*2021/11/24 16:55:30.89 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2010/08/15 11:51:50.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 4F51B22E NUMBER OF CHANNELS : 56 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 1805 1823 2 Bottle_Number n/a 1 19 3 Bottle:Firing_Sequence n/a 1 19 4 Pressure decibar 2.2 176.2 5 Temperature:Secondary 'deg C (ITS90)' 6.4836 9.709 6 Transmissivity %/metre 39.6 55.9 7 Fluorescence:URU:Seapoint mg/m^3 0.119 0.613 8 PAR uE/m^2/sec 0 0.1 9 Salinity:T1:C1 PSS-78 32.243 33.8696 10 Oxygen:Dissolved:SBE mL/L 1.74 4.13 11 Oxygen:Dissolved:SBE umol/kg 75.7 179.8 12 Number_of_bin_records n/a 66 121 13 Salinity:Bottle PSS-78 32.2485 33.8721 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 1.721 4.201 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 21.7 35.6 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 35.7 54.6 20 Flag:Silicate n/a 21 Phosphate umol/L 1.9 2.72 22 Flag:Phosphate n/a 23 Carbon:Dissolved:Inorganic umol/kg 2050.92 2255.76 24 Flag:Carbon:Dissolved:Inorganic n/a 25 Alkalinity:Total umol/kg 2177.4 2268.1 26 Flag:Alkalinity:Total n/a 27 pH n/a 7.35 7.58 28 Flag:pH ' ' 29 Chlorophyll:Extracted mg/m^3 0.44 1.27 30 Flag:Chlorophyll:Extracted n/a 31 Phaeo-Pigment:Extracted mg/m^3 0.14 0.63 32 HPLC:Chl-c3 mg/m^3 0 0.11E-01 33 HPLC:Chlide-a mg/m^3 0 0 34 HPLC:MgDVP mg/m^3 0.2E-02 0.7E-02 35 HPLC:Chl-c2 mg/m^3 0.34E-01 0.79E-01 36 HPLC:Me-chlide mg/m^3 0 0 37 HPLC:Peri mg/m^3 0 0.2E-01 38 HPLC:Pheide-a mg/m^3 0 0 39 HPLC:But-fuco mg/m^3 0.5E-02 0.8E-02 40 HPLC:Fuco mg/m^3 0.101 0.325 41 HPLC:Neo mg/m^3 0 0.7E-02 42 HPLC:Pras mg/m^3 0 0 43 HPLC:Viola mg/m^3 0 0 44 HPLC:Hex-fuco mg/m^3 0 0 45 HPLC:Diadino mg/m^3 0.16E-01 0.22E-01 46 HPLC:Allo mg/m^3 0.3E-02 0.12E-01 47 HPLC:Diato mg/m^3 0 0.4E-02 48 HPLC:Zea mg/m^3 0.2E-02 0.6E-02 49 HPLC:Lut mg/m^3 0 0 50 HPLC:Chl-b mg/m^3 0 0.4E-02 51 HPLC:DVChl-a mg/m^3 0 0 52 HPLC:Chl-a mg/m^3 0.321 0.832 53 HPLC:Phe mg/m^3 0 0 54 HPLC:B-Car mg/m^3 0.5E-02 0.12E-01 55 HPLC:TChl-a mg/m^3 0.321 0.832 56 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 1 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 8 F R4 4 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 3 NQ C ' ' 31 -99 ' ' 7 F R4 2 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2010-36 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Ocean Acidification SCIENTIST : Ianson D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : JF2 EVENT NUMBER : 225 LATITUDE : 48 18.03000 N ! (deg min) LONGITUDE : 124 0.00000 W ! (deg min) WATER DEPTH : 186 ALTIMETER (M) : 11.82 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/01/03 15:44:40 2244 2244 CLEAN 5.0.2 2011/01/03 15:45:52 ? ? CTDEDIT 4.61 2011/01/04 11:51:06 2244 2244 ADDSAMP 3.4 2011/01/10 13:11:47 2244 2244 BINAVE 4.1.1 2011/01/10 13:12:48 2244 19 MERGE 3.4 2011/01/17 14:07:12 19 19 CLEAN 5.0.2 2011/01/17 14:07:15 ? ? CALIB 11.7 2011/02/07 09:15:39 19 19 SORT 3.5 2011/02/08 13:09:37 19 19 REMOVECH 8.0 2011/02/08 17:07:21 19 19 REMOVECH 8.0 2011/02/08 17:10:30 19 19 CHGUNITS 3.0 2011/02/08 17:18:38 19 19 REORDER 1.3 2011/02/09 14:56:49 ? ? HDREDIT2 2.5.1 2011/02/09 14:56:57 ? ? CALIB 11.7 2013/07/11 15:10:03 19 19 HDREDIT2 2.6 2013/07/11 15:17:38 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:10 19 19 CHANGE_FLAGS 2.0 2014/11/20 09:57:27 19 19 SORT 3.6 2016/11/29 13:19:53 19 19 MERGE 3.5 2016/12/14 13:29:31 19 19 SORT 3.6 2018/05/30 16:29:43 19 19 CLEAN 5.2.3 2018/05/30 16:30:33 19 19 CLEAN 5.2.3 2018/05/30 16:31:13 19 19 HDREDIT2 3.1.1 2018/05/31 15:34:24 ? ? SORT 3.6 2020/11/30 13:15:11 19 19 REORDER 1.3.1 2021/11/24 16:53:56 ? ? MERGE 3.5.1 2021/11/24 16:54:19 19 19 SORT 3.6 2021/11/24 16:54:27 19 19 CLEAN 5.2.4 2021/11/24 16:54:37 19 19 HDREDIT2 3.2 2021/11/24 16:55:08 ? ? $END $REMARKS -CLEAN functions: 2011/01/03 15:44:50 20 Set event to last 4 characters of file name -CTDEDIT 2011/01/04 11:51:06 3 changes in channel Salinity:T1:C1 -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\addsamp3.