*2014/11/20 09:58:20.58 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2012/09/07 13:42:55.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 3 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 77E256A NUMBER OF CHANNELS : 19 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 3 2 Bottle_Number n/a 1 3 3 Pressure decibar 3 31.5 4 Temperature:Secondary 'deg C (ITS90)' 8.7869 10.863 5 Transmissivity %/metre 23.6 63.7 6 Fluorescence:URU:Seapoint mg/m^3 0.112 2.209 7 Fluorescence:URU:Wetlabs mg/m^3 0.254 5.549 8 PAR uE/m^2/sec 0 2.1 9 Salinity:T1:C1 PSS-78 29.4554 31.7275 10 Oxygen:Dissolved:SBE mL/L 4.17 5.95 11 Oxygen:Dissolved:SBE umol/kg 181.9 259.6 12 Number_of_bin_records n/a 121 121 13 Sample_Number n/a 463 465 14 Nitrate_plus_Nitrite umol/L 13.4171 20.67798 15 Flag:Nitrate_plus_Nitrite n/a 16 Silicate umol/L 26.7 35.1 17 Flag:Silicate n/a 18 Phosphate umol/L 1.329905 1.62324 19 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 ' ' ' ' 5 I I 0 13 -99 ' ' 5 I I 0 14 -99 ' ' 6 F R4 1 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2012-59 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : UBC7 EVENT NUMBER : 129 LATITUDE : 51 29.82000 N ! (deg min) LONGITUDE : 127 49.01000 W ! (deg min) WATER DEPTH : 152 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1.2 2013/02/11 13:47:05 363 363 CLEAN 5.1 2013/02/11 13:48:01 363 363 ADDSAMP 3.5 2013/02/11 16:23:23 363 363 BINAVE 4.1.1 2013/02/11 16:23:36 363 3 MERGE 3.4 2013/02/12 11:42:24 3 3 CLEAN 5.1 2013/02/12 11:42:47 ? ? CALIB 11.7 2013/02/22 09:02:18 3 3 SORT 3.6 2013/02/22 15:47:46 3 3 REMOVECH 8.1.1 2013/02/22 15:48:29 3 3 CHGUNITS 3.0 2013/02/22 15:52:11 3 3 CHGUNITS 3.0 2013/02/22 15:52:52 3 3 REORDER 1.3 2013/02/22 15:53:58 ? ? HDREDIT2 2.6 2013/02/22 15:55:42 ? ? CALIB 11.7 2013/06/04 13:18:49 3 3 HDREDIT2 2.6 2013/07/08 08:52:49 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:38:41 3 3 CHANGE_FLAGS 2.0 2014/11/20 09:58:20 3 3 $END $REMARKS -CLEAN functions: 2013/02/11 13:47:39 20 Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2012-59\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2013/02/12 11:42:21 2013/02/12 11:42:21 2013/02/12 11:42: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2012-59\Processing\hydro\2012-59-0129.samavg Secondary file: P:\Cruise_Data_Processing\2012-59\Processing\hydro\2012-59-0129.mrgcln1s -CLEAN functions: 2013/02/12 11:42:07 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2013/02/12 11:42:11 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2013/02/12 11:42:45 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2013/02/22 09:02:18 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2012-59\Processing\doc\2012-59-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.3290000E-01 0.1046500E+01 -SORT parameters: 2013/02/22 15:47:46 Sorted in ascending order of channel Pressure -REMOVECH 2013/02/22 15:48:29 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: - No units changed -HEADER EDITS: 2013/02/22 15:55:42 Applied edit header: P:\Cruise_Data_Processing\2012-59\Processing\doc\HYDRO\2012-59-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 15: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 16: Silicate [umol/L] Units: ==> umol/L Channel 17: Flag:Silicate [n/a] Units: ==> n/a Channel 18: Phosphate [umol/L] Units: ==> umol/L Channel 19: Flag:Phosphate [n/a] Units: ==> n/a Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint -CALIB parameters: 2013/06/04 13:18:49 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 18 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:52:49 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt $END *COMMENTS Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “Precision” in file QF2012-59CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2012-59OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 2 months after collection. Full details including a duplicate analysis are in file QF2012-59SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. THey were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see worksheet QF2012-59nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2012-59_NH4*.xls. References*: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2012-12-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.329E-01 1.0465) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !1- 2- --3--- ---4---- --5-- ---6--- ---7--- --8--- ---9---- --10-- --11- -12- -13- --14- 15 --16- 17 --18-- 19 !Bo Bo Pressu Temperat Trans Fluores Fluores PAR Salinity Oxygen Oxyge Numb Samp Nitra Fl Silic Fl Phosph Fl !tt tt re ure: missi cence: cence: :T1:C1 : n: er_o le_ te_ ag ate ag ate ag !~u ~u Secondar vity URU: URU: Dissol Disso ~bin Numb plus_ ~t ~i ~p !en mb y Seapoin Wetlabs ved: lved: _rec er Nitri ri ca ha !ce er t SBE SBE ords te te te te !-- -- ------ -------- ----- ------- ------- ------ -------- ------ ----- ---- ---- ----- -- ----- -- ------ -- *END OF HEADER 3 3 3.0 10.8630 23.6 2.209 5.549 2.1 29.4554 5.95 259.6 121 465 -99.0 0 -99.0 0 -99.00 0 2 2 6.6 9.9164 45.8 1.230 2.373 0.5 30.1057 5.18 226.1 121 464 13.4 0 26.7 0 1.33 0 1 1 31.5 8.7869 63.7 0.112 0.254 0.0 31.7275 4.17 181.9 121 463 20.7 0 35.1 0 1.62 0