*2014/11/20 09:58:34.37 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2013/06/28 21:58:33.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 864964F3 NUMBER OF CHANNELS : 28 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 13 2 Bottle_Number n/a 1 13 3 Pressure decibar 1.967 183.838 4 Temperature:Primary 'deg C (ITS90)' 6.6024 9.836 5 Transmissivity %/metre 37.5 54.2 6 Fluorescence:URU:Seapoint mg/m^3 0.126 1.796 7 PAR uE/m^2/sec 0 563.637 8 PAR:Reference uE/m^2/sec 266.637 346.1 9 Salinity:T0:C0 PSS-78 31.8323 33.7948 10 Oxygen:Dissolved:SBE mL/L 1.971 4.459 11 Oxygen:Dissolved:SBE umol/kg 85.7 194.3 12 Number_of_bin_records n/a 121 121 13 Sample_Number n/a 51 63 14 Temperature:Draw 'deg C (ITS90)' 7 9.9 15 Salinity:Bottle PSS-78 33.7932 33.7932 16 Flag:Salinity:Bottle n/a 17 Chlorophyll:Extracted mg/m^3 0.96 2.47 18 Flag:Chlorophyll:Extracted n/a 19 Phaeo-Pigment:Extracted mg/m^3 0.66 1 20 Oxygen:Dissolved mL/L 1.832 4.343 21 Oxygen:Dissolved umol/kg 79.68433 189.2481 22 Flag:Oxygen:Dissolved n/a 23 Nitrate_plus_Nitrite umol/L 26 35.3 24 Flag:Nitrate_plus_Nitrite n/a 25 Silicate umol/L 44.8 55.4 26 Flag:Silicate n/a 27 Phosphate umol/L 2.05 2.56 28 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 ' ' ' ' 5 I I 0 13 -99 ' ' 5 I I 0 14 -99 ' ' 5 F R4 1 15 -99 ' ' 9 F R4 4 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 8 F R4 3 21 -99 ' ' 6 F ' ' 1 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 6 F R4 1 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 6 F R4 1 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-13 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG / JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 72 EVENT NUMBER : 14 LATITUDE : 48 18.63000 N ! (deg min) LONGITUDE : 124 3.98000 W ! (deg min) WATER DEPTH : 186 ALTIMETER (M) : 5.69 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 3321 'Pressure:Digiquartz with TC' ' ' 77511 Temperature:2 ' ' 4700 Conductivity:2 ' ' 1766 Fluorometer:Seapoint ' ' 2356 'Oxygen:SBE 43' ' ' 0047 'Transmissometer:WET Labs C-Star' ' ' 1185DDR Altimeter ' ' ' ' pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4601 Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.2.1 2013/12/19 13:05:24 1573 1573 CLEAN 5.1 2013/12/19 13:06:12 1573 1573 ADDSAMP 3.6 2013/12/19 13:06:43 1573 1573 BINAVE 4.1.1 2013/12/19 13:06:56 1573 13 MERGE 3.5 2014/01/07 13:27:53 13 13 CLEAN 5.1 2014/01/07 13:28:01 13 13 CALIB 11.8 2014/01/07 13:28:08 13 13 SORT 3.6 2014/01/07 13:28:19 13 13 REMOVECH 8.2 2014/01/07 13:29:02 13 13 CHGUNITS 3.1 2014/01/07 13:32:59 13 13 CHGUNITS 3.1 2014/01/07 14:03:37 13 13 REORDER 1.3 2014/01/07 14:04:08 ? ? HDREDIT2 2.6 2014/01/07 14:04:23 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:34 13 13 $END $REMARKS -CLEAN functions: 2013/12/19 13:06:10 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-13\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/01/07 13:27:53 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-13\Processing\hydro\2013-13-0014.samavg Secondary file: P:\Cruise_Data_Processing\2013-13\Processing\hydro\2013-13-0014.mrgcln1s -SORT parameters: 2014/01/07 13:27:46 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/01/07 13:28:01 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/01/07 13:28:08 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-13\Processing\doc\2013-13-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1075200E+01 -SORT parameters: 2014/01/07 13:28:19 Sorted in ascending order of channel Pressure -REMOVECH 2014/01/07 13:29:02 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] pH:SBE [pH Units] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temp* Salinity reference channel: Sal* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Sal* 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/01/07 14:04:23 Applied edit header: P:\Cruise_Data_Processing\2013-13\Processing\doc\HYDRO\2013-13-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F5.1 Channel 15: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 16: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 17: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 19: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 20: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 