*2021/11/25 11:34:49.37 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/06/10 08:21:21.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 2 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 2461A9F4 NUMBER OF CHANNELS : 48 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 495 496 2 Bottle_Number n/a 1 2 3 Bottle:Firing_Sequence n/a 1 2 4 Pressure decibar 5.2 39.9 5 Temperature:Secondary 'deg C (ITS90)' 7.5753 9.1489 6 Transmissivity %/metre 55.8 56.1 7 Fluorescence:URU:Wetlabs mg/m^3 1.22 2.414 8 Salinity:T1:C1 PSS-78 32.4971 32.5636 9 Oxygen:Dissolved:SBE mL/L 6.86 7.09 10 Oxygen:Dissolved:SBE umol/kg 299 308.8 11 Number_of_bin_records n/a 241 241 12 Salinity:Bottle PSS-78 32.5606 32.5606 13 Flag:Salinity:Bottle n/a 14 Nitrate_plus_Nitrite umol/L 7.5 8.4 15 Flag:Nitrate_plus_Nitrite n/a 16 Silicate umol/L 13.2 14 17 Flag:Silicate n/a 18 Phosphate umol/L 0.95 0.98 19 Flag:Phosphate n/a 20 Chlorophyll:Extracted mg/m^3 0.35 0.42 21 Flag:Chlorophyll:Extracted n/a 22 Phaeo-Pigment:Extracted mg/m^3 0.5E-01 0.11 23 HPLC:Chl-c3 mg/m^3 0.2E-01 0.47E-01 24 HPLC:Chlide-a mg/m^3 0 0 25 HPLC:MgDVP mg/m^3 0 0.1E-02 26 HPLC:Chl-c2 mg/m^3 0.31E-01 0.57E-01 27 HPLC:Chl-c1 mg/m^3 0 0 28 HPLC:Me-chlide mg/m^3 0 0 29 HPLC:Peri mg/m^3 0 0 30 HPLC:Pheide-a mg/m^3 0 0 31 HPLC:But-fuco mg/m^3 0.16E-01 0.39E-01 32 HPLC:Fuco mg/m^3 0.45E-01 0.77E-01 33 HPLC:Neo mg/m^3 0 0 34 HPLC:Pras mg/m^3 0 0 35 HPLC:Viola mg/m^3 0.3E-02 0.6E-02 36 HPLC:Hex-fuco mg/m^3 0.86E-01 0.149 37 HPLC:Diadino mg/m^3 0.16E-01 0.35E-01 38 HPLC:Allo mg/m^3 0.2E-02 0.3E-02 39 HPLC:Diato mg/m^3 0 0.4E-02 40 HPLC:Zea mg/m^3 0.1E-01 0.11E-01 41 HPLC:Lut mg/m^3 0 0 42 HPLC:Chl-b mg/m^3 0.8E-02 0.17E-01 43 HPLC:DVChl-a mg/m^3 0 0 44 HPLC:Chl-a mg/m^3 0.217 0.298 45 HPLC:Phe mg/m^3 0 0 46 HPLC:B-Car mg/m^3 0 0.2E-02 47 HPLC:TChl-a mg/m^3 0.217 0.298 48 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-26 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P21 EVENT NUMBER : 65 LATITUDE : 49 38.02000 N ! (deg min) LONGITUDE : 139 40.12000 W ! (deg min) WATER DEPTH : 3959 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/11/24 15:50:33 482 482 CLEAN 5.0.4 2011/11/24 15:58:26 ? ? ADTIMCH 4.3 2011/11/30 14:09:53 482 482 ADDSAMP 3.5 2011/11/30 14:11:24 482 482 BINAVE 4.1.1 2011/11/30 14:12:03 482 2 MERGE 3.4 2011/11/30 15:31:33 2 2 CALIB 11.7 2011/12/01 11:26:50 2 2 SORT 3.5 2011/12/06 15:53:38 2 2 REMOVECH 8.1.1 2011/12/06 16:01:15 2 2 CHGUNITS 3.0 2011/12/06 16:11:23 2 2 CHGUNITS 3.0 2011/12/06 16:12:01 2 2 REORDER 1.3 2011/12/06 16:12:59 ? ? HDREDIT2 2.5.1 2011/12/15 09:32:56 ? ? HDREDIT2 2.5.1 2011/12/20 13:13:07 ? ? CALIB 11.7 2013/06/04 13:16:34 2 2 HDREDIT2 2.6 2013/07/08 08:51:31 ? ? ADTIMCH 4.3 2013/08/09 13:50:02 2 2 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:36:17 2 2 CHANGE_FLAGS 2.0 2014/11/20 09:57:45 2 2 HDREDIT2 3.2 2020/01/22 11:40:55 ? ? SORT 3.6 2020/08/30 10:30:41 2 2 REORDER 1.3.1 2021/11/25 11:32:31 ? ? MERGE 3.5.1 2021/11/25 11:32:44 2 2 SORT 3.6 2021/11/25 11:33:05 2 2 CLEAN 5.2.4 2021/11/25 11:33:13 2 2 HDREDIT2 3.2 2021/11/25 11:33:46 ? ? HDREDIT2 3.2 2021/11/25 11:34:49 ? ? $END $REMARKS -CLEAN functions: 2011/11/24 15:57:55 20 Set event to last 4 characters of file name -The following ADTIMCH parameters were used. Add Day-Of-Year Add -1.00 hours to times in header file section -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-26\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/11/30 15:31:31 2011/11/30 15:31:31 2011/11/30 15:31: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2011-26\Processing\hydro\2011-26-0065.samavg Secondary file: P:\Cruise_Data_Processing\2011-26\Processing\hydro\2011-26-0065.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-26\Processing\hydro\2011-26-0065.