*2023/03/19 10:46:31.68 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/09/12 15:52:08.000 TIME INCREMENT : 0 0 0 1 0 ! (day hr min sec ms) NUMBER OF RECORDS : 15 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 5386689D NUMBER OF CHANNELS : 52 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 181 195 2 Bottle_Number n/a 1 15 3 Bottle:Firing_Sequence n/a 1 15 4 Pressure decibar 2 273.2 5 Temperature:Secondary 'deg C (ITS90)' 8.77 17.6447 6 Transmissivity %/metre 29.3 59.6 7 Fluorescence:URU:Wetlabs mg/m^3 0.15 7.69 8 PAR uE/m^2/sec 0 766.3 9 PAR:Reference uE/m^2/sec 1799.9 1888.2 10 Salinity:T1:C1 PSS-78 24.9463 31.0003 11 Oxygen:Dissolved:SBE mL/L 3.03 6.61 12 Oxygen:Dissolved:SBE umol/kg 132 289.8 13 Number_of_bin_records n/a 11 11 14 Temperature:Draw 'deg C (ITS90)' 9.4 18.1 15 Salinity:Bottle PSS-78 31.1272 31.1272 16 Flag:Salinity:Bottle n/a 17 Oxygen:Dissolved mL/L 3.05 6.624 18 Oxygen:Dissolved umol/kg 133 290.6 19 Flag:Oxygen:Dissolved n/a 20 Nitrate_plus_Nitrite umol/L 0.2 29.1 21 Flag:Nitrate_plus_Nitrite n/a 22 Silicate umol/L 31.2 61.7 23 Silicate:Flag n/a 24 Phosphate umol/L 0.47 2.61 25 Flag:Phosphate n/a 26 Chlorophyll:Extracted mg/m^3 0.16 5.24 27 Flag:Chlorophyll:Extracted n/a 28 Phaeo-Pigment:Extracted mg/m^3 0.18 0.51 29 HPLC:Chl-c3 mg/m^3 0 0.108 30 HPLC:Chlide-a mg/m^3 0 0 31 HPLC:MgDVP mg/m^3 0 0.29E-01 32 HPLC:Chl-c2 mg/m^3 0.18E-01 0.618 33 HPLC:Peri mg/m^3 0 0.112 34 HPLC:Pheide-a mg/m^3 0 0.341 35 HPLC:But-fuco mg/m^3 0.12E-01 0.562 36 HPLC:Fuco mg/m^3 0.45E-01 1.261 37 HPLC:Neo mg/m^3 0 0.8E-02 38 HPLC:Pras mg/m^3 0 0.19E-01 39 HPLC:Viola mg/m^3 0 0.23E-01 40 HPLC:Hex-fuco mg/m^3 0 0 41 HPLC:Diadino mg/m^3 0.6E-02 0.286 42 HPLC:Allo mg/m^3 0.14E-01 0.44E-01 43 HPLC:Diato mg/m^3 0 0.19E-01 44 HPLC:Zea mg/m^3 0.7E-02 0.118 45 HPLC:Lut mg/m^3 0 0.6E-02 46 HPLC:Chl-b mg/m^3 0 0.105 47 HPLC:DVChl-a mg/m^3 0 0 48 HPLC:Chl-a mg/m^3 0.145 3.367 49 HPLC:Phe mg/m^3 0 0 50 HPLC:B-Car mg/m^3 0 0.5E-02 51 HPLC:TChl-a mg/m^3 0.145 3.367 52 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 5 I I 0 14 -99 ' ' 6 F R4 1 15 -99 ' ' 9 F R4 4 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 -99 ' ' 6 F ' ' 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 6 F R4 1 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-10 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 2 EVENT NUMBER : 55 LATITUDE : 49 24.09000 N ! (deg min) LONGITUDE : 124 9.30000 W ! (deg min) WATER DEPTH : 279 ALTIMETER (M) : 5.4 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $REMARKS SOFTWARE VERSION SEASAVE V 7.21D $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2012/03/02 08:57:46 165 165 CLEAN 5.0.4 2012/03/02 08:58:05 ? ? ADDSAMP 3.5 2012/03/02 09:17:15 165 165 BINAVE 4.1.1 2012/03/02 09:17:41 165 15 MERGE 3.4 2012/03/02 14:21:31 15 15 CLEAN 5.0.4 2012/03/02 17:29:13 15 15 CALIB 11.7 2012/03/05 09:18:19 15 15 SORT 3.5 2012/03/05 10:43:11 15 15 REMOVECH 8.1.1 2012/03/05 10:43:39 15 15 CHGUNITS 3.0 2012/03/05 10:45:00 15 15 CHGUNITS 3.0 2012/03/05 10:45:17 15 15 REORDER 1.3 2012/03/05 10:47:44 ? ? HDREDIT2 2.5.1 2012/03/05 10:55:47 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:34 15 15 CHANGE_FLAGS 2.0 2014/11/20 09:57:34 15 15 Silicate_Correction 1.0 2018/02/20 14:43:25 15 15 SORT 3.6 2020/11/30 15:44:13 15 15 REORDER 1.3.1 2021/11/25 10:38:45 ? ? MERGE 3.5.1 2021/11/25 10:39:00 15 15 SORT 3.6 2021/11/25 10:39:42 15 15 CLEAN 5.2.4 2021/11/25 10:39:52 15 15 HDREDIT2 3.2 2021/11/25 10:40:19 ? ? HDREDIT2 3.2 2021/11/25 10:40:43 ? ? Silicate_Modification 1.2 2023/03/19 10:46:31 15 15 $END $REMARKS -CLEAN functions: 2012/03/02 08:58:04 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-10\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2012/03/02 14:21:30 2012/03/02 14:21:30 2012/03/02 14:21: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0055.samavg Secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0055.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0055.