*2021/11/25 11:06:20.45 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/05/28 01:49:04.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 261A63A4 NUMBER OF CHANNELS : 55 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 227 245 2 Bottle_Number n/a 1 19 3 Bottle:Firing_Sequence n/a 1 19 4 Pressure decibar 5.4 750.8 5 Temperature:Secondary 'deg C (ITS90)' 4.3785 11.6237 6 Transmissivity %/metre 53.3 63.3 7 Fluorescence:URU:Wetlabs mg/m^3 -0.31E-01 1.995 8 PAR uE/m^2/sec 0 139.9 9 Salinity:T1:C1 PSS-78 31.7613 34.2445 10 Oxygen:Dissolved:SBE mL/L 0.34 6.93 11 Oxygen:Dissolved:SBE umol/kg 14.6 301.9 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 0.3 11.1 14 Salinity:Bottle PSS-78 34.1336 34.1336 15 Flag:Salinity:Bottle n/a 16 Oxygen:Dissolved mL/L 0.313 6.923 17 Oxygen:Dissolved umol/kg 13.6 301.5 18 Flag:Oxygen:Dissolved n/a 19 Nitrate_plus_Nitrite umol/L 0.2 43.3 20 Flag:Nitrate_plus_Nitrite n/a 21 Silicate umol/L 4.6 105.7 22 Flag:Silicate n/a 23 Phosphate umol/L 0.37 3.22 24 Flag:Phosphate n/a 25 Ammonium umol/L 0 0.8E-01 26 Flag:Ammonium n/a 27 Chlorophyll:Extracted mg/m^3 0.33 0.47 28 Flag:Chlorophyll:Extracted n/a 29 Phaeo-Pigment:Extracted mg/m^3 0.7E-01 0.14 30 HPLC:Chl-c3 mg/m^3 0.13E-01 0.113 31 HPLC:Chlide-a mg/m^3 0 0 32 HPLC:MgDVP mg/m^3 0 0.7E-02 33 HPLC:Chl-c2 mg/m^3 0.18E-01 0.8E-01 34 HPLC:Chl-c1 mg/m^3 0 0 35 HPLC:Me-chlide mg/m^3 0 0 36 HPLC:Peri mg/m^3 0 0.3E-02 37 HPLC:Pheide-a mg/m^3 0 0 38 HPLC:But-fuco mg/m^3 0.9E-02 0.73E-01 39 HPLC:Fuco mg/m^3 0.16E-01 0.115 40 HPLC:Neo mg/m^3 0 0.8E-02 41 HPLC:Pras mg/m^3 0 0.4E-02 42 HPLC:Viola mg/m^3 0.6E-02 0.9E-02 43 HPLC:Hex-fuco mg/m^3 0.48E-01 0.241 44 HPLC:Diadino mg/m^3 0.11E-01 0.24E-01 45 HPLC:Allo mg/m^3 0.5E-02 0.8E-02 46 HPLC:Diato mg/m^3 0 0 47 HPLC:Zea mg/m^3 0.1E-01 0.13 48 HPLC:Lut mg/m^3 0 0.11E-01 49 HPLC:Chl-b mg/m^3 0.36E-01 0.1 50 HPLC:DVChl-a mg/m^3 0 0 51 HPLC:Chl-a mg/m^3 0.349 0.544 52 HPLC:Phe mg/m^3 0 0 53 HPLC:B-Car mg/m^3 0.5E-02 0.13E-01 54 HPLC:TChl-a mg/m^3 0.349 0.544 55 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 9 F R4 4 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 6 F R4 1 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-16 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LD08 EVENT NUMBER : 63 LATITUDE : 48 39.27000 N ! (deg min) LONGITUDE : 126 23.17000 W ! (deg min) WATER DEPTH : 752 ALTIMETER (M) : 14.59 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/10/13 12:36:27 4579 4579 CLEAN 5.0.3 2011/10/13 12:38:20 ? ? ADDSAMP 3.5 2011/10/13 12:40:24 4579 4579 BINAVE 4.1.1 2011/10/13 12:40:57 4579 19 MERGE 3.4 2011/10/14 16:01:54 19 19 CLEAN 5.0.3 2011/10/14 17:24:07 19 19 SORT 3.5 2011/10/24 15:12:18 19 19 REMOVECH 8.0 2011/10/24 15:15:13 19 19 CHGUNITS 3.0 2011/10/24 15:31:15 19 19 CHGUNITS 3.0 2011/10/24 15:33:33 19 19 REORDER 1.3 2011/10/25 11:16:21 ? ? HDREDIT2 2.5.1 2011/10/25 11:16:55 ? ? CALIB 11.7 2013/06/04 13:15:59 19 19 HDREDIT2 2.6 2013/07/08 08:51:07 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:45 19 19 CHANGE_FLAGS 2.0 2014/11/20 09:57:37 19 19 SORT 3.6 2020/08/23 13:31:04 19 19 REORDER 1.3.1 2021/11/25 11:04:59 ? ? MERGE 3.5.1 2021/11/25 11:05:18 19 19 SORT 3.6 2021/11/25 11:05:26 19 19 CLEAN 5.2.4 2021/11/25 11:05:34 19 19 HDREDIT2 3.2 2021/11/25 11:06:01 ? ? HDREDIT2 3.2 2021/11/25 11:06:20 ? ? $END $REMARKS -CLEAN functions: 2011/10/13 12:38:02 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-16\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/10/14 16:01:52 2011/10/14 16:01:52 2011/10/14 16:01: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium Primary file : P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0063.samavg Secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0063.