*2021/11/25 11:42:33.06 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/08/18 16:23:31.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 14 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 11C39678 NUMBER OF CHANNELS : 53 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 23 36 2 Bottle_Number n/a 1 15 3 Bottle:Firing_Sequence n/a 1 15 4 Pressure decibar 1.4 100.2 5 Temperature:Secondary 'deg C (ITS90)' 7.2677 14.978 6 Transmissivity %/metre 31.4 64.5 7 Fluorescence:URU:Wetlabs mg/m^3 0.67E-01 5.476 8 PAR uE/m^2/sec 0 602.6 9 Salinity:T1:C1 PSS-78 31.5142 33.6674 10 Oxygen:Dissolved:SBE mL/L 3.28 6.51 11 Oxygen:Dissolved:SBE umol/kg 142.5 284 12 Number_of_bin_records n/a 70 241 13 Nitrate_plus_Nitrite umol/L 0.2 27.5 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 10.7 34.8 16 Flag:Silicate n/a 17 Phosphate umol/L 0.29 2.12 18 Flag:Phosphate n/a 19 Dimethyl_Sulphide nmol/L 0.13 3.52 20 Flag:Dimethyl_Sulphide n/a 21 Dimethylsulfoniopropionate_Dissolved nmol/L 0 3.2 22 Flag:Dimethylsulfoniopropionate_Dissolved n/a 23 Dimethylsulfoniopropionate_Total nmol/L 0 22 24 Flag:Dimethylsulfoniopropionate_Total n/a 25 Chlorophyll:Extracted mg/m^3 0.1E-01 3.01 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.15 1.97 28 HPLC:Chl-c3 mg/m^3 0.74E-01 0.321 29 HPLC:Chlide-a mg/m^3 0 0.23E-01 30 HPLC:MgDVP mg/m^3 0.6E-02 0.63E-01 31 HPLC:Chl-c2 mg/m^3 0.67E-01 0.353 32 HPLC:Chl-c1 mg/m^3 0 0.4E-02 33 HPLC:Me-chlide mg/m^3 0 0 34 HPLC:Peri mg/m^3 0.12E-01 0.112 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0.12E-01 0.117 37 HPLC:Fuco mg/m^3 0.266 1.25 38 HPLC:Neo mg/m^3 0.5E-02 0.48E-01 39 HPLC:Pras mg/m^3 0.8E-02 0.57E-01 40 HPLC:Viola mg/m^3 0 0.35E-01 41 HPLC:Hex-fuco mg/m^3 0.59E-01 0.159 42 HPLC:Diadino mg/m^3 0.16E-01 0.95E-01 43 HPLC:Allo mg/m^3 0.2E-01 0.131 44 HPLC:Diato mg/m^3 0 0.9E-02 45 HPLC:Zea mg/m^3 0.1E-01 0.156 46 HPLC:Lut mg/m^3 0 0.3E-02 47 HPLC:Chl-b mg/m^3 0.6E-01 0.432 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 0.633 2.905 50 HPLC:Phe mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0.9E-02 0.67E-01 52 HPLC:TChl-a mg/m^3 0.633 2.928 53 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-27 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P2 EVENT NUMBER : 6 LATITUDE : 48 36.04000 N ! (deg min) LONGITUDE : 125 59.99000 W ! (deg min) WATER DEPTH : 116 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2012/02/03 13:04:21 1205 1205 CLEAN 5.0.4 2012/02/03 13:05:11 ? ? JOIN 2.4.2 2012/02/03 13:11:59 3386 3386 ADDSAMP 3.5 2012/02/03 13:12:43 3386 3386 BINAVE 4.1.1 2012/02/03 13:13:24 3386 15 MERGE 3.4 2012/02/03 13:13:45 15 15 CLEAN 5.0.4 2012/02/03 13:23:00 14 14 CALIB 11.7 2012/02/14 13:36:20 14 14 SORT 3.5 2012/02/14 15:58:35 14 14 REMOVECH 8.1.1 2012/02/14 16:00:14 14 14 CHGUNITS 3.0 2012/02/14 16:08:17 14 14 CHGUNITS 3.0 2012/02/14 16:08:33 14 14 REORDER 1.3 2012/02/14 16:10:09 ? ? HDREDIT2 2.5.1 2012/03/28 13:51:18 ? ? CALIB 11.7 2013/06/04 13:16:49 14 14 HDREDIT2 2.6 2013/07/08 08:51:38 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:36:35 14 14 CHANGE_FLAGS 2.0 2014/11/20 09:57:50 14 14 SORT 3.6 2015/07/16 10:11:35 14 14 MERGE 3.5 2015/07/16 10:11:48 14 14 SORT 3.6 2015/07/16 10:12:14 14 14 CLEAN 5.2.4 2020/07/27 11:27:10 14 14 HDREDIT2 3.2 2020/07/27 11:28:16 ? ? SORT 3.6 2020/08/30 10:55:52 14 14 REORDER 1.3.1 2021/11/25 11:41:18 ? ? MERGE 3.5.1 2021/11/25 11:41:26 14 14 SORT 3.6 2021/11/25 11:41:33 14 14 CLEAN 5.2.4 2021/11/25 11:41:40 14 14 HDREDIT2 3.2 2021/11/25 11:42:11 ? ? HDREDIT2 3.2 2021/11/25 11:42:33 ? ? $END $REMARKS -CLEAN functions: 2012/02/03 13:05:09 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-27\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2012/02/03 13:13:45 2012/02/03 13:13:45 2012/02/03 13:13: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2011-27\Processing\hydro\2011-27-0006.samavg Secondary file: P:\Cruise_Data_Processing\2011-27\Processing\hydro\2011-27-0006.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-27\Processing\hydro\2011-27-0006.