*2020/11/30 15:58:59.99 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/06/24 23:01:45.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 16 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 511DFEA2 NUMBER OF CHANNELS : 55 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 242 257 2 Bottle_Number n/a 1 16 3 Bottle:Firing_Sequence n/a 1 16 4 Pressure decibar 1.7 350 5 Temperature:Secondary 'deg C (ITS90)' 8.1623 17.1724 6 Transmissivity %/metre 19.8 60.4 7 Fluorescence:URU:Wetlabs mg/m^3 0.92E-01 6.87 8 PAR uE/m^2/sec 0 48.3 9 Salinity:T1:C1 PSS-78 18.8445 30.6097 10 Oxygen:Dissolved:SBE mL/L 2.97 10.36 11 Oxygen:Dissolved:SBE umol/kg 129.3 456.5 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 8.2 17.3 14 Oxygen:Dissolved mL/L 3.028 9.986 15 Oxygen:Dissolved umol/kg 132 440 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 0.1 30.8 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 25.4 83.1 20 Flag:Silicate n/a 21 Phosphate umol/L 0.19 2.87 22 Flag:Phosphate n/a 23 Carbon:Dissolved:Inorganic umol/kg 1169.44 2117.7 24 Flag:Carbon:Dissolved:Inorganic n/a 25 Alkalinity:Total umol/kg 1560.3 2118.5 26 Flag:Alkalinity:Total n/a 27 pH n/a 7.31 8.43 28 Flag:pH ' ' 29 Chlorophyll:Extracted mg/m^3 7.04 8.18 30 Flag:Chlorophyll:Extracted n/a 31 Phaeo-Pigment:Extracted mg/m^3 -0.75 0.71 32 HPLC:Chl-c3 mg/m^3 0 0.11E-01 33 HPLC:Chlide-a mg/m^3 0.9E-02 0.49E-01 34 HPLC:MgDVP mg/m^3 0 0.18E-01 35 HPLC:Chl-c2 mg/m^3 0.145 0.545 36 HPLC:Peri mg/m^3 0.25E-01 0.312 37 HPLC:Pheide-a mg/m^3 0 0 38 HPLC:But-fuco mg/m^3 0.1E-01 0.74E-01 39 HPLC:Fuco mg/m^3 0.781 2.602 40 HPLC:Neo mg/m^3 0 0.9E-02 41 HPLC:Pras mg/m^3 0 0.3E-02 42 HPLC:Viola mg/m^3 0.92E-01 0.621 43 HPLC:Hex-fuco mg/m^3 0 0.1E-01 44 HPLC:Diadino mg/m^3 0.5E-02 0.135 45 HPLC:Allo mg/m^3 0.24E-01 0.234 46 HPLC:Diato mg/m^3 0 0.22E-01 47 HPLC:Zea mg/m^3 0.68E-01 0.268 48 HPLC:Lut mg/m^3 0 0.7E-02 49 HPLC:Chl-b mg/m^3 0.1E-01 0.163 50 HPLC:DVChl-a mg/m^3 0 0 51 HPLC:Chl-a mg/m^3 1.869 6.713 52 HPLC:Phe mg/m^3 0 0 53 HPLC:B-Car mg/m^3 0.49E-01 0.238 54 HPLC:TChl-a mg/m^3 1.878 6.762 55 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 1 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 8 F R4 4 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 3 NQ C ' ' 31 -99 ' ' 7 F R4 2 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF SCIENTIST : Chandler P. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 12 EVENT NUMBER : 62 LATITUDE : 49 43.60000 N ! (deg min) LONGITUDE : 124 40.82000 W ! (deg min) WATER DEPTH : 355 ALTIMETER (M) : 6.13 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/12/13 13:20:18 3856 3856 CLEAN 5.0.4 2011/12/13 13:39:12 ? ? ADDSAMP 3.5 2011/12/13 14:40:20 3856 3856 BINAVE 4.1.1 2011/12/13 14:40:37 3856 16 MERGE 3.4 2011/12/19 11:52:18 16 16 CLEAN 5.0.4 2011/12/20 14:44:36 16 16 CALIB 11.7 2012/01/05 11:55:57 16 16 SORT 3.5 2012/01/05 13:25:20 16 16 REMOVECH 8.1.1 2012/01/05 13:26:59 16 16 CHGUNITS 3.0 2012/01/05 13:36:51 16 16 CHGUNITS 3.0 2012/01/05 13:38:03 16 16 REORDER 1.3 2012/01/05 13:39:46 ? ? HDREDIT2 2.5.1 2012/01/05 14:03:31 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:30 16 16 CHANGE_FLAGS 2.0 2014/11/20 09:57:33 16 16 SORT 3.6 2016/11/29 13:19:53 16 16 MERGE 3.5 2016/12/14 13:29:31 16 16 SORT 3.6 2018/05/31 10:40:14 16 16 CLEAN 5.2.3 2018/05/31 10:40:41 16 16 CLEAN 5.2.3 2018/05/31 10:40:51 16 16 HDREDIT2 3.1.1 2018/05/31 15:42:17 ? ? HDREDIT2 3.2 2020/01/22 11:20:50 ? ? SORT 3.6 2020/11/30 15:05:54 16 16 REORDER 1.3.1 2020/11/30 15:08:34 ? ? MERGE 3.5.1 2020/11/30 15:08:44 16 16 SORT 3.6 2020/11/30 15:11:19 16 16 CLEAN 5.2.4 2020/11/30 15:11:31 16 16 HDREDIT2 3.2 2020/11/30 15:58:22 ? ? HDREDIT2 3.2 2020/11/30 15:58:59 ? ? $END $REMARKS -CLEAN functions: 2011/12/13 13:38:51 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/12/19 11:52:17 2011/12/19 11:52:17 2011/12/19 11:52: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0062.samavg Secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0062.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0062.