*2019/12/13 12:08:51.72 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/07/22 08:48:24.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : E2E09CD0 NUMBER OF CHANNELS : 40 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 189 201 2 Pressure decibar 3.566 41.129 3 Depth metres 3.53 40.705 4 Temperature:Primary 'deg C (ITS90)' -1.7541 -1.4685 5 Transmissivity %/metre 21.9 33.2 6 Fluorescence:URU:Seapoint mg/m^3 1.814 8.157 7 PAR uE/m^2/sec 0 20.049 8 PAR:Reference uE/m^2/sec 49.994 56.748 9 Salinity:T0:C0 PSS-78 30.6508 33.3919 10 Conductivity:Primary S/m 2.462526 2.640767 11 Oxygen:Dissolved:SBE mL/L 6.819 11.145 12 Oxygen:Dissolved:SBE umol/kg 296.4557 485.58 13 Number_of_bin_records n/a 49 241 14 Bottle_Number n/a 1 13 15 Bottle:Firing_Sequence n/a 1 13 16 Flag:Niskin_Bottle ' ' 17 Salinity:Bottle PSS-78 30.808 33.394 18 Flag:Salinity:Bottle ' ' 19 Nitrate_plus_Nitrite umol/L 0 13.5 20 Flag:Nitrate_plus_Nitrite n/a 21 Silicate umol/L 17.5 45.3 22 Flag:Silicate n/a 23 Phosphate umol/L 0.99 1.8 24 Flag:Phosphate n/a 25 Carbon:Dissolved:Inorganic umol/kg 1944.5 2259 26 Flag:Carbon:Dissolved:Inorganic n/a 27 Alkalinity:Total umol/kg 2109.1 2292.3 28 Flag:Alkalinity:Total n/a 29 Nitrate_plus_Nitrite2 umol/L 0.1 13.9 30 Flag:Nitrate_plus_Nitrite2 n/a 31 Silicate2 umol/L 16.1 45 32 Flag:Silicate2 n/a 33 Phosphate2 umol/L 0.65 1.84 34 Flag:Phosphate2 n/a 35 Ammonium umol/L 0.35 4.05 36 Flag:Ammonium n/a 37 Chlorophyll:Extracted mg/m^3 2.784 7.84 38 Flag:Chlorophyll:Extracted n/a 39 Oxygen:Isotope:18 /mille -2.29 -2.04 40 Flag:Oxygen:Isotope:18 n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 10 F ' ' 6 11 -99 ' ' 7 F ' ' 1 12 -99 ' ' 6 F ' ' 0 13 ' ' ' ' 5 I I 0 14 -99 ' ' 3 I I 0 15 -99 ' ' 3 I I 0 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 9 F R4 4 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' ' ' F8.2 R4 ' ' 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 1 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 0 ' ' 3 NQ C ' ' 31 -99 ' ' 7 F R4 2 32 0 ' ' 3 NQ C ' ' 33 -99 ' ' 8 F R4 3 34 0 ' ' 3 NQ C ' ' 35 -99 ' ' 7 F R4 2 36 0 ' ' 3 NQ C ' ' 37 -99 ' ' 7 F R4 2 38 0 ' ' 3 NQ C ' ' 39 -99 ' ' 7 F R4 2 40 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-05 AGENCY : IOS, Ocean Sciences Division, Sidney, BC COUNTRY : Canada PROJECT : C3O SCIENTIST : Vagle S. PLATFORM : Sir Wilfrid Laurier *LOCATION GEOGRAPHIC AREA : North Pacific/ Bering Sea/Chukchi Sea STATION : DBO-4_4 EVENT NUMBER : 39 LATITUDE : 71 21.65000 N ! (deg min) LONGITUDE : 163 1.85000 W ! (deg min) WATER DEPTH : 42 ALTIMETER (M) : 4.18 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 03P5048 Conductivity ' ' 3579 'Pressure:Digiquartz with TC' ' ' 0941 Temperature:2 ' ' 03P5073 Conductivity:2 ' ' 3581 Fluorometer:Seapoint ' ' 2745 'Transmissometer:WET Labs C-Star' ' ' 'Wetlabs CStar 1050-D' 'Oxygen:SBE 43' ' ' 1117 Altimeter ' ' 40853 PAR/Irradiance:Biospherical/Licor ' ' 70123 Unavailable ' ' ' ' 'SPAR/Surface Irradiance' ' ' 'QSR2200 sn20279' $END $REMARKS Software Version Seasave V 7.22.5 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2018/06/15 16:53:57 2920 2920 ADDSAMP 3.6 2018/06/18 10:16:15 2920 2920 BINAVE 4.2 2018/06/18 15:42:09 2920 16 MERGE 3.5 2018/07/03 10:04:16 13 13 CLEAN 5.2.3 2018/07/03 10:11:53 13 13 SORT 3.6 2018/07/03 10:11:58 13 13 REMOVECH 8.2 2018/07/03 10:12:03 13 13 CHGUNITS 3.1.1 2018/07/03 10:12:18 13 13 REORDER 1.3.1 2018/07/03 10:12:46 ? ? HDREDIT2 3.1.1 2018/07/03 10:12:50 ? ? HDREDIT2 3.1.1 2019/12/13 12:08:51 ? ? $END $REMARKS -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-05\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number [n/a] -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2018/07/03 10:04:16 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Secondary Primary Channels to Include: ALL Secondary Channels to Include: Flag:Niskin_Bottle, Salinity:Bottle, Flag:Salinity:Bottle, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, Nitrate_plus_Nitrite2, Flag:Nitrate_plus_Nitrite2, Silicate2, Flag:Silicate2, Phosphate2, Flag:Phosphate2, Ammonium, Flag:Ammonium, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Isotope:18, Flag:Oxygen:Isotope:18 Primary file : P:\Cruise_Data_Processing\2013-005\Processing\test\hydro\2013-005-0039.samavg Secondary file: P:\Cruise_Data_Processing\2013-005\Processing\test\hydro\2013-005-0039.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2013-005\Processing\test\hydro\2013-005-0039.mrgcln1s --------------------------------------------------------------------------- -SORT parameters: 2018/06/18 13:22:21 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2018/07/03 10:11:52 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag* Delete Empty Channels: 0 deleted. Set event to last 4 characters of file name -SORT parameters: 2018/07/03 10:11:58 Sorted in ascending order of channel Pressure -REMOVECH 2018/07/03 10:12:03 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2018/07/03 10:12:50 Applied edit header: P:\Cruise_Data_Processing\2013-005\Processing\doc\HYDRO\2013-005-bot-hdr.txt Channel 15: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.1 Channel 12: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.0 Channel 14: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 38: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 20: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 22: Flag:Silicate [n/a] Units: ==> n/a Channel 24: Flag:Phosphate [n/a] Units: ==> n/a Channel 30: Flag:Nitrate_plus_Nitrite2 [n/a] Units: ==> n/a Channel 32: Flag:Silicate2 [n/a] Units: ==> n/a Channel 33: Phosphate2 [umol/L] Format: F7.2 ==> F8.3 Channel 34: Flag:Phosphate2 [n/a] Units: ==> n/a Channel 36: Flag:Ammonium [n/a] Units: ==> n/a Channel 26: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 27: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 28: Flag:Alkalinity:Total [n/a] Units: ==> n/a Channel 40: Flag:Oxygen:Isotope:18 [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 3: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 10: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 -HEADER EDITS: 2019/12/13 12:08:51 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\Archive-updates\2011-018\Bottle\country.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\2013-05_SWL-Leg1\Raw\2013-05-39-DBO-4_4.hex Software Version Seasave V 7.22.5 Temperature SN = 03P5048 Conductivity SN = 3579 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jul 22 2013 08:48:17 NMEA Latitude = 71 21.65 N NMEA Longitude = 163 01.85 W NMEA UTC (Time) = Jul 22 2013 08:48:24 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.2 number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 3 Latitude/Longitude added to scan GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds autorun on power up is disabled S> Cruise: 2013-05 Canada's Three Oceans (C3O) Ship: CCGS Sir Wilfrid Laurier Scientist: Svein Vagle Station: DBO-4_4 Depth: 42 System UTC = Jul 22 2013 08:48:17 # nquan = 21 # nvalues = 2920 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = spar: SPAR/Surface Irradiance # name 14 = dz/dtM: Descent Rate [m/s] # name 15 = altM: Altimeter [m] # name 16 = pumps: Pump Status # name 17 = sal00: Salinity, Practical [PSU] # name 18 = sal11: Salinity, Practical, 2 [PSU] # name 19 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 20 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jul 22 2013 08:48:24 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 03P5048 # 02-Nov-12 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.33962000e-003 # 6.38187300e-004 # 2.14146000e-005 # 1.91225000e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3579 # 02-Nov-12 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.41187072e+000 # 1.16776492e+000 # -1.60525088e-003 # 1.62784571e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0941 # 07-Dec-09 # -4.259763e+004 # -9.844260e-001 # 1.376500e-002 # 3.562200e-002 # 0.000000e+000 # 3.042047e+001 # -6.119116e-004 # 4.117890e-006 # 3.466810e-009 # 1.00000000 # -4.40000 # 0.000000e+000 # 1.281400e-002 # -9.482010e+000 # # # # # # 03P5073 # 02-Nov-12 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616900e-003 # 6.43070900e-004 # 2.27064600e-005 # 2.13583500e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3581 # 02-Nov-12 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.27926260e+000 # 1.14259204e+000 # -1.58289205e-003 # 1.60260667e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 2745 # # # 2 # 0.000 # # # # # # Wetlabs CStar 1050-DR # 24 Jun 2013 # 17.3950 # -0.9980 # 0.250 # # # # # # 1117 # 02-Nov-12 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 3.9800e-001 # -0.5149 # -2.2500e-003 # 1.4800e-004 # -2.8100e-006 # 2.5826e+000 # 1.92630e-004 # -4.64800e-002 # 3.6000e-002 # 1.4900 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 40853 # # 15.000 # 0.000 # # # # # # 70123 # 13 mar 2007 # 1.00000000 # 0.00000000 # 11297000000.00000000 # 1.00000000 # -0.08983177 # # # # # # # # # # # # # # # # # # QSR2200 sn20279 # 13 Mar 2007 # 1574.80000000 # 1.00000000 # # # # datcnv_date = Jun 15 2018 16:40:59, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2013-05\RAW\CTD\2013-05-0039.hex P:\Crui se_Data_Processing\2013-05\Processing\doc\2013-05-ctd.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Analysis methods: ----------------- Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 5 months after collection. Calculated Standard pool of the mean (Sp) was 0.0034 using 25 out of 26 replicates. The unused replicate was rejected using the Chauvenet criteria. Full details are in file "SWL2013-05 Salinity Data*". There are two sets of nutrient samples. The following comments refer to channels Nitrate_plus_Nitrite, Silicate and Phosphate; these data were analyzed at the Institute of Ocean Sciences. Nutrient samples were collected in polystyrene tubes, quick frozen in aluminum blocks and stored in -20°C freezer until analysis at IOS, about six months later in January 2014. Samples were analyzed on a three-channel Technicon Nutrient Auto Analyser, following methods described in Barwell-Clarke and Whitney (1996). Full details are in files “Nutrients_C3O_2013-05SWL_04.02.2014.docx and “2013-05_C3O_FrozenNutrientData_2016-08-08.xlsx”. There are two sets of nutrient samples. The following comments refer to channels Nitrate_plus_Nitrite2, Silicate2 and Phosphate2 and Ammonium: Nutrient samples (nitrate+nitrite, orthophosphate,silicate and ammonium) were analyzed at Chesapeake Biological Laboratory of the University of Maryland Center for Environmental Science (CBL-UMCES, http://www.umces.edu/nutrient-analytical-services-laboratory ). They were filtered from the Niskin bottles using 0.45 µM nylon syringe filters and frozen at -20°C until analysis at UMCES. Samples were thawed for 2 weeks at 8 degrees C before analysis. using a Technicon Bran & Luebbe AutoAnalyzer II, following these methods: Nitrate+Nitrite: Technicon Ind. Method No.158-71, 1977 and USEPA 1979 Method 353.2. Silicate: Technicon Ind. Method No.811-86T, 1986. Phosphate: Technicon Ind. Method No.155-71W, 1973, 1971 USEPA 1979 Method 365.1 and Froelich, 1978. NH4: References Standard Methods 4500-NH3 G-1997 (for further details, see CBL-UMCES_Ammonium Method 2017-3_3.pdf) Data provided by Lee Cooper (UMCES) Oxygen isotopic analysis water samples were collected in 10 or 20 mL glass scintillation vials, sealed with Polyseal caps and wrapped with Parafilm as a precaution to prevent evaporation and isotopic fractionation. Samples were returned to the Chesapeake Biological Laboratory of the University of Maryland Center for Environmental Science. Water samples were analyzed by equilibration with carbon dioxide using a Thermo Fisher Gas Bench II peripheral linked to a continuous flow Delta V Plus isotope ratio mass spectrometer. The oxygen isotope composition is referenced to Vienna-Standard Mean Ocean Water (V-SMOW): (V-SMOW): d18O = ((Rsample-Rstandard) / Rstandard) *1000 per mille, where R=18O/16O and V-SMOW is Vienna Standard Mean Ocean Water, as distributed by the International Atomic Energy Agency. Analytical precision was