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/01/17 14:07:12 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Flag:Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0225.samavg Secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0225.mrgx Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0225.mrgx -------------------------------------------------------------------- -SORT parameters: 2011/01/17 14:07:06 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/01/17 14:07:15 Remove Sea-Bird comments from the header. -CALIB parameters: 2011/02/07 09:15:39 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-recal-fit1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 -0.2370000E-01 0.1049200E+01 -SORT parameters: 2011/02/08 13:09:37 Sorted in ascending order of channel Pressure -REMOVECH 2011/02/08 17:07:21 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Status:Pump Altimeter [metres] Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -REMOVECH 2011/02/08 17:10:30 The following CHANNEL(S) were removed: pH:SBE [pH Units] -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2011/02/09 14:56:57 Applied edit header: Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-bot-hdr.txt Channel 11: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 4: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 5: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 8: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 -CALIB parameters: 2013/07/11 15:10:03 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 24 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/11 15:17:38 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2016/11/29 13:19:53 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2016/12/14 13:29:31 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : C:\DATA\Debby\2010-36-0225.chesort Secondary file: C:\DATA\Debby\2010-36-0225.dic -SORT parameters: 2018/05/30 16:29:43 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/05/30 16:30:33 20 Reset #RECS, MIN & MAX values in header. Change character data from "2" to "0" Remove Sea-Bird comments from the header. -CLEAN functions: 2018/05/30 16:31:13 20 Change character data from " " to "0" -HEADER EDITS: 2018/05/31 15:34:24 Applied edit header: P:\Cruise_Data_Processing\Ianson-carbon\2010-36\Processing\2010-36-hdr.txt Channel 1: Sample_Number [n/a] Pad: -99 ==> -9 Channel 27: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 28: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 Channel 29: Flag:Alkalinity:Total [n/a] Units: ==> n/a -SORT parameters: 2020/11/30 13:15:11 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 16:54:19 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\ IOS\2010-036-0225.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\ IOS\2010-036-0225.hplc -SORT parameters: 2021/11/24 16:54:27 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 16:54:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 16:55:08 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 32: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 27: pH [n/a] Format: F7.2 ==> F8.4 -HEADER EDITS: 2021/11/24 16:55:30 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036-bot-hdr2.txt $END *COMMENTS CTDEDIT was used to remove 3 bad points in the secondary salinity channel. Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0225.mrgx -------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0225.nut ------------------------------------------------------------------- Sample_Number 1814: NUTS: Outlier in profile; likely mis-sample. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone for 24 hours in the lab immediately following the cruise and analyzed on a Turner 10AU flourometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen 1978). For details including information on precision see file 2010-36CHL.xls HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~7-10 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2010-036_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). The titration system consists of a Brinkmann 665 Dosimat, a UV light source and a UV detector with a 365nm filter custom built by Scripps Institution of Oceanography. For details including details on precision, see document 2010-36oxy.xls. Salinity samples were collected in glass bottles and analyzed at sea using a Guildline Portasal (#58879) or at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. See file 2010-36-salinity.xls for data for information on precision see 2010-36-salinity-duplicates.csv. Nutrient samples were collected in plastic tubes. Most samples were analyzed at sea on an Astoria-Pacific analyzer following methods described in Barwell-Clarke and Whitney (1996). Samples from Event #225 at station JF2 were frozen and analyzed after 2 weeks. For full data and details on nutrient duplicates and precision see file QF2010-36nuts.xls. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Methods including analysis and quality control are detailed in Dickson et al (1993) and Ianson et al (2007). pH on the total hydrogren ion concentration scale was determined photometrically following methods described in Clayton and Byrne (1993) and is reported at 25C and surface pressure. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson, C. H., and R. T. Williams. 1991. A comparison of methods for the determination of dissolved oxygen in seawater. Report No. WHPO 91-2. WOCE Hydrographic Programme Office. Woods Hole Oceanographic Institution, Woods Hole, Mass. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 4. Holm-Hansen, O. (1978). Chlorophyll a determination: improvement in methodology. Oikos 30:438-447. 5. Dickson, A. G., C. L. Sabine, and J. R. Christian (2007), Determination of dissolved organic carbon and total dissolved nitrogen in sea water, PICES Special Publication 3. 6. Ianson, D., Susan E. Allen, Benjamin L. Moore-Maley, Sophia C. Johannessen and Robie W. Macdonald (2016), Vulnerability of a semienclosed estuarine sea to ocean acidification in contrast with hypoxia, Geophys. Res. Lett., 43, 5793-5801, doi:10.1002/2016GL068996. 7. Clayton, T. D., and R. H. Byrne (1993), Spectrophotometric seawater pH measurements: total hydrogen ion concentration scale calibration of m-cresol purple and at-sea results, Deep Sea Res. I, 40, 2115–2129. 8. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The pH:SBE channel was removed from the files because sensor performance and recalibration are being studied and are not yet considered ready for the archive. The SBE Dissolved Oxygen sensor behaved poorly for all or part of some casts with concentration values offset by approximately 0.24mL/L from the normal looking casts. Data were recalibrated by applying an offset where appropriate before applying a general recalibration. The DO data must be considered of lower quality than usual. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\IOS\2010-036-0225. hplc --------------------------------------------------------------------------- Sample_Number 1823: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.237E-01 1.0492) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 ---23-- 24 --25-- 26 ---27-- 28 --29-- 30 --31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- 56 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Carbon: Fl Alkali Fl pH Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag Dissolv ag nity: ag ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p ed: ~g Total ~T : Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec tt lv Nitri ri ca ha Inorgan an ot pH ted ct