*2020/11/30 15:58:58.75 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/06/22 04:40:09.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 14 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : BB7CDD6 NUMBER OF CHANNELS : 57 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 10 23 2 Bottle_Number n/a 1 14 3 Bottle:Firing_Sequence n/a 1 14 4 Pressure decibar 1.4 227.4 5 Temperature:Secondary 'deg C (ITS90)' 8.2113 9.719 6 Transmissivity %/metre 21.3 45.3 7 Fluorescence:URU:Wetlabs mg/m^3 0.287 2.473 8 PAR uE/m^2/sec 0 0.4 9 Salinity:T1:C1 PSS-78 29.9168 32.291 10 Oxygen:Dissolved:SBE mL/L 3.31 4.93 11 Oxygen:Dissolved:SBE umol/kg 144 215.3 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 8.1 9.5 14 Salinity:Bottle PSS-78 32.32 32.32 15 Flag:Salinity:Bottle n/a 16 Oxygen:Dissolved mL/L 3.292 4.922 17 Oxygen:Dissolved umol/kg 143.4 214.8 18 Flag:Oxygen:Dissolved n/a 19 Nitrate_plus_Nitrite umol/L 20.6 28.2 20 Flag:Nitrate_plus_Nitrite n/a 21 Silicate umol/L 38.7 43.9 22 Flag:Silicate n/a 23 Phosphate umol/L 1.7 2.3 24 Flag:Phosphate n/a 25 Carbon:Dissolved:Inorganic umol/kg 2006.84 2155.87 26 Flag:Carbon:Dissolved:Inorganic n/a 27 Alkalinity:Total umol/kg 2077.4 2198.9 28 Flag:Alkalinity:Total n/a 29 pH n/a 7.47 7.62 30 Flag:pH ' ' 31 Chlorophyll:Extracted mg/m^3 2.9 8.97 32 Flag:Chlorophyll:Extracted n/a 33 Phaeo-Pigment:Extracted mg/m^3 -0.51 0.34 34 HPLC:Chl-c3 mg/m^3 0 0.13E-01 35 HPLC:Chlide-a mg/m^3 0.9E-02 0.35E-01 36 HPLC:MgDVP mg/m^3 0.11E-01 0.19E-01 37 HPLC:Chl-c2 mg/m^3 0.134 0.24 38 HPLC:Peri mg/m^3 0.45E-01 0.61E-01 39 HPLC:Pheide-a mg/m^3 0 0 40 HPLC:But-fuco mg/m^3 0 0.14E-01 41 HPLC:Fuco mg/m^3 0.56 1.008 42 HPLC:Neo mg/m^3 0 0.6E-02 43 HPLC:Pras mg/m^3 0 0.8E-02 44 HPLC:Viola mg/m^3 0.121 0.223 45 HPLC:Hex-fuco mg/m^3 0 0 46 HPLC:Diadino mg/m^3 0.16E-01 0.27E-01 47 HPLC:Allo mg/m^3 0.24E-01 0.5E-01 48 HPLC:Diato mg/m^3 0 0.3E-02 49 HPLC:Zea mg/m^3 0.15E-01 0.38E-01 50 HPLC:Lut mg/m^3 0 0 51 HPLC:Chl-b mg/m^3 0.31E-01 0.58E-01 52 HPLC:DVChl-a mg/m^3 0 0 53 HPLC:Chl-a mg/m^3 1.42 2.808 54 HPLC:Phe mg/m^3 0 0 55 HPLC:B-Car mg/m^3 0.24E-01 0.52E-01 56 HPLC:TChl-a mg/m^3 1.429 2.843 57 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 9 F R4 4 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 1 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 8 F R4 4 30 -99 ' ' 3 NQ C ' ' 31 -99 ' ' 7 F R4 2 32 -99 ' ' 3 NQ C ' ' 33 -99 ' ' 7 F R4 2 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF SCIENTIST : Chandler P. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 59 EVENT NUMBER : 3 LATITUDE : 48 37.84000 N ! (deg min) LONGITUDE : 123 14.59000 W ! (deg min) WATER DEPTH : 234 ALTIMETER (M) : 5.93 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $REMARKS SOFTWARE VERSION SEASAVE V 7.21B $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/12/13 13:19:56 3374 3374 CLEAN 5.0.4 2011/12/13 13:38:51 ? ? ADDSAMP 3.5 2011/12/13 14:40:00 3374 3374 BINAVE 4.1.1 2011/12/13 14:40:25 3374 14 MERGE 3.4 2011/12/19 11:52:17 14 14 CLEAN 5.0.4 2011/12/20 14:44:35 14 14 CALIB 11.7 2012/01/05 11:55:56 14 14 SORT 3.5 2012/01/05 13:25:19 14 14 REMOVECH 8.1.1 2012/01/05 13:26:59 14 14 CHGUNITS 3.0 2012/01/05 13:36:51 14 14 CHGUNITS 3.0 2012/01/05 13:38:03 14 14 REORDER 1.3 2012/01/05 13:39:45 ? ? HDREDIT2 2.5.1 2012/01/05 14:03:30 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:30 14 14 CHANGE_FLAGS 2.0 2014/11/20 09:57:32 14 14 SORT 3.6 2016/11/29 13:19:53 14 14 