*2021/11/12 14:22:06.13 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2013/02/11 14:06:36.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 2 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 1D322726 NUMBER OF CHANNELS : 48 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 212 213 2 Bottle_Number n/a 1 2 3 Bottle:Firing_Sequence n/a 1 2 4 Pressure decibar 5.3 51.6 5 Temperature:Primary 'deg C (ITS90)' 5.7786 5.7805 6 Transmissivity %/metre 58.4 58.6 7 Fluorescence:URU:Seapoint mg/m^3 0.801 0.816 8 Salinity:T0:C0 PSS-78 32.5592 32.5594 9 Oxygen:Dissolved:SBE mL/L 7.13 7.15 10 Oxygen:Dissolved:SBE umol/kg 310.5 311 11 Number_of_bin_records n/a 121 121 12 Salinity:Bottle PSS-78 32.5602 32.5602 13 Flag:Salinity:Bottle n/a 14 Nitrate_plus_Nitrite umol/L 15.6 15.7 15 Flag:Nitrate_plus_Nitrite n/a 16 Silicate umol/L 24.2 24.3 17 Flag:Silicate n/a 18 Phosphate umol/L 1.33 1.34 19 Flag:Phosphate n/a 20 Chlorophyll:Extracted mg/m^3 0.73 0.73 21 Flag:Chlorophyll:Extracted n/a 22 Phaeo-Pigment:Extracted mg/m^3 0.19 0.21 23 HPLC:Chl-c3 mg/m^3 0.87E-01 0.99E-01 24 HPLC:Chlide-a mg/m^3 0 0 25 HPLC:MgDVP mg/m^3 0.7E-02 0.9E-02 26 HPLC:Chl-c2 mg/m^3 0.91E-01 0.91E-01 27 HPLC:Chl-c1 mg/m^3 0 0 28 HPLC:Me-chlide mg/m^3 0.3E-02 0.4E-02 29 HPLC:Peri mg/m^3 0.21E-01 0.27E-01 30 HPLC:Pheide-a mg/m^3 0 0 31 HPLC:But-fuco mg/m^3 0.99E-01 0.101 32 HPLC:Fuco mg/m^3 0.138 0.138 33 HPLC:Neo mg/m^3 0.4E-02 0.6E-02 34 HPLC:Pras mg/m^3 0.3E-02 0.4E-02 35 HPLC:Viola mg/m^3 0 0.9E-02 36 HPLC:Hex-fuco mg/m^3 0.179 0.189 37 HPLC:Diadino mg/m^3 0.3E-01 0.34E-01 38 HPLC:Allo mg/m^3 0.4E-02 0.4E-02 39 HPLC:Diato mg/m^3 0.3E-02 0.4E-02 40 HPLC:Zea mg/m^3 0 0.3E-02 41 HPLC:Lut mg/m^3 0.4E-02 0.4E-02 42 HPLC:Chl-b mg/m^3 0.48E-01 0.5E-01 43 HPLC:DVChl-a mg/m^3 0 0 44 HPLC:Chl-a mg/m^3 0.522 0.536 45 HPLC:Phe mg/m^3 0 0 46 HPLC:B-Car mg/m^3 0.5E-02 0.5E-02 47 HPLC:TChl-a mg/m^3 0.525 0.54 48 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2013-01 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P22 EVENT NUMBER : 38 LATITUDE : 49 42.58000 N ! (deg min) LONGITUDE : 140 39.43000 W ! (deg min) WATER DEPTH : 3844 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 3321 'Pressure:Digiquartz with TC' ' ' 77511 Temperature:2 ' ' 4700 Conductivity:2 ' ' 1766 Fluorometer:Seapoint ' ' ' ' PAR/Irradiance:Biospherical/Licor ' ' 4601 'Oxygen:SBE 43' ' ' 1438 'Transmissometer:WET Labs C-Star' ' ' 1396 Altimeter ' ' 1204 Fluorometer:Seapoint:2 ' ' 2228 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.2 2013/04/30 13:01:08 242 242 CLEAN 5.1 2013/04/30 13:01:33 ? ? ADDSAMP 3.5 2013/04/30 15:55:58 242 242 BINAVE 4.1.1 2013/04/30 15:56:38 242 2 MERGE 3.5 2013/05/02 09:42:25 2 2 CLEAN 5.1 2013/05/02 09:42:30 2 2 CALIB 11.7 2013/05/30 08:33:58 2 2 SORT 3.6 2013/05/30 10:20:58 2 2 REMOVECH 8.1.1 2013/05/30 11:41:42 2 2 CHGUNITS 3.0 2013/05/30 11:43:27 2 2 CHGUNITS 3.0 2013/05/30 11:44:26 2 2 REORDER 1.3 2013/05/30 11:45:18 ? ? HDREDIT2 2.6 2013/07/09 15:53:36 ? ? HDREDIT2 2.6 2013/12/15 14:06:53 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:39:01 2 2 CHANGE_FLAGS 2.0 2014/11/20 09:58:22 2 2 SORT 3.6 2020/08/26 19:20:27 2 2 REORDER 1.3.1 2021/11/11 10:46:47 ? ? MERGE 3.5.1 2021/11/11 10:47:34 2 2 SORT 3.6 2021/11/11 10:48:14 2 2 CLEAN 5.2.4 2021/11/11 10:48:28 2 2 HDREDIT2 3.2 2021/11/11 10:50:33 ? ? HDREDIT2 3.2 2021/11/12 14:22:06 ? ? $END $REMARKS -CLEAN functions: 2013/04/30 13:01:24 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2013-01\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2013/05/02 09:42:25 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2013-01\Processing\hydro\2013-01-0038.samavg Secondary file: P:\Cruise_Data_Processing\2013-01\Processing\hydro\2013-01-0038.mrgcln1s -SORT parameters: 2013/05/02 09:42:14 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2013/05/02 09:42:29 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2013/05/30 08:33:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2013-01\Processing\doc\2013-01-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.1890000E-01 0.1066400E+01 -SORT parameters: 2013/05/30 10:20:58 Sorted in ascending order of channel Pressure -REMOVECH 2013/05/30 11:41:42 