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2011/12/19 11:50:44 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/12/20 14:44:35 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/01/05 11:55:57 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-09\Processing\doc\2011-09-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.3100000E-01 0.1000000E+01 17 Salinity:T0:C0 PSS-78 10 0.8000000E-03 0.1000000E+01 -SORT parameters: 2012/01/05 13:25:20 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/01/05 13:26:59 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR:Reference [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/01/05 14:03:31 Applied edit header: P:\Cruise_Data_Processing\2011-09\Processing\doc\2011-09-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 19: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 22: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 24: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 26: Phosphate [umol/L] Units: ==> umol/L Channel 13: Temperature:Draw [deg C (ITS90)] Format: F9.4 ==> F5.1 Channel 10: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 20: Oxygen:Dissolved [umol/kg] Format: F6.2 ==> F6.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs -SORT parameters: 2016/11/29 13:19:53 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2016/12/14 13:29:31 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : C:\DATA\Debby\2011-09-0062.chesort Secondary file: C:\DATA\Debby\2011-09-0062.dic -SORT parameters: 2018/05/31 10:40:14 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/05/31 10:40:41 20 Reset #RECS, MIN & MAX values in header. Change character data from "2" to "0" Delete Empty Channels: 2 deleted. -CLEAN functions: 2018/05/31 10:40:51 20 Change character data from " " to "0" -HEADER EDITS: 2018/05/31 15:42:17 Applied edit header: P:\Cruise_Data_Processing\Ianson-carbon\2011-09\Processing\2011-09-hdr.txt Channel 1: Sample_Number [n/a] Pad: -99 ==> -9 Channel 27: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 28: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 29: Flag:Alkalinity:Total [n/a] Units: ==> n/a Channel 13: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 -HEADER EDITS: 2020/01/22 11:20:50 Channel 1: Sample_Number [n/a] Pad: -9 ==> -99 Channel 13: Temperature:Draw [deg C (ITS90)] Format: F6.1 ==> F5.1 -SORT parameters: 2020/11/30 15:05:54 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/11/30 15:08:44 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011- 009-0062.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011- 009-0062.hplc -SORT parameters: 2020/11/30 15:11:19 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/11/30 15:11:30 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/11/30 15:58:22 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 17: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 32: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2020/11/30 15:58:59 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009-bot-hdr2.txt $END *COMMENTS Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0062.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0062.sal ------------------------------------------------------------------- Sample_Number 243: Sal: No liner; sample not analyzed Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0062.chl ------------------------------------------------------------------- Sample_Number 255: CHL:variability of replicates >15%CV Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0062.oxy ------------------------------------------------------------------- Sample_Number 245: OXY: Titration incomplete Sample_Number 246: OXY: Titration incomplete Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone for 24 hours in the lab about 1 week after the cruise and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-09CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1-2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-009_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2011-09oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-09-sal*.xls. Nutrient samples were collected in plastic tubes. Samples were stored frozen and later analysed at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-09nuts*.xls" includes the raw data and a precision study. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Methods including analysis and quality control are detailed in Dickson et al (1993) and Ianson et al (2007). pH on the total hydrogren ion concentration scale was determined photometrically following methods described in Clayton and Byrne (1993) and is reported at 25C and surface pressure. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. 5. Dickson, A. G., C. L. Sabine, and J. R. Christian (2007), Determination of dissolved organic carbon and total dissolved nitrogen in sea water, PICES Special Publication 3. 6. Ianson, D., Susan E. Allen, Benjamin L. Moore-Maley, Sophia C. Johannessen and Robie W. Macdonald (2016), Vulnerability of a semienclosed estuarine sea to ocean acidification in contrast with hypoxia, Geophys. Res. Lett., 43, 5793-5801, doi:10.1002/2016GL068996. 