*2021/11/24 16:55:26.42 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2010/07/24 01:26:58.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 6F31F357 NUMBER OF CHANNELS : 49 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 155 178 2 Bottle_Number n/a 1 24 3 Bottle:Firing_Sequence n/a 1 24 4 Pressure decibar 3 1065.1 5 Temperature:Secondary 'deg C (ITS90)' 3.1762 12.6951 6 Transmissivity %/metre 41.4 65.3 7 Fluorescence:URU:Seapoint mg/m^3 0.25E-01 1.88 8 Salinity:T1:C1 PSS-78 31.7455 34.3931 9 Oxygen:Dissolved:SBE mL/L 0.28 6.48 10 Oxygen:Dissolved:SBE umol/kg 12 282.7 11 Number_of_bin_records n/a 70 121 12 Salinity:Bottle PSS-78 31.7469 34.2853 13 Flag:Salinity:Bottle n/a 14 Oxygen:Dissolved mL/L 0.38 6.442 15 Flag:Oxygen:Dissolved n/a 16 Nitrate_plus_Nitrite umol/L 2.4 45.8 17 Flag:Nitrate_plus_Nitrite n/a 18 Silicate umol/L 9.2 138.4 19 Flag:Silicate n/a 20 Phosphate umol/L 0.62 3.27 21 Flag:Phosphate n/a 22 Chlorophyll:Extracted mg/m^3 1.52 2.5 23 Flag:Chlorophyll:Extracted n/a 24 Phaeo-Pigment:Extracted mg/m^3 0.7 0.81 25 HPLC:Chl-c3 mg/m^3 0.1 0.144 26 HPLC:Chlide-a mg/m^3 0.7E-02 0.2E-01 27 HPLC:MgDVP mg/m^3 0.21E-01 0.27E-01 28 HPLC:Chl-c2 mg/m^3 0.192 0.308 29 HPLC:Me-chlide mg/m^3 0 0.5E-02 30 HPLC:Peri mg/m^3 0.83E-01 0.208 31 HPLC:Pheide-a mg/m^3 0 0.174 32 HPLC:But-fuco mg/m^3 0.3E-01 0.52E-01 33 HPLC:Fuco mg/m^3 0.383 0.457 34 HPLC:Neo mg/m^3 0.2E-01 0.26E-01 35 HPLC:Pras mg/m^3 0.31E-01 0.37E-01 36 HPLC:Viola mg/m^3 0.12E-01 0.27E-01 37 HPLC:Hex-fuco mg/m^3 0.182 0.2 38 HPLC:Diadino mg/m^3 0.46E-01 0.138 39 HPLC:Allo mg/m^3 0.61E-01 0.169 40 HPLC:Diato mg/m^3 0.2E-02 0.12E-01 41 HPLