*2014/11/20 09:58:43.13 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2013/09/27 03:07:03.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 12 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : F93E6322 NUMBER OF CHANNELS : 29 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 12 2 Bottle_Number n/a 1 12 3 Pressure decibar 2.024 175.696 4 Temperature:Primary 'deg C (ITS90)' 7.1805 10.2408 5 Transmissivity %/metre 51.2 59.3 6 Fluorescence:URU:Seapoint mg/m^3 0.143 1.206 7 PAR uE/m^2/sec 0 4.565 8 PAR:Reference uE/m^2/sec 15.026 15.812 9 pH:SBE:Nominal n/a 8.522 8.727 10 Salinity:T0:C0 PSS-78 31.5754 33.7493 11 Oxygen:Dissolved:SBE mL/L 1.686 4.114 12 Oxygen:Dissolved:SBE umol/kg 73.3 179.3 13 Number_of_bin_records n/a 121 121 14 Sample_Number n/a 65 76 15 Temperature:Draw 'deg C (ITS90)' 7.4 10.1 16 Salinity:Bottle PSS-78 33.7413 33.7413 17 Flag:Salinity:Bottle n/a 18 Chlorophyll:Extracted mg/m^3 0.9 1.51 19 Flag:Chlorophyll:Extracted n/a 20 Phaeo-Pigment:Extracted mg/m^3 0.41 0.58 21 Oxygen:Dissolved mL/L 1.655 4.187 22 Oxygen:Dissolved umol/kg 71.98508 182.4918 23 Flag:Oxygen:Dissolved n/a 24 Nitrate_plus_Nitrite umol/L 25.4 34.6 25 Flag:Nitrate_plus_Nitrite n/a 26 Silicate umol/L 46.7 53.6 27 Flag:Silicate n/a 28 Phosphate umol/L 2.28 2.62 29 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 8 F R4 3 22 -99 ' ' 6 F ' ' 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 6 F R4 1 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 6 F R4 1 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-14 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Juan de Fuca Strait / Strait of Georgia STATION : 69 EVENT NUMBER : 16 LATITUDE : 48 15.60000 N ! (deg min) LONGITUDE : 123 43.23000 W ! (deg min) WATER DEPTH : 177 ALTIMETER (M) : 4.13 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 3321 'Pressure:Digiquartz with TC' ' ' 77511 Temperature:2 ' ' 4700 Conductivity:2 ' ' 1766 Fluorometer:Seapoint ' ' 2356 'Oxygen:SBE 43' ' ' 0047 'Transmissometer:WET Labs C-Star' ' ' 1185DDR Altimeter ' ' ' ' pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4601 Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.3 2014/02/05 16:41:32 1452 1452 CLEAN 5.1 2014/02/05 16:41:55 ? ? ADDSAMP 3.6 2014/02/10 16:23:00 1452 1452 BINAVE 4.1.1 2014/02/10 16:23:14 1452 12 MERGE 3.5 2014/02/10 17:07:34 12 12 CLEAN 5.1 2014/02/10 17:07:37 12 12 CALIB 11.8 2014/02/14 16:59:14 12 12 SORT 3.6 2014/02/17 16:14:02 12 12 REMOVECH 8.2 2014/02/17 16:14:24 12 12 CHGUNITS 3.1 2014/02/17 16:27:41 12 12 CHGUNITS 3.1 2014/02/17 16:28:04 12 12 REORDER 1.3 2014/02/17 16:28:40 ? ? HDREDIT2 2.6 2014/02/17 16:35:06 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:43 12 12 $END $REMARKS -CLEAN functions: 2014/02/05 16:41:51 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-14\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/02/10 17:07:34 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-14\Processing\hydro\2013-14-0016.samavg Secondary file: P:\Cruise_Data_Processing\2013-14\Processing\hydro\2013-14-0016.mrgcln1s -SORT parameters: 2014/02/10 17:07:27 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/02/10 17:07:37 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/02/14 16:59:14 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-14\Processing\doc\2013-14-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T0:C0 PSS-78 10 0.3600000E-02 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1084000E+01 -SORT parameters: 2014/02/17 16:14:02 Sorted in ascending order of channel Pressure -REMOVECH 2014/02/17 16:14:24 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Sal* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Sal* 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/02/17 16:35:06 Applied edit header: P:\Cruise_Data_Processing\2013-14\Processing\doc\2013-14-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 