*2023/03/19 10:46:46.46 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/06/30 19:10:43.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 16 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 8F79214B NUMBER OF CHANNELS : 24 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 16 2 Bottle_Number n/a 1 16 3 Pressure decibar 1.8 319.1 4 Temperature:Primary 'deg C (ITS90)' 8.3169 16.9538 5 Transmissivity %/metre 22.5 59.6 6 Fluorescence:URU:Seapoint mg/m^3 0.93E-01 3.192 7 PAR uE/m^2/sec 0 201.8 8 PAR:Reference uE/m^2/sec 2446.7 2482.1 9 Salinity:T0:C0 PSS-78 16.6255 30.9776 10 Oxygen:Dissolved:SBE mL/L 2.7 7.38 11 Oxygen:Dissolved:SBE umol/kg 117.8 325.6 12 Number_of_bin_records n/a 121 121 13 Sample_Number n/a 197 212 14 Salinity:Bottle PSS-78 30.9518 30.9518 15 Flag:Salinity:Bottle n/a 16 Chlorophyll:Extracted mg/m^3 0.54 4.12 17 Flag:Chlorophyll:Extracted n/a 18 Phaeo-Pigment:Extracted mg/m^3 0.71 1.34 19 Nitrate_plus_Nitrite umol/L 0.1 30.4 20 Flag:Nitrate_plus_Nitrite n/a 21 Phosphate umol/L 0.12 2.83 22 Flag:Phosphate n/a 23 Silicate umol/L 30.026 72.1 24 Silicate:Flag n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 ' ' ' ' 5 I I 0 13 -99 ' ' 5 I I 0 14 -99 ' ' 9 F R4 4 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 6 F R4 1 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 6 F R4 1 24 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-13 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG / JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 3 EVENT NUMBER : 65 LATITUDE : 49 26.57000 N ! (deg min) LONGITUDE : 124 20.21000 W ! (deg min) WATER DEPTH : 325 ALTIMETER (M) : 7.03 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 3321 'Pressure:Digiquartz with TC' ' ' 77511 Temperature:2 ' ' 4700 Conductivity:2 ' ' 1766 Fluorometer:Seapoint ' ' 2356 'Oxygen:SBE 43' ' ' 0047 'Transmissometer:WET Labs C-Star' ' ' 1185DDR Altimeter ' ' ' ' pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4601 Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! --------------------- ------ ---------- -------- --------- --------- SBE_IOS 3.2.1 2013/12/19 13:05:30 1936 1936 CLEAN 5.1 2013/12/19 13:06:18 1936 1936 ADDSAMP 3.6 2013/12/19 13:06:49 1936 1936 BINAVE 4.1.1 2013/12/19 13:06:59 1936 16 MERGE 3.5 2014/01/07 13:27:54 16 16 CLEAN 5.1 2014/01/07 13:28:02 16 16 CALIB 11.8 2014/01/07 13:28:08 16 16 SORT 3.6 2014/01/07 13:28:19 16 16 REMOVECH 8.2 2014/01/07 13:29:02 16 16 CHGUNITS 3.1 2014/01/07 13:32:59 16 16 CHGUNITS 3.1 2014/01/07 14:03:37 16 16 REORDER 1.3 2014/01/07 14:04:09 ? ? HDREDIT2 2.6 2014/01/07 14:04:24 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:33 16 16 Silicate_Correction 1.0 2018/02/20 14:45:15 16 16 Silicate_Modification 1.2 2023/03/19 10:46:46 16 16 $END $REMARKS -CLEAN functions: 2013/12/19 13:06:10 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-13\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/01/07 13:27:54 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-13\Processing\hydro\2013-13-0065.samavg Secondary file: P:\Cruise_Data_Processing\2013-13\Processing\hydro\2013-13-0065.mrgcln1s -SORT parameters: 2014/01/07 13:27:46 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/01/07 13:28:01 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/01/07 13:28:08 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-13\Processing\doc\2013-13-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1075200E+01 -SORT parameters: 2014/01/07 13:28:19 Sorted in ascending order of channel Pressure -REMOVECH 2014/01/07 13:29:02 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] pH:SBE [pH Units] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temp* Salinity reference channel: Sal* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Sal* - No units changed -HEADER EDITS: 2014/01/07 14:04:24 Applied edit header: P:\Cruise_Data_Processing\2013-13\Processing\doc\HYDRO\2013-13-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 15: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 16: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 18: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 