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2012/02/02 16:58:27 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2012/02/03 13:23:00 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/02/14 13:36:20 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-27\Processing\doc\2011-27-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.9100000E-01 0.1000000E+01 18 Oxygen:Dissolved:SBE mL/L 10 -0.2590000E-01 0.1002700E+01 -SORT parameters: 2012/02/14 15:58:35 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/02/14 16:00:14 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: - No units changed -HEADER EDITS: 2012/03/28 13:51:18 Applied edit header: P:\Cruise_Data_Processing\2011-27\Processing\doc\2011-27-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 10: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 16: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 17: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 18: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 19: Flag:Silicate [n/a] Units: ==> n/a Channel 20: Phosphate [umol/L] Units: ==> umol/L Channel 21: Flag:Phosphate [n/a] Units: ==> n/a Channel 22: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L Format: F8.3 ==> F7.2 Channel 23: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -CALIB parameters: 2013/06/04 13:16:49 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 16 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 20 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:51:38 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2015/07/16 10:11:35 Sorted in ascending order of channel Sample_number -The following MERGE parameters were used: 2015/07/16 10:11:48 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : P:\Cruise_Data_Processing\DMSP\2011-27\Bottle\2011-27-0006.che1 Secondary file: P:\Cruise_Data_Processing\DMSP\2011-27\Bottle\2011-27-0006.dmsp -SORT parameters: 2015/07/16 10:12:14 Sorted in ascending order of channel Pressure -CLEAN functions: 2020/07/27 11:27:10 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* -HEADER EDITS: 2020/07/27 11:28:16 Channel 25: Flag:Dimethylsulfoniopropionate_Dissolved [n/a] Name: Flag:Dimethylsulfoniopropionate_Dissolve ==> Flag:Dimethylsulfoniopropionate_Dissolved -SORT parameters: 2020/08/30 10:55:52 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 11:41:26 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-027_Nov2021\Processing\ IOS\2011-027-0006.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-027_Nov2021\Processing\ IOS\2011-027-0006.hplc -SORT parameters: 2021/11/25 11:41:33 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 11:41:40 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 11:42:11 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-027-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 11:42:33 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-027-bot-hdr2.txt $END *COMMENTS Sample_Number 23: CHL: Value unreasonable. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2011-27_CHL-*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2011-027_HPLC*.xlsx. Oxygen samples were analyzed on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). All samples were analyzed at sea. For details including a duplicate analysis, see document QF2011-27oxy*.xls. Salinity samples were collected in 200 mL type ll glass bottles with plastic inserts and screw caps supplied by Ocean Scientific Internation Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater within 2 months of collection. Full details are in file QF2011-27sal*.xls. Nutrient samples were collected in plastic tubes. Most samples were analyzed fresh at sea. A few loop samples were analyzed frozen at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-27nuts*.xls" includes the raw data and a precision study. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2011-27 DMS Report.doc. For the data see DMS 2011-27 summary.xls and for the precision study see "std dev of pairs 2011-27.xls". The minimum detectable level for DMSP_Dissolved is 0.1 nM, so “0” values should be interpreted as <0.1 nM. The minimum detectable level for DMSP_Total in this file is 1 nM from 20m to 200m and 0.1 nM from 0 to 20m, so “0” values should be interpreted as < those values. For details on analysis and raw data, see document "2011-27 dmsp QF summary.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-27-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-027_Nov2021\Processing\IOS\2011-027-0006. hplc --------------------------------------------------------------------------- Sample_Number 35: HPLC: sample possibly poorly extracted *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.91E-01 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.259E-01 1.0027) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- 14 --15- 16 --17-- 18 --19-- 20 --21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitra Fl Silic Fl Phosph Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o te_ ag ate ag ate ag yl_ ag ylsulf ag ylsulf ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Nitri ri ca ha de hi te_Dis lv ionate ot ted ct Extrac HP ! ence SBE SBE ords te te te te de solved ed _Total al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -- ----- -- ------ -- ------ -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 33 15 15 1.4 14.9780 36.5 1.231 602.6 31.5142 6.34 276.8 241 0.2 0 10.9 0 0.29 0 1.37 0 3.20 0 0.00 0 1.27 0 0.40 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 36 14 14 4.5 14.9295 35.6 1.709 274.2 31.5212 6.37 278.1 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.074 0.000 0.032 0.135 0.003 0.000 0.044 0.000 0.056 0.266 0.021 0.033 0.028 0.105 0.069 0.093 0.007 0.156 0.002 0.204 0.000 1.312 0.000 0.046 1.312 6 32 10 12 4.7 14.8669 35.1 1.933 274.9 31.5334 6.36 277.4 70 0.2 0 11.1 0 0.30 0 1.43 0 2.70 0 0.00 0 1.08 0 1.72 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 31 9 11 10.1 14.3637 31.4 3.174 69.7 31.6213 6.51 284.0 241 0.2 0 11.2 0 0.30 0 2.32 0 -99.00 0 -99.00 0 1.27 0 0.42 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 35 13 10 15.6 10.7216 33.3 5.347 15.9 32.1445 6.28 273.8 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.321 0.023 0.063 0.353 0.004 0.000 0.112 0.000 0.117 1.250 0.048 0.057 0.035 0.159 0.095 0.131 0.009 0.109 0.003 0.432 0.000 2.905 0.000 0.067 2.928 26 30 8 9 15.7 10.6402 33.8 5.476 15.5 32.1531 6.29 274.0 183 5.9 0 18.0 0 0.91 0 3.52 0 -99.00 0 -99.00 0 3.01 0 1.97 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 29 7 8 20.1 8.8087 53.4 1.952 7.0 32.4320 4.71 204.9 241 15.8 0 22.1 0 1.52 0 0.63 6 0.70 6 22.00 6 0.88 0 1.70 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 34 12 7 25.5 8.3595 59.2 1.266 4.8 32.5474 4.92 214.4 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.097 0.000 0.006 0.067 0.000 0.000 0.012 0.000 0.012 0.273 0.005 0.008 0.000 0.059 0.016 0.020 0.000 0.010 0.000 0.060 0.000 0.633 0.000 0.009 0.633 6 28 6 6 25.6 8.3477 59.4 1.254 4.9 32.5508 4.98 216.9 241 16.6 0 22.1 0 1.56 0 0.40 0 -99.00 0 -99.00 0 0.65 6 0.39 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 27 5 5 29.8 8.2160 62.1 0.736 2.7 32.6280 5.84 254.4 241 16.5 0 22.0 0 1.55 0 0.32 0 -99.00 0 -99.00 0 1.00 0 0.17 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 26 4 4 40.6 7.9069 63.7 0.357 0.8 32.7122 6.11 266.1 241 10.3 0 10.7 0 1.12 0 0.28 0 -99.00 0 -99.00 0 0.17 0 0.15 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 25 3 3 50.1 7.7166 64.5 0.208 0.4 32.8941 5.57 242.6 241 14.0 0 15.2 0 1.32 0 0.25 0 -99.00 0 -99.00 0 0.01 0 0.26 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 24 2 2 73.7 7.4724 63.6 0.101 0.1 33.2434 4.00 174.1 241 21.2 6 25.8 6 1.76 6 0.19 0 -99.00 0 -99.00 0 0.09 0 0.15 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 23 1 1 100.2 7.2677 63.4 0.067 0.0 33.6674 3.28 142.5 241 27.5 0 34.8 0 2.12 0 0.13 0 0.00 0 0.60 0 -99.00 5 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0