7. Clayton, T. D., and R. H. Byrne (1993), Spectrophotometric seawater pH measurements: total hydrogen ion concentration scale calibration of m-cresol purple and at-sea results, Deep Sea Res. I, 40, 2115–2129. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-09-proc.doc. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011-009-0062.hplc --------------------------------------------------------------------------- Sample_Number 254: HPLC: >30%CV for TChl-a Sample_Number 255: HPLC: >30%CV for TChl-a Sample_Number 257: HPLC: >30%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.31E-01 1) Salinity:T0:C0 PSS-78 10 -99 () (0.8E-03 1) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14-- --15- 16 --17-- 18 --19-- 20 ---21-- 22 ---23-- 24 --25-- 26 ---27-- 28 --29-- 30 --31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- 55 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Carbon: Fl Alkali Fl pH Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur Dissolv n: ag e_ ag te ag te ag Dissolv ag nity: ag ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ed Disso ~o plus_ ~t ~i ~p ed: ~g Total ~T : Extrac ~a t: a a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw lved lv Nitrit ri ca ha Inorgan an ot pH ted ct Extrac HP ! ence SBE SBE ords ed e te te te ic ic al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- ------- -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 257 16 16 1.7 17.1724 19.8 6.870 48.3 18.8445 10.36 456.5 241 17.3 9.986 440.0 0 0.10 0 39.70 0 0.290 0 1169.44 0 1560.3 0 -99.0000 9 7.04 6 0.71 0.000 0.049 0.018 0.545 0.312 0.000 0.074 2.602 0.009 0.000 0.621 0.010 0.135 0.234 0.022 0.182 0.007 0.163 0.000 6.713 0.000 0.238 6.762 46 256 15 15 5.5 16.7775 30.4 3.961 2.3 19.8758 9.19 404.7 241 15.9 8.272 364.1 0 0.10 0 33.00 0 0.190 0 1370.72 0 1681.7 0 8.4300 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 255 14 14 10.3 12.6489 40.6 3.879 0.4 26.9771 5.71 249.8 241 12.0 5.638 246.7 0 1.50 0 25.40 0 0.330 0 1826.99 0 1927.0 0 7.8200 0 8.18 36 0.02 0.011 0.009 0.004 0.145 0.025 0.000 0.010 0.781 0.002 0.003 0.092 0.000 0.009 0.031 0.002 0.068 0.000 0.021 0.000 1.869 0.000 0.049 1.878 46 254 13 13 20.5 9.9289 44.2 3.851 0.0 28.8739 4.85 211.9 241 9.7 4.821 210.5 0 20.90 0 40.20 0 1.930 0 1942.74 6 1968.4 6 7.5900 6 8.00 6 -0.75 0.010 0.016 0.000 0.412 0.025 0.000 0.013 2.414 0.000 0.000 0.434 0.000 0.005 0.024 0.000 0.268 0.000 0.010 0.000 4.862 0.000 0.120 4.878 46 253 12 12 30.7 9.3051 50.5 2.601 0.0 29.2814 4.71 205.6 241 9.3 4.741 207.0 6 23.00 6 40.00 6 2.090 6 1960.72 0 2020.1 0 7.5600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 252 11 11 40.8 9.0674 60.0 0.276 0.0 29.4592 4.65 202.8 241 8.9 4.662 203.5 0 24.40 0 42.90 0 2.160 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 251 10 10 50.8 8.7477 60.4 0.181 0.0 29.5746 4.41 192.5 241 8.7 4.428 193.2 0 26.70 0 47.30 0 2.290 0 2002.60 0 2037.3 0 7.4800 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 250 9 9 75.8 8.2561 60.0 0.122 0.0 29.8889 4.24 184.9 241 8.3 4.228 184.5 0 30.00 0 54.10 0 2.550 0 2046.14 0 2038.2 3 7.4100 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 249 8 8 101.3 8.1623 59.3 0.107 0.0 30.0245 4.37 190.8 241 8.2 4.386 191.3 0 29.60 0 53.40 0 2.370 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 248 7 7 125.8 8.1814 58.2 0.105 0.0 30.1967 4.37 190.4 241 8.2 4.379 191.0 0 29.10 0 53.20 0 2.370 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 247 6 6 150.9 8.2405 57.6 0.097 0.0 30.2948 4.32 188.4 241 8.2 4.324 188.6 0 28.70 0 52.80 0 2.360 0 2055.59 0 2083.2 0 7.4500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 246 5 5 175.2 8.3429 56.4 0.096 0.0 30.4043 4.01 174.9 241 8.3 4.038 176.1 0 29.40 6 57.80 6 2.430 6 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 245 4 4 200.7 8.3757 53.0 0.092 0.0 30.4392 3.79 165.5 241 8.3 -99.000 -99.0 5 30.40 0 63.30 0 2.550 0 2071.22 0 2118.5 0 7.3900 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 244 3 3 250.6 8.4915 55.4 0.095 0.0 30.5106 3.66 159.7 241 8.5 3.666 159.9 0 30.30 0 64.90 0 2.680 0 2078.57 0 2048.6 3 7.3800 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 243 2 2 300.7 8.5887 53.7 0.092 0.0 30.5572 3.49 152.1 241 8.6 3.494 152.4 0 30.30 0 67.40 0 2.670 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 242 1 1 350.0 8.7969 39.2 0.129 0.0 30.6097 2.97 129.3 241 8.8 3.028 132.0 0 30.80 0 83.10 0 2.870 0 2117.70 0 2084.5 3 7.3100 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0