*2021/11/25 10:40:43.20 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/09/12 03:28:06.000 TIME INCREMENT : 0 0 0 1 0 ! (day hr min sec ms) NUMBER OF RECORDS : 15 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 765E5003 NUMBER OF CHANNELS : 58 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 133 147 2 Bottle_Number n/a 1 15 3 Bottle:Firing_Sequence n/a 1 15 4 Pressure decibar 2.4 312.5 5 Temperature:Secondary 'deg C (ITS90)' 8.8707 17.4526 6 Transmissivity %/metre 25.9 55.6 7 Fluorescence:URU:Wetlabs mg/m^3 0.153 7.884 8 PAR uE/m^2/sec 0 0.7 9 PAR:Reference uE/m^2/sec 9.3 9.3 10 Salinity:T1:C1 PSS-78 23.4528 31.0605 11 Oxygen:Dissolved:SBE mL/L 2.98 6.4 12 Oxygen:Dissolved:SBE umol/kg 129.7 280.9 13 Number_of_bin_records n/a 11 11 14 Temperature:Draw 'deg C (ITS90)' 9.4 17.9 15 Salinity:Bottle PSS-78 30.9698 30.9698 16 Flag:Salinity:Bottle n/a 17 Oxygen:Dissolved mL/L 2.992 6.233 18 Oxygen:Dissolved umol/kg 130.4 273.7 19 Flag:Oxygen:Dissolved n/a 20 Nitrate_plus_Nitrite umol/L 1.7 29.3 21 Flag:Nitrate_plus_Nitrite n/a 22 Silicate umol/L 34.8 56.8 23 Flag:Silicate n/a 24 Phosphate umol/L 0.59 2.56 25 Flag:Phosphate n/a 26 Carbon:Dissolved:Inorganic umol/kg 1576.03 2108.98 27 Flag:Carbon:Dissolved:Inorganic n/a 28 Alkalinity:Total umol/kg 1750.8 2141.5 29 Flag:Alkalinity:Total n/a 30 pH n/a 7.4 8.07 31 Flag:pH ' ' 32 Chlorophyll:Extracted mg/m^3 0.25 9.28 33 Flag:Chlorophyll:Extracted n/a 34 Phaeo-Pigment:Extracted mg/m^3 0.26 0.42 35 HPLC:Chl-c3 mg/m^3 0 0.283 36 HPLC:Chlide-a mg/m^3 0 0.33E-01 37 HPLC:MgDVP mg/m^3 0 0.52E-01 38 HPLC:Chl-c2 mg/m^3 0.23E-01 1.5 39 HPLC:Peri mg/m^3 0 0.169 40 HPLC:Pheide-a mg/m^3 0 0.392 41 HPLC:But-fuco mg/m^3 0.13E-01 1.254 42 HPLC:Fuco mg/m^3 0.103 3.457 43 HPLC:Neo mg/m^3 0 0 44 HPLC:Pras mg/m^3 0 0.19E-01 45 HPLC:Viola mg/m^3 0 0.24E-01 46 HPLC:Hex-fuco mg/m^3 0 0 47 HPLC:Diadino mg/m^3 0.8E-02 0.507 48 HPLC:Allo mg/m^3 0.9E-02 0.44E-01 49 HPLC:Diato mg/m^3 0 0.19E-01 50 HPLC:Zea mg/m^3 0.1E-01 0.7E-01 51 HPLC:Lut mg/m^3 0 0 52 HPLC:Chl-b mg/m^3 0 0.104 53 HPLC:DVChl-a mg/m^3 0 0 54 HPLC:Chl-a mg/m^3 0.22 7.865 55 HPLC:Phe mg/m^3 0 0 56 HPLC:B-Car mg/m^3 0 0.38E-01 57 HPLC:TChl-a mg/m^3 0.22 7.898 58 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 5 I I 0 14 -99 ' ' 6 F R4 1 15 -99 ' ' 9 F R4 4 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 -99 ' ' 6 F ' ' 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 6 F R4 1 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 6 F R4 1 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 1 29 -99 ' ' 3 NQ C ' ' 30 -99 ' ' 8 F R4 4 31 -99 ' ' 3 NQ C ' ' 32 -99 ' ' 7 F R4 2 33 -99 ' ' 3 NQ C ' ' 34 -99 ' ' 7 F R4 2 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 8 F R4 3 58 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-10 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 42 EVENT NUMBER : 43 LATITUDE : 49 1.80000 N ! (deg min) LONGITUDE : 123 26.19000 W ! (deg min) WATER DEPTH : 320 ALTIMETER (M) : 9.01 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $REMARKS SOFTWARE VERSION SEASAVE V 7.21D $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2012/03/02 08:57:46 165 165 CLEAN 5.0.4 2012/03/02 08:58:05 ? ? ADDSAMP 3.5 2012/03/02 09:17:15 165 165 BINAVE 4.1.1 2012/03/02 09:17:41 165 15 MERGE 3.4 2012/03/02 14:21:31 15 15 CLEAN 5.0.4 2012/03/02 17:29:13 15 15 CALIB 11.7 2012/03/05 09:18:19 15 15 SORT 3.5 2012/03/05 10:43:11 15 15 REMOVECH 8.1.1 2012/03/05 10:43:39 15 15 CHGUNITS 3.0 2012/03/05 10:44:59 15 15 CHGUNITS 3.0 2012/03/05 10:45:17 15 15 REORDER 1.3 2012/03/05 10:47:44 ? ? HDREDIT2 2.5.1 2012/03/05 10:55:47 