*2018/05/31 16:11:34.41 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2012/04/03 15:34:25.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 15506A48 NUMBER OF CHANNELS : 27 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 45 68 2 Bottle_Number n/a 1 24 3 Bottle:Firing_Sequence n/a 1 24 4 Pressure decibar 2 330.1 5 Temperature:Secondary 'deg C (ITS90)' 7.4272 8.6539 6 Transmissivity %/metre 45.1 60.8 7 Fluorescence:URU:Wetlabs mg/m^3 0.171 1.754 8 Salinity:T1:C1 PSS-78 29.1354 30.6479 9 Oxygen:Dissolved:SBE mL/L 3.35 6.59 10 Oxygen:Dissolved:SBE umol/kg 146 287 11 Number_of_bin_records n/a 37 241 12 Temperature:Draw 'deg C (ITS90)' 7.3 8.3 13 Salinity:Bottle PSS-78 29.1414 30.6481 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 3.4 6.58 16 Oxygen:Dissolved umol/kg 148 287 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 26.2 30.6 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 49.6 64.3 21 Flag:Silicate n/a 22 Phosphate umol/L 2.2 2.6 23 Flag:Phosphate n/a 24 Carbon:Dissolved:Inorganic umol/kg 1832.43 2098.36 25 Flag:Carbon:Dissolved:Inorganic n/a 26 Alkalinity:Total umol/kg 2016.18 2125.87 27 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -9 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F ' ' 0 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 6 F R4 1 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 2 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 1 27 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2012-19 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG Moorings SCIENTIST : Johannessen S. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia STATION : SOGN EVENT NUMBER : 7 LATITUDE : 49 50.14000 N ! (deg min) LONGITUDE : 124 52.08000 W ! (deg min) WATER DEPTH : 337 ALTIMETER (M) : 4.2 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1.2 2012/06/08 11:52:45 3472 3472 CLEAN 5.0.4 2012/06/08 11:52:53 ? ? ADDSAMP 3.5 2012/06/08 11:53:02 3472 3472 BINAVE 4.1.1 2012/06/08 11:53:08 3472 24 MERGE 3.4 2012/06/08 11:53:25 24 24 CLEAN 5.0.4 2012/06/11 09:55:36 24 24 CALIB 11.7 2012/06/11 09:55:45 24 24 CALIB 11.7 2012/06/11 09:55:57 24 24 SORT 3.5 2012/06/11 10:54:42 24 24 REMOVECH 8.1.1 2012/06/11 10:55:00 24 24 CHGUNITS 3.0 2012/06/11 11:24:12 24 24 CHGUNITS 3.0 2012/06/11 11:25:31 24 24 REORDER 1.3 2012/06/11 11:31:34 ? ? HDREDIT2 2.5.1 2012/06/11 11:34:58 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:38:07 24 24 HDREDIT2 2.6 2013/12/18 14:01:04 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:58:12 24 24 SORT 3.6 2016/11/29 13:19:54 24 24 MERGE 3.5 2016/12/14 13:29:34 24 24 SORT 3.6 2018/05/31 15:04:18 24 24 CLEAN 5.2.3 2018/05/31 15:04:24 24 24 CLEAN 5.2.3 2018/05/31 15:04:39 24 24 HDREDIT2 3.1.1 2018/05/31 16:11:34 ? ? $END $REMARKS -CLEAN functions: 2012/06/08 11:52:52 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2012-19\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2012/06/08 11:53:25 2012/06/08 11:53:25 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2012-19\Processing\hydro\2012-19-0007.samavg Secondary file: P:\Cruise_Data_Processing\2012-19\Processing\hydro\2012-19-0007.mrgcln1s -SORT parameters: 2012/06/07 16:26:22 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2012/06/11 09:55:36 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2012/06/11 09:55:45 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2012-19\Processing\doc\2012-19-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.1200000E+01 0.1000000E+01 -CALIB parameters: 2012/06/11 09:55:57 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2012-19\Processing\doc\2012-19-recal2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T1:C1 PSS-78 10 0.5000000E-02 0.1000000E+01 -SORT parameters: 2012/06/11 10:54:42 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/06/11 10:55:00 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] pH:SBE [pH Units] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/06/11 