Extrac HP ! ence t SBE SBE ords le ed te te te te ic ic al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------- -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 1820 16 19 2.2 9.7090 55.7 0.251 0.1 32.2441 4.13 179.8 121 -99.0000 0 4.201 0 23.8 0 40.6 0 2.10 0 2110.40 0 2183.4 0 7.5800 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1819 15 17 6.2 9.5743 55.8 0.254 0.0 32.2430 4.06 176.8 121 32.2485 0 4.049 0 23.7 0 40.2 0 2.08 0 2109.73 0 2177.4 0 7.5700 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1823 19 18 6.2 9.5587 55.8 0.262 0.0 32.2440 4.05 176.5 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.0 0 -99.0000 0 0.44 6 0.14 0.005 0.000 0.002 0.034 0.000 0.020 0.000 0.006 0.101 0.000 0.000 0.000 0.000 0.016 0.012 0.000 0.006 0.000 0.004 0.000 0.321 0.000 0.005 0.321 36 1818 14 16 11.2 9.3068 55.7 0.236 0.0 32.2594 3.95 172.0 121 -99.0000 0 3.948 0 24.6 0 40.9 0 2.14 0 2121.82 6 2184.2 6 7.5600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1817 13 15 16.6 9.1257 55.9 0.261 0.0 32.3241 3.83 166.9 121 -99.0000 0 3.843 0 24.8 0 40.1 0 2.11 0 2123.67 0 2191.1 0 7.5600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1816 12 14 21.7 8.9009 54.7 0.376 0.0 32.4306 3.81 166.1 121 -99.0000 0 3.814 0 24.9 0 40.4 0 2.10 0 2130.68 0 2218.5 3 7.5500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1815 11 13 31.5 8.9012 54.3 0.448 0.0 32.4531 3.85 167.8 121 -99.0000 0 3.897 0 24.5 0 39.7 0 2.08 0 2127.24 0 2197.2 0 7.5600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1814 10 12 41.6 8.9216 53.8 0.613 0.0 32.4810 3.97 172.8 121 -99.0000 0 3.960 0 21.7 3 35.7 3 1.90 3 2129.11 0 2194.6 0 7.5700 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1822 18 11 41.6 8.9211 53.6 0.572 0.0 32.4874 3.97 173.1 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.0 0 -99.0000 0 1.27 6 0.52 0.011 0.000 0.007 0.079 0.000 0.013 0.000 0.008 0.325 0.004 0.000 0.000 0.000 0.022 0.007 0.003 0.005 0.000 0.000 0.000 0.832 0.000 0.012 0.832 6 1813 9 9 51.6 8.4341 54.7 0.562 0.0 32.7184 3.51 152.8 121 -99.0000 0 3.535 6 25.9 0 40.7 0 2.15 0 2148.19 0 2205.3 0 7.5300 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1821 17 10 51.6 8.4331 54.7 0.571 0.0 32.7195 3.52 153.0 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.0 0 -99.0000 0 1.21 6 0.63 0.000 0.000 0.003 0.066 0.000 0.000 0.000 0.005 0.291 0.007 0.000 0.000 0.000 0.018 0.003 0.004 0.002 0.000 0.000 0.000 0.681 0.000 0.011 0.681 6 1812 8 8 71.2 7.6734 54.7 0.223 0.0 33.1356 2.80 122.0 121 -99.0000 0 2.796 0 27.6 0 41.4 0 2.21 0 2050.92 3 2232.5 0 7.4500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1811 7 7 96.4 7.3291 53.0 0.170 0.0 33.3426 2.45 106.8 121 -99.0000 0 2.408 0 31.9 0 47.0 0 2.51 0 2212.04 0 2234.4 0 7.4100 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1810 6 6 106.3 6.8362 39.6 0.177 0.0 33.5994 1.84 79.8 121 -99.0000 0 1.828 0 34.1 0 53.4 0 2.57 0 2235.49 0 2260.3 0 7.3600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1809 5 5 121.2 6.5041 46.8 0.128 0.0 33.8521 1.74 75.8 118 -99.0000 0 1.730 0 35.2 0 54.2 0 2.71 0 2255.76 0 2262.9 0 7.3500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1808 4 4 131.0 6.4903 46.0 0.120 0.0 33.8632 1.74 75.7 121 -99.0000 0 1.721 0 35.4 0 54.6 0 2.72 0 2245.42 6 2265.0 6 7.3500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1806 2 2 151.6 6.4844 44.6 0.119 0.0 33.8681 1.74 75.8 66 33.8721 0 1.726 6 35.4 0 54.0 0 2.70 0 2251.35 0 2264.9 0 7.3600 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1807 3 3 151.6 6.4848 44.8 0.120 0.0 33.8679 1.74 75.8 121 -99.0000 0 1.722 0 35.3 0 53.9 0 2.70 0 2246.79 0 2268.1 0 7.3500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 1805 1 1 176.2 6.4836 44.1 0.180 0.0 33.8696 1.75 76.3 121 -99.0000 0 1.723 0 35.6 0 54.2 0 2.63 0 2247.97 0 2261.6 0 7.3500 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0