20: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 21: Silicate [umol/L] Units: ==> umol/L Channel 22: Flag:Silicate [n/a] Units: ==> n/a Channel 23: Phosphate [umol/L] Units: ==> umol/L Channel 24: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 3, Sample Number: 212, Silicate corrected using CTD salinity. At Station: 3, Sample Number: 211, Silicate corrected using CTD salinity. At Station: 3, Sample Number: 210, Silicate corrected using CTD salinity. ===================================================================================== Sample_Number 200: NO3: poor dup Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in room 1409. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2013-13CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-13OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 15 to 21 days after collection. Full details are in file QF2013-13SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples is collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) is collected and stored at 4C in the dark. All samples are returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see spreadsheet QF2013-13nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, Fluorescence, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. A pH sensor was attached to the CTD, but the data are not included in the files to be placed in the IOS Data Library because no field calibration information was available at the time of processing, and there are some concerns about how the sensors perform. For details on the processing see the report: 2013-13-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0752) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- -13- ---14--- 15 --16-- 17 --18-- --19- 20 --21-- 22 --23- 24 !Bo Bo Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Samp Salinity Fl Chloro Fl Phaeo- Nitra Fl Phosph Fl Silic Si !tt tt re ure: missi cence: Refere :T0:C0 : n: er_o le_ :Bottle ag phyll: ag Pigmen te_ ag ate ag ate li !~u ~u Primary vity URU: nce Dissol Disso ~bin Numb ~o Extrac ~a t: plus_ ~t ~p ~: !en mb Seapoin ved: lved: _rec er tt ted ct Extrac Nitri ri ha Fl !ce er t SBE SBE ords le ed ted te te te ag !-- -- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ---- -------- -- ------ -- ------ ----- -- ------ -- ----- -- *END OF HEADER 16 16 1.8 16.9538 22.5 2.128 151.4 2458.8 16.6255 7.38 325.6 121 212 -99.0000 0 4.12 6 1.34 0.1 0 0.12 0 43.2 0 15 15 4.9 15.0839 37.2 3.192 201.8 2457.8 21.4759 6.09 267.6 121 211 -99.0000 0 -99.00 0 -99.00 1.9 0 0.39 0 31.4 0 14 14 10.0 13.8695 50.8 1.409 32.4 2456.5 24.6818 5.44 238.5 121 210 -99.0000 0 1.05 6 0.93 8.1 0 0.88 0 30.0 0 13 13 20.1 11.6682 56.5 0.790 4.9 2455.6 27.9005 4.90 214.3 121 209 -99.0000 0 0.54 6 0.71 16.0 0 1.51 0 36.2 0 12 12 29.8 10.0476 59.6 0.220 1.1 2452.0 29.0065 4.15 181.1 121 208 -99.0000 0 -99.00 0 -99.00 24.5 6 2.13 6 48.0 6 11 11 40.2 9.3807 59.1 0.203 0.3 2449.1 29.5053 3.85 168.3 121 207 -99.0000 0 -99.00 0 -99.00 27.1 0 2.34 0 52.9 0 10 10 50.1 9.1617 59.2 0.149 0.1 2446.7 29.6530 3.77 164.8 121 206 -99.0000 0 -99.00 0 -99.00 27.9 0 2.43 0 54.3 0 9 9 74.8 8.5966 59.3 0.114 0.0 2448.3 29.9838 3.68 160.5 121 205 -99.0000 0 -99.00 0 -99.00 29.9 0 2.54 0 54.3 0 8 8 100.1 8.3221 57.8 0.108 0.0 2449.1 30.2934 3.79 165.5 121 204 -99.0000 0 -99.00 0 -99.00 30.0 0 2.49 0 53.3 0 7 7 125.0 8.3169 57.0 0.108 0.0 2454.1 30.4354 3.80 165.7 121 203 -99.0000 0 -99.00 0 -99.00 29.6 0 2.48 0 53.6 0 6 6 149.9 8.3335 57.3 0.099 0.0 2458.6 30.5781 3.75 163.7 121 202 -99.0000 0 -99.00 0 -99.00 29.3 0 2.45 0 54.7 0 5 5 174.5 8.3906 57.2 0.096 0.0 2460.4 30.7070 3.54 154.2 121 201 -99.0000 0 -99.00 0 -99.00 29.5 0 2.53 0 58.4 0 4 4 199.6 8.4862 56.7 0.096 0.0 2462.6 30.8080 3.18 138.5 121 200 -99.0000 0 -99.00 0 -99.00 30.1 36 2.66 6 64.4 6 3 3 249.5 8.6316 52.6 0.096 0.0 2466.8 30.9238 2.71 118.0 121 199 -99.0000 0 -99.00 0 -99.00 30.4 0 2.80 0 72.0 0 2 2 298.9 8.6287 48.8 0.093 0.0 2476.5 30.9559 2.70 117.8 121 198 30.9518 0 -99.00 0 -99.00 30.1 0 2.83 0 72.1 0 1 1 319.1 8.5690 48.9 0.095 0.0 2482.1 30.9776 2.85 124.4 121 197 -99.0000 0 -99.00 0 -99.00 29.9 0 2.80 0 70.0 0