*2021/11/25 11:06:20.03 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/05/27 07:54:17.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 18 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 66F2DD2D NUMBER OF CHANNELS : 54 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 127 144 2 Bottle_Number n/a 1 18 3 Bottle:Firing_Sequence n/a 1 18 4 Pressure decibar 5.3 594.8 5 Temperature:Secondary 'deg C (ITS90)' 4.8431 11.6505 6 Transmissivity %/metre 54.8 63.5 7 Fluorescence:URU:Wetlabs mg/m^3 -0.3E-01 1.559 8 Salinity:T1:C1 PSS-78 31.3845 34.1768 9 Oxygen:Dissolved:SBE mL/L 0.46 6.98 10 Oxygen:Dissolved:SBE umol/kg 20 304 11 Number_of_bin_records n/a 241 241 12 Temperature:Draw 'deg C (ITS90)' 5.7 11.2 13 Salinity:Bottle PSS-78 31.3891 34.1082 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 0.449 6.915 16 Oxygen:Dissolved umol/kg 19.5 301.2 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 0.2 43.4 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 4 92.6 21 Flag:Silicate n/a 22 Phosphate umol/L 0.31 3.14 23 Flag:Phosphate n/a 24 Ammonium umol/L 0.4E-01 0.18 25 Flag:Ammonium n/a 26 Chlorophyll:Extracted mg/m^3 0.27 0.34 27 Flag:Chlorophyll:Extracted n/a 28 Phaeo-Pigment:Extracted mg/m^3 0.5E-01 0.12 29 HPLC:Chl-c3 mg/m^3 0 0.11 30 HPLC:Chlide-a mg/m^3 0 0 31 HPLC:MgDVP mg/m^3 0 0.15E-01 32 HPLC:Chl-c2 mg/m^3 0.12E-01 0.77E-01 33 HPLC:Chl-c1 mg/m^3 0 0 34 HPLC:Me-chlide mg/m^3 0 0 35 HPLC:Peri mg/m^3 0 0.5E-02 36 HPLC:Pheide-a mg/m^3 0 0 37 HPLC:But-fuco mg/m^3 0 0.58E-01 38 HPLC:Fuco mg/m^3 0.18E-01 0.172 39 HPLC:Neo mg/m^3 0 0.19E-01 40 HPLC:Pras mg/m^3 0 0.32E-01 41 HPLC:Viola mg/m^3 0 0.13E-01 42 HPLC:Hex-fuco mg/m^3 0.23E-01 0.144 43 HPLC:Diadino mg/m^3 0.4E-02 0.17E-01 44 HPLC:Allo mg/m^3 0.1E-01 0.21E-01 45 HPLC:Diato mg/m^3 0 0 46 HPLC:Zea mg/m^3 0.4E-02 0.173 47 HPLC:Lut mg/m^3 0 0.4E-02 48 HPLC:Chl-b mg/m^3 0.16E-01 0.191 49 HPLC:DVChl-a mg/m^3 0 0 50 HPLC:Chl-a mg/m^3 0.251 0.833 51 HPLC:Phe mg/m^3 0 0 52 HPLC:B-Car mg/m^3 0.2E-02 0.17E-01 53 HPLC:TChl-a mg/m^3 0.251 0.833 54 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F ' ' 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 6 F R4 1 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-16 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LC09 EVENT NUMBER : 40 LATITUDE : 48 25.98000 N ! (deg min) LONGITUDE : 126 13.66000 W ! (deg min) WATER DEPTH : 595 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/10/13 12:36:17 4338 4338 CLEAN 5.0.3 2011/10/13 12:38:12 ? ? ADDSAMP 3.5 2011/10/13 12:40:16 4338 4338 BINAVE 4.1.1 2011/10/13 12:40:53 4338 18 MERGE 3.4 2011/10/14 16:01:53 18 18 CLEAN 5.0.3 2011/10/14 17:24:07 18 18 SORT 3.5 2011/10/24 15:12:17 18 18 REMOVECH 8.0 2011/10/24 15:17:50 18 18 CHGUNITS 3.0 2011/10/24 15:31:15 18 18 CHGUNITS 3.0 2011/10/24 15:33:33 18 18 REORDER 1.3 2011/10/25 11:16:21 ? ? HDREDIT2 2.5.1 2011/10/25 11:16:55 ? ? CALIB 11.7 2013/06/04 13:15:59 18 18 HDREDIT2 2.6 2013/07/08 08:51:07 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:45 18 18 CHANGE_FLAGS 2.0 2014/11/20 09:57:37 18 18 SORT 3.6 2020/08/23 13:31:04 18 18 REORDER 1.3.1 2021/11/25 11:04:58 ? ? MERGE 3.5.1 2021/11/25 11:05:18 18 18 SORT 3.6 2021/11/25 11:05:26 18 18 CLEAN 5.2.4 2021/11/25 11:05:34 18 18 HDREDIT2 3.2 2021/11/25 11:06:00 ? ? HDREDIT2 3.2 2021/11/25 11:06:20 ? ? $END $REMARKS -CLEAN functions: 2011/10/13 12:38:02 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-16\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/10/14 16:01:52 2011/10/14 16:01:52 2011/10/14 16:01: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium Primary file : P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0040.samavg Secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0040.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0040.mrgcln1s ------------------------------------------------------------------------ -CLEAN functions: 2011/10/14 16:01:37 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2011/10/14 16:01:43 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/10/14 17:24:06 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -SORT parameters: 2011/10/24 15:12:17 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2011/10/24 15:17:50 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2011/10/25 11:16:55 Applied edit header: P:\Cruise_Data_Processing\2011-16\Processing\doc\2011-16-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Silicate [umol/L] Format: F7.2 ==> F6.1 Channel 27: Ammonium [umol/L] Units: ==> umol/L Format: F8.4 ==> F7.2 Channel 9: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 19: Oxygen:Dissolved [umol/kg] Format: F6.2 ==> F6.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs -CALIB parameters: 2013/06/04 13:15:59 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 21 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 25 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:51:07 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/08/23 13:31:04 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 11:05:18 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016_Nov2021\Processing\ IOS\2011-016-0040.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016_Nov2021\Processing\ IOS\2011-016-0040.hplc -SORT parameters: 2021/11/25 11:05:26 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 11:05:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 11:06:00 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016\2011-016-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 12: Temperature:Draw [deg C (ITS90)] Format: F9.4 ==> F6.1 Channel 29: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 11:06:20 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016\2011-016-bot- hdr2.txt $END *COMMENTS Comments from secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0040.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0040.oxy ------------------------------------------------------------------- Sample_Number 131: Oxy: Broke flask, lost sample Comments from secondary file: P:\Cruise_Data_Processing\2011-16\Processing\hydro\2011-16-0040.nut ------------------------------------------------------------------- Sample_Number 128: Nuts: Si cool dup only Sample_Number 132: Nuts: Poor PO4 dup Sample_Number 133: Nuts: Cracked tube, leaked Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-16CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6-8 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2011-016_HPLC*.xlsx. Oxygen samples were analyzed on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). All samples were analyzed at sea. For details including a duplicate analysis, see document 2011-16oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-16-sal*.xls. Nutrient samples were collected in plastic tubes. Most samples were stored frozen and later analysed at IOS. Deep Silicate samples (400m and deeper) were analyzed cool at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-16nuts*.xls" includes the raw data and a precision study. Ammonia samples were analysed fresh at sea using a TD700 fluorometer. For more information including details on precision see 2011-16_NH4.