*2018/05/31 15:58:42.86 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2012/06/17 00:42:31.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 14 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 8E5B6D40 NUMBER OF CHANNELS : 31 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 198 211 2 Bottle_Number n/a 1 14 3 Bottle:Firing_Sequence n/a 1 14 4 Pressure decibar 2 244.5 5 Temperature:Secondary 'deg C (ITS90)' 6.325 9.6593 6 Transmissivity %/metre 45 60.3 7 Fluorescence:URU:Seapoint mg/m^3 0.49E-01 2.279 8 Fluorescence:URU:Wetlabs mg/m^3 0.98E-01 2.08 9 Salinity:T1:C1 PSS-78 31.0481 33.959 10 Oxygen:Dissolved:SBE mL/L 1.65 5.41 11 Oxygen:Dissolved:SBE umol/kg 71.8 235.9 12 Number_of_bin_records n/a 39 241 13 Temperature:Draw 'deg C (ITS90)' 7.5 10 14 Salinity:Bottle PSS-78 31.0519 33.957 15 Flag:Salinity:Bottle n/a 16 Chlorophyll:Extracted mg/m^3 0.46 1.78 17 Flag:Chlorophyll:Extracted n/a 18 Phaeo-Pigment:Extracted mg/m^3 0.34 0.7 19 Oxygen:Dissolved mL/L 1.707 5.455 20 Oxygen:Dissolved umol/kg 74.2 237.8 21 Flag:Oxygen:Dissolved n/a 22 Nitrate_plus_Nitrite umol/L 23.2 37.3 23 Flag:Nitrate_plus_Nitrite n/a 24 Silicate umol/L 38.7 60.4 25 Flag:Silicate n/a 26 Phosphate umol/L 1.79 2.65 27 Flag:Phosphate n/a 28 Carbon:Dissolved:Inorganic umol/kg 2046.92 2259.43 29 Flag:Carbon:Dissolved:Inorganic n/a 30 Alkalinity:Total umol/kg 2119.23 2280.55 31 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -9 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 ' ' ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 9 F R4 4 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 8 F R4 3 20 -99 ' ' 6 F ' ' 1 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 6 F R4 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 6 F R4 1 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 8 F R4 2 29 0 ' ' 3 NQ C ' ' 30 -99 ' ' 7 F R4 1 31 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2012-05 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Strait of Georgia SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia STATION : 102 EVENT NUMBER : 64 LATITUDE : 48 30.02000 N ! (deg min) LONGITUDE : 124 44.09000 W ! (deg min) WATER DEPTH : 254 ALTIMETER (M) : 11.67 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $REMARKS SOFTWARE VERSION SEASAVE V 7.21G $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1.2 2012/11/08 11:52:09 3455 3455 CLEAN 5.0.4 2012/11/08 11:52:45 3455 3455 ADDSAMP 3.5 2012/11/08 11:54:28 3455 3455 BINAVE 4.1.1 2012/11/08 11:54:48 3455 16 MERGE 3.4 2012/11/19 11:46:04 16 16 CLEAN 5.0.4 2012/11/19 11:46:11 16 16 CALIB 11.7 2012/11/19 11:46:24 16 16 SORT 3.5 2012/11/19 11:46:30 16 16 REMOVECH 8.1.1 2012/11/19 11:47:05 16 16 CHGUNITS 3.0 2012/11/19 11:48:18 16 16 CHGUNITS 3.0 2012/11/19 11:48:59 16 16 REORDER 1.3 2012/11/19 11:49:27 ? ? HDREDIT2 2.5.1 2012/11/19 11:49:44 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:37:15 16 16 CHANGE_FLAGS 2.0 2014/11/20 09:58:01 16 16 SORT 3.6 2016/11/29 13:19:54 16 16 MERGE 3.5 2016/12/14 13:29:33 16 14 SORT 3.6 2018/05/31 14:19:07 14 14 CLEAN 5.2.3 2018/05/31 14:19:28 14 14 CLEAN 5.2.3 2018/05/31 14:19:39 14 14 HDREDIT2 3.1.1 2018/05/31 15:58:42 ? ? $END $REMARKS -CLEAN functions: 2012/11/08 11:52:27 20 Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2012-05\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2012/11/19 11:46:04 2012/11/19 11:46:04 2012/11/19 11:46: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2012-05\Processing\hydro\2012-05-0064.samavg Secondary file: P:\Cruise_Data_Processing\2012-05\Processing\hydro\2012-05-0064.mrgcln1s -SORT parameters: 2012/11/19 11:33:21 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2012/11/19 11:46:11 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2012/11/19 11:46:24 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2012-05\Processing\doc\2012-05-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.5000000E+00 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1070400E+01 -SORT parameters: 2012/11/19 11:46:30 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/11/19 11:47:05 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] pH:SBE [pH Units] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/11/19 11:49:44 Applied edit header: P:\Cruise_Data_Processing\2012-05\Processing\doc\HYDRO\2012-05-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F11.2 ==> F7.1 Channel 7: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F5.1 Channel 14: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 15: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 16: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 18: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 21: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 22: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 23: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 24: Silicate [umol/L] Units: ==> umol/L Channel 25: Flag:Silicate [n/a] Units: ==> n/a Channel 26: Phosphate [umol/L] Units: ==> umol/L Channel 27: Flag:Phosphate [n/a] Units: ==> n/a Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint -SORT parameters: 2016/11/29 13:19:54 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2016/12/14 13:29:33 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : C:\DATA\Debby\2012-05-0064.chesort Secondary file: C:\DATA\Debby\2012-05-0064.dic -SORT parameters: 2018/05/31 14:19:07 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/05/31 14:19:28 20 Reset #RECS, MIN & MAX values in header. Change character data from "2" to "0" Delete Empty Channels: 2 deleted. -CLEAN functions: 2018/05/31 14:19:39 20 Change character data from " " to "0" -HEADER EDITS: 2018/05/31 15:58:42 Applied edit header: P:\Cruise_Data_Processing\Ianson-carbon\2012-05\Processing\2012-05-hdr.txt Channel 1: Sample_Number [n/a] Pad: -99 ==> -9 Channel 29: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 30: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 31: Flag:Alkalinity:Total [n/a] Units: ==> n/a Channel 13: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 $END *COMMENTS Sample_Number 206: SAL: Flushed cell with dH2O prior to next sample. Autosal erratic. Sample_Number 203: OXY: Curve ended abruptly. Over titrated and recalculated. Sample_Number 205: OXY: Titration noisy at end. Endpoint ok. Sample_Number 208: OXY: DO2 Tiny bubble under stopper. Titration ok. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2012-05_CHL-*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2012-05oxy*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater within 4 to 12 days of collection. Full details are in file QF2012-05sal*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer and anlayzed later at the Institute of Ocean Sciences using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). File QF2012-05nuts*.xls includes the raw data and a precision study. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Methods including analysis and quality control are detailed in Dickson et al (1993) and Ianson et al (2007). References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson, C. H., and R. T. Williams. 1991. A comparison of methods for the determination of dissolved oxygen in seawater. Report No. WHPO 91-2. WOCE Hydrographic Programme Office. Woods Hole Oceanographic Institution, Woods Hole, Mass. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 4. Holm-Hansen, O. (1978). Chlorophyll a determination: improvement in methodology. Oikos 30:438-447. 5. Dickson, A. G., C. L. Sabine, and J. R. Christian (2007), Determination of dissolved organic carbon and total dissolved nitrogen in sea water, PICES Special Publication 3. 