22: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 23: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 24: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 25: Silicate [umol/L] Units: ==> umol/L Channel 26: Flag:Silicate [n/a] Units: ==> n/a Channel 27: Phosphate [umol/L] Units: ==> umol/L Channel 28: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 $END *COMMENTS Sample_Number 51: OXY: Sample sat stirring for about 60 sec before realizing the 'run sample' button wasn’t selected. Curve also ended early and abruptly. Sample over-titrated and value recalculated. Sample_Number 58: OXY-1: Endpoint overshot. Dosimat did not reach the finest doing rate near end of titration. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in room 1409. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2013-13CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-13OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 15 to 21 days after collection. Full details are in file QF2013-13SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples is collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) is collected and stored at 4C in the dark. All samples are returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see spreadsheet QF2013-13nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, Fluorescence, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application Note #64-2, June 2012 revision. A pH sensor was attached to the CTD, but the data are not included in the files to be placed in the IOS Data Library because no field calibration information was available at the time of processing, and there are some concerns about how the sensors perform. For details on the processing see the report: 2013-13-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0752) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- -13- -14- ---15--- 16 --17-- 18 --19-- ---20-- --21- 22 --23- 24 --25- 26 --27-- 28 !Bo Bo Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Samp Temp Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl !tt tt re ure: missi cence: Refere :T0:C0 : n: er_o le_ erat :Bottle ag phyll: ag Pigmen Dissolv n: ag te_ ag ate ag ate ag !~u ~u Primary vity URU: nce Dissol Disso ~bin Numb ure: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !en mb Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitri ri ca ha !ce er t SBE SBE ords le ed ted ed te te te te !-- -- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ---- ---- -------- -- ------ -- ------ ------- ----- -- ----- -- ----- -- ------ -- *END OF HEADER 13 13 2.0 9.8360 41.2 1.599 563.6 299.2 31.8323 4.46 194.3 121 63 9.9 -99.0000 0 2.47 6 1.00 4.343 189.2 0 26.0 0 44.8 0 2.05 0 12 12 5.0 9.4082 43.0 1.796 251.9 292.3 31.8921 4.26 185.6 121 62 9.5 -99.0000 0 -99.00 0 -99.00 4.136 180.2 0 26.8 0 45.9 0 2.19 0 11 11 10.2 8.9670 48.3 1.515 95.7 266.6 31.9940 3.82 166.2 121 61 9.2 -99.0000 0 1.33 6 0.86 3.812 166.1 0 27.7 0 46.7 0 2.17 0 10 10 19.6 8.8176 51.2 1.269 23.7 281.7 32.0300 3.67 160.0 121 60 9.3 -99.0000 0 0.96 6 0.66 3.642 158.7 0 28.3 0 47.1 0 2.20 0 9 9 29.6 8.6940 53.0 0.875 6.2 289.4 32.1130 3.55 154.7 121 59 9.0 -99.0000 0 -99.00 0 -99.00 3.544 154.4 0 28.5 6 47.3 6 2.22 6 8 8 39.7 8.6618 53.3 0.780 1.6 277.7 32.1376 3.52 153.5 121 58 8.9 -99.0000 0 -99.00 0 -99.00 3.520 153.3 46 28.7 0 47.3 0 2.23 0 7 7 50.1 8.5341 54.1 0.518 0.4 278.0 32.2083 3.41 148.7 121 57 8.9 -99.0000 0 -99.00 0 -99.00 3.405 148.3 0 28.9 0 47.5 0 2.24 0 6 6 75.3 8.2219 54.2 0.401 0.0 288.8 32.4973 3.21 139.8 121 56 8.6 -99.0000 0 -99.00 0 -99.00 3.202 139.4 0 30.0 0 47.9 0 2.28 0 5 5 100.4 7.2691 51.2 0.163 0.0 279.3 33.1887 2.46 106.8 121 55 8.1 -99.0000 0 -99.00 0 -99.00 2.437 106.1 0 33.0 0 52.3 0 2.50 0 4 4 124.5 6.7608 37.5 0.175 0.0 279.3 33.6126 2.05 89.2 121 54 7.0 -99.0000 0 -99.00 0 -99.00 2.046 89.0 6 34.6 0 55.4 0 2.54 0 3 3 150.1 6.6192 46.3 0.127 0.0 346.1 33.7897 1.99 86.4 121 53 7.5 -99.0000 0 -99.00 0 -99.00 1.975 85.9 0 35.0 6 54.5 6 2.54 6 2 2 175.4 6.6024 45.5 0.130 0.0 290.9 33.7947 1.97 85.7 121 52 7.5 33.7932 0 -99.00 0 -99.00 1.968 85.6 0 35.2 0 54.9 0 2.55 0 1 1 183.8 6.6034 45.3 0.126 0.0 299.0 33.7948 1.98 86.0 121 51 7.7 -99.0000 0 -99.00 0 -99.00 1.832 79.7 4 35.3 0 54.9 0 2.56 0