*2021/11/24 16:55:26.95 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2010/07/27 18:08:04.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 22 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : B841C737 NUMBER OF CHANNELS : 50 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 377 398 2 Bottle_Number n/a 1 22 3 Bottle:Firing_Sequence n/a 1 22 4 Pressure decibar 2.7 796.9 5 Temperature:Secondary 'deg C (ITS90)' 3.5024 11.9809 6 Transmissivity %/metre 48.7 65 7 Fluorescence:URU:Seapoint mg/m^3 0.44E-01 1.484 8 PAR uE/m^2/sec 0 411.1 9 Salinity:T1:C1 PSS-78 32.1181 34.2977 10 Oxygen:Dissolved:SBE mL/L 0.33 6.59 11 Oxygen:Dissolved:SBE umol/kg 14.2 287 12 Number_of_bin_records n/a 62 121 13 Salinity:Bottle PSS-78 32.1185 34.2528 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 0.327 6.541 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 3.3 45.6 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 8.7 127.5 20 Flag:Silicate n/a 21 Phosphate umol/L 0.73 3.3 22 Flag:Phosphate n/a 23 Chlorophyll:Extracted mg/m^3 0.44 0.81 24 Flag:Chlorophyll:Extracted n/a 25 Phaeo-Pigment:Extracted mg/m^3 0.21 0.37 26 HPLC:Chl-c3 mg/m^3 0.67E-01 0.121 27 HPLC:Chlide-a mg/m^3 0 0 28 HPLC:MgDVP mg/m^3 0.6E-02 0.9E-02 29 HPLC:Chl-c2 mg/m^3 0.57E-01 0.107 30 HPLC:Me-chlide mg/m^3 0 0 31 HPLC:Peri mg/m^3 0 0.8E-02 32 HPLC:Pheide-a mg/m^3 0 0 33 HPLC:But-fuco mg/m^3 0.42E-01 0.55E-01 34 HPLC:Fuco mg/m^3 0.126 0.198 35 HPLC:Neo mg/m^3 0.6E-02 0.1E-01 36 HPLC:Pras mg/m^3 0 0.7E-02 37 HPLC:Viola mg/m^3 0.6E-02 0.8E-02 38 HPLC:Hex-fuco mg/m^3 0.62E-01 0.235 39 HPLC:Diadino mg/m^3 0.8E-02 0.115 40 HPLC:Allo mg/m^3 0.12E-01 0.46E-01 41 HPLC:Diato mg/m^3 0 0.18E-01 42 HPLC:Zea mg/m^3 0.28E-01 0.96E-01 43 HPLC:Lut mg/m^3 0.8E-02 0.32E-01 44 HPLC:Chl-b mg/m^3 0.74E-01 0.77E-01 45 HPLC:DVChl-a mg/m^3 0 0 46 HPLC:Chl-a mg/m^3 0.461 0.832 47 HPLC:Phe mg/m^3 0 0 48 HPLC:B-Car mg/m^3 0.7E-02 0.15E-01 49 HPLC:TChl-a mg/m^3 0.461 0.832 50 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2010-36 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Ocean Acidification SCIENTIST : Ianson D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : W7 EVENT NUMBER : 47 LATITUDE : 56 1.62000 N ! (deg min) LONGITUDE : 135 34.47000 W ! (deg min) WATER DEPTH : 795 ALTIMETER (M) : 10.21 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/01/03 15:43:45 2554 2554 CLEAN 5.0.2 2011/01/03 15:45:03 ? ? ADDSAMP 3.4 2011/01/10 13:10:57 2554 2554 BINAVE 4.1.1 2011/01/10 13:12:24 2554 22 MERGE 3.4 2011/01/14 15:31:31 22 22 CLEAN 5.0.2 2011/01/14 17:23:07 ? ? CALIB 11.7 2011/02/07 09:25:03 22 22 SORT 3.5 2011/02/08 13:09:34 22 22 REMOVECH 8.0 2011/02/08 17:07:20 22 22 REMOVECH 8.0 2011/02/08 17:10:28 22 22 CHGUNITS 3.0 2011/02/08 17:18:36 22 22 REORDER 1.3 2011/02/09 14:56:46 ? ? HDREDIT2 2.5.1 2011/02/09 14:56:54 ? ? CALIB 11.7 2013/07/11 15:09:58 22 22 HDREDIT2 2.6 2013/07/11 15:17:36 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:08 22 22 CHANGE_FLAGS 2.0 2014/11/20 09:57:23 22 22 SORT 3.6 2020/11/30 13:15:08 22 22 REORDER 1.3.1 2021/11/24 16:53:51 ? ? MERGE 3.5.1 2021/11/24 16:54:17 22 22 SORT 3.6 2021/11/24 16:54:26 22 22 CLEAN 5.2.4 2021/11/24 16:54:35 22 22 HDREDIT2 3.2 2021/11/24 16:55:03 ? ? HDREDIT2 3.2 2021/11/24 16:55:26 ? ? $END $REMARKS -CLEAN functions: 2011/01/03 15:44:50 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\addsamp3.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/01/14 15:31:30 2011/01/14 15:31:30 2011/01/14 15:31: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Flag:Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0047.samavg Secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0047.mrgx Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0047.mrgx -------------------------------------------------------------------- -SORT parameters: 2011/01/14 15:31:11 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/01/14 17:23:07 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2011/02/07 09:25:03 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-recal-fit2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.2383000E+00 0.1034700E+01 -SORT parameters: 2011/02/08 