better than ±0.1 per mille and was assessed by analysis of in-house water standards during sample analysis and calibration to international water isotope standards (V-SMOW, V-SLAP, GISP). Data corrections were made based upon analysis of the in-house standards relative to international standards, which were normalized as per recommendations of Paul et al. [2007]. Data provided by Lee Cooper (UMCES) DIC/Alkalinity samples were collected in 250 mL glass reagent bottles, preserved with HgCl2, sealed with grease and stored at 4°C, until analysis at IOS about 7 months after collection. Samples were first analysed for DIC on a SOMMA-1 (Single-Operator Multi-Metabolic Analyzer), a computer controlled automated dynamic headspace analyser. The coulometer system is similar to that described by Johnson et al (1993) and was calibrated with Dickson CRM seawater (Batch 133 with a concentration of 2021.12 µmol/kg) (DOE 1994; Dickson 2001; Dickson et al. 2003) supplied by Andrew Dickson (Scripps Institute of Oceanography, San Diego, USA). There was only one duplicate collected so the pooled standard deviation could not be calculated. Samples were then analyzed for alkalinity by means of potentiometric titration using 0.1N HCl/0.6N NaCl, using a program written by Paul Covert, PMEL, University of Washington which is based on Andrew Dickson’s, SCRIPPS system. The mean accuracy (%recovery) was calculated to be 99.87%, ranging from 99.76 to 100.13%. Only one sample was collected in duplicate and so, the pooled standard deviation could not be calculated. Full details are in files "DIC and ALK 2013-05V2016-08-08.xlsx", "2013-05_DIC report_SAQ.docx" and "2013-05_ALKALINITY 2013 report_SAQ.docx" Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials. Filters were frozen at -20°C initially to fracture cell membranes, then 10 mL of 90% acetone was added and samples stored in the dark for 24 hours at 2°C. Chlorophyll concentration in acetone was then analyzed shipboard on a Turner 10AU fluorometer without acidification (Welschmeyer, 1994). The fluorometer was calibrated with a pure chlorophyll-a standard obtained from Turner Designs, (Turner Designs Part No.10-850) before and after all sampling, with use of a secondary solid standard (Part No.10-AU-904) during sampling to identify any possible instrument drift. Data provided by Lee Cooper (UMCES) References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Dickson, A. 2001. Reference materials for oceanic measurements. Oceanography. 14(4):21-22. 3. Dickson, A.G., Afghan, J.D., Anderson, G.C. 2003. Reference for oceanic CO2 analysis: a method for the certification of total alkalinity. Mar. Chem. 80(2-3):185-197. 4. Dickson, A.G., Sabine, C.L. and Christian, J.R. (Eds.) 2007. Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 191 pp. 5. DOE (1994) Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water.Version 2, A. G. Dickson & C. Goyet, eds. ORNL/CDIAC-74. 6. Froelich, P.N. and M.E.Q. Pilson. 1978. Systematic absorbance error with Technicon AutoAnalyzer II colorimeter. Water Res. 12:599-603. 7. Johnson, K.M., Wills, K.D., Butler, D.B., Johnson, W.K. and Wong, C.S. 1993. Coulometric total carbon dioxide analysis for marine studies: maximizing the performance of an automated gas extraction system and coulometric detector. Mar. Chem. 44:167-187. 8. Paul, D., G. Skrzypek, and I. Forizs. 2007. Normalization of measured stable isotopic compositions to isotope reference scales - a review. Rapid Communications in Mass Spectrometry 21 (18): 3006-3014. 9. Welschmeyer, N.A. 1994. Fluorometric analysis of chlorophyll a in the presence of chlorophyll b and pheopigments. Limnology and Oceanography 39 1985-1992. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, Fluorescence:SeaPoint, PAR, PAR:Reference and Oxygen:Dissolved:SBE are nominal and unedited except that some records were removed in editing temperature and salinity. There was no calibration sampling for dissolved oxygen, so values are reported with 1 less significant figure than usual. The post-cruise factory calibration indicates salinity drift was insignificant. For further processing details see the processing report 2013-05_Processing_Report.doc. --------------------------------------------------------------------------------------- This research cruise is part of the Distributed Biological Observatory (DBO) effort, which is an international effort to make repeat oceanographic observations at chosen stations in the Bering and Chukchi Seas and in Barrow Canyon. It is also a continuation of the Canada Three Oceans project “C3O” which was part of Canada’s contribution to the International Polar Year (IPY) research effort. Collaborators include University of Maryland, Center for Environmental Science (UMCES), Clark University and NOAA in the US, and the Universities of Victoria and British Columbia in Canada. Principle investigator Lee Cooper (UMCES) has provided nutrients, O18 and Chl-a data to be included in the chemistry data set --------------------------------------------------------------------------------------- !-1-- --2--- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- ----10--- --11-- --12- -13- 14 15 16 ---17--- 18 --19-- 20 --21-- 22 --23-- 24 ---25-- 26 --27-- 28 --29-- 30 --31-- 32 ---33-- 34 --35-- 36 --37-- 38 --39-- 40 !Samp Pressu Depth Temperat Trans Fluores PAR PAR: Salinity Conductiv Oxygen Oxyge Numb Bo Bo Fl Salinity Fl Nitrat Fl Silica Fl Phosph Fl Carbon: Fl Alkali Fl Nitrat Fl Silica Fl Phospha Fl Ammoni Fl Chloro Fl Oxygen Fl !le_ re ure: missi cence: Refere :T0:C0 ity: : n: er_o tt tt ag :Bottle ag e_ ag te ag ate ag Dissolv ag nity: ag e_ ag te2 ag te2 ag um ag phyll: ag : ag !Numb Primary vity URU: nce Primary Dissol Disso ~bin ~u ~u ~o ~o plus_ ~t ~i ~p ed: ~g Total ~T plus_ ~r ~c ~h ~o Extrac ~a Isotop ~p !er Seapoin ved: lved: _rec mb en tt tt Nitrit ri ca ha Inorgan an ot Nitrit it at at ni ted ct e:18 e: ! t SBE SBE ords er ce le le e te te te ic ic al e2 e2 e2 e2 um ed 18 !---- ------ ------ -------- ----- ------- ------ ------ -------- --------- ------ ----- ---- -- -- -- -------- -- ------ -- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- *END OF HEADER 201 3.6 3.5 -1.4685 22.2 6.537 20.0 53.8 30.6508 2.462526 11.1 486. 49 13 13 0 30.8080 0 0.00 0 17.50 0 0.99 0 1944.50 0 2109.1 0 0.70 0 16.10 0 0.650 0 4.05 0 2.82 0 -2.04 0 200 7.7 7.7 -1.5172 23.6 7.267 2.4 53.8 31.3674 2.511404 10.8 471. 241 12 12 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 199 10.2 10.1 -1.5926 25.3 8.157 0.6 51.9 32.3564 2.577546 11.1 482. 241 11 11 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 198 14.7 14.6 -1.6200 32.9 5.395 0.1 51.9 32.5415 2.588985 10.2 442. 241 10 10 0 32.5710 0 0.20 0 20.90 0 1.11 0 -99.00 0 -99.0 0 0.10 0 18.80 0 1.040 0 0.35 0 5.32 0 -2.29 0 197 17.3 17.1 -1.6275 33.2 4.934 0.0 51.9 32.6167 2.593950 9.8 426. 241 9 9 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 196 21.3 21.0 -1.6436 31.7 5.141 0.0 50.0 32.6511 2.595331 9.4 410. 241 8 8 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 195 24.8 24.6 -1.6491 26.9 7.175 0.0 51.9 32.6881 2.597729 9.3 405. 241 7 7 0 32.7950 0 4.50 0 30.00 0 1.47 0 -99.00 0 -99.0 0 3.50 0 29.30 0 1.200 0 1.03 0 7.84 0 -2.12 0 192 35.4 35.0 -1.7534 22.5 2.226 0.0 53.8 33.3812 2.639784 6.8 296. 182 4 4 0 33.3750 0 13.40 0 45.10 0 1.78 0 -99.00 0 -99.0 0 13.90 0 45.00 0 1.840 0 0.95 0 5.16 0 -2.22 0 193 35.4 35.0 -1.7535 22.5 2.407 0.0 53.8 33.3819 2.639830 6.8 297. 123 5 5 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 194 35.4 35.1 -1.7534 22.4 2.197 0.0 53.8 33.3817 2.639822 6.8 297. 241 6 6 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 189 41.1 40.7 -1.7541 21.9 2.068 0.0 56.7 33.3918 2.640754 6.8 297. 193 1 1 0 33.3940 0 13.50 0 45.30 0 1.80 0 2259.00 0 2292.3 0 13.20 0 43.80 0 1.820 0 0.69 0 2.78 0 -2.08 0 191 41.1 40.7 -1.7541 22.0 1.926 0.0 55.8 33.3918 2.640755 6.8 297. 241 3 3 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 190 41.1 40.7 -1.7540 22.0 1.814 0.0 55.8 33.3919 2.640767 6.8 297. 99 2 2 0 -99.0000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0