*2014/11/20 09:57:40.83 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2011/09/05 23:49:57.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 7 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : C4B1AED9 NUMBER OF CHANNELS : 29 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 7 2 Bottle:Firing_Sequence n/a 1 7 3 Pressure decibar 5.4 42.6 4 Temperature:Secondary 'deg C (ITS90)' 8.9697 11.9468 5 Transmissivity %/metre 39.7 58.2 6 Fluorescence:URU:Wetlabs mg/m^3 0.391 8.245 7 PAR uE/m^2/sec 0.2 101.7 8 Salinity:T1:C1 PSS-78 31.1333 32.1673 9 Oxygen:Dissolved:SBE mL/L 2.73 5.93 10 Oxygen:Dissolved:SBE umol/kg 118.8 258.5 11 Number_of_bin_records n/a 115 241 12 Sample_Number n/a 316 322 13 Temperature:Draw 'deg C (ITS90)' 9.2 12.1 14 Salinity:Bottle PSS-78 31.1136 31.1136 15 Flag:Salinity:Bottle n/a 16 Chlorophyll:Extracted mg/m^3 0.49 10.38 17 Flag:Chlorophyll:Extracted n/a 18 Phaeo-Pigment:Extracted mg/m^3 0.39 0.95 19 Oxygen:Dissolved mL/L 2.652 6.206 20 Oxygen:Dissolved umol/kg 115.5 270.7 21 Flag:Oxygen:Dissolved n/a 22 Nitrate_plus_Nitrite umol/L 11.06222 29.99938 23 Flag:Nitrate_plus_Nitrite n/a 24 Silicate umol/L 28.5 54.2 25 Flag:Silicate n/a 26 Phosphate umol/L 1.228755 2.49313 27 Flag:Phosphate n/a 28 Ammonium umol/L 0.33 1.29 29 Flag:Ammonium n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 5 F R4 1 14 -99 ' ' 9 F R4 4 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 8 F R4 3 20 -99 ' ' 6 F ' ' 1 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 6 F R4 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 6 F R4 1 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 0 ' ' 3 NQ C ' ' $END $REMARKS This file converted from Sea-Bird file: P:\Cruise_Data_Processing\2011-17\Pro REPLACE Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-17 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse - WCVI SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LG01 EVENT NUMBER : 78 LATITUDE : 49 20.56000 N ! (deg min) LONGITUDE : 126 34.95000 W ! (deg min) WATER DEPTH : 52 ALTIMETER (M) : 8.38 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2012/02/16 10:26:12 1373 1373 CLEAN 5.0.4 2012/02/16 10:26:55 ? ? ADDSAMP 3.5 2012/02/16 10:46:34 1373 1373 BINAVE 4.1.1 2012/02/16 10:47:15 1373 7 MERGE 3.4 2012/02/21 15:44:08 7 7 CLEAN 5.0.4 2012/02/21 15:44:12 7 7 CALIB 11.7 2012/02/27 11:25:46 7 7 SORT 3.5 2012/02/27 11:56:48 7 7 REMOVECH 8.1.1 2012/02/27 12:01:25 7 7 CHGUNITS 3.0 2012/02/27 12:02:27 7 7 CHGUNITS 3.0 2012/02/27 12:02:49 7 7 REORDER 1.3 2012/02/27 12:09:49 ? ? HDREDIT2 2.5.1 2012/02/28 10:35:51 ? ? CALIB 11.7 2013/06/04 13:16:13 7 7 HDREDIT2 2.6 2013/07/08 08:51:18 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:58 7 7 CHANGE_FLAGS 2.0 2014/11/20 09:57:40 7 7 $END $REMARKS -CLEAN functions: 2012/02/16 10:26:28 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-17\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2012/02/21 15:44:06 2012/02/21 15:44:06 2012/02/21 15:44: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2011-17\Processing\hydro\2011-17-0078.samavg Secondary file: P:\Cruise_Data_Processing\2011-17\Processing\hydro\2011-17-0078.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-17\Processing\hydro\2011-17-0078.mrgcln1s ------------------------------------------------------------------------ -CLEAN functions: 2012/02/16 12:49:37 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2012/02/16 12:49:41 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2012/02/21 15:44:11 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/02/27 11:25:46 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-17\Processing\doc\2011-17-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.9100000E-01 0.1000000E+01 -SORT parameters: 2012/02/27 11:56:48 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/02/27 12:01:25 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/02/28 10:35:51 Applied edit header: P:\Cruise_Data_Processing\2011-17\Processing\doc\2011-17-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 10: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Channel 