 CHGUNITS 3.1 2014/02/17 16:27:43 12 12 CHGUNITS 3.1 2014/02/17 16:28:04 12 12 REORDER 1.3 2014/02/17 16:28:41 ? ? HDREDIT2 2.6 2014/02/17 16:35:07 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:42 12 12 $END $REMARKS -CLEAN functions: 2014/02/05 16:41:51 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-14\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/02/10 17:07:35 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-14\Processing\hydro\2013-14-0054.samavg Secondary file: P:\Cruise_Data_Processing\2013-14\Processing\hydro\2013-14-0054.mrgcln1s -SORT parameters: 2014/02/10 17:07:27 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/02/10 17:07:37 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/02/14 16:59:14 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-14\Processing\doc\2013-14-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T0:C0 PSS-78 10 0.3600000E-02 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1084000E+01 -SORT parameters: 2014/02/17 16:14:03 Sorted in ascending order of channel Pressure -REMOVECH 2014/02/17 16:14:25 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Sal* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Sal* - No units changed -HEADER EDITS: 2014/02/17 16:35:07 Applied edit header: P:\Cruise_Data_Processing\2013-14\Processing\doc\2013-14-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 16: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 17: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 19: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 20: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 21: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 22: Silicate [umol/L] Units: ==> umol/L Channel 23: Flag:Silicate [n/a] Units: ==> n/a Channel 24: Phosphate [umol/L] Units: ==> umol/L Channel 25: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a $END *COMMENTS Sample_Number 197: A chlorophyll sample was incorrectly named 197, but looks like it should be #195 from Event #54. Sample_Number 197: PO4: Unreasonably High Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in November/December, 2013. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QFCHL2013-14*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-14OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 45 to 51 days after collection. Full details re in file QF2013-14SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All samples are returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see spreadsheet QF2013-14nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, Fluorescence, pH, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. Salinity data were recalibrated based on a post-cruise factory calibration. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2013-14-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.36E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.084) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9--- ---10--- --11-- --12- -13- -14- ---15--- 16 --17-- 18 --19-- --20- 21 --22- 23 --24-- 25 !Bo Bo Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Samp Salinity Fl Chloro Fl Phaeo- Nitra Fl Silic Fl Phosph Fl !tt tt re ure: missi cence: Refere Nominal :T0:C0 : n: er_o le_ :Bottle ag phyll: ag Pigmen te_ ag ate ag ate ag !~u ~u Primary vity URU: nce Dissol Disso ~bin Numb ~o Extrac ~a t: plus_ ~t ~i ~p !en mb Seapoin ved: lved: _rec er tt ted ct Extrac Nitri ri ca ha !ce er t SBE SBE ords le ed ted te te te te !-- -- ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ---- -------- -- ------ -- ------ ----- -- ----- -- ------ -- *END OF HEADER 12 12 1.7 11.2276 56.8 0.741 7.3 29.8 8.796 28.9499 4.59 200.4 121 207 -99.0000 0 0.61 6 0.49 21.7 0 47.0 0 2.00 0 11 11 4.8 11.2321 56.9 0.760 3.8 31.7 8.795 28.9488 4.59 200.4 121 206 -99.0000 0 -99.00 0 -99.00 21.7 0 46.5 0 2.00 0 10 10 10.1 11.2282 56.9 0.726 1.5 32.7 8.788 28.9495 4.56 199.2 121 205 -99.0000 0 0.64 6 0.41 21.8 0 46.5 0 2.00 0 9 9 20.1 11.0971 57.0 0.652 0.4 33.6 8.757 28.9879 4.34 189.5 121 204 -99.0000 0 0.59 6 0.49 22.8 0 47.9 0 2.08 0 8 8 29.8 10.1818 58.7 0.221 0.1 35.4 8.629 29.3617 3.39 148.1 121 203 -99.0000 0 -99.00 0 -99.00 28.1 0 55.2 0 2.40 0 7 7 39.9 9.8181 58.6 0.144 0.0 35.4 8.599 29.5653 3.25 142.0 121 202 -99.0000 0 -99.00 0 -99.00 29.2 0 56.3 0 2.48 0 6 6 49.9 9.5644 58.2 0.132 0.0 37.3 8.582 29.7037 3.18 139.0 121 201 -99.0000 0 -99.00 0 -99.00 30.0 6 56.7 6 2.54 6 5 5 75.2 9.0590 57.1 0.101 0.0 41.0 8.552 30.2178 2.88 125.8 121 200 -99.0000 0 -99.00 0 -99.00 31.6 0 56.8 0 2.62 0 4 4 100.2 8.9039 55.6 0.095 0.0 44.8 8.543 30.5150 2.72 118.5 121 199 -99.0000 0 -99.00 0 -99.00 32.1 6 59.2 6 2.67 6 3 3 125.0 8.8019 50.2 0.100 0.0 50.4 8.539 30.5981 2.69 117.5 121 198 -99.0000 0 -99.00 0 -99.00 31.9 0 63.3 0 2.72 0 2 2 150.2 8.6678 44.1 0.104 0.0 54.6 8.522 30.7668 2.53 110.4 121 197 30.7742 0 -99.00 0 -99.00 31.4 0 76.9 0 3.99 5 1 1 166.0 8.6257 32.0 0.113 0.0 61.0 8.519 30.8871 2.44 106.4 121 196 -99.0000 0 -99.00 0 -99.00 30.7 0 84.3 0 2.97 0