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:34 15 15 CHANGE_FLAGS 2.0 2014/11/20 09:57:34 15 15 SORT 3.6 2016/11/29 13:19:53 15 15 MERGE 3.5 2016/12/14 13:29:31 15 15 SORT 3.6 2018/05/31 11:22:46 15 15 CLEAN 5.2.3 2018/05/31 11:23:04 15 15 CLEAN 5.2.3 2018/05/31 11:23:14 15 15 HDREDIT2 3.1.1 2018/05/31 15:45:25 ? ? SORT 3.6 2020/11/30 15:44:13 15 15 REORDER 1.3.1 2021/11/25 10:38:45 ? ? MERGE 3.5.1 2021/11/25 10:39:00 15 15 SORT 3.6 2021/11/25 10:39:42 15 15 CLEAN 5.2.4 2021/11/25 10:39:52 15 15 HDREDIT2 3.2 2021/11/25 10:40:19 ? ? HDREDIT2 3.2 2021/11/25 10:40:43 ? ? $END $REMARKS -CLEAN functions: 2012/03/02 08:58:04 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-10\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2012/03/02 14:21:30 2012/03/02 14:21:30 2012/03/02 14:21: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0043.samavg Secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0043.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0043.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2012/03/02 14:21:25 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2012/03/02 17:29:12 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/03/05 09:18:19 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-10\Processing\doc\2011-10-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.6100000E-01 0.1000000E+01 -SORT parameters: 2012/03/05 10:43:11 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/03/05 10:43:39 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/03/05 10:55:47 Applied edit header: P:\Cruise_Data_Processing\2011-10\Processing\doc\2011-10-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Channel 20: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 25: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 27: Phosphate [umol/L] Units: ==> umol/L Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -SORT parameters: 2016/11/29 13:19:53 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2016/12/14 13:29:31 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : C:\DATA\Debby\2011-10-0043.chesort Secondary file: C:\DATA\Debby\2011-10-0043.dic -SORT parameters: 2018/05/31 11:22:46 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/05/31 11:23:04 20 Reset #RECS, MIN & MAX values in header. Change character data from "2" to "0" Delete Empty Channels: 0 deleted. -CLEAN functions: 2018/05/31 11:23:13 20 Change character data from " " to "0" -HEADER EDITS: 2018/05/31 15:45:25 Applied edit header: P:\Cruise_Data_Processing\Ianson-carbon\2011-10\Processing\2011-10-hdr.txt Channel 1: Sample_Number [n/a] Pad: -99 ==> -9 Channel 30: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 31: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 32: Flag:Alkalinity:Total [n/a] Units: ==> n/a Channel 14: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 -SORT parameters: 2020/11/30 15:44:13 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 10:39:00 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\ IOS\2011-010-0043.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\ IOS\2011-010-0043.hplc -SORT parameters: 2021/11/25 10:39:42 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 10:39:50 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 10:40:19 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 35: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 57: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 30: pH [n/a] Format: F7.2 ==> F8.4 -HEADER EDITS: 2021/11/25 10:40:43 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010-bot-hdr2.txt $END *COMMENTS Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0043.