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2012/03/02 14:21:25 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2012/03/02 17:29:12 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/03/05 09:18:19 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-10\Processing\doc\2011-10-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.6100000E-01 0.1000000E+01 -SORT parameters: 2012/03/05 10:43:11 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/03/05 10:43:39 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/03/05 10:55:47 Applied edit header: P:\Cruise_Data_Processing\2011-10\Processing\doc\2011-10-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Channel 20: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 25: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 27: Phosphate [umol/L] Units: ==> umol/L Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -SORT parameters: 2020/11/30 15:44:13 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 10:39:00 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\ IOS\2011-010-0055.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\ IOS\2011-010-0055.hplc -SORT parameters: 2021/11/25 10:39:42 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 10:39:50 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 10:40:19 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 14: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 Channel 31: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 24: Silicate:Corrected [umol/L] Format: F6.1 ==> F7.2 -HEADER EDITS: 2021/11/25 10:40:43 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010-bot-hdr2.txt $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 2, Sample Number: 195, Silicate corrected using CTD salinity. ===================================================================================== Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0055.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0055.sal ------------------------------------------------------------------- Sample_Number 182: SAL: No liner, screw cap only; severe outlier in comparison with CTD salinity. Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0055.nut ------------------------------------------------------------------- Sample_Number 185: PO4: Poor duplicate Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours n the lab ~1 week after collection and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2011-10_CHL-*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-010_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2011-10oxy*.xls. Salinity samples were collected in 200mL type II glass bottles with disposable plastic inserts and screw cap supplied by Ocean Scientific International Ltd. They were analyzed in a temperature-controlled lab on a Guildline 8400B salinometer standardized with IAPSO standard seawater 4 months after collection. Full results including a duplicate analysis , see file QF2011-10sal*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. They were later analysed at IOS using an Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). For precision and duplicate details see worksheets in file QF2011-10nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- The SBE data are considered of lower quality than normal because 24 scans were averaged in acquisition. These averages may contain spikes that would normally be removed in processing. Given the casts are mostly from areas that are not particularly prone to extremely noisy CTD descent rates, and the CTD is believed to have worked well with few spikes, it is likely the errors caused by this problems are are small. The effects on the bottle files are considered less serious than those on the full profile files. Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-10-proc.doc. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\IOS\2011-010-0055. hplc --------------------------------------------------------------------------- Sample_Number 192: HPLC: one rep discarded due to low numbers of measurable pigments, But-fuco value possibly unknown peak Sample_Number 193: HPLC: But-fuco value possibly unknown peak Sample_Number 195: HPLC: >10%CV for TChl-a, But-fuco value likely unknown peak *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.61E-01 1) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10--- --11-- --12- -13- --14- ---15--- 16 ---17-- --18- 19 --20- 21 --22-- 23 --24-- 25 --26-- 27 --28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- 52 !Samp Bott Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silica Si Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: Refere :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag te li ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: nce Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~: ~p Extrac ~a t: a a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw tt lved lv Nitri ri Fl ha ted ct Extrac HP ! ence SBE SBE ords le ed te te ag te ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 195 15 15 2.0 17.6447 31.4 4.454 766.3 1888.2 24.9463 6.61 289.8 11 18.1 -99.0000 0 6.624 290.6 0 0.2 0 31.20 0 0.47 0 5.24 6 0.51 0.108 0.000 0.029 0.618 0.112 0.341 0.562 1.261 0.000 0.018 0.023 0.000 0.286 0.021 0.019 0.118 0.006 0.105 0.000 3.367 0.000 0.000 3.367 36 194 14 14 4.9 17.0113 29.3 7.690 104.3 1883.1 25.2122 6.39 280.4 11 17.5 -99.0000 0 6.375 279.6 0 1.4 0 34.10 0 0.63 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 193 13 13 9.5 12.9697 51.9 1.121 8.9 1876.3 26.5735 4.72 206.8 11 12.9 -99.0000 0 4.576 200.3 0 17.4 0 47.30 0 1.64 0 0.73 6 0.40 0.009 0.000 0.008 0.064 0.004 0.000 0.032 0.170 0.008 0.019 0.003 0.000 0.014 0.044 0.002 0.035 0.000 0.085 0.000 0.632 0.000 0.000 0.632 36 192 12 12 20.1 10.2678 59.6 0.275 0.8 1873.6 28.4645 4.07 178.0 11 10.7 -99.0000 0 4.066 177.7 6 24.8 0 53.20 0 2.18 0 0.16 6 0.18 0.000 0.000 0.000 0.018 0.000 0.000 0.012 0.045 0.000 0.000 0.000 0.000 0.006 0.014 0.000 0.007 0.000 0.000 0.000 0.145 0.000 0.005 0.145 3 191 11 11 30.4 9.5900 58.8 0.219 0.2 1866.7 29.0200 3.97 173.5 11 10.1 -99.0000 0 3.984 174.0 0 26.7 6 54.30 6 2.32 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 190 10 10 40.0 9.4429 58.0 0.200 0.0 1858.2 29.1616 3.94 172.2 11 10.0 -99.0000 0 3.942 172.1 0 27.6 0 54.30 0 2.38 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 189 9 9 49.6 9.2375 57.5 0.186 0.0 1854.6 29.4397 3.85 167.9 11 9.9 -99.0000 0 3.853 168.2 0 27.5 0 47.90 0 2.31 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 188 8 8 73.8 8.9231 56.7 0.153 0.0 1852.5 29.8882 3.73 162.6 11 9.5 -99.0000 0 3.731 162.8 0 28.6 0 48.50 0 2.36 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 187 7 7 99.9 8.8268 55.7 0.153 0.0 1847.2 30.2736 3.72 162.2 11 9.5 -99.0000 0 3.739 163.1 0 28.3 0 49.40 0 2.35 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 186 6 6 124.1 8.7816 55.1 0.153 0.0 1838.2 30.4022 3.66 159.5 11 9.4 -99.0000 0 3.663 159.8 0 28.5 0 51.60 0 2.40 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 185 5 5 149.9 8.7918 54.4 0.153 0.0 1832.9 30.5630 3.49 152.0 11 9.5 -99.0000 0 3.470 151.3 0 28.8 6 55.10 6 2.53 36 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 184 4 4 175.0 8.7700 55.0 0.153 0.0 1827.8 30.6985 3.37 147.0 11 9.5 -99.0000 0 3.382 147.5 6 29.1 0 57.00 0 2.53 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 183 3 3 199.7 8.8253 54.4 0.150 0.0 1820.4 30.8038 3.20 139.5 11 9.5 -99.0000 0 3.206 139.8 0 29.1 0 60.30 0 2.61 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 182 2 2 249.9 8.8202 50.1 0.153 0.0 1810.6 30.9302 3.08 134.1 11 9.5 31.1272 4 3.063 133.6 0 29.0 0 61.70 0 2.61 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 181 1 1 273.2 8.8388 43.9 0.153 0.0 1799.9 31.0003 3.03 132.0 11 9.5 -99.0000 0 3.050 133.0 0 29.1 0 61.20 0 2.60 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0