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Fluorescence:Seapoint [mg/m^3] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: - No units changed -HEADER EDITS: 2013/07/09 15:53:36 Applied edit header: P:\Cruise_Data_Processing\2013-01\Processing\doc\HYDRO\2013-01-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint:2 ==> Fluorescence:URU:Seapoint Channel 7: Salinity:Practical:T0:C0 [PSS-78] Name: Salinity:T0:C0 ==> Salinity:Practical:T0:C0 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 13: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 14: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 15: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 16: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 18: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 19: Silicate [umol/L] Units: ==> umol/L Channel 20: Flag:Silicate [n/a] Units: ==> n/a Channel 21: Phosphate [umol/L] Units: ==> umol/L Channel 22: Flag:Phosphate [n/a] Units: ==> n/a -HEADER EDITS: 2013/12/15 14:06:53 - none. -SORT parameters: 2020/08/26 19:20:27 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/11 10:47:34 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-001_Nov2021\Processing\ 2013-001-0038.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-001_Nov2021\Processing\ 2013-001-0038.hplc -SORT parameters: 2021/11/11 10:48:14 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/11 10:48:27 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/11 10:50:33 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-001\2013-001-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 14: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 16: Silicate [umol/L] Format: F6.1 ==> F7.2 Channel 18: Phosphate [umol/L] Format: F7.2 ==> F8.3 Channel 23: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/12 14:22:06 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2013\2013-001\2013-001-bot- hdr2.txt Channel 14: Nitrate_plus_Nitrite [umol/L] Format: F7.2 ==> F6.1 Channel 16: Silicate [umol/L] Format: F7.2 ==> F6.1 Channel 18: Phosphate [umol/L] Format: F8.3 ==> F7.2 $END *COMMENTS Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “Precision” in file QF2013-01CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~8 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2013-001_HPLC*.xlsx. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2013-01OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater within 2 to 21 days after collection. Full details including a duplicate analysis are in file QF2013-01SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. THey were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see worksheet QF2013-01nuts*.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2013-01 DMS Report.doc and for data see DMS summary (2013-01 data)*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2 with a modification allowing a small offset. For further processing details see the processing report 2013-01-proc.doc. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.189E-01 1.0664) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- ---12--- 13 --14- 15 --16- 17 --18-- 19 --20-- 21 --22-- ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- 48 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Salinity Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T0:C0 : n: er_o :Bottle ag te_ ag ate ag ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: Dissol Disso ~bin ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec tt Nitri ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le te te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- -------- -- ----- -- ----- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 213 2 2 5.3 5.7786 58.4 0.816 32.5592 7.15 311.0 121 32.5602 0 15.6 0 24.2 0 1.34 0 0.73 0 0.21 0.087 0.000 0.007 0.091 0.000 0.004 0.021 0.000 0.101 0.138 0.004 0.003 0.009 0.179 0.034 0.004 0.004 0.003 0.004 0.048 0.000 0.536 0.000 0.005 0.540 6 212 1 1 51.6 5.7805 58.6 0.801 32.5594 7.13 310.5 121 -99.0000 0 15.7 0 24.3 0 1.33 0 0.73 6 0.19 0.099 0.000 0.009 0.091 0.000 0.003 0.027 0.000 0.099 0.138 0.006 0.004 0.000 0.189 0.030 0.004 0.003 0.000 0.004 0.050 0.000 0.522 0.000 0.005 0.525 6