*2023/03/19 10:46:40.66 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2012/07/11 14:45:03.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 6 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 57B8C5D4 NUMBER OF CHANNELS : 26 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 6 2 Bottle_Number n/a 1 6 3 Pressure decibar 1.9 41.2 4 Temperature:Primary 'deg C (ITS90)' 10.3008 17.9811 5 Transmissivity %/metre 38.6 54.8 6 Fluorescence:URU:Seapoint mg/m^3 0.211 1.868 7 Fluorescence:URU:Wetlabs mg/m^3 0.463 1.733 8 PAR uE/m^2/sec 0 105.8 9 PAR:Reference uE/m^2/sec 1762.3 1803.5 10 Salinity:T0:C0 PSS-78 21.6972 28.5145 11 Oxygen:Dissolved:SBE mL/L 4.01 6.87 12 Oxygen:Dissolved:SBE umol/kg 175.1 302 13 Number_of_bin_records n/a 241 241 14 Sample_Number n/a 122 1121 15 Temperature:Draw 'deg C (ITS90)' 10.8 18.6 16 Salinity:Bottle PSS-78 27.2711 27.2711 17 Flag:Salinity:Bottle n/a 18 Oxygen:Dissolved mL/L 4.061 6.843 19 Oxygen:Dissolved umol/kg 177.4 301 20 Flag:Oxygen:Dissolved n/a 21 Nitrate_plus_Nitrite umol/L 1.8 17.2 22 Flag:Nitrate_plus_Nitrite n/a 23 Phosphate umol/L 0.35 2.42 24 Flag:Phosphate n/a 25 Silicate umol/L 38.0853 64.1 26 Silicate:Flag n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 5 F R4 1 16 -99 ' ' 9 F R4 4 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 8 F R4 3 19 -99 ' ' 6 F ' ' 1 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 6 F R4 1 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 6 F R4 1 26 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2012-16 AGENCY : 'WVL, Marine Ecosystems and Aquaculture Division,' CONTINUED : ' Vancouver, B.C.' COUNTRY : Canada PROJECT : Baynes Sound SCIENTIST : Sutherland T. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Baynes Sound STATION : BS16 EVENT NUMBER : 21 LATITUDE : 49 29.26000 N ! (deg min) LONGITUDE : 124 45.74000 W ! (deg min) WATER DEPTH : 43 ALTIMETER (M) : 2.805 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $REMARKS SOFTWARE VERSION SEASAVE V 7.21G $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1.2 2012/12/21 16:04:00 1446 1446 CLEAN 5.0.4 2012/12/21 16:05:10 1446 1446 ADDSAMP 3.5 2012/12/21 16:37:23 1446 1446 BINAVE 4.1.1 2012/12/21 16:37:38 1446 6 MERGE 3.4 2013/01/05 16:20:39 6 6 CLEAN 5.0.4 2013/01/05 16:20:46 6 6 CALIB 11.7 2013/01/05 16:20:59 6 6 SORT 3.5 2013/01/05 16:21:42 6 6 REMOVECH 8.1.1 2013/01/05 16:23:24 6 6 CHGUNITS 3.0 2013/01/05 16:24:13 6 6 CHGUNITS 3.0 2013/01/05 17:00:47 6 6 REORDER 1.3 2013/01/05 17:01:34 ? ? HDREDIT2 2.5.1 2013/01/07 11:28:52 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:38:05 6 6 CHANGE_FLAGS 2.0 2014/11/20 09:58:12 6 6 Silicate_Correction 1.0 2018/02/20 14:44:37 6 6 Silicate_Modification 1.2 2023/03/19 10:46:40 6 6 $END $REMARKS -CLEAN functions: 2012/12/21 16:04:57 20 Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2012-16\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2013/01/05 16:20:37 2013/01/05 16:20:37 2013/01/05 16:20: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2012-16\Processing\hydro\2012-16-0021.samavg Secondary file: P:\Cruise_Data_Processing\2012-16\Processing\hydro\2012-16-0021.mrgcln1s -SORT parameters: 2013/01/05 16:20:16 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2013/01/05 16:20:46 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2013/01/05 16:20:59 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2012-16\Processing\doc\2012-16-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1051600E+01 -SORT parameters: 2013/01/05 16:21:42 Sorted in ascending order of channel Pressure -REMOVECH 