*2021/11/25 10:11:25.44 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2011/02/10 20:29:16.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 23F297BD NUMBER OF CHANNELS : 50 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 93 116 2 Bottle_Number n/a 1 24 3 Bottle:Firing_Sequence n/a 1 24 4 Pressure decibar 3.6 2001.4 5 Temperature:Secondary 'deg C (ITS90)' 1.908 7.8807 6 Transmissivity %/metre 59.3 64.5 7 Fluorescence:URU:Seapoint mg/m^3 0 1.388 8 Salinity:T1:C1 PSS-78 32.4342 34.5947 9 Oxygen:Dissolved:SBE mL/L 0.22 1.41 10 Oxygen:Dissolved:SBE umol/kg 9.5 61.3 11 Number_of_bin_records n/a 75 241 12 Salinity:Bottle PSS-78 32.4348 34.5938 13 Flag:Salinity:Bottle n/a 14 Oxygen:Dissolved mL/L 0.232 6.819 15 Flag:Oxygen:Dissolved n/a 16 Nitrate_plus_Nitrite umol/L 7.3 45.9 17 Flag:Nitrate_plus_Nitrite n/a 18 Silicate umol/L 8.3 174.3 19 Flag:Silicate n/a 20 Phosphate umol/L 0.93 3.33 21 Flag:Phosphate n/a 22 Chlorophyll:Extracted mg/m^3 0.2E-01 0.43 23 Flag:Chlorophyll:Extracted n/a 24 Phaeo-Pigment:Extracted mg/m^3 0.6E-01 0.34 25 HPLC:Chl-c3 mg/m^3 0.22E-01 0.32E-01 26 HPLC:Chlide-a mg/m^3 0 0 27 HPLC:MgDVP mg/m^3 0.8E-02 0.1E-01 28 HPLC:Chl-c2 mg/m^3 0.25E-01 0.33E-01 29 HPLC:Chl-c1 mg/m^3 0 0 30 HPLC:Me-chlide mg/m^3 0 0 31 HPLC:Peri mg/m^3 0 0 32 HPLC:Pheide-a mg/m^3 0 0 33 HPLC:But-fuco mg/m^3 0.18E-01 0.27E-01 34 HPLC:Fuco mg/m^3 0.24E-01 0.29E-01 35 HPLC:Neo mg/m^3 0.8E-02 0.9E-02 36 HPLC:Pras mg/m^3 0.16E-01 0.18E-01 37 HPLC:Viola mg/m^3 0.4E-02 0.8E-02 38 HPLC:Hex-fuco mg/m^3 0.62E-01 0.82E-01 39 HPLC:Diadino mg/m^3 0.1E-01 0.14E-01 40 HPLC:Allo mg/m^3 0.9E-02 0.1E-01 41 HPLC:Diato mg/m^3 0 0 42 HPLC:Zea mg/m^3 0.6E-02 0.9E-02 43 HPLC:Lut mg/m^3 0 0 44 HPLC:Chl-b mg/m^3 0.71E-01 0.9E-01 45 HPLC:DVChl-a mg/m^3 0 0 46 HPLC:Chl-a mg/m^3 0.272 0.324 47 HPLC:Phe mg/m^3 0 0 48 HPLC:B-Car mg/m^3 0.2E-02 0.5E-02 49 HPLC:TChl-a mg/m^3 0.272 0.324 50 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 8 F R4 3 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2011-01 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P8 EVENT NUMBER : 21 LATITUDE : 48 49.04000 N ! (deg min) LONGITUDE : 128 40.50000 W ! (deg min) WATER DEPTH : 2515 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.20G $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/08/30 09:12:55 5438 5438 CLEAN 5.0.3 2011/08/30 09:14:12 ? ? CLEAN 5.0.3 2011/08/30 09:46:28 5438 5438 ADDSAMP 3.5 2011/08/30 09:47:23 5438 5438 BINAVE 4.1.1 2011/08/30 09:48:08 5438 24 MERGE 3.4 2011/08/30 09:54:56 24 24 CLEAN 5.0.3 2011/08/30 09:55:00 ? ? SORT 3.5 2011/08/30 10:17:20 24 24 REMOVECH 8.0 2011/08/30 10:23:08 24 24 CHGUNITS 3.0 2011/08/30 10:51:35 24 24 REORDER 1.3 2011/08/30 10:51:41 ? ? HDREDIT2 2.5.1 2011/10/12 15:38:28 ? ? CALIB 11.7 2013/06/04 13:15:40 24 24 HDREDIT2 2.6 2013/07/08 08:50:53 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:14 24 24 CHANGE_FLAGS 2.0 2014/11/20 09:57:29 24 24 SORT 3.6 2020/08/30 09:35:53 24 24 REORDER 1.3.1 2021/11/25 10:04:31 ? ? MERGE 3.5.1 2021/11/25 10:04:44 24 24 SORT 3.6 2021/11/25 10:04:57 24 24 CLEAN 5.2.4 2021/11/25 10:05:04 24 24 HDREDIT2 3.2 2021/11/25 10:10:43 ? ? HDREDIT2 3.2 2021/11/25 10:11:25 ? ? $END $REMARKS -CLEAN functions: 2011/08/30 09:14:06 20 Set event to last 4 characters of file name -CLEAN functions: 2011/08/30 09:46:21 20 Reset #RECS, MIN & MAX values in header. Insert Pad Values in Channel: Salinity:T0:C0 [PSS-78] where channel Salinity:T0:C0 [PSS-78] is in the range 1000 to 9000 10117 data records in pad range. -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2011-01\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/08/30 09:54:55 2011/08/30 09:54:55 2011/08/30 09:54: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2011-01\Processing\hydro\2011-01-0021.samavg Secondary file: Q:\Cruise_Data_Processing\2011-01\Processing\hydro\2011-01-0021.mrgcln1s Comments from secondary file: Q:\Cruise_Data_Processing\2011-01\Processing\hydro\2011-01-0021.