*2020/11/30 15:58:58.96 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/06/22 21:41:45.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 841926D9 NUMBER OF CHANNELS : 55 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 51 63 2 Bottle_Number n/a 1 13 3 Bottle:Firing_Sequence n/a 1 13 4 Pressure decibar 2 183.2 5 Temperature:Secondary 'deg C (ITS90)' 6.7617 9.5175 6 Transmissivity %/metre 44.5 53.9 7 Fluorescence:URU:Wetlabs mg/m^3 0.61E-01 1.214 8 PAR uE/m^2/sec 0 1454.7 9 Salinity:T1:C1 PSS-78 31.5414 33.8808 10 Oxygen:Dissolved:SBE mL/L 1.91 4.58 11 Oxygen:Dissolved:SBE umol/kg 83.1 199.8 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 6.9 9.3 14 Oxygen:Dissolved mL/L 1.924 4.66 15 Oxygen:Dissolved umol/kg 83.7 203.1 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 25.3 35 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 40.7 52.4 20 Flag:Silicate n/a 21 Phosphate umol/L 1.97 2.51 22 Flag:Phosphate n/a 23 Carbon:Dissolved:Inorganic umol/kg 2085.93 2247.78 24 Flag:Carbon:Dissolved:Inorganic n/a 25 Alkalinity:Total umol/kg 2087.1 2220.1 26 Flag:Alkalinity:Total n/a 27 pH n/a 7.38 7.56 28 Flag:pH ' ' 29 Chlorophyll:Extracted mg/m^3 1.42 1.59 30 Flag:Chlorophyll:Extracted n/a 31 Phaeo-Pigment:Extracted mg/m^3 0.39 0.43 32 HPLC:Chl-c3 mg/m^3 0.23E-01 0.26E-01 33 HPLC:Chlide-a mg/m^3 0.3E-02 0.12E-01 34 HPLC:MgDVP mg/m^3 0.14E-01 0.19E-01 35 HPLC:Chl-c2 mg/m^3 0.114 0.119 36 HPLC:Peri mg/m^3 0.69E-01 0.94E-01 37 HPLC:Pheide-a mg/m^3 0 0 38 HPLC:But-fuco mg/m^3 0.6E-02 0.1E-01 39 HPLC:Fuco mg/m^3 0.224 0.262 40 HPLC:Neo mg/m^3 0.16E-01 0.19E-01 41 HPLC:Pras mg/m^3 0.21E-01 0.24E-01 42 HPLC:Viola mg/m^3 0.34E-01 0.42E-01 43 HPLC:Hex-fuco mg/m^3 0.5E-02 0.7E-02 44 HPLC:Diadino mg/m^3 0.48E-01 0.66E-01 45 HPLC:Allo mg/m^3 0.1 0.114 46 HPLC:Diato mg/m^3 0.5E-02 0.6E-02 47 HPLC:Zea mg/m^3 0.4E-02 0.7E-02 48 HPLC:Lut mg/m^3 0.7E-02 0.1E-01 49 HPLC:Chl-b mg/m^3 0.165 0.182 50 HPLC:DVChl-a mg/m^3 0 0 51 HPLC:Chl-a mg/m^3 1.126 1.208 52 HPLC:Phe mg/m^3 0 0 53 HPLC:B-Car mg/m^3 0.25E-01 0.29E-01 54 HPLC:TChl-a mg/m^3 1.129 1.215 55 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 1 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 8 F R4 4 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 3 NQ C ' ' 31 -99 ' ' 7 F R4 2 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF SCIENTIST : Chandler P. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 72 EVENT NUMBER : 13 LATITUDE : 48 18.73000 N ! (deg min) LONGITUDE : 124 3.90000 W ! (deg min) WATER DEPTH : 185 ALTIMETER (M) : 3.66 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/12/13 13:20:00 3133 3133 CLEAN 5.0.4 2011/12/13 13:38:55 ? ? CTDEDIT 4.61 2011/12/13 14:22:36 3133 3133 ADDSAMP 3.5 2011/12/13 14:40:03 3133 3133 BINAVE 4.1.1 2011/12/13 14:40:27 3133 13 MERGE 3.4 2011/12/19 11:52:17 13 13 CLEAN 5.0.4 2011/12/20 14:44:35 13 13 CALIB 11.7 2012/01/05 11:55:56 13 13 SORT 3.5 2012/01/05 13:25:19 13 13 REMOVECH 8.1.1 2012/01/05 13:26:59 13 13 CHGUNITS 3.0 2012/01/05 13:36:51 13 13 CHGUNITS 3.0 2012/01/05 13:38:03 13 13 REORDER 1.3 2012/01/05 13:39:45 ? ? HDREDIT2 2.5.1 2012/01/05 14:03:31 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:30 13 13 CHANGE_FLAGS 2.0 2014/11/20 09:57:32 13 13 SORT 3.6 2016/11/29 13:19:53 13 13 MERGE 3.5 2016/12/14 13:29:31 13 13 SORT 3.6 2018/05/31 10:40:14 13 13 CLEAN 5.2.3 2018/05/31 10:40:41 13 13 CLEAN 5.2.3 2018/05/31 10:40:51 13 13 HDREDIT2 3.1.1 2018/05/31 15:42:17 ? ? HDREDIT2 3.2 2020/01/22 11:20:49 ? ? SORT 3.6 2020/11/30 15:05:53 13 13 REORDER 1.3.1 2020/11/30 15:08:32 ? ? MERGE 3.5.1 2020/11/30 15:08:43 13 13 SORT 3.6 2020/11/30 15:11:17 13 13 CLEAN 5.2.4 2020/11/30 15:11:30 13 13 HDREDIT2 3.2 2020/11/30 15:58:21 ? ? HDREDIT2 3.2 2020/11/30 15:58:58 ? ? $END $REMARKS -CLEAN functions: 2011/12/13 13:38:51 20 Set event to last 4 characters of file name -CTDEDIT 2011/12/13 14:22:36 5 changes in channel Salinity:T1:C1 -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/12/19 11:52:17 2011/12/19 11:52:17 2011/12/19 11:52: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0013.samavg Secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0013.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0013.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2011/12/19 11:50:44 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/12/20 14:44:35 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/01/05 11:55:56 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-09\Processing\doc\2011-09-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.3100000E-01 0.1000000E+01 17 Salinity:T0:C0 PSS-78 10 0.8000000E-03 0.1000000E+01 -SORT parameters: 2012/01/05 13:25:19 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/01/05 13:26:59 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR:Reference [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/01/05 14:03:31 Applied edit header: P:\Cruise_Data_Processing\2011-09\Processing\doc\2011-09-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 19: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 22: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 24: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 26: Phosphate [umol/L] Units: ==> umol/L Channel 13: Temperature:Draw [deg C (ITS90)] Format: F9.4 ==> F5.1 Channel 10: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 20: Oxygen:Dissolved [umol/kg] Format: F6.2 ==> F6.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs -SORT parameters: 2016/11/29 13:19:53 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2016/12/14 13:29:31 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : C:\DATA\Debby\2011-09-0013.chesort Secondary file: C:\DATA\Debby\2011-09-0013.dic -SORT parameters: 2018/05/31 10:40:14 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/05/31 10:40:41 20 Reset #RECS, MIN & MAX values in header. Change character data from "2" to "0" Delete Empty Channels: 2 deleted. -CLEAN functions: 2018/05/31 10:40:51 20 Change character data from " " to "0" -HEADER EDITS: 2018/05/31 15:42:17 Applied edit header: P:\Cruise_Data_Processing\Ianson-carbon\2011-09\Processing\2011-09-hdr.txt Channel 1: Sample_Number [n/a] Pad: -99 ==> -9 Channel 27: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 28: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 29: Flag:Alkalinity:Total [n/a] Units: ==> n/a Channel 13: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 -HEADER EDITS: 2020/01/22 11:20:49 Channel 1: Sample_Number [n/a] Pad: -9 ==> -99 Channel 13: Temperature:Draw [deg C (ITS90)] Format: F6.1 ==> F5.1 -SORT parameters: 2020/11/30 15:05:53 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/11/30 15:08:43 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011- 009-0013.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011- 009-0013.hplc -SORT parameters: 2020/11/30 15:11:17 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/11/30 15:11:30 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/11/30 15:58:21 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 17: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 32: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2020/11/30 15:58:58 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009-bot-hdr2.txt $END *COMMENTS CTDEDIT was used to clean a few points in the secondary salinity. Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0013.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0013.sal ------------------------------------------------------------------- Sample_Number 52: Sal: No liner or cap; open sample; not analyzed Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0013.oxy ------------------------------------------------------------------- Sample_Number 53: OXY: Niskin bottle empty Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0013.nut ------------------------------------------------------------------- Sample_Number 53: ALL: no sample - niskin did not close Sample_Number 62: NUTS: no sample collected Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone for 24 hours in the lab about 1 week after the cruise and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-09CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1-2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-009_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2011-09oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-09-sal*.xls. Nutrient samples were collected in plastic tubes. Samples were stored frozen and later analysed at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-09nuts*.xls" includes the raw data and a precision study. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Methods including analysis and quality control are detailed in Dickson et al (1993) and Ianson et al (2007). pH on the total hydrogren ion concentration scale was determined photometrically following methods described in Clayton and Byrne (1993) and is reported at 25C and surface pressure. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. 5. Dickson, A. G., C. L. Sabine, and J. R. Christian (2007), Determination of dissolved organic carbon and total dissolved nitrogen in sea water, PICES Special Publication 3. 6. Ianson, D., Susan E. Allen, Benjamin L. Moore-Maley, Sophia C. Johannessen and Robie W. Macdonald (2016), Vulnerability of a semienclosed estuarine sea to ocean acidification in contrast with hypoxia, Geophys. Res. Lett., 43, 5793-5801, doi:10.1002/2016GL068996. 7. Clayton, T. D., and R. H. Byrne (1993), Spectrophotometric seawater pH measurements: total hydrogen ion concentration scale calibration of m-cresol purple and at-sea results, Deep Sea Res. I, 40, 2115–2129. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-09-proc.doc. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011-009-0013.hplc --------------------------------------------------------------------------- Sample_Number 61: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.31E-01 1) Salinity:T0:C0 PSS-78 10 -99 () (0.8E-03 1) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14-- --15- 16 --17-- 18 --19-- 20 ---21-- 22 ---23-- 24 --25-- 26 ---27-- 28 --29-- 30 --31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- 55 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Carbon: Fl Alkali Fl pH Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur Dissolv n: ag e_ ag te ag te ag Dissolv ag nity: ag ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ed Disso ~o plus_ ~t ~i ~p ed: ~g Total ~T : Extrac ~a t: a a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw lved lv Nitrit ri ca ha Inorgan an ot pH ted ct Extrac HP ! ence SBE SBE ords ed e te te te ic ic al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- ------- -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 63 13 13 2.0 9.5175 44.5 0.692 1454.7 31.5414 4.58 199.7 241 9.3 4.636 202.0 0 25.30 0 40.70 0 1.970 0 2085.93 0 2087.1 3 7.5600 0 1.59 6 0.39 0.023 0.003 0.014 0.114 0.090 0.000 0.008 0.224 0.016 0.021 0.034 0.007 0.060 0.100 0.005 0.004 0.007 0.182 0.000 1.126 0.000 0.026 1.129 6 62 12 12 5.1 9.4995 44.5 0.877 663.3 31.5423 4.57 199.0 241 9.3 4.660 203.1 0 -99.00 9 -99.00 9 -99.000 9 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 61 11 11 10.0 9.5003 44.5 1.114 221.2 31.5419 4.58 199.8 241 9.2 4.603 200.6 6 25.40 6 40.70 6 2.070 6 2088.77 0 2153.9 0 7.5500 0 1.48 6 0.43 0.023 0.012 0.017 0.118 0.094 0.000 0.006 0.238 0.019 0.024 0.042 0.005 0.066 0.114 0.006 0.007 0.010 0.179 0.000 1.181 0.000 0.029 1.193 36 60 10 10 20.1 9.3355 45.0 1.214 41.0 31.5747 4.42 192.6 241 9.1 4.481 195.3 0 25.60 0 40.80 0 2.020 0 -99.00 9 -99.0 9 -99.0000 9 1.42 6 0.41 0.026 0.007 0.019 0.119 0.069 0.000 0.010 0.262 0.017 0.023 0.035 0.006 0.048 0.114 0.005 0.005 0.007 0.165 0.000 1.208 0.000 0.025 1.215 6 59 9 9 30.4 8.8895 48.6 0.677 5.8 31.7215 3.98 173.5 241 8.7 4.054 176.6 0 26.10 0 41.40 0 2.120 0 2104.75 0 2131.1 0 7.5200 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 58 8 8 39.9 8.5936 49.3 0.472 1.6 31.9795 3.72 162.1 241 8.5 3.753 163.5 0 27.10 0 42.10 0 2.090 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 57 7 7 50.9 8.3855 50.9 0.350 0.3 32.2258 3.54 154.0 241 8.3 3.569 155.4 0 27.90 0 42.40 0 2.130 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 56 6 6 74.8 7.7792 53.9 0.135 0.0 32.9055 2.96 129.1 241 7.8 3.089 134.5 0 29.90 0 42.70 0 2.180 0 2177.82 0 2213.0 0 7.4600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 55 5 5 100.3 7.1287 51.8 0.097 0.0 33.6190 2.23 97.2 241 7.2 2.275 99.0 0 32.70 0 47.00 0 2.370 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 54 4 4 126.3 6.7654 52.6 0.066 0.0 33.8784 1.91 83.1 241 6.9 1.924 83.7 0 34.90 0 52.20 0 2.480 0 2246.31 0 2213.0 3 7.3800 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 53 3 3 149.8 6.7649 51.9 0.061 0.0 33.8796 1.91 83.2 241 -99.0 -99.000 -99.0 9 -99.00 9 -99.00 9 -99.000 9 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 52 2 2 175.6 6.7617 51.0 0.061 0.0 33.8808 1.91 83.3 241 6.9 1.936 84.2 6 35.00 6 52.40 6 2.480 6 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 51 1 1 183.2 6.7632 52.2 0.061 0.0 33.8807 1.92 83.7 241 6.9 1.946 84.6 0 35.00 0 52.30 0 2.510 0 2247.78 0 2220.1 3 7.3800 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0