11:34:58 Applied edit header: P:\Cruise_Data_Processing\2012-19\Processing\doc\HYDRO\2012-19-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 7: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 9: Oxygen:Dissolved:SBE [umol/kg] Format: F6.0 ==> F6.1 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 17: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 18: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 19: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 20: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 21: Flag:Silicate [n/a] Units: ==> n/a Channel 22: Phosphate [umol/L] Units: ==> umol/L Channel 23: Flag:Phosphate [n/a] Units: ==> n/a -HEADER EDITS: 2013/12/18 14:01:04 Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L -SORT parameters: 2016/11/29 13:19:54 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2016/12/14 13:29:34 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : C:\DATA\Debby\2012-19-0007.chesort Secondary file: C:\DATA\Debby\2012-19-0007.dic -SORT parameters: 2018/05/31 15:04:18 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/05/31 15:04:24 20 Reset #RECS, MIN & MAX values in header. Change character data from "2" to "0" Delete Empty Channels: 2 deleted. -CLEAN functions: 2018/05/31 15:04:39 20 Change character data from " " to "0" -HEADER EDITS: 2018/05/31 16:11:34 Applied edit header: P:\Cruise_Data_Processing\Ianson-carbon\2012-19\Processing\2012-19-hdr.txt Channel 1: Sample_Number [n/a] Pad: -99 ==> -9 Channel 15: Oxygen:Dissolved [mL/L] Format: F7.2 ==> F8.3 Channel 25: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 26: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 27: Flag:Alkalinity:Total [n/a] Units: ==> n/a Channel 12: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 $END *COMMENTS Sample_Number 63: SAL: Liner creased Sample_Number 68: SAL: Replicate Outliers; value 29.1481 was low by 0.35 while 29.1414 was low by 0.011. The 1st replicate was not used. Sample_Number 45: OXY: Systematic error likely as a result of sampling technique Sample_Number 49: OXY: Titration ended abruptly. No definitive endpoint. Sample_Number 51: OXY: Duplicate value not used Sample_Number 67: OXY: Systematic error likely as a result of sampling technique Analysis methods: ----------------- Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). Oxygen values are reported to 2 decimal places only due to analyst's concern over precision. For details including a duplicate analysis, see document QF2012-19oxy*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 20 days after collection. Full details including a duplicate analysis are in file QF2012-19SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20 freezer. They were later analysed at IOS using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details including a duplicate analysis see file QF2012-19nuts*.xls. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Methods including analysis and quality control are detailed in Dickson et al (1993) and Ianson et al (2007). References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson, C. H., and R. T. Williams. 1991. A comparison of methods for the determination of dissolved oxygen in seawater. Report No. WHPO 91-2. WOCE Hydrographic Programme Office. Woods Hole Oceanographic Institution, Woods Hole, Mass. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 4. Dickson, A. G., C. L. Sabine, and J. R. Christian (2007), Determination of dissolved organic carbon and total dissolved nitrogen in sea water, PICES Special Publication 3. 5. Ianson, D., Susan E. Allen, Benjamin L. Moore-Maley, Sophia C. Johannessen and Robie W. Macdonald (2016), Vulnerability of a semienclosed estuarine sea to ocean acidification in contrast with hypoxia, Geophys. Res. Lett., 43, 5793-5801, doi:10.1002/2016GL068996. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2012-19-proc.doc. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------- -------- ---- ------ ------------ Pressure dbars 10 -99 () (1.2 1) Salinity:T1:C1 PSS-78 10 -99 () (0.5E-02 1) $END !-1-- 2- 3- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- --12- ---13--- 14 ---15-- --16- 17 --18- 19 --20- 21 --22-- 23 ---24-- 25 --26-- 27 !Samp Bo Bo Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Carbon: Fl Alkali Fl !le_ tt tt re ure: missi cence: :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag ate ag ate ag Dissolv ag nity: ag !Numb ~u ~u Secondar vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ed: ~g Total ~T !er mb en y Wetlabs ved: lved: _rec Draw tt lved lv Nitri ri ca ha Inorgan an ot ! er ce SBE SBE ords le ed te te te te ic ic al !---- -- -- ------ -------- ----- ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ----- -- ------ -- ------- -- ------ -- *END OF HEADER 67 23 23 2.0 7.4928 54.4 1.754 29.1356 6.43 281.0 43 7.3 29.1494 0 6.440 281. 36 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 68 24 24 2.0 7.4919 54.6 1.743 29.1354 6.43 281.0 241 -99.0 29.1414 26 -99.000 -99. 0 26.2 6 50.7 6 2.20 6 1966.80 0 2019.6 0 65 21 21 6.0 7.4852 55.6 1.662 29.1615 6.47 282.0 37 7.3 29.1575 0 6.480 283. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 66 22 22 6.0 7.4816 55.7 1.627 29.1616 6.49 283.0 241 -99.0 29.1595 0 -99.000 -99. 0 26.5 0 50.2 0 2.22 0 1961.98 0 2026.9 0 63 19 19 11.5 7.4375 57.0 1.437 29.1642 6.57 287.0 44 7.3 29.1735 3 6.570 287. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 64 20 20 11.5 7.4365 56.9 1.704 29.1642 6.57 287.0 241 -99.0 29.1680 0 -99.000 -99. 0 26.6 0 49.6 0 2.23 0 1955.98 0 2016.2 0 61 17 17 16.2 7.4275 57.7 1.416 29.1688 6.58 287.0 42 7.3 29.1770 0 6.580 287. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 62 18 18 16.2 7.4272 57.6 1.410 29.1694 6.59 287.0 241 -99.0 29.1770 0 -99.000 -99. 0 26.9 0 50.0 0 2.25 0 1969.84 0 2018.7 0 59 15 15 26.2 7.4444 60.3 1.139 29.2223 6.59 287.0 53 7.4 29.2320 0 6.570 287. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 60 16 16 26.2 7.4506 60.2 1.208 29.2282 6.56 286.0 241 -99.0 29.2311 0 -99.000 -99. 0 27.3 0 50.7 0 2.28 0 1837.99 3 2020.0 0 57 13 13 51.1 7.5335 59.9 1.120 29.3163 6.33 276.0 58 7.3 29.3215 0 6.330 276. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 58 14 14 51.1 7.5336 59.7 1.413 29.3163 6.33 276.0 241 -99.0 29.3216 0 -99.000 -99. 0 27.5 0 51.6 0 2.26 0 1832.43 3 -99.0 9 55 11 11 76.3 7.5890 60.8 0.921 29.3794 6.08 265.0 50 7.4 29.4172 0 5.980 261. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 56 12 12 76.3 7.5866 60.8 0.901 29.3775 6.09 266.0 241 -99.0 29.4237 0 -99.000 -99. 0 28.1 0 54.0 0 2.33 0 1997.97 0 2028.8 0 53 9 9 101.4 8.1923 60.4 0.279 30.0763 4.38 191.0 58 7.7 30.0286 0 4.420 193. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 54 10 10 101.4 8.1703 60.4 0.303 30.0498 4.57 200.0 241 -99.0 30.0270 0 -99.000 -99. 0 30.2 0 58.7 0 2.44 0 2041.05 0 2066.0 0 51 7 7 150.9 8.3676 60.3 0.180 30.3504 3.93 171.0 40 7.9 30.3565 6 3.940 172. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 52 8 8 150.9 8.3672 60.5 0.204 30.3503 3.93 171.0 241 -99.0 30.3561 0 -99.000 -99. 0 30.6 6 58.6 6 2.48 6 2082.55 6 2080.4 6 49 5 5 201.1 8.4827 59.0 0.171 30.4900 3.73 163.0 50 8.0 30.4983 0 3.750 164. 4 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 50 6 6 201.1 8.4827 58.7 0.173 30.4900 3.73 163.0 241 -99.0 30.4957 0 -99.000 -99. 0 30.5 0 59.4 0 2.53 0 2097.79 0 2096.6 3 47 3 3 251.1 8.4983 58.5 0.175 30.5380 3.68 161.0 44 8.1 30.5407 0 3.730 163. 0 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 48 4 4 251.1 8.4983 58.4 0.175 30.5381 3.68 160.0 241 -99.0 30.5413 0 -99.000 -99. 0 30.5 0 60.3 0 2.55 0 2095.26 0 2125.9 0 45 1 1 330.1 8.6539 45.3 0.193 30.6478 3.36 146.0 61 8.3 30.6481 6 3.400 148. 36 -99.0 0 -99.0 0 -99.00 0 -99.00 9 -99.0 9 46 2 2 330.1 8.6539 45.1 0.183 30.6479 3.35 146.0 241 -99.0 30.6472 0 -99.000 -99. 0 30.6 6 64.3 6 2.60 6 2098.36 6 2125.3 6