*2023/03/19 10:46:31.72 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/09/12 20:48:20.000 TIME INCREMENT : 0 0 0 1 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 9933C6C9 NUMBER OF CHANNELS : 52 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 212 224 2 Bottle_Number n/a 1 13 3 Bottle:Firing_Sequence n/a 1 13 4 Pressure decibar 1.9 188.4 5 Temperature:Secondary 'deg C (ITS90)' 8.7371 18.8372 6 Transmissivity %/metre 27.6 58.8 7 Fluorescence:URU:Wetlabs mg/m^3 0.153 8.248 8 PAR uE/m^2/sec 0 536.6 9 PAR:Reference uE/m^2/sec 2226.9 2292 10 Salinity:T1:C1 PSS-78 24.5987 30.801 11 Oxygen:Dissolved:SBE mL/L 3.02 6.67 12 Oxygen:Dissolved:SBE umol/kg 131.5 292.5 13 Number_of_bin_records n/a 11 11 14 Temperature:Draw 'deg C (ITS90)' 9.4 19.4 15 Salinity:Bottle PSS-78 30.7222 30.7222 16 Flag:Salinity:Bottle n/a 17 Oxygen:Dissolved mL/L 3.014 6.596 18 Oxygen:Dissolved umol/kg 131.4 289.5 19 Flag:Oxygen:Dissolved n/a 20 Nitrate_plus_Nitrite umol/L 0 29.3 21 Flag:Nitrate_plus_Nitrite n/a 22 Silicate umol/L 30 68.9 23 Silicate:Flag n/a 24 Phosphate umol/L 0.49 2.75 25 Flag:Phosphate n/a 26 Chlorophyll:Extracted mg/m^3 0.55 4.62 27 Flag:Chlorophyll:Extracted n/a 28 Phaeo-Pigment:Extracted mg/m^3 0.22 0.47 29 HPLC:Chl-c3 mg/m^3 0.9E-02 0.201 30 HPLC:Chlide-a mg/m^3 0 0 31 HPLC:MgDVP mg/m^3 0 0.31E-01 32 HPLC:Chl-c2 mg/m^3 0.7E-01 1.028 33 HPLC:Peri mg/m^3 0 0.275 34 HPLC:Pheide-a mg/m^3 0 0 35 HPLC:But-fuco mg/m^3 0.59E-01 0.931 36 HPLC:Fuco mg/m^3 0.158 1.911 37 HPLC:Neo mg/m^3 0 0 38 HPLC:Pras mg/m^3 0 0.26E-01 39 HPLC:Viola mg/m^3 0 0.3E-01 40 HPLC:Hex-fuco mg/m^3 0 0 41 HPLC:Diadino mg/m^3 0.17E-01 0.456 42 HPLC:Allo mg/m^3 0.16E-01 0.67E-01 43 HPLC:Diato mg/m^3 0 0.56E-01 44 HPLC:Zea mg/m^3 0.8E-02 0.187 45 HPLC:Lut mg/m^3 0 0.9E-02 46 HPLC:Chl-b mg/m^3 0 0.178 47 HPLC:DVChl-a mg/m^3 0 0 48 HPLC:Chl-a mg/m^3 0.411 4.959 49 HPLC:Phe mg/m^3 0 0 50 HPLC:B-Car mg/m^3 0.8E-02 0.121 51 HPLC:TChl-a mg/m^3 0.411 4.959 52 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 5 I I 0 14 -99 ' ' 6 F R4 1 15 -99 ' ' 9 F R4 4 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 -99 ' ' 6 F ' ' 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 6 F R4 1 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-10 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 6 EVENT NUMBER : 60 LATITUDE : 49 30.59000 N ! (deg min) LONGITUDE : 124 27.75000 W ! (deg min) WATER DEPTH : 190 ALTIMETER (M) : 4.52 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $REMARKS SOFTWARE VERSION SEASAVE V 7.21D $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2012/03/02 08:57:46 143 143 CLEAN 5.0.4 2012/03/02 08:58:06 ? ? ADDSAMP 3.5 2012/03/02 09:17:15 143 143 BINAVE 4.1.1 2012/03/02 09:17:41 143 13 MERGE 3.4 2012/03/02 14:21:31 13 13 CLEAN 5.0.4 2012/03/02 17:29:13 13 13 CALIB 11.7 2012/03/05 09:18:19 13 13 SORT 3.5 2012/03/05 10:43:11 13 13 REMOVECH 8.1.1 2012/03/05 10:43:39 13 13 CHGUNITS 3.0 2012/03/05 10:45:00 13 13 CHGUNITS 3.0 2012/03/05 10:45:17 13 13 REORDER 1.3 2012/03/05 10:47:44 ? ? HDREDIT2 2.5.1 2012/03/05 10:55:47 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:35 13 13 CHANGE_FLAGS 2.0 2014/11/20 09:57:34 13 13 Silicate_Correction 1.0 2018/02/20 14:43:26 13 13 SORT 3.6 2020/11/30 15:44:13 13 13 REORDER 1.3.1 2021/11/25 10:38:45 ? ? MERGE 3.5.1 2021/11/25 10:39:00 13 13 SORT 3.6 2021/11/25 10:39:42 13 13 CLEAN 5.2.4 2021/11/25 10:39:52 13 13 HDREDIT2 3.2 2021/11/25 10:40:20 ? ? HDREDIT2 3.2 2021/11/25 10:40:44 ? ? Silicate_Modification 1.2 2023/03/19 10:46:31 13 13 $END $REMARKS -CLEAN functions: 2012/03/02 08:58:04 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-10\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2012/03/02 14:21:30 2012/03/02 14:21:30 2012/03/02 14:21: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0060.samavg Secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0060.