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0063.mrgcln1s ------------------------------------------------------------------------ -CLEAN functions: 2011/10/14 16:01:37 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2011/10/14 16:01:43 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/10/14 17:24:06 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -SORT parameters: 2011/10/24 15:12:18 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2011/10/24 15:15:13 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2011/10/25 11:16:55 Applied edit header: P:\Cruise_Data_Processing\2011-16\Processing\doc\2011-16-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 19: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 24: Silicate [umol/L] Format: F7.2 ==> F6.1 Channel 28: Ammonium [umol/L] Units: ==> umol/L Format: F8.4 ==> F7.2 Channel 10: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 20: Oxygen:Dissolved [umol/kg] Format: F6.2 ==> F6.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs -CALIB parameters: 2013/06/04 13:15:59 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 22 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 26 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:51:07 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/08/23 13:31:04 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 11:05:18 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016_Nov2021\Processing\ IOS\2011-016-0063.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016_Nov2021\Processing\ IOS\2011-016-0063.hplc -SORT parameters: 2021/11/25 11:05:26 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 11:05:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 11:06:01 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016\2011-016-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 13: Temperature:Draw [deg C (ITS90)] Format: F9.4 ==> F6.1 Channel 30: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 11:06:20 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016\2011-016-bot- hdr2.txt $END *COMMENTS Comments from secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0063.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0063.nut ------------------------------------------------------------------- Sample_Number 228: Nuts: Si cool dup only Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-16CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6-8 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2011-016_HPLC*.xlsx. Oxygen samples were analyzed on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). All samples were analyzed at sea. For details including a duplicate analysis, see document 2011-16oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-16-sal*.xls. Nutrient samples were collected in plastic tubes. Most samples were stored frozen and later analysed at IOS. Deep Silicate samples (400m and deeper) were analyzed cool at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-16nuts*.xls" includes the raw data and a precision study. Ammonia samples were analysed fresh at sea using a TD700 fluorometer. For more information including details on precision see 2011-16_NH4.