MERGE 3.5 2016/12/14 13:29:31 14 14 SORT 3.6 2018/05/31 10:40:13 14 14 CLEAN 5.2.3 2018/05/31 10:40:41 14 14 CLEAN 5.2.3 2018/05/31 10:40:51 14 14 HDREDIT2 3.1.1 2018/05/31 15:42:17 ? ? HDREDIT2 3.2 2020/01/22 11:20:48 ? ? SORT 3.6 2020/11/30 15:05:53 14 14 REORDER 1.3.1 2020/11/30 15:08:32 ? ? MERGE 3.5.1 2020/11/30 15:08:43 14 14 SORT 3.6 2020/11/30 15:11:17 14 14 CLEAN 5.2.4 2020/11/30 15:11:30 14 14 HDREDIT2 3.2 2020/11/30 15:58:20 ? ? HDREDIT2 3.2 2020/11/30 15:58:58 ? ? $END $REMARKS -CLEAN functions: 2011/12/13 13:38:51 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/12/19 11:52:17 2011/12/19 11:52:17 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0003.samavg Secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0003.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0003.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2011/12/19 11:50:44 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/12/20 14:44:35 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2012/01/05 11:55:56 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-09\Processing\doc\2011-09-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 0.3100000E-01 0.1000000E+01 17 Salinity:T0:C0 PSS-78 10 0.8000000E-03 0.1000000E+01 -SORT parameters: 2012/01/05 13:25:19 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2012/01/05 13:26:59 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR:Reference [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2012/01/05 14:03:30 Applied edit header: P:\Cruise_Data_Processing\2011-09\Processing\doc\2011-09-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 19: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 22: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 24: Silicate [umol/L] Units: ==> umol/L Format: F7.2 ==> F6.1 Channel 26: Phosphate [umol/L] Units: ==> umol/L Channel 13: Temperature:Draw [deg C (ITS90)] Format: F9.4 ==> F5.1 Channel 10: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 20: Oxygen:Dissolved [umol/kg] Format: F6.2 ==> F6.1 Channel 6: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs -SORT parameters: 2016/11/29 13:19:53 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2016/12/14 13:29:31 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : C:\DATA\Debby\2011-09-0003.chesort Secondary file: C:\DATA\Debby\2011-09-0003.dic -SORT parameters: 2018/05/31 10:40:13 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/05/31 10:40:41 Reset #RECS, MIN & MAX values in header. Change character data from "2" to "0" Delete Empty Channels: 0 deleted. -CLEAN functions: 2018/05/31 10:40:51 Change character data from " " to "0" -HEADER EDITS: 2018/05/31 15:42:17 Applied edit header: P:\Cruise_Data_Processing\Ianson-carbon\2011-09\Processing\2011-09-hdr.txt Channel 1: Sample_Number [n/a] Pad: -99 ==> -9 Channel 29: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 30: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 31: Flag:Alkalinity:Total [n/a] Units: ==> n/a Channel 13: Temperature:Draw [deg C (ITS90)] Format: F5.1 ==> F6.1 -HEADER EDITS: 2020/01/22 11:20:48 Channel 1: Sample_Number [n/a] Pad: -9 ==> -99 Channel 13: Temperature:Draw [deg C (ITS90)] Format: F6.1 ==> F5.1 -SORT parameters: 2020/11/30 15:05:53 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/11/30 15:08:43 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011- 009-0003.