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0060.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2012/03/02 14:21:25 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2012/03/02 17:29:12 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/03/05 09:18:19 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-10\Processing\doc\2011-10-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.6100000E-01 0.1000000E+01 -SORT parameters: 2012/03/05 10:43:11 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/03/05 10:43:39 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/03/05 10:55:47 Applied edit header: P:\Cruise_Data_Processing\2011-10\Processing\doc\2011-10-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Channel 20: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 25: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 27: Phosphate [umol/L] Units: ==> umol/L Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -SORT parameters: 2020/11/30 15:44:13 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 10:39:00 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\ IOS\2011-010-0060.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\ IOS\2011-010-0060.hplc -SORT parameters: 2021/11/25 10:39:42 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 10:39:50 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 10:40:20 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 14: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 Channel 31: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 24: Silicate:Corrected [umol/L] Format: F6.1 ==> F7.2 -HEADER EDITS: 2021/11/25 10:40:44 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010-bot-hdr2.txt $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 6, Sample Number: 224, Silicate corrected using CTD salinity. At Station: 6, Sample Number: 223, Silicate corrected using CTD salinity. ===================================================================================== Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0060.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0060.chl ------------------------------------------------------------------- Sample_Number 224: CHL: variability >15% Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0060.oxy ------------------------------------------------------------------- Sample_Number 215: OXY: Leaky Niskin Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours n the lab ~1 week after collection and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2011-10_CHL-*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-010_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2011-10oxy*.xls. Salinity samples were collected in 200mL type II glass bottles with disposable plastic inserts and screw cap supplied by Ocean Scientific International Ltd. They were analyzed in a temperature-controlled lab on a Guildline 8400B salinometer standardized with IAPSO standard seawater 4 months after collection. Full results including a duplicate analysis , see file QF2011-10sal*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. They were later analysed at IOS using an Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). For precision and duplicate details see worksheets in file QF2011-10nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- The SBE data are considered of lower quality than normal because 24 scans were averaged in acquisition. These averages may contain spikes that would normally be removed in processing. Given the casts are mostly from areas that are not particularly prone to extremely noisy CTD descent rates, and the CTD is believed to have worked well with few spikes, it is likely the errors caused by this problems are are small. The effects on the bottle files are considered less serious than those on the full profile files. Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-10-proc.doc. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\IOS\2011-010-0060. hplc --------------------------------------------------------------------------- Sample_Number 221: HPLC: But-fuco value likely unknown peak Sample_Number 222: HPLC: But-fuco value likely unknown peak Sample_Number 224: HPLC: >10%CV for TChl-a, But-fuco value likely unknown peak *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.61E-01 1) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10--- --11-- --12- -13- --14- ---15--- 16 ---17-- --18- 19 --20- 21 --22-- 23 --24-- 25 --26-- 27 --28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- 52 !Samp Bott Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silica Si Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: Refere :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag te li ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: nce Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~: ~p Extrac ~a t: a a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw tt lved lv Nitri ri Fl ha ted ct Extrac HP ! ence SBE SBE ords le ed te te ag te ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 224 13 13 1.9 18.8372 33.9 3.175 536.6 2257.8 24.5987 6.48 284.6 11 19.4 -99.0000 0 6.546 287.3 0 0.1 0 30.00 0 0.49 0 4.62 36 0.47 0.201 0.000 0.031 1.028 0.275 0.000 0.931 1.911 0.000 0.026 0.030 0.000 0.456 0.067 0.056 0.187 0.009 0.178 0.000 4.959 0.000 0.121 4.959 36 223 12 12 5.1 17.3323 27.6 8.248 35.8 2276.9 24.8739 6.67 292.5 11 19.0 -99.0000 0 6.596 289.5 0 0.0 0 30.90 0 0.64 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 222 11 11 10.0 12.6903 53.3 0.738 17.7 2292.0 27.0132 4.90 214.3 11 13.7 -99.0000 0 5.091 222.8 0 13.5 0 45.10 0 1.44 0 0.81 6 0.42 0.016 0.000 0.006 0.110 0.024 0.000 0.078 0.307 0.000 0.008 0.003 0.000 0.026 0.018 0.006 0.033 0.000 0.036 0.000 0.689 0.000 0.013 0.689 36 221 10 10 20.2 10.0724 58.7 0.492 2.6 2289.8 28.4195 3.99 174.4 11 10.8 -99.0000 0 4.012 175.3 0 25.3 6 53.80 6 2.22 6 0.55 6 0.22 0.009 0.000 0.000 0.070 0.000 0.000 0.059 0.158 0.000 0.000 0.000 0.000 0.017 0.016 0.000 0.008 0.000 0.000 0.000 0.411 0.000 0.008 0.411 36 220 9 9 30.0 9.8988 58.8 0.403 0.7 2291.0 28.8992 4.16 181.8 11 10.5 -99.0000 0 4.135 180.6 0 25.4 0 54.20 0 2.24 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 219 8 8 39.9 9.7656 58.8 0.336 0.2 2276.4 29.0223 4.12 179.8 11 10.3 -99.0000 0 4.085 178.4 0 26.1 6 54.60 6 2.28 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 218 7 7 50.2 9.5070 57.9 0.267 0.0 2242.0 29.1687 3.99 174.1 11 10.2 -99.0000 0 3.963 173.0 0 27.0 0 55.00 0 2.33 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 217 6 6 75.3 8.7697 56.1 0.161 0.0 2232.9 29.8341 3.67 160.1 11 9.5 -99.0000 0 3.647 159.2 6 28.9 0 51.70 0 2.48 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 216 5 5 100.8 8.8291 55.2 0.153 0.0 2234.5 30.2024 3.58 156.3 11 9.6 -99.0000 0 3.567 155.6 0 29.2 0 51.90 0 2.46 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 215 4 4 126.4 8.7805 54.0 0.153 0.0 2231.2 30.3814 3.51 153.3 11 9.5 -99.0000 0 3.509 153.1 3 29.0 0 54.60 0 2.47 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 214 3 3 150.8 8.7371 53.3 0.153 0.0 2226.9 30.5775 3.39 147.8 11 9.4 -99.0000 0 3.386 147.7 0 29.1 0 59.30 0 2.57 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 213 2 2 174.4 8.7470 52.9 0.153 0.0 2227.7 30.7076 3.21 139.8 11 9.5 30.7222 0 3.148 137.3 6 29.3 0 65.80 0 2.71 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 212 1 1 188.4 8.7876 44.7 0.153 0.0 2228.3 30.8010 3.02 131.5 11 9.5 -99.0000 0 3.014 131.4 0 29.1 0 68.90 0 2.75 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0