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-01-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-016_Nov2021\Processing\IOS\2011-016-0040. hplc --------------------------------------------------------------------------- Sample_Number 143: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- --12- ---13--- 14 ---15-- --16- 17 --18- 19 --20- 21 --22-- 23 --24-- 25 --26-- 27 --28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- 54 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag ate ag ate ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw tt lved lv Nitri ri ca ha ni ted ct Extrac HP ! ence SBE SBE ords le ed te te te te um ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 142 16 18 5.3 11.6452 56.5 0.310 31.3845 6.56 285.9 241 11.2 31.3891 0 6.493 283.1 0 0.2 0 4.0 0 0.31 0 0.04 6 0.28 6 0.05 0.000 0.000 0.000 0.012 0.000 0.000 0.005 0.000 0.000 0.018 0.000 0.000 0.003 0.023 0.013 0.010 0.000 0.173 0.000 0.028 0.000 0.330 0.000 0.015 0.330 6 141 15 17 10.8 11.6505 56.4 0.332 31.3905 6.53 284.5 241 11.2 -99.0000 0 6.508 283.7 0 0.2 0 4.0 0 0.32 0 0.08 6 0.27 6 0.05 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 140 14 16 19.1 10.7113 54.8 0.663 32.1230 6.98 304.0 241 10.5 -99.0000 0 6.861 298.9 0 0.2 0 5.3 0 0.40 0 0.18 6 0.34 6 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 139 13 15 29.2 9.3043 55.5 1.559 32.3855 6.94 302.1 241 9.3 -99.0000 0 6.915 301.2 0 2.0 0 6.6 0 0.59 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 144 18 14 38.9 8.7349 56.6 1.479 32.4726 6.62 288.5 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.110 0.000 0.015 0.077 0.000 0.000 0.000 0.000 0.058 0.172 0.019 0.032 0.013 0.144 0.017 0.021 0.000 0.040 0.004 0.191 0.000 0.833 0.000 0.017 0.833 6 143 17 13 48.2 8.2685 60.5 0.365 32.5411 5.55 241.8 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0.036 0.000 0.000 0.027 0.000 0.000 0.000 0.000 0.014 0.093 0.000 0.000 0.000 0.033 0.004 0.011 0.000 0.004 0.000 0.016 0.000 0.251 0.000 0.002 0.251 36 138 12 12 49.6 8.2132 60.7 0.324 32.5666 5.46 237.6 241 8.3 -99.0000 0 5.498 239.4 0 11.7 0 15.9 0 1.22 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 137 11 11 75.7 7.8970 61.8 0.162 32.9410 5.15 224.2 241 8.0 -99.0000 0 5.026 218.8 0 16.3 0 18.4 0 1.43 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 136 10 10 100.1 7.6445 61.9 0.031 33.3916 4.06 176.5 241 7.8 -99.0000 0 4.094 178.1 0 22.7 0 27.2 0 1.80 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 135 9 9 124.7 7.6054 62.4 0.027 33.7158 3.27 142.2 241 7.8 -99.0000 0 3.278 142.6 0 27.6 0 34.6 0 2.09 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 134 8 8 150.3 7.2655 62.2 0.029 33.8242 3.02 131.5 241 7.5 -99.0000 0 3.041 132.3 6 29.4 0 38.8 0 2.14 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 133 7 7 175.6 6.9961 61.9 0.013 33.8764 2.66 115.5 241 7.3 -99.0000 0 2.681 116.6 0 -99.0 1 -99.0 1 -99.00 1 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 132 6 6 199.8 6.7610 62.6 0.000 33.9430 2.08 90.4 241 7.1 -99.0000 0 2.066 89.8 0 34.5 6 50.1 6 2.34 36 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 131 5 5 251.0 6.2819 63.5 -0.014 33.9718 1.87 81.4 241 -99.0 -99.0000 0 -99.000 -99.0 5 36.3 0 56.3 0 2.59 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 130 4 4 299.7 5.9894 63.4 -0.018 34.0136 1.39 60.4 241 6.5 -99.0000 0 1.386 60.3 0 38.6 0 63.7 0 2.74 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 129 3 3 400.8 5.4767 61.8 -0.030 34.0839 0.83 36.2 241 6.1 -99.0000 0 0.858 37.3 0 41.3 0 76.7 0 3.01 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 128 2 2 499.5 5.3068 62.2 -0.018 34.1072 0.71 31.1 241 6.0 34.1082 0 0.752 32.7 0 42.0 0 80.7 6 3.08 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 127 1 1 594.8 4.8431 63.0 -0.025 34.1768 0.46 20.0 241 5.7 -99.0000 0 0.449 19.5 0 43.4 0 92.6 0 3.14 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0