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2011/08/30 09:54:47 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/08/30 09:55:00 20 Remove Sea-Bird comments from the header. -SORT parameters: 2011/08/30 10:17:20 Sorted in ascending order of channel Pressure -REMOVECH 2011/08/30 10:23:08 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Status:Pump Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2011/10/12 15:38:28 Applied edit header: P:\Cruise_Data_Processing\2011-01\Processing\doc\2011-01-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 3: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: Salinity:Practical:T1:C1 [PSS-78] Name: Salinity:T1:C1 ==> Salinity:Practical:T1:C1 Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 9: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 -CALIB parameters: 2013/06/04 13:15:40 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 23 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:50:53 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/08/30 09:35:53 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 10:04:44 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-001_Nov2021\Processing\ IOS\2011-001-0021.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-001_Nov2021\Processing\ IOS\2011-001-0021.hplc -SORT parameters: 2021/11/25 10:04:57 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 10:05:04 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 10:10:43 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-001-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 10:11:25 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-001-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data_Processing\2011-01\Processing\hydro\2011-01-0021.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: Q:\Cruise_Data_Processing\2011-01\Processing\hydro\2011-01-0021.sal ------------------------------------------------------------------- Sample_Number 95: SAL: leaky liner; bottle value looks slightly high in COMPARE. Sample_Number 105: SAL: salt crystals on threads of bottleneck; bottle value looks slightly high in COMPARE. Comments from secondary file: Q:\Cruise_Data_Processing\2011-01\Processing\hydro\2011-01-0021.nut ------------------------------------------------------------------- Sample_Number 93: ALL: Air valve not tight Sample_Number 99: Nuts:Water for the 5l carboy Sample_Number 113: Nuts: Water for the 5l carboy Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab and at IOS. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file 2011-01CHL*.xls. Phaeopigment data are provided for information only and no quality flags are assigned to them. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2011-001_HPLC*.xlsx. Oxygen samples were analyzed on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). All samples were analyzed at sea. A shift in the DO standardization parameters occurred between events #32 and #44; this was not investigated to determine if the resultant change in Thiosulfate normality was real, or the result of a shift in lab temperature. Checks of the fit of SBE Dissolved Oxygen against titrated DO suggest that the titrated values from the first part of the cruise are lower than those of the latter part by about 0.02mL/L. For details including a duplicate analysis, see document 2011-01oxy*.xls. Salinity samples were collected in glass bottles and analyzed on Guildline Autosal model 8400B, S/N 68572, at IOS. Salinometers are standardized with IAPSO standard seawater. Full results are in file 2011-01-sal*.xls. Nutrient samples were collected in plastic tubes. Most samples were stored frozen and later analysed at IOS. Deep Silicate samples (400m and deeper) were analyzed cool at IOS. An Astoria analyzer was used following methods described in Barwell-Clarke and Whitney (1996). File "QF 2011-01nuts*.xls" includes the raw data and a precision study. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2011-01 DMS Report.doc and for data see DMS 2011-01 summary.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Data Processing Notes: ---------------------- Transmissivity, PAR and SBE Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". SBE DO calibration was done using the method described in the SeaBird Application NOte #64-2. The Oxygen:Dissolved:SBE channel was corrupted for all or parts of Events #7, 10, 15, 17, 18, 19 and 21. For further processing details see the processing report 2011-01-proc.doc. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2011\2011-001_Nov2021\Processing\IOS\2011-001-0021. hplc --------------------------------------------------------------------------- Sample_Number 112: HPLC: >30%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- ---12--- 13 ---14-- 15 --16- 17 --18- 19 --20-- 21 --22-- 23 --24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- 50 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le ed te te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 113 21 23 3.6 7.8790 59.3 1.373 32.4345 -99.00 -99.0 100 -99.0000 0 -99.000 0 7.4 0 8.3 0 0.93 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 114 22 24 3.6 7.8776 59.4 1.354 32.4346 -99.00 -99.0 241 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 112 20 22 3.8 7.8791 59.4 1.367 32.4342 -99.00 -99.0 75 32.4348 0 6.817 0 7.3 0 8.3 0 0.95 0 0.38 6 0.30 0.032 0.000 0.010 0.033 0.000 0.000 0.000 0.000 0.027 0.029 0.009 0.016 0.004 0.082 0.014 0.009 0.000 0.006 0.000 0.076 0.000 0.294 0.000 0.002 0.294 46 111 19 21 9.6 7.8788 59.5 1.388 32.4343 -99.00 -99.0 241 32.4373 0 6.812 0 7.4 0 8.3 0 0.93 0 0.43 0 0.34 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 116 24 20 14.6 7.8783 59.5 1.355 32.4343 -99.00 -99.0 241 -99.0000 0 -99.000 0 8.5 0 11.3 0 0.98 0 0.43 6 0.32 0.022 0.000 0.008 0.025 0.000 0.000 0.000 0.000 0.018 0.024 0.009 0.016 0.007 0.062 0.010 0.010 0.000 0.008 0.000 0.071 0.000 0.272 0.000 0.004 0.272 6 110 18 18 24.8 7.8778 59.6 1.380 32.4343 -99.00 -99.0 241 32.4354 0 6.819 6 7.4 0 8.3 0 0.93 0 0.39 6 0.31 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 115 23 19 25.1 7.8782 59.7 1.375 32.4343 -99.00 -99.0 241 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 0.37 6 0.30 0.031 0.000 0.009 0.031 0.000 0.000 0.000 0.000 0.024 0.028 0.008 0.018 0.008 0.076 0.010 0.009 0.000 0.009 0.000 0.090 0.000 0.324 0.000 0.005 0.324 6 109 17 17 49.9 7.8792 59.9 1.369 32.4344 -99.00 -99.0 241 32.4348 0 6.806 0 7.4 0 8.3 0 0.93 0 0.34 0 0.28 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 108 16 16 73.4 7.8807 60.8 1.100 32.4388 -99.00 -99.0 241 32.4432 0 6.765 0 7.6 6 8.4 6 0.94 6 0.29 0 0.27 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 107 15 15 99.7 7.1649 63.6 0.032 33.3730 -99.00 -99.0 241 33.3669 0 4.307 0 23.6 0 28.8 0 1.84 0 0.02 0 0.06 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 106 14 14 122.8 6.9749 63.7 0.023 33.6603 -99.00 -99.0 241 33.6560 0 3.681 0 27.4 0 35.5 0 2.04 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 105 13 13 150.1 6.7185 63.7 0.016 33.7945 -99.00 -99.0 241 33.7986 4 3.315 0 29.6 0 40.9 0 2.16 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 104 12 12 175.8 6.5063 63.7 0.017 33.8482 -99.00 -99.0 241 33.8479 0 3.059 0 30.9 0 45.0 0 2.24 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 103 11 11 199.3 6.2863 63.7 0.018 33.8678 -99.00 -99.0 241 33.8677 0 2.880 0 32.3 0 48.4 0 2.32 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 102 10 10 249.7 5.7254 63.8 0.018 33.9023 -99.00 -99.0 241 33.9004 0 2.294 0 35.5 0 58.1 0 2.55 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 101 9 9 301.0 5.3931 64.1 0.020 33.9446 -99.00 -99.0 241 33.9462 0 1.719 0 38.3 0 66.8 0 2.76 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 100 8 8 400.7 5.0021 64.2 0.023 34.0423 0.90 39.3 241 34.0415 0 0.937 0 42.0 0 80.7 0 3.02 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 99 7 7 600.1 4.3629 64.3 0.024 34.2177 0.30 13.2 241 -99.0000 0 -99.000 0 44.4 0 103.4 0 3.23 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 98 6 6 600.5 4.3579 64.3 0.024 34.2166 0.30 13.2 202 34.2169 0 0.318 0 44.5 0 103.6 0 3.26 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 97 5 5 801.7 3.8213 64.3 0.025 34.3372 0.22 9.5 241 34.3367 0 0.232 6 45.4 0 121.2 0 3.28 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 96 4 4 1001.2 3.3481 64.4 0.027 34.4112 0.28 12.1 241 34.4111 0 0.289 0 45.9 0 134.9 0 3.33 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 95 3 3 1248.9 2.8961 64.3 0.026 34.4769 0.47 20.3 241 34.4779 4 0.498 0 45.5 0 148.3 0 3.29 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 94 2 2 1498.5 2.4712 64.4 0.027 34.5210 0.71 31.0 241 34.5213 0 0.756 0 44.8 0 160.5 0 3.21 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 93 1 1 2001.4 1.9080 64.5 0.000 34.5947 1.41 61.3 241 34.5938 6 1.594 3 42.8 6 174.3 6 3.06 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0