*2014/11/20 09:57:24.25 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2010/07/31 15:36:38.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 12 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : CB3AC930 NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Pressure decibar 2 92.1 2 Temperature:Secondary 'deg C (ITS90)' 7.6254 12.1343 3 Transmissivity %/metre 43 57.6 4 Fluorescence:URU:Seapoint mg/m^3 0.229 2.765 5 PAR uE/m^2/sec 0 490.9 6 Salinity:T1:C1 PSS-78 30.6411 32.7958 7 Oxygen:Dissolved:SBE mL/L 3.05 7.45 8 Oxygen:Dissolved:SBE umol/kg 132.9 324.9 9 Sample_Number n/a 692 703 10 Bottle_Number n/a 1 12 11 Bottle:Firing_Sequence n/a 1 12 12 Number_of_bin_records n/a 76 121 13 Salinity:Bottle PSS-78 30.6508 32.6175 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 3.262 7.4 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 0.1709 24.40654 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 1.2 44.6 20 Flag:Silicate n/a 21 Phosphate umol/L 0.34875 2.04807 22 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 7 F ' ' 1 2 -99 ' ' 9 F ' ' 4 3 -99 ' ' 6 F ' ' 1 4 -99 ' ' 8 F ' ' 3 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 7 F ' ' 2 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 5 I I 0 10 -99 ' ' 3 I I 0 11 -99 ' ' 3 I I 0 12 ' ' ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2010-36 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Ocean Acidification SCIENTIST : Ianson D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : AQ1 EVENT NUMBER : 80 LATITUDE : 52 49.82000 N ! (deg min) LONGITUDE : 130 38.01000 W ! (deg min) WATER DEPTH : 103 ALTIMETER (M) : 10.82 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/01/03 15:43:57 1407 1407 CLEAN 5.0.2 2011/01/03 15:45:14 ? ? ADDSAMP 3.4 2011/01/10 13:11:09 1407 1407 BINAVE 4.1.1 2011/01/10 13:12:30 1407 12 MERGE 3.4 2011/01/14 15:31:32 12 12 CLEAN 5.0.2 2011/01/14 17:23:08 ? ? CALIB 11.7 2011/02/07 09:25:04 12 12 SORT 3.5 2011/02/08 13:09:34 12 12 REMOVECH 8.0 2011/02/08 17:07:21 12 12 REMOVECH 8.0 2011/02/08 17:10:29 12 12 CHGUNITS 3.0 2011/02/08 17:18:36 12 12 REORDER 1.3 2011/02/09 14:56:46 ? ? HDREDIT2 2.5.1 2011/02/09 14:56:55 ? ? CALIB 11.7 2013/07/11 15:09:59 12 12 HDREDIT2 2.6 2013/07/11 15:17:36 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:08 12 12 CHANGE_FLAGS 2.0 2014/11/20 09:57:24 12 12 $END $REMARKS -CLEAN functions: 2011/01/03 15:44:50 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\addsamp3.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/01/14 15:31:30 2011/01/14 15:31:30 2011/01/14 15:31: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Flag:Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0080.samavg Secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0080.mrgx Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0080.mrgx -------------------------------------------------------------------- -SORT parameters: 2011/01/14 15:31:11 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/01/14 17:23:07 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2011/02/07 09:25:04 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-recal-fit2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.2383000E+00 0.1034700E+01 -SORT parameters: 2011/02/08 13:09:34 Sorted in ascending order of channel Pressure -REMOVECH 2011/02/08 17:07:21 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Status:Pump Altimeter [metres] Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -REMOVECH 2011/02/08 17:10:29 The following CHANNEL(S) were removed: pH:SBE [pH Units] -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2011/02/09 14:56:55 Applied edit header: Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-bot-hdr.txt Channel 11: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 4: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 5: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 8: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 -CALIB parameters: 2013/07/11 15:09:59 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 21 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/11 15:17:36 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0080.mrgx -------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0080.sal ------------------------------------------------------------------- Sample_Number 693: SAL: Outlier in COMPARE but CTD salinity is relatively noisy Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0080.add ------------------------------------------------------------------- Sample_Number 692: OXY: dup not used, drawn after delay of sampling N11 Analysis methods: - ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone for 24 hours in the lab immediately following the cruise and analyzed on a Turner 10AU flourometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen 1978). For details including information on precision see file 2010-36CHL.xls Oxygen samples were analyzed at sea using an automated Winkler titration system with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). The titration system consists of a Brinkmann 665 Dosimat, a UV light source and a UV detector with a 365nm filter custom built by Scripps Institution of Oceanography. For details including details on precision, see document 2010-36oxy.xls. Salinity samples were collected in glass bottles and analyzed at sea using a Guildline Portasal (#58879) or at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. See file 2010-36-salinity.xls for data for information on precision see 2010-36-salinity-duplicates.csv. Nutrient samples were collected in plastic tubes. Most samples were analyzed at sea on an Astoria-Pacific analyzer following methods described in Barwell-Clarke and Whitney (1996). Samples from Event #225 at station JF2 were frozen and analyzed after 2 weeks. For full data and details on nutrient duplicates and precision see file QF2010-36nuts.xls. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson, C. H., and R. T. Williams. 1991. A comparison of methods for the determination of dissolved oxygen in seawater. Report No. WHPO 91-2. WOCE Hydrographic Programme Office. Woods Hole Oceanographic Institution, Woods Hole, Mass. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 4. Holm-Hansen, O. (1978). Chlorophyll a determination: improvement in methodology. Oikos 30:438-447. ----------------------------------------------------------------------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The pH:SBE channel was removed from the files because sensor performance and recalibration are being studied and are not yet considered ready for the archive. The SBE Dissolved Oxygen sensor behaved poorly for all or part of some casts with concentration values offset by approximately 0.24mL/L from the normal looking casts. Data were recalibrated by applying an offset where appropriate before applying a general recalibration. The DO data must be considered of lower quality than usual. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.2383 1.0347) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !--1--- ---2---- --3-- ---4--- --5--- ---6---- --7--- --8-- -9-- 10 11 -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 !Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Samp Bo Bo Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl !re ure: missi cence: :T1:C1 : n: le_ tt tt er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag ! Secondar vity URU: Dissol Disso Numb ~u ~u ~bin ~o ed ~o plus_ ~t ~i ~p ! y Seapoin ved: lved: er mb en _rec tt lv Nitri ri ca ha ! t SBE SBE er ce ords le ed te te te te !------ -------- ----- ------- ------ -------- ------ ----- ---- -- -- ---- -------- -- ------- -- ----- -- ----- -- ------ -- *END OF HEADER 2.0 12.1343 45.5 0.750 490.9 30.6411 7.32 319.5 703 12 12 121 -99.0000 0 7.276 0 0.2 6 1.4 6 0.35 6 6.0 12.1232 45.7 1.261 136.9 30.6438 7.31 318.9 702 11 11 121 30.6508 0 7.290 0 0.2 0 1.4 0 0.36 0 10.9 12.0682 48.3 1.054 48.3 30.6593 7.45 324.9 701 10 10 121 -99.0000 0 7.400 0 0.2 0 1.2 0 0.36 0 15.7 11.8129 50.6 1.498 17.5 30.7411 7.02 306.2 700 9 9 121 -99.0000 0 7.065 0 0.5 0 2.5 0 0.46 0 21.2 11.8295 48.8 1.544 5.3 30.8562 6.74 294.1 699 8 8 121 -99.0000 0 6.718 0 0.6 0 2.4 0 0.52 0 30.5 11.9524 43.0 2.765 1.0 31.1301 5.52 240.6 698 7 7 121 -99.0000 0 5.685 0 3.5 0 10.3 0 0.95 0 40.9 11.1487 47.9 1.397 0.2 31.2071 5.64 246.1 697 6 6 121 -99.0000 0 5.621 0 6.0 0 13.5 0 1.05 0 50.8 11.0009 45.2 1.690 0.0 31.3356 5.45 237.7 696 5 5 121 -99.0000 0 5.293 0 8.2 0 16.9 0 1.19 0 71.1 9.4973 57.6 0.437 0.0 31.8079 4.64 202.1 695 4 4 121 -99.0000 0 4.666 0 15.0 0 26.1 0 1.49 0 81.0 8.8360 56.4 0.407 0.0 32.2847 4.41 192.3 694 3 3 121 -99.0000 0 4.340 0 18.1 0 31.1 0 1.65 0 92.1 7.6254 55.9 0.256 0.0 32.7958 3.06 133.3 692 1 1 76 -99.0000 0 3.331 0 24.4 0 44.2 0 2.05 0 92.1 7.6334 55.1 0.229 0.0 32.7903 3.05 132.9 693 2 2 121 32.6175 3 3.262 0 24.3 0 44.6 0 2.05 0