6. Ianson, D., Susan E. Allen, Benjamin L. Moore-Maley, Sophia C. Johannessen and Robie W. Macdonald (2016), Vulnerability of a semienclosed estuarine sea to ocean acidification in contrast with hypoxia, Geophys. Res. Lett., 43, 5793-5801, doi:10.1002/2016GL068996. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Based on the recommendation from SeaBird, the method for calibration of Dissolved Oxygen concentration was changed from that used for 2011 and some 2012 cruises. For more information see the SeaBird Application NOte #64-2, June 2012 revision. It is not expected that this will make a significant difference in the results. For further processing details see the processing report 2012-05-proc.doc. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------- ---- ------ ------------ Pressure dbars 10 -99 () (0.5 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0704) $END !-1-- 2- 3- --4--- ---5---- --6-- ---7--- ---8--- ---9---- --10-- --11- -12- --13- ---14--- 15 --16-- 17 --18-- ---19-- --20- 21 --22- 23 --24- 25 --26-- 27 ---28-- 29 --30-- 31 !Samp Bo Bo Pressu Temperat Trans Fluores Fluores Salinity Oxygen Oxyge Numb Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Carbon: Fl Alkali Fl !le_ tt tt re ure: missi cence: cence: :T1:C1 : n: er_o ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag te_ ag ate ag ate ag Dissolv ag nity: ag !Numb ~u ~u Secondar vity URU: URU: Dissol Disso ~bin e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p ed: ~g Total ~T !er mb en y Seapoin Wetlabs ved: lved: _rec Draw tt ted ct Extrac lved lv Nitri ri ca ha Inorgan an ot ! er ce t SBE SBE ords le ed ted ed te te te te ic ic al !---- -- -- ------ -------- ----- ------- ------- -------- ------ ----- ---- ----- -------- -- ------ -- ------ ------- ----- -- ----- -- ----- -- ------ -- ------- -- ------ -- *END OF HEADER 211 14 14 2.0 9.6593 45.0 2.279 1.863 31.0481 5.41 235.9 39 10.0 31.0519 0 1.76 6 0.70 5.455 237.8 0 23.2 0 38.7 0 1.81 0 2046.92 0 2119.2 0 210 13 13 5.1 9.6429 45.0 2.245 2.080 31.0557 5.41 235.8 241 9.9 31.0527 0 1.78 6 0.67 5.442 237.3 0 23.4 6 38.7 6 1.85 0 -99.00 9 -99.0 9 209 12 12 9.4 9.4732 46.3 2.163 1.898 31.1126 5.22 227.7 241 9.7 31.1318 0 -99.00 0 -99.00 5.256 229.2 0 23.8 0 39.0 0 1.86 0 2051.95 0 2127.9 0 208 11 11 21.1 8.5405 52.1 0.582 0.568 31.8695 3.99 173.8 241 8.9 31.8639 0 0.46 6 0.34 4.017 175.0 26 26.9 0 42.4 0 2.07 0 2110.12 0 2168.6 0 207 10 10 30.2 8.2632 52.6 0.381 0.405 32.2395 3.70 161.0 241 8.7 32.2225 0 -99.00 0 -99.00 3.746 163.2 0 28.1 0 43.7 0 1.79 0 -99.00 9 -99.0 9 206 9 9 40.8 8.1257 53.4 0.270 0.312 32.3671 3.53 153.8 241 8.6 32.3523 2 -99.00 0 -99.00 3.586 156.2 0 28.7 0 44.2 0 2.16 0 -99.00 9 -99.0 9 205 8 8 51.3 7.7764 55.3 0.300 0.322 32.8597 3.14 136.8 241 8.3 32.8387 0 -99.00 0 -99.00 3.132 136.3 2 30.0 0 44.9 0 2.21 0 2168.16 0 2215.5 0 204 7 7 75.7 7.5526 58.0 0.307 0.321 33.3662 3.08 133.9 241 8.2 33.3624 0 -99.00 0 -99.00 3.111 135.4 6 28.4 0 39.9 0 2.10 0 -99.00 9 -99.0 9 203 6 6 101.3 7.3983 60.3 0.111 0.153 33.5891 2.92 127.1 241 8.2 33.5747 0 -99.00 0 -99.00 2.981 129.7 3 29.3 0 39.2 0 2.13 0 2189.60 0 2243.5 0 202 5 5 125.8 7.0021 59.4 0.068 0.104 33.7780 2.28 99.2 241 7.9 33.7687 0 -99.00 0 -99.00 2.294 99.8 0 32.8 6 46.9 6 2.36 6 -99.00 9 -99.0 9 201 4 4 153.3 6.8458 60.0 0.052 0.098 33.8353 2.07 89.8 241 7.9 33.8309 0 -99.00 0 -99.00 2.087 90.8 0 33.9 0 49.9 0 2.42 0 -99.00 9 -99.0 9 200 3 3 174.9 6.7090 60.3 0.050 0.098 33.8830 1.97 85.7 241 7.8 33.8811 0 -99.00 0 -99.00 1.976 85.9 0 34.8 0 52.3 0 1.94 0 -99.00 9 -99.0 9 199 2 2 200.7 6.5358 58.7 0.049 0.098 33.9276 1.88 81.6 241 7.6 33.9254 0 -99.00 0 -99.00 1.870 81.3 0 35.6 0 55.0 0 2.52 0 2247.01 6 2277.8 6 198 1 1 244.5 6.3250 53.2 0.049 0.107 33.9590 1.65 71.8 241 7.5 33.9570 0 -99.00 0 -99.00 1.707 74.2 0 37.3 0 60.4 0 2.65 0 2259.43 0 2280.6 0