2013/01/05 16:23:24 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2013/01/07 11:28:52 Applied edit header: P:\Cruise_Data_Processing\2012-16\Processing\doc\HYDRO\2012-16-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F5.1 Channel 16: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 17: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 20: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 21: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Silicate [umol/L] Units: ==> umol/L Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Phosphate [umol/L] Units: ==> umol/L Channel 26: Flag:Phosphate [n/a] Units: ==> n/a Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 10: Salinity:Practical:T0:C0 [PSS-78] Name: Salinity:T0:C0 ==> Salinity:Practical:T0:C0 $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: BS16, Sample Number: 122, Silicate corrected using CTD salinity. ===================================================================================== Sample_Number 1121: OXY: Particles in sample creating a very noisy curve. Overtitration was no better. Concentration not trusted even after corrections. Sample_Number 1120: SAL: Problem suspected in all samples above 15db based on comparison with CTD salinity and results during cruise 2012-57; possibly due to Autosal non-linearity. Analysis methods: ----------------- Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2012-16oxy*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 4 months after collection. Full details are in file QF2012-16sAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer and analyzed later at the Institute of Ocean Sciences using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). File QF2012-16nuts*.xls includes the raw data and a precision study. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, fluorescence, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". For further processing details see the processing report 2012-16-proc.doc. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0516) $END !1- 2- --3--- ---4---- --5-- ---6--- ---7--- --8--- --9--- ---10--- --11-- --12- -13- -14- -15- ---16--- 17 ---18-- --19- 20 --21- 22 --23-- 24 --25- 26 !Bo Bo Pressu Temperat Trans Fluores Fluores PAR PAR: Salinity Oxygen Oxyge Numb Samp Temp Salinity Fl Oxygen: Oxyge Fl Nitra Fl Phosph Fl Silic Si !tt tt re ure: missi cence: cence: Refere :T0:C0 : n: er_o le_ erat :Bottle ag Dissolv n: ag te_ ag ate ag ate li !~u ~u Primary vity URU: URU: nce Dissol Disso ~bin Numb ure: ~o ed Disso ~o plus_ ~t ~p ~: !en mb Seapoin Wetlabs ved: lved: _rec er Draw tt lved lv Nitri ri ha Fl !ce er t SBE SBE ords le ed te te te ag !-- -- ------ -------- ----- ------- ------- ------ ------ -------- ------ ----- ---- ---- ---- -------- -- ------- ----- -- ----- -- ------ -- ----- -- *END OF HEADER 6 6 1.9 17.9811 38.6 1.868 1.697 105.8 1798.8 21.6972 6.87 302.0 241 122 18.6 -99.0000 0 6.843 301.0 0 1.8 0 0.35 0 38.1 0 5 5 5.6 13.8541 46.4 1.861 1.733 37.5 1803.5 25.2243 5.95 260.7 241 1121 13.7 -99.0000 0 5.774 253.0 4 11.2 6 1.15 6 42.3 6 4 4 10.6 12.4703 51.0 1.282 1.425 11.8 1788.4 26.2531 5.37 235.2 241 1120 11.8 27.2711 0 4.925 215.6 6 16.8 0 1.73 0 49.1 0 3 3 37.6 10.3532 54.8 0.236 0.482 0.1 1774.8 28.4212 4.07 177.7 241 1119 10.8 -99.0000 0 4.112 179.7 0 16.2 0 2.40 0 63.3 0 2 2 39.4 10.3354 54.2 0.214 0.463 0.1 1770.4 28.4510 4.03 176.0 241 1118 10.8 -99.0000 0 4.061 177.4 0 16.0 0 2.42 0 64.1 0 1 1 41.2 10.3008 52.8 0.211 0.466 0.0 1762.3 28.5145 4.01 175.1 241 1117 10.9 -99.0000 0 4.322 188.8 0 17.2 0 2.30 0 59.9 0