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2011/11/30 14:16:19 Sorted in ascending order of channel Bottle_Number -CALIB parameters: 2011/12/01 11:26:50 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-26\Processing\doc\2011-26-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 10 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.6200000E-01 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 11 -0.1087352E+01 0.6760000E-02 Time:Day_Of_Year -SORT parameters: 2011/12/06 15:53:38 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2011/12/06 16:01:15 The following CHANNEL(S) were removed: Time:Day_Of_Year [DAY_OF_YEAR] Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -CHANGE units: - No units changed -HEADER EDITS: 2011/12/15 09:32:56 Applied edit header: P:\Cruise_Data_Processing\2011-26\Processing\doc\2011-26-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 17: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 19: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 21: Phosphate [umol/L] Units: ==> umol/L Channel 9: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs -HEADER EDITS: 2011/12/20 13:13:07 Channel 7: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 -CALIB parameters: 2013/06/04 13:16:34 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 21 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:51:31 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -The following ADTIMCH parameters were used. Add 1.00 hours to times in header file section -HEADER EDITS: 2020/01/22 11:40:55 - none. -SORT parameters: 2020/08/30 10:30:41 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 11:32:44 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-026_Nov2021\Processing\ IOS\2011-026-0065.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-026_Nov2021\Processing\ IOS\2011-026-0065.hplc -SORT parameters: 2021/11/25 11:33:05 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 11:33:12 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 11:33:46 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-026-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 23: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 11:34:49 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-026-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = E:\Data\2011-26\2011-26-0065.hex Software Version Seasave V 7.21b Temperature SN = 2374 Conductivity SN = 3396 Number of Bytes Per Scan = 41 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jun 10 2011 01:22:47 NMEA Latitude = 49 38.02 N NMEA Longitude = 139 40.12 W NMEA UTC (Time) = Jun 10 2011 08:21:21 Store Lat/Lon Data = Append to Every Scan Ship Tully Station: P21 Depth: 3959 System UTC = Jun 10 2011 08:22:47 # nquan = 19 # nvalues = 482 # units = specified # name 0 = scan: Scan Count # name 1 = prDM: Pressure, Digiquartz [db] # name 2 = t090C: Temperature [ITS-90, deg C] # name 3 = t190C: Temperature, 2 [ITS-90, deg C] # name 4 = c0S/m: Conductivity [S/m] # name 5 = c1S/m: Conductivity, 2 [S/m] # name 6 = xmiss: Beam Transmission, Chelsea/Seatech [%] # name 7 = flECO-AFL: Fluorescence, WET Labs ECO-AFL/FL [mg/m^3] # name 8 = sbeox0V: Oxygen raw, SBE 43 [V] # name 9 = par: PAR/Irradiance, Biospherical/Licor # name 10 = altM: Altimeter [m] # name 11 = pumps: Pump Status # name 12 = dz/dtM: Descent Rate [m/s] # name 13 = bpos: Bottle Position in Carousel # name 14 = nbf: Bottles Fired # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jun 10 2011 08:22:44 [NMEA time, first data scan] # bad_flag = -9.990e-29 # # # # # 2374 # 01-Apr-11 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.34933399e-003 # 6.45978519e-004 # 2.36515700e-005 # 2.25853980e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3396 # 29-Mar-11 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.91328016e+000 # 1.31301026e+000 # 2.66193245e-004 # 4.87230021e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 75636 # 13-Apr-11 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99993936 # 0.23996 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 2668 # 01-Apr-11 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.35634083e-003 # 6.48582753e-004 # 2.44368386e-005 # 2.40505893e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2754 # 29-Mar-11 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.05922233e+001 # 1.61309216e+000 # -1.72181967e-003 # 2.24719869e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1176 # 01-Apr-11p # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.6700e-001 # -0.5229 # -3.5502e-003 # 1.8841e-004 # -3.3087e-006 # 2.5826e+000 # 1.92630e-004 # -4.64800e-002 # 3.6000e-002 # 1.9100 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

#
#
#
# # # # 2216 # # 2.50000000e+001 # # 0.0281 # # # # # # 1185dr # Aug- 15-2010 # 19.4920 # -1.1110 # 0.250 # # # # # # # # # # # 15.000 # 0.000 # # # # # # # # # 4601 # 16-Mar-11 # 1.00000000 # 0.00000000 # 4219409282.69999980 # 1.00000000 # -0.34320000 # # # # # #
# datcnv_date = Nov 24 2011 15:46:07, 7.21d # datcnv_in = P:\Cruise_Data_Processing\2011-26\RAW\CTD\2011-26-0065.hex P:\Crui se_Data_Processing\2011-26\Processing\doc\2011-26-ctd0550-new.con # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2011-26\Processing\hydro\2011-26-0065.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-26\Processing\hydro\2011-26-0065.sal ------------------------------------------------------------------- Sample_Number 496: SAL: The value recorded for this sample was an Outlier in COMPARE, but value looks fine when presumed to be from Niskin #1, sample 495. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-26CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2011-026_HPLC*.xlsx. Oxygen samples were analyzed on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). All samples were analyzed at sea. For details including a duplicate analysis, see document 2011-26oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-26-sal*.xls. Nutrient samples were collected in plastic tubes. Most samples were stored frozen and later analysed at IOS. Deep Silicate samples (400m and deeper) were analyzed cool at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-26nuts*.xls" includes the raw data and a precision study. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2011-26 DMS Report.doc. For the data see DMS 2011-26 summary.xls and for the precision study see "std dev of pairs 2011-26.xls". References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-26-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-026_Nov2021\Processing\IOS\2011-026-0065. hplc --------------------------------------------------------------------------- Sample_Number 496: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.62E-01 1) Oxygen:Dissolved:SBE mL/L 11 -99 (Time:Day_Of_Year) (-1.087352 0.676E-02) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- ---12--- 13 --14- 15 --16- 17 --18-- 19 --20-- 21 --22-- ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- 48 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Salinity Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o :Bottle ag te_ ag ate ag ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec tt Nitri ri ca ha ted ct Extrac HP ! ence SBE SBE ords le te te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- -------- -- ----- -- ----- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 496 2 2 5.2 9.1489 56.1 1.220 32.4971 6.86 299.0 241 -99.0000 9 7.5 0 13.2 0 0.95 0 0.35 0 0.05 0.020 0.000 0.000 0.031 0.000 0.000 0.000 0.000 0.016 0.045 0.000 0.000 0.003 0.086 0.035 0.002 0.004 0.011 0.000 0.008 0.000 0.217 0.000 0.002 0.217 36 495 1 1 39.9 7.5753 55.8 2.414 32.5636 7.09 308.8 241 32.5606 0 8.4 0 14.0 0 0.98 0 0.42 0 0.11 0.047 0.000 0.001 0.057 0.000 0.000 0.000 0.000 0.039 0.077 0.000 0.000 0.006 0.149 0.016 0.003 0.000 0.010 0.000 0.017 0.000 0.298 0.000 0.000 0.298 6