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-01-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14--- 15 ---16-- --17- 18 --19- 20 --21- 22 --23-- 24 --25-- 26 --27-- 28 --29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- 55 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag ate ag ate ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw tt lved lv Nitri ri ca ha ni ted ct Extrac HP ! ence SBE SBE ords le ed te te te te um ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 242 16 18 5.4 11.6148 54.6 0.357 139.9 31.7629 6.64 289.2 241 11.1 -99.0000 0 6.579 286.8 0 0.2 0 5.1 0 0.37 0 0.00 6 0.33 6 0.07 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 245 19 19 5.5 11.6237 54.6 0.379 112.8 31.7613 6.64 289.2 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.013 0.000 0.000 0.018 0.000 0.000 0.003 0.000 0.009 0.016 0.000 0.004 0.009 0.048 0.024 0.008 0.000 0.130 0.000 0.036 0.000 0.349 0.000 0.013 0.349 6 241 15 17 9.8 11.2442 53.3 0.500 94.8 31.8213 6.65 289.8 241 10.7 -99.0000 0 6.700 292.0 0 0.3 0 5.3 0 0.40 0 0.00 6 0.47 6 0.13 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 240 14 16 20.5 9.1941 54.8 1.686 24.2 32.4638 6.93 301.9 241 9.0 -99.0000 0 6.923 301.5 0 3.3 0 5.9 0 0.66 0 0.08 6 0.42 6 0.14 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 239 13 15 29.5 8.9550 55.5 1.995 12.4 32.5102 6.88 299.4 241 8.8 -99.0000 0 6.831 297.5 0 4.2 0 5.0 0 0.71 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 244 18 14 35.1 8.8577 56.6 1.960 8.2 32.5361 6.88 299.6 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.111 0.000 0.006 0.080 0.000 0.000 0.000 0.000 0.065 0.079 0.008 0.000 0.009 0.241 0.014 0.007 0.000 0.023 0.011 0.100 0.000 0.544 0.000 0.005 0.544 6 243 17 13 45.1 8.5367 57.7 1.563 3.5 32.5592 6.78 295.2 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.113 0.000 0.007 0.067 0.000 0.000 0.000 0.000 0.073 0.115 0.004 0.004 0.006 0.179 0.011 0.005 0.000 0.010 0.006 0.084 0.000 0.496 0.000 0.005 0.496 6 238 12 12 50.4 8.3794 59.0 1.224 2.3 32.5748 6.57 286.2 241 0.3 -99.0000 0 6.635 288.7 0 6.0 0 4.6 0 0.82 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 237 11 11 75.0 7.7605 62.3 0.147 0.4 33.0704 5.02 218.3 241 7.9 -99.0000 0 5.028 218.8 0 17.3 0 19.3 0 1.48 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 236 10 10 100.1 7.7677 62.6 0.017 0.1 33.6933 3.19 139.0 241 7.9 -99.0000 0 3.275 142.5 0 27.7 0 33.9 0 2.06 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 235 9 9 125.3 7.5729 62.4 0.030 0.0 33.8570 2.53 109.9 241 7.7 -99.0000 0 2.571 111.8 6 31.0 6 40.4 6 2.28 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 234 8 8 151.4 7.3337 62.9 0.005 0.0 33.9004 2.35 102.1 241 7.5 -99.0000 0 2.340 101.8 0 32.2 0 43.5 0 2.36 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 233 7 7 174.9 7.0543 62.6 0.023 0.0 33.9342 2.20 95.5 241 7.3 -99.0000 0 2.191 95.3 0 33.1 0 46.7 0 2.35 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 232 6 6 201.4 6.7197 62.9 0.011 0.0 33.9609 1.96 85.2 241 6.9 -99.0000 0 2.026 88.1 0 34.4 0 50.9 0 2.40 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 231 5 5 251.2 6.3450 62.5 -0.004 0.0 33.9920 1.53 66.7 241 6.7 -99.0000 0 1.542 67.1 0 36.9 0 58.4 0 2.63 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 230 4 4 300.9 6.0005 63.3 -0.013 0.0 34.0175 1.35 58.8 241 6.5 -99.0000 0 1.353 58.8 0 38.1 0 63.8 0 2.76 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 229 3 3 400.6 5.5187 63.3 -0.017 0.0 34.0792 0.86 37.3 241 6.0 -99.0000 0 0.847 36.8 0 40.5 0 75.2 0 3.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 228 2 2 500.4 5.1787 63.3 -0.031 0.0 34.1231 0.63 27.4 241 5.8 34.1336 0 0.622 27.0 0 41.8 0 83.4 6 3.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 227 1 1 750.8 4.3785 62.1 -0.007 0.0 34.2445 0.34 14.6 241 5.2 -99.0000 0 0.313 13.6 0 43.3 0 105.7 0 3.22 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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