17: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 18: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 20: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 21: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 24: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 25: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 26: Silicate [umol/L] Units: ==> umol/L Channel 27: Flag:Silicate [n/a] Units: ==> n/a Channel 28: Phosphate [umol/L] Units: ==> umol/L Channel 29: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a $END *COMMENTS Sample_Number 72: OXY: Step up at end of titration curve. Endpoint was late but corrected. Sample_Number 76: OXY: Particles swirling in sample. Noisy titration curve at end. Titration slightly ambiguous Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in November/December, 2013. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QFCHL2013-14*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-14OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 45 to 51 days after collection. Full details re in file QF2013-14SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All samples are returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see spreadsheet QF2013-14nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, Fluorescence, pH, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. Salinity data were recalibrated based on a post-cruise factory calibration. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2013-14-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.36E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.084) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9--- ---10--- --11-- --12- -13- -14- --15- ---16--- 17 --18-- 19 --20-- ---21-- --22- 23 --24- 25 --26- 27 --28-- 29 !Bo Bo Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl !tt tt re ure: missi cence: Refere Nominal :T0:C0 : n: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag te_ ag ate ag ate ag !~u ~u Primary vity URU: nce Dissol Disso ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !en mb Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitri ri ca ha !ce er t SBE SBE ords le ed ted ed te te te te !-- -- ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ----- -- ----- -- ------ -- *END OF HEADER 12 12 2.0 10.2408 52.0 1.133 4.6 15.1 8.727 31.5754 4.11 179.3 121 76 10.1 -99.0000 0 1.51 6 0.58 4.187 182.5 3 25.4 0 46.8 0 2.32 0 11 11 4.8 10.0774 51.2 1.206 1.7 15.2 8.707 31.6082 3.91 170.4 121 75 9.9 -99.0000 0 -99.00 0 -99.00 4.026 175.5 0 25.6 0 46.9 0 2.28 0 10 10 9.9 9.8463 52.3 1.033 0.3 15.3 8.683 31.7241 3.58 156.1 121 74 9.5 -99.0000 0 1.28 6 0.54 3.484 151.8 0 27.0 0 47.9 0 2.29 0 9 9 20.1 9.5410 53.8 0.751 0.0 15.0 8.656 31.9696 3.26 142.2 121 73 9.3 -99.0000 0 0.90 6 0.41 3.264 142.2 0 27.6 6 48.3 6 2.32 6 8 8 29.8 9.5051 54.1 0.730 0.0 15.1 8.653 32.0036 3.23 140.5 121 72 9.3 -99.0000 0 -99.00 0 -99.00 3.214 140.0 3 27.6 0 48.2 0 2.32 0 7 7 39.9 9.4172 54.8 0.534 0.0 15.3 8.648 32.0596 3.16 137.6 121 71 9.2 -99.0000 0 -99.00 0 -99.00 3.171 138.1 6 27.8 0 48.1 0 2.35 0 6 6 49.8 9.4252 56.9 0.465 0.0 15.5 8.661 32.2030 3.29 143.5 121 70 9.1 -99.0000 0 -99.00 0 -99.00 3.287 143.2 0 27.3 0 46.7 0 2.33 0 5 5 74.6 9.0567 59.3 0.316 0.0 15.6 8.641 32.5466 3.13 136.4 121 69 8.8 -99.0000 0 -99.00 0 -99.00 2.984 129.9 0 28.7 0 46.7 0 2.46 0 4 4 100.0 8.1138 55.4 0.241 0.0 15.8 8.571 33.1100 2.35 102.4 121 68 8.1 -99.0000 0 -99.00 0 -99.00 2.329 101.4 0 31.4 6 48.7 6 2.55 6 3 3 125.2 7.3502 53.1 0.148 0.0 15.6 8.552 33.6517 1.97 85.8 121 67 7.5 -99.0000 0 -99.00 0 -99.00 1.953 85.0 6 33.2 0 50.6 0 2.61 0 2 2 149.8 7.2062 52.6 0.150 0.0 15.8 8.528 33.7371 1.75 76.2 121 66 7.5 33.7413 0 -99.00 0 -99.00 1.720 74.8 0 34.1 0 52.8 0 2.61 0 1 1 175.7 7.1805 51.7 0.143 0.0 15.1 8.522 33.7493 1.69 73.3 121 65 7.4 -99.0000 0 -99.00 0 -99.00 1.655 72.0 0 34.6 0 53.6 0 2.62 0