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-10\Processing\hydro\2011-10-0043.oxy ------------------------------------------------------------------- Sample_Number 136: OXY: Spigot dripping Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours n the lab ~1 week after collection and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2011-10_CHL-*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-010_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2011-10oxy*.xls. Salinity samples were collected in 200mL type II glass bottles with disposable plastic inserts and screw cap supplied by Ocean Scientific International Ltd. They were analyzed in a temperature-controlled lab on a Guildline 8400B salinometer standardized with IAPSO standard seawater 4 months after collection. Full results including a duplicate analysis , see file QF2011-10sal*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. They were later analysed at IOS using an Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). For precision and duplicate details see worksheets in file QF2011-10nuts*.xls. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Methods including analysis and quality control are detailed in Dickson et al (1993) and Ianson et al (2007). pH on the total hydrogren ion concentration scale was determined photometrically following methods described in Clayton and Byrne (1993) and is reported at 25C and surface pressure. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. 5. Dickson, A. G., C. L. Sabine, and J. R. Christian (2007), Determination of dissolved organic carbon and total dissolved nitrogen in sea water, PICES Special Publication 3. 6. Ianson, D., Susan E. Allen, Benjamin L. Moore-Maley, Sophia C. Johannessen and Robie W. Macdonald (2016), Vulnerability of a semienclosed estuarine sea to ocean acidification in contrast with hypoxia, Geophys. Res. Lett., 43, 5793-5801, doi:10.1002/2016GL068996. 7. Clayton, T. D., and R. H. Byrne (1993), Spectrophotometric seawater pH measurements: total hydrogen ion concentration scale calibration of m-cresol purple and at-sea results, Deep Sea Res. I, 40, 2115–2129. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- The SBE data are considered of lower quality than normal because 24 scans were averaged in acquisition. These averages may contain spikes that would normally be removed in processing. Given the casts are mostly from areas that are not particularly prone to extremely noisy CTD descent rates, and the CTD is believed to have worked well with few spikes, it is likely the errors caused by this problems are are small. The effects on the bottle files are considered less serious than those on the full profile files. Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-10-proc.doc. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-010_Nov2021\Processing\IOS\2011-010-0043. hplc --------------------------------------------------------------------------- Sample_Number 144: HPLC: But-fuco value likely unknown peak Sample_Number 145: HPLC: >10%CV for TChl-a, But-fuco value likely unknown peak Sample_Number 147: HPLC: But-fuco value likely unknown peak *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.61E-01 1) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10--- --11-- --12- -13- --14- ---15--- 16 ---17-- --18- 19 --20- 21 --22- 23 --24-- 25 ---26-- 27 --28-- 29 ---30-- 31 --32-- 33 --34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- ---57-- 58 !Samp Bott Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silic Fl Phosph Fl Carbon: Fl Alkali Fl pH Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: Refere :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag ate ag ate ag Dissolv ag nity: ag ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: nce Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ed: ~g Total ~T : Extrac ~a t: a a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw tt lved lv Nitri ri ca ha Inorgan an ot pH ted ct Extrac HP ! ence SBE SBE ords le ed te te te te ic ic al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ----- -- ------ -- ------- -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 147 15 15 2.4 17.4526 29.8 7.884 0.7 9.3 23.4528 6.40 280.9 11 17.9 -99.0000 0 6.233 273.7 0 1.7 0 34.8 0 0.59 0 2096.91 3 1750.8 0 8.0700 0 9.28 6 0.42 0.283 0.033 0.052 1.500 0.169 0.392 1.254 3.457 0.000 0.019 0.024 0.000 0.507 0.044 0.019 0.070 0.000 0.104 0.000 7.865 0.000 0.000 7.898 36 146 14 14 5.0 17.3080 31.9 7.049 0.1 9.3 23.4866 6.24 273.8 11 17.7 -99.0000 0 6.085 267.2 0 2.0 0 35.2 0 0.65 0 1576.03 0 1768.0 0 8.0600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 145 13 13 9.8 13.8961 41.2 3.128 0.0 9.3 26.1514 4.78 209.4 11 14.5 -99.0000 0 4.889 214.1 0 12.1 6 42.5 6 1.29 6 1755.91 0 1873.2 0 7.8000 0 3.14 6 0.26 0.117 0.010 0.015 0.553 0.052 0.133 0.407 1.310 0.000 0.002 0.010 0.000 0.154 0.018 0.008 0.026 0.000 0.029 0.000 2.740 0.000 0.038 2.750 36 144 12 12 19.7 10.7458 55.6 0.397 0.0 9.3 28.1833 4.04 176.6 11 11.1 -99.0000 0 4.039 176.5 6 23.9 0 49.7 0 2.07 0 1931.27 0 1956.2 0 7.5000 0 0.25 6 0.33 0.000 0.000 0.000 0.023 0.000 0.000 0.013 0.103 0.000 0.000 0.000 0.000 0.008 0.009 0.000 0.010 0.000 0.000 0.000 0.220 0.000 0.003 0.220 36 143 11 11 39.9 9.8499 54.5 0.211 0.0 9.3 29.2823 3.70 161.5 11 10.4 -99.0000 0 3.665 160.0 0 26.3 0 48.3 0 2.16 0 2002.31 0 2027.3 0 7.4600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 142 10 10 49.9 9.6824 52.9 0.214 0.0 9.3 29.4782 3.63 158.7 11 10.2 -99.0000 0 3.634 158.6 0 26.9 0 47.6 0 2.21 0 2014.27 6 2042.1 6 7.4600 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 141 9 9 75.6 9.6155 51.8 0.183 0.0 9.3 29.7954 3.45 150.6 11 10.1 -99.0000 0 3.441 150.2 0 27.6 0 47.6 0 2.23 0 2031.41 0 2064.6 0 7.4500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 140 8 8 101.1 9.7408 49.9 0.183 0.0 9.3 30.1493 3.26 142.1 11 10.3 -99.0000 0 3.249 141.8 0 27.5 0 49.2 0 2.20 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 139 7 7 125.4 9.4589 46.6 0.180 0.0 9.3 30.3922 3.27 142.4 11 9.9 -99.0000 0 3.314 144.6 0 28.0 0 49.4 0 2.27 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 138 6 6 150.6 8.9586 45.6 0.153 0.0 9.3 30.6285 3.29 143.3 11 9.5 -99.0000 0 3.278 143.0 0 28.6 0 54.7 0 2.44 0 2096.02 0 2107.3 0 7.4200 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 137 5 5 175.6 8.8707 45.4 0.153 0.0 9.3 30.7539 3.24 141.1 11 9.5 -99.0000 0 3.231 140.9 6 28.8 0 55.9 0 2.48 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 136 4 4 201.9 8.9089 41.4 0.153 0.0 9.3 30.8360 3.16 137.6 11 9.4 -99.0000 0 3.133 136.6 3 28.8 6 56.1 6 2.49 6 2100.63 0 2104.8 0 7.4100 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 135 3 3 251.7 8.9276 36.1 0.153 0.0 9.3 30.9614 3.06 133.4 11 9.5 30.9698 0 3.070 133.9 0 29.1 0 56.2 0 2.50 0 2105.18 0 2141.5 0 7.4100 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 134 2 2 302.6 8.9290 30.1 0.186 0.0 9.3 31.0457 2.99 130.5 11 9.5 -99.0000 0 2.992 130.4 0 29.2 0 56.5 0 2.56 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 133 1 1 312.5 8.9349 25.9 0.200 0.0 9.3 31.0605 2.98 129.7 11 9.7 -99.0000 0 3.014 131.4 0 29.3 0 56.8 0 2.55 0 2108.98 0 2131.5 0 7.4000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0