19: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 20: Oxygen:Dissolved [umol/kg] Format: F6.2 ==> F6.1 Channel 22: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 24: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 26: Phosphate [umol/L] Units: ==> umol/L Channel 28: Ammonium [umol/L] Format: F8.4 ==> F7.2 -CALIB parameters: 2013/06/04 13:16:13 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 22 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 26 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:51:18 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt $END *COMMENTS Comments from secondary file: P:\Cruise_Data_Processing\2011-17\Processing\hydro\2011-17-0078.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-17\Processing\hydro\2011-17-0078.chl ------------------------------------------------------------------- Sample_Number 320: CHL: variability of reps between 15-50 % Sample_Number 321: CHL: variability of reps between 15-50 % Comments from secondary file: P:\Cruise_Data_Processing\2011-17\Processing\hydro\2011-17-0078.oxy ------------------------------------------------------------------- Sample_Number 316: OXY: Bottle leaking Sample_Number 317: OXY: Bottle leaking a lot Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2011-17_CHL-*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). All samples were analyzed at sea. For details including a duplicate analysis, see document QF2011-17oxy*.xls. Salinity samples were collected in 200 mL type ll glass bottles with plastic inserts and screw caps supplied by Ocean Scientific Internation Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater within 1 month of collection. after collection. Full details are in file QF2011-17sal*.xls. Nutrient samples were collected in plastic tubes. Most samples were analyzed cool or frozen at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-17nuts*.xls" includes the raw data and a precision study. Ammonia samples were analysed fresh at sea using a TD700 fluorometer. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For more information including details on precision see QF2011-17NH4.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminot, A., Kerouel, R., Hooker, B.A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-17-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.91E-01 1) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- -12- -13- ---14--- 15 --16-- 17 --18-- ---19-- --20- 21 --22- 23 --24- 25 --26-- 27 --28-- 29 !Bo Bo Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Samp Temp Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl !tt tt re ure: missi cence: :T1:C1 : n: er_o le_ erat :Bottle ag phyll: ag Pigmen Dissolv n: ag te_ ag ate ag ate ag um ag !~u ~u Secondar vity URU: Dissol Disso ~bin Numb ure: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p ~o !mb en y Wetlabs ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitri ri ca ha ni !er ce SBE SBE ords le ed ted ed te te te te um !-- -- ------ -------- ----- ------- ------ -------- ------ ----- ---- ---- ---- -------- -- ------ -- ------ ------- ----- -- ----- -- ----- -- ------ -- ------ -- *END OF HEADER 7 7 5.4 11.8146 39.7 7.548 101.7 31.1569 5.93 258.4 241 322-99.0 -99.0000 0 10.38 6 0.39 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 0.70 6 4 6 5.5 11.9468 40.3 8.245 95.7 31.1333 5.93 258.5 115 319 12.1 31.1136 0 -99.00 0 -99.00 6.206 270.7 0 11.1 0 28.5 0 1.23 0 -99.00 0 6 4 10.8 10.1306 52.4 2.044 13.9 31.4609 4.14 180.7 137 321-99.0 -99.0000 0 3.68 36 0.95 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 1.29 6 3 5 10.9 10.1769 52.6 1.951 12.5 31.4405 4.18 182.3 241 318 10.3 -99.0000 0 -99.00 0 -99.00 4.165 181.6 6 24.6 0 41.3 0 2.10 0 -99.00 0 5 3 25.8 9.0731 58.2 0.391 1.4 32.0769 2.79 121.4 241 320-99.0 -99.0000 0 0.49 36 0.86 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 0.33 0 2 2 25.9 9.0718 57.9 0.392 1.4 32.0775 2.79 121.6 157 317 9.2 -99.0000 0 -99.00 0 -99.00 2.741 119.4 3 30.0 6 53.4 6 2.49 6 -99.00 0 1 1 42.6 8.9697 58.0 0.414 0.2 32.1673 2.73 118.8 241 316 9.2 -99.0000 0 -99.00 0 -99.00 2.652 115.5 3 30.0 0 54.2 0 2.49 0 -99.00 0