*2023/03/19 10:46:31.26 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/04/15 17:28:39.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 737A6172 NUMBER OF CHANNELS : 52 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 116 132 2 Bottle:Firing_Sequence n/a 1 17 3 Pressure decibar 2.7 372.6 4 Temperature:Secondary 'deg C (ITS90)' 7.6344 9.3423 5 Transmissivity %/metre 5.7 57.5 6 Fluorescence:URU:Seapoint mg/m^3 0.111 16.294 7 PAR uE/m^2/sec 0 1137.5 8 PAR:Reference uE/m^2/sec 1689.2 2350.5 9 Salinity:T1:C1 PSS-78 23.0641 30.9841 10 Oxygen:Dissolved:SBE mL/L 2.59 9.02 11 Oxygen:Dissolved:SBE umol/kg 113.1 395.7 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 7.6 8.3 14 Salinity:Bottle PSS-78 30.9497 30.9497 15 Flag:Salinity:Bottle n/a 16 Oxygen:Dissolved mL/L 2.623 9.058 17 Oxygen:Dissolved umol/kg 114.3 397.2 18 Flag:Oxygen:Dissolved n/a 19 Nitrate_plus_Nitrite umol/L 4.3 30.5 20 Flag:Nitrate_plus_Nitrite n/a 21 Silicate umol/L 18.9 70.2 22 Silicate:Flag n/a 23 Phosphate umol/L 0.7 2.96 24 Flag:Phosphate n/a 25 Chlorophyll:Extracted mg/m^3 3.71 36.95 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.52 2.01 28 Bottle:Firing_Sequence n/a 1 17 29 HPLC:Chl-c3 mg/m^3 0.12E-01 0.64E-01 30 HPLC:Chlide-a mg/m^3 0.12 2.64 31 HPLC:MgDVP mg/m^3 0.12E-01 0.297 32 HPLC:Chl-c2 mg/m^3 0.307 2.319 33 HPLC:Peri mg/m^3 0 0 34 HPLC:Pheide-a mg/m^3 0 0.195 35 HPLC:But-fuco mg/m^3 0 0.25E-01 36 HPLC:Fuco mg/m^3 2.217 14.859 37 HPLC:Neo mg/m^3 0 0.18E-01 38 HPLC:Pras mg/m^3 0 0 39 HPLC:Viola mg/m^3 0.2E-02 0.34E-01 40 HPLC:Hex-fuco mg/m^3 0 0 41 HPLC:Diadino mg/m^3 0.116 1.697 42 HPLC:Allo mg/m^3 0.2E-02 0.49E-01 43 HPLC:Diato mg/m^3 0.7E-02 0.152 44 HPLC:Zea mg/m^3 0.23E-01 0.7E-01 45 HPLC:Lut mg/m^3 0 0.6E-02 46 HPLC:Chl-b mg/m^3 0.2E-01 0.73E-01 47 HPLC:DVChl-a mg/m^3 0 0 48 HPLC:Chl-a mg/m^3 3.075 17.347 49 HPLC:Phe mg/m^3 0.61E-01 0.241 50 HPLC:B-Car mg/m^3 0.51E-01 0.382 51 HPLC:TChl-a mg/m^3 3.195 18.86 52 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 9 F R4 4 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 5 I I 0 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-08 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdeF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 39 EVENT NUMBER : 30 LATITUDE : 49 9.79000 N ! (deg min) LONGITUDE : 123 33.00000 W ! (deg min) WATER DEPTH : 375 ALTIMETER (M) : 5.1 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0941 $REMARKS SOFTWARE VERSION SEASAVE V 7.20G $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/09/29 14:52:17 3133 3133 CLEAN 5.0.3 2011/09/29 14:52:55 ? ? JOIN 2.4.2 2011/09/29 14:54:44 4979 4979 ADDSAMP 3.5 2011/09/29 15:27:58 4979 4979 BINAVE 4.1.1 2011/09/29 15:28:22 4979 17 MERGE 3.4 2011/10/05 09:15:35 17 17 CLEAN 5.0.3 2011/10/05 09:15:41 ? ? CALIB 11.7 2011/10/05 09:15:49 17 17 SORT 3.5 2011/10/05 09:16:05 17 17 REMOVECH 8.0 2011/10/05 09:16:10 17 17 CHGUNITS 3.0 2011/10/05 09:16:47 17 17 CHGUNITS 3.0 2011/10/05 09:17:11 17 17 REORDER 1.3 2011/10/05 09:17:20 ? ? HDREDIT2 2.5.1 2011/10/05 09:17:33 ? ? HDREDIT2 2.5.1 2011/10/10 15:38:39 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:25 17 17 CHANGE_FLAGS 2.0 2014/11/20 09:57:31 17 17 Silicate_Correction 1.0 2018/02/20 14:43:15 17 17 SORT 3.6 2020/11/30 14:17:33 17 17 REORDER 1.3.1 2021/11/25 10:35:31 ? ? MERGE 3.5.1 2021/11/25 10:35:40 17 17 SORT 3.6 2021/11/25 10:35:47 17 17 CLEAN 5.2.4 2021/11/25 10:35:54 17 17 HDREDIT2 3.2 2021/11/25 10:36:27 ? ? HDREDIT2 3.2 2021/11/25 10:36:49 ? ? Silicate_Modification 1.2 2023/03/19 10:46:31 17 17 $END $REMARKS -CLEAN functions: 2011/09/29 14:52:45 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2011-08\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/10/05 09:15:33 2011/10/05 09:15:33 2011/10/05 09:15: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2011-08\Processing\hydro\2011-08-0030.samavg Secondary file: P:\Cruise_Data_Processing\2011-08\Processing\hydro\2011-08-0030.mrgcln1 -CLEAN functions: 2011/10/05 09:15:41 