13:09:34 Sorted in ascending order of channel Pressure -REMOVECH 2011/02/08 17:07:20 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Status:Pump Altimeter [metres] Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -REMOVECH 2011/02/08 17:10:28 The following CHANNEL(S) were removed: pH:SBE [pH Units] -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2011/02/09 14:56:54 Applied edit header: Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-bot-hdr.txt Channel 11: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 4: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 5: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 8: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 -CALIB parameters: 2013/07/11 15:09:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 24 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/11 15:17:36 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/11/30 13:15:08 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 16:54:17 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\ IOS\2010-036-0047.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\ IOS\2010-036-0047.hplc -SORT parameters: 2021/11/24 16:54:26 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 16:54:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 16:55:03 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 26: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 16:55:26 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0047.mrgx -------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0047.add ------------------------------------------------------------------- Sample_Number 379: OXY: vent open, integrity compromised; looks ok in COMPARE Sample_Number 387: OXY: vent open, integrity compromised; looks ok in COMPARE Analysis methods: - ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone for 24 hours in the lab immediately following the cruise and analyzed on a Turner 10AU flourometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen 1978). For details including information on precision see file 2010-36CHL.xls HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~7-10 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2010-036_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). The titration system consists of a Brinkmann 665 Dosimat, a UV light source and a UV detector with a 365nm filter custom built by Scripps Institution of Oceanography. For details including details on precision, see document 2010-36oxy.xls. Salinity samples were collected in glass bottles and analyzed at sea using a Guildline Portasal (#58879) or at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. See file 2010-36-salinity.xls for data for information on precision see 2010-36-salinity-duplicates.csv. Nutrient samples were collected in plastic tubes. Most samples were analyzed at sea on an Astoria-Pacific analyzer following methods described in Barwell-Clarke and Whitney (1996). Samples from Event #225 at station JF2 were frozen and analyzed after 2 weeks. For full data and details on nutrient duplicates and precision see file QF2010-36nuts.xls. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson, C. H., and R. T. Williams. 1991. A comparison of methods for the determination of dissolved oxygen in seawater. Report No. WHPO 91-2. WOCE Hydrographic Programme Office. Woods Hole Oceanographic Institution, Woods Hole, Mass. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 4. Holm-Hansen, O. (1978). Chlorophyll a determination: improvement in methodology. Oikos 30:438-447. ----------------------------------------------------------------------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The pH:SBE channel was removed from the files because sensor performance and recalibration are being studied and are not yet considered ready for the archive. The SBE Dissolved Oxygen sensor behaved poorly for all or part of some casts with concentration values offset by approximately 0.24mL/L from the normal looking casts. Data were recalibrated by applying an offset where appropriate before applying a general recalibration. The DO data must be considered of lower quality than usual. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\IOS\2010-036-0047. hplc --------------------------------------------------------------------------- Sample_Number 394: HPLC: >10%CV for TChl-a Sample_Number 395: HPLC: >10%CV for TChl-a 8. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.2383 1.0347) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 --25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- 50 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le ed te te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 393 17 22 2.7 11.9796 48.7 0.550 411.1 32.1185 6.57 286.5 121 -99.0000 0 6.540 0 3.3 0 8.7 0 0.73 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 392 16 18 6.1 11.9809 48.9 0.611 218.6 32.1181 6.56 286.1 121 32.1185 0 6.541 0 3.3 6 8.7 6 0.74 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 397 21 20 6.1 11.9729 48.9 0.632 212.7 32.1185 6.56 286.1 62 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 396 20 19 6.2 11.9755 48.8 0.659 215.6 32.1184 6.56 285.8 72 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 0.79 6 0.21 0.085 0.000 0.006 0.104 0.000 0.008 0.000 0.054 0.131 0.006 0.000 0.007 0.235 0.115 0.046 0.018 0.096 0.032 0.074 0.000 0.832 0.000 0.014 0.832 6 398 22 21 6.2 11.9723 48.8 0.606 208.0 32.1185 6.57 286.3 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 395 19 17 13.4 11.6621 49.6 1.484 83.0 32.1346 6.59 287.0 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 0.81 6 0.31 0.121 0.000 0.008 0.107 0.000 0.007 0.000 0.055 0.198 0.010 0.002 0.008 0.224 0.069 0.022 0.007 0.088 0.028 0.077 0.000 0.804 0.000 0.015 0.804 36 391 15 16 21.4 9.8420 58.4 0.875 33.0 32.1870 6.39 278.5 121 -99.0000 0 6.389 0 7.7 0 12.9 0 1.02 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 394 18 15 26.1 9.4371 59.9 0.704 20.1 32.2180 6.37 277.6 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 0.44 6 0.37 0.067 0.000 0.009 0.057 0.000 0.000 0.000 0.042 0.126 0.007 0.007 0.006 0.062 0.008 0.012 0.000 0.028 0.008 0.074 0.000 0.461 0.000 0.007 0.461 36 390 14 14 31.5 8.5401 62.7 0.379 12.1 32.2606 6.11 265.9 121 -99.0000 0 6.104 0 11.7 0 16.6 0 1.24 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 389 13 13 51.4 7.3199 64.0 0.123 3.3 32.3093 6.03 262.4 121 -99.0000 0 6.023 6 15.1 0 19.8 0 1.42 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 388 12 12 75.8 6.7203 64.4 0.073 0.9 32.4761 6.15 267.7 121 -99.0000 0 6.152 0 15.7 0 20.9 0 1.44 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 387 11 11 91.4 6.5668 64.4 0.062 0.4 32.5481 5.92 257.7 121 -99.0000 0 5.927 3 16.9 0 23.7 0 1.52 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 386 10 10 101.2 6.5141 64.4 0.053 0.2 32.6096 5.63 244.9 121 -99.0000 0 5.482 0 19.4 0 28.0 0 1.67 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 385 9 9 126.0 6.4149 64.3 0.050 0.0 33.0838 4.33 188.6 121 -99.0000 0 4.354 0 24.9 0 36.9 0 1.98 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 384 8 8 151.2 4.9616 64.6 0.093 0.0 33.2831 4.58 199.1 121 -99.0000 0 4.558 0 27.9 0 41.9 0 2.13 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 383 7 7 201.6 4.8790 64.7 0.044 0.0 33.7593 2.78 120.7 121 -99.0000 0 2.782 6 35.2 0 59.4 0 2.55 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 382 6 6 301.7 4.5375 64.9 0.049 0.0 33.9287 1.34 58.1 121 -99.0000 0 1.328 0 41.4 0 78.9 0 2.95 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 381 5 5 401.4 4.3449 65.0 0.049 0.0 34.0123 0.89 38.7 121 -99.0000 0 0.886 0 43.1 0 89.9 0 3.08 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 380 4 4 501.9 4.1453 65.0 0.049 0.0 34.1369 0.52 22.4 121 -99.0000 0 0.549 0 44.3 0 102.7 0 3.18 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 379 3 3 601.5 3.8631 64.8 0.049 0.0 34.2140 0.39 17.1 121 -99.0000 0 0.382 3 45.0 0 114.4 0 3.25 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 378 2 2 701.6 3.6903 64.5 0.049 0.0 34.2548 0.36 15.7 121 34.2528 0 0.362 0 45.6 0 121.2 0 3.27 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 377 1 1 796.9 3.5024 64.8 0.049 0.0 34.2977 0.33 14.2 121 -99.0000 0 0.327 0 45.4 0 127.5 0 3.30 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0