*2014/11/20 09:58:05.46 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2012/08/15 21:33:04.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 11 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : E77DCFC0 NUMBER OF CHANNELS : 16 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 11 2 Bottle_Number n/a 1 11 3 Pressure decibar 5.6 221.2 4 Temperature:Secondary 'deg C (ITS90)' 8.6454 16.8936 5 Transmissivity %/metre 17.6 61.3 6 Fluorescence:URU:Seapoint mg/m^3 0.95E-01 4.238 7 PAR uE/m^2/sec 0 13.7 8 Salinity:T1:C1 PSS-78 25.9564 31.2625 9 Oxygen:Dissolved:SBE mL/L 0.6E-01 9.21 10 Oxygen:Dissolved:SBE umol/kg 2.7 403.5 11 Number_of_bin_records n/a 241 241 12 Sample_Number n/a 1 11 13 Temperature:Draw 'deg C (ITS90)' 7.4 17.8 14 Oxygen:Dissolved mL/L 0 9.07 15 Oxygen:Dissolved umol/kg 0 396.9 16 Flag:Oxygen:Dissolved n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 5 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2012-13 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : SI EVENT NUMBER : 1 LATITUDE : 48 35.59000 N ! (deg min) LONGITUDE : 123 29.98000 W ! (deg min) WATER DEPTH : 225 ALTIMETER (M) : 4.71 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1.2 2013/01/24 12:15:22 2651 2651 CLEAN 5.0.4 2013/01/24 12:16:13 2651 2651 ADDSAMP 3.5 2013/01/24 12:18:46 2651 2651 BINAVE 4.1.1 2013/01/24 13:05:51 2651 11 MERGE 3.4 2013/01/24 13:06:16 11 11 CLEAN 5.0.4 2013/01/30 16:56:25 11 11 CALIB 11.7 2013/02/06 13:02:55 11 11 SORT 3.6 2013/02/06 13:38:51 11 11 REMOVECH 8.1.1 2013/02/06 13:42:43 11 11 CHGUNITS 3.0 2013/02/06 13:49:42 11 11 CHGUNITS 3.0 2013/02/06 13:49:57 11 11 REORDER 1.3 2013/02/06 13:51:00 ? ? HDREDIT2 2.6 2013/02/06 14:49:09 ? ? CALIB 11.7 2013/06/04 13:20:12 11 11 HDREDIT2 2.6 2013/07/08 08:52:13 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:37:44 11 11 CHANGE_FLAGS 2.0 2014/11/20 09:58:05 11 11 $END $REMARKS -CLEAN functions: 2013/01/24 12:16:13 Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2012-13\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2013/01/24 13:06:16 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2012-13\Processing\ios\2012-13-0001.samavg Secondary file: P:\Cruise_Data_Processing\2012-13\Processing\ios\2012-13-0001.mrgcln1s -SORT parameters: 2013/01/22 14:40:19 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2013/01/30 16:56:25 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2013/02/06 13:02:55 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2012-13\Processing\doc\2012-13-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.1590000E-01 0.1043500E+01 -SORT parameters: 2013/02/06 13:38:51 Sorted in ascending order of channel Pressure -REMOVECH 2013/02/06 13:42:43 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2013/02/06 14:49:09 Applied edit header: P:\Cruise_Data_Processing\2012-13\Processing\doc\HYDRO\2012-13-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F5.1 Channel 14: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint -CALIB parameters: 2013/06/04 13:20:12 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf WARNING: No calibration done on file C:\Data\Nutrients\2012-13\2012-13-0001.cor1 -HEADER EDITS: 2013/07/08 08:52:13 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt $END *COMMENTS Sample_Number 5: OXY: Small bubble under stopper Sample_Number 6: OXY: Particles, tried rerun but end point reached. No discernible end point. Curve does not flatten and is noisy. Sample_Number 8: OXY: Bubble under stopper of both samples. Neither of the duplicate values are close to CTD value. Replicate outliers. Values not trusted. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “Precision” in file QF2012-13CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Note: The variability between replicates was higher than usual and the values are lower than they typically are in comparison to HPLC chl. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2012-13OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater within 1.6 months after collection. Full details including a duplicate analysis are in file QF2012-13SAL*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater within 1.6 months after collection. Full details including a duplicate analysis are in file QF2012-13SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. THey were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see worksheet QF2012-13nuts*.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2012-13DMS Report.doc and for data see 2012-13DMS*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2 with a modification allowing a small offset. For further processing details see the processing report 2012-13-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.159E-01 1.0435) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- -12- -13- ---14-- --15- 16 !Bo Bo Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Samp Temp Oxygen: Oxyge Fl !tt tt re ure: missi cence: :T1:C1 : n: er_o le_ erat Dissolv n: ag !~u ~u Secondar vity URU: Dissol Disso ~bin Numb ure: ed Disso ~o !en mb y Seapoin ved: lved: _rec er Draw lved lv !ce er t SBE SBE ords ed !-- -- ------ -------- ----- ------- ------ -------- ------ ----- ---- ---- ---- ------- ----- -- *END OF HEADER 11 11 5.6 16.7524 31.2 4.238 13.7 25.9564 9.21 403.5 241 11 7.4 9.070 396.9 0 10 10 10.7 16.8936 46.0 1.604 2.5 26.7243 8.86 388.1 241 10 17.8 7.809 342.1 0 9 9 25.8 11.6263 61.3 0.229 0.2 28.5738 4.37 191.1 241 9 16.0 4.198 183.6 0 8 8 50.7 8.8037 61.2 0.165 0.0 29.9007 2.59 113.0 241 8 10.8 -99.000 -99.0 5 7 7 75.5 8.6454 49.7 0.211 0.0 30.8140 0.47 20.4 241 7 9.4 0.435 19.0 0 6 6 100.6 8.7867 46.7 0.111 0.0 30.9900 0.66 28.7 241 6 9.6 -99.000 -99.0 5 5 5 125.2 8.9434 50.5 0.095 0.0 31.1261 0.14 5.9 241 5 9.6 0.059 2.6 2 4 4 150.2 9.0512 43.4 0.098 0.0 31.2005 0.06 2.7 241 4 9.7 0.000 0.0 0 3 3 175.8 9.0912 53.8 0.099 0.0 31.2270 0.06 2.8 241 3 9.8 0.000 0.0 6 2 2 201.2 9.1169 57.5 0.105 0.0 31.2435 0.07 2.9 241 2 9.7 0.000 0.0 0 1 1 221.2 8.9489 17.6 0.119 0.0 31.2625 0.47 20.4 241 1 9.8 0.000 0.0 0