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2011/10/05 09:15:49 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2011-08\Processing\doc\2011-08-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 -0.9039000E+00 0.1000000E+01 12 PAR:Reference uE/m^2/se 10 0.0000000E+00 0.1527282E+04 -SORT parameters: 2011/10/05 09:16:05 Sorted in ascending order of channel Pressure -REMOVECH 2011/10/05 09:16:10 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2011/10/05 09:17:33 Applied edit header: P:\Cruise_Data_Processing\2011-08\Processing\doc\2011-08-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 17: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 20: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 25: Silicate [umol/L] Format: F7.2 ==> F6.1 Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 21: Oxygen:Dissolved [umol/kg] Format: F6.2 ==> F6.1 -HEADER EDITS: 2011/10/10 15:38:39 Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 9: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 -SORT parameters: 2020/11/30 14:17:33 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 10:35:40 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-008_Nov2021\Processing\ IOS\2011-008-0030.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-008_Nov2021\Processing\ IOS\2011-008-0030.hplc -SORT parameters: 2021/11/25 10:35:47 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 10:35:53 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 10:36:27 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-008-bot-hdr1.txt Channel 2: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 30: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 13: Temperature:Draw [deg C (ITS90)] Format: F9.4 ==> F6.1 Channel 31: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 23: Silicate:Corrected [umol/L] Format: F6.1 ==> F7.2 -HEADER EDITS: 2021/11/25 10:36:49 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-008-bot-hdr2.txt $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 39, Sample Number: 132, Silicate corrected using CTD salinity. At Station: 39, Sample Number: 131, Silicate corrected using CTD salinity. ===================================================================================== Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab within a week of collection and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab and at IOS. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-08_CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-008_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 and a UV light source and detector with a 365 nm filter controlled by LVO2 software designed and built by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document 2011-08oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-08-sal*.xls. Nutrient samples were collected in plastic tubes. Samples were stored frozen and later analysed at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-08nuts*.xls" includes the raw data and a precision study. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. For further processing details see the processing report 2011-08-proc.doc. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-008_Nov2021\Processing\IOS\2011-008-0030. hplc --------------------------------------------------------------------------- Sample_Number 130: HPLC:one rep discarded, value low compared to Turner Sample_Number 132: HPLC:one rep discarded, value low compared to Turner *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! --------------- ------------ ---- ------ ------------ Pressure dbars 10 -99 () (-0.9039 1) PAR:Reference uE/m^2/sec 10 -99 () (0 1527.282) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- --13- ---14--- 15 ---16-- --17- 18 --19- 20 --21-- 22 --23-- 24 --25-- 26 --27-- -28- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- 52 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silica Si Phosph Fl Chloro Fl Phaeo- Bott HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le:F re ure: missi cence: Refere :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag te li ate ag phyll: ag Pigmen le:F Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb ~ng_ Secondar vity URU: nce Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~: ~p Extrac ~a t: ~ng_ a a fuco fuco : !er Sequ y Seapoin ved: lved: _rec Draw tt lved lv Nitri ri Fl ha ted ct Extrac Sequ HP ! ence t SBE SBE ords le ed te te ag te ed ted ence LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ------ -- ------ -- ------ -- ------ ---- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 132 17 2.7 7.6344 5.7 6.264 1137.5 2304.7 23.0641 9.02 395.7 241 7.7 -99.0000 0 9.058 397.2 0 4.4 0 23.10 0 0.70 0 28.16 6 0.52 17 0.047 1.187 0.297 1.944 0.000 0.000 0.025 12.026 0.014 0.000 0.034 0.000 1.697 0.049 0.152 0.038 0.006 0.056 0.000 17.347 0.241 0.382 18.534 3 131 16 3.3 7.7247 5.9 11.955 755.2 2347.4 24.8828 8.94 391.7 241 7.6 -99.0000 0 9.042 396.0 0 4.3 0 20.40 0 0.74 0 -99.00 0 -99.00 16 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 130 15 9.3 7.7938 15.6 16.294 6.2 2347.4 28.2260 8.20 358.1 241 7.7 -99.0000 0 8.157 356.3 0 10.2 0 18.90 0 1.16 0 36.95 6 2.01 15 0.064 2.640 0.281 2.319 0.000 0.000 0.000 14.859 0.018 0.000 0.028 0.000 0.878 0.033 0.077 0.070 0.000 0.073 0.000 16.220 0.165 0.219 18.860 3 129 14 18.7 7.8146 48.1 2.546 0.1 2344.4 29.0998 5.94 259.2 241 7.7 -99.0000 0 5.860 255.8 0 26.1 0 50.50 0 2.27 0 3.71 6 1.43 14 0.012 0.120 0.012 0.307 0.000 0.195 0.000 2.217 0.000 0.000 0.002 0.000 0.116 0.002 0.007 0.023 0.001 0.020 0.000 3.075 0.061 0.051 3.195 6 128 13 30.2 7.8955 56.7 0.536 0.0 2310.8 29.3756 5.28 230.7 241 7.8 -99.0000 0 5.316 232.0 0 29.2 0 57.50 0 2.45 0 -99.00 0 -99.00 13 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 127 12 41.1 7.9890 57.5 0.285 0.0 2310.8 29.5113 5.07 221.4 241 7.8 -99.0000 0 5.098 222.5 6 29.7 0 58.60 0 2.50 0 -99.00 0 -99.00 12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 126 11 49.3 8.0286 57.5 0.263 0.0 2309.2 29.6024 4.97 217.1 241 7.9 -99.0000 0 4.976 217.1 0 29.8 0 58.40 0 2.48 0 -99.00 0 -99.00 11 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 125 10 73.7 7.6973 51.1 0.325 0.0 2269.5 29.6626 5.77 251.8 241 7.6 -99.0000 0 5.767 251.6 0 27.7 0 51.90 0 2.20 0 -99.00 0 -99.00 10 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 124 9 98.2 7.9654 55.8 0.206 0.0 2278.7 29.8380 5.01 218.8 241 7.8 -99.0000 0 5.020 219.0 0 29.9 6 55.90 6 2.41 6 -99.00 0 -99.00 9 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 123 8 124.1 8.0076 57.3 0.149 0.0 2274.1 30.0598 4.87 212.3 241 7.7 -99.0000 0 4.890 213.3 0 30.0 0 55.60 0 2.44 0 -99.00 0 -99.00 8 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 122 7 150.1 7.8258 54.9 0.145 0.0 1954.9 30.1861 4.99 217.9 241 7.7 -99.0000 0 5.002 218.2 0 29.6 0 55.70 0 2.41 0 -99.00 0 -99.00 7 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 121 6 172.4 7.8892 55.4 0.134 0.0 2177.9 30.3014 4.80 209.4 241 7.6 -99.0000 0 4.783 208.6 0 29.6 0 56.40 0 2.45 0 -99.00 0 -99.00 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 120 5 197.5 8.1161 52.0 0.135 0.0 1713.6 30.4205 4.43 193.4 241 7.9 -99.0000 0 4.377 190.9 6 29.8 0 58.20 0 2.51 0 -99.00 0 -99.00 5 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 119 4 248.9 8.7023 55.4 0.119 0.0 1689.2 30.6955 3.61 157.3 241 8.1 -99.0000 0 3.557 155.1 0 30.1 0 62.20 0 2.65 0 -99.00 0 -99.00 4 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 118 3 300.0 9.0834 53.8 0.113 0.0 2350.5 30.8545 3.08 134.4 241 8.3 -99.0000 0 3.086 134.5 0 30.3 0 64.30 0 2.74 0 -99.00 0 -99.00 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 117 2 348.9 9.2760 50.1 0.111 0.0 2333.7 30.9448 2.77 120.8 241 8.3 30.9497 0 2.774 120.9 0 30.4 0 67.50 0 2.85 0 -99.00 0 -99.00 2 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 116 1 372.6 9.3423 37.5 0.117 0.0 2344.4 30.9841 2.59 113.1 241 8.3 -99.0000 0 2.623 114.3 0 30.5 0 70.20 0 2.96 0 -99.00 0 -99.00 1 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0