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011- 009-0003.hplc -SORT parameters: 2020/11/30 15:11:17 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/11/30 15:11:30 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/11/30 15:58:20 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 14: Salinity:Bottle [PSS-78] Format: F7.2 ==> F9.4 Channel 19: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 34: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2020/11/30 15:58:58 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009-bot-hdr2.txt $END *COMMENTS Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0003.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0003.chl ------------------------------------------------------------------- Sample_Number 20: CHL:variability of replicates >15%CV Sample_Number 23: CHL:variability of replicates >15%CV Comments from secondary file: P:\Cruise_Data_Processing\2011-09\Processing\hydro\2011-09-0003.oxy ------------------------------------------------------------------- Sample_Number 11: OXY: Stopper loose/No good; outlier in comparison with CTD Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone for 24 hours in the lab about 1 week after the cruise and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-09CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1-2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-009_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2011-09oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-09-sal*.xls. Nutrient samples were collected in plastic tubes. Samples were stored frozen and later analysed at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-09nuts*.xls" includes the raw data and a precision study. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Methods including analysis and quality control are detailed in Dickson et al (1993) and Ianson et al (2007). pH on the total hydrogren ion concentration scale was determined photometrically following methods described in Clayton and Byrne (1993) and is reported at 25C and surface pressure. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. 5. Dickson, A. G., C. L. Sabine, and J. R. Christian (2007), Determination of dissolved organic carbon and total dissolved nitrogen in sea water, PICES Special Publication 3. 6. Ianson, D., Susan E. Allen, Benjamin L. Moore-Maley, Sophia C. Johannessen and Robie W. Macdonald (2016), Vulnerability of a semienclosed estuarine sea to ocean acidification in contrast with hypoxia, Geophys. Res. Lett., 43, 5793-5801, doi:10.1002/2016GL068996. 7. Clayton, T. D., and R. H. Byrne (1993), Spectrophotometric seawater pH measurements: total hydrogen ion concentration scale calibration of m-cresol purple and at-sea results, Deep Sea Res. I, 40, 2115–2129. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-09-proc.doc. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-009\Processing\IOS\2011-009-0003.hplc --------------------------------------------------------------------------- Sample_Number 20: HPLC: >10%CV for TChl-a Sample_Number 21: HPLC: one rep removed, values anomalously low Sample_Number 23: HPLC: >30%CV for TChl-a, values very low compared to Turner *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !------------------------------ -------- ---- ------ ------------ Fluorescence:Wetlabs:ECO-AFL mg/m^3 10 -99 () (0.31E-01 1) Salinity:T0:C0 PSS-78 10 -99 () (0.8E-03 1) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14--- 15 ---16-- --17- 18 --19-- 20 --21-- 22 ---23-- 24 ---25-- 26 --27-- 28 ---29-- 30 --31-- 32 --33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- 57 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Carbon: Fl Alkali Fl pH Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag Dissolv ag nity: ag ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ed: ~g Total ~T : Extrac ~a t: a a fuco fuco : !er er Sequ y Wetlabs ved: lved: _rec Draw tt lved lv Nitrit ri ca ha Inorgan an ot pH ted ct Extrac HP ! ence SBE SBE ords le ed e te te te ic ic al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- ------- -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 23 14 14 1.4 9.7190 39.5 2.473 0.4 29.9168 4.93 215.3 241 9.5 -99.0000 0 4.922 214.8 0 20.60 0 38.80 0 1.790 0 2016.75 0 2077.4 0 7.6200 0 8.97 36 -0.51 0.000 0.009 0.011 0.134 0.045 0.000 0.000 0.560 0.000 0.000 0.121 0.000 0.016 0.024 0.000 0.015 0.000 0.031 0.000 1.420 0.000 0.052 1.429 46 22 13 13 5.1 9.6644 40.5 2.235 0.1 30.0015 4.85 211.5 241 9.5 -99.0000 0 4.851 211.7 0 21.00 0 38.70 0 1.700 0 -99.00 9 -99.0 9 7.6000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 21 12 12 10.6 9.5838 41.2 1.855 0.0 30.0370 4.78 208.7 241 9.5 -99.0000 0 4.788 208.9 0 21.10 0 38.90 0 1.790 0 2006.84 0 2078.7 0 -99.0000 0 3.83 6 0.05 0.012 0.035 0.019 0.240 0.061 0.000 0.000 1.008 0.006 0.007 0.223 0.000 0.027 0.050 0.000 0.038 0.000 0.058 0.000 2.808 0.000 0.045 2.843 2 20 11 11 20.2 9.5328 41.9 1.489 0.0 30.2536 4.65 203.0 241 9.4 -99.0000 0 4.650 202.9 0 21.70 0 39.00 0 1.880 0 -99.00 9 -99.0 9 -99.0000 9 2.90 36 0.34 0.013 0.024 0.016 0.170 0.049 0.000 0.014 0.670 0.004 0.008 0.128 0.000 0.026 0.039 0.003 0.015 0.000 0.054 0.000 1.761 0.000 0.024 1.785 36 19 10 10 30.4 9.3513 42.6 1.015 0.0 30.5133 4.45 194.3 241 9.2 -99.0000 0 4.456 194.3 0 22.50 0 39.40 0 1.820 0 2036.28 0 2115.3 0 7.5700 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 18 9 9 41.0 9.2241 43.5 0.881 0.0 30.6908 4.33 188.7 241 9.2 -99.0000 0 4.349 189.7 6 23.10 0 39.80 0 2.020 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 17 8 8 50.9 9.1826 44.1 0.808 0.0 30.7367 4.29 187.1 241 9.1 -99.0000 0 4.309 187.9 0 23.40 0 39.90 0 1.940 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 16 7 7 75.2 8.9684 45.3 0.549 0.0 31.0751 4.07 177.4 241 8.8 -99.0000 0 4.066 177.3 0 24.40 6 40.50 6 1.990 6 2076.68 6 2115.3 6 7.5300 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 15 6 6 101.0 8.8058 41.7 0.499 0.0 31.3685 3.90 169.9 241 8.7 -99.0000 0 3.922 170.9 0 25.10 0 41.20 0 2.050 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 14 5 5 125.1 8.5898 40.2 0.392 0.0 31.7155 3.69 160.7 241 8.5 -99.0000 0 3.729 162.5 0 25.80 0 41.80 0 2.170 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 13 4 4 151.2 8.3000 30.4 0.365 0.0 32.1539 3.41 148.5 241 8.2 -99.0000 0 3.424 149.1 0 27.40 0 43.20 0 2.120 0 2131.18 0 2175.8 0 7.4800 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 12 3 3 175.9 8.2156 24.8 0.287 0.0 32.2808 3.31 144.1 241 8.2 -99.0000 0 3.329 145.0 6 27.90 0 43.70 0 2.230 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 11 2 2 201.1 8.2113 21.3 0.332 0.0 32.2910 3.31 144.0 241 8.1 32.3200 0 3.330 145.0 3 28.20 0 43.90 0 2.300 0 -99.00 9 -99.0 9 -99.0000 9 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 10 1 1 227.4 8.2142 22.3 0.349 0.0 32.2909 3.31 144.2 241 8.2 -99.0000 0 3.292 143.4 0 26.70 0 41.80 0 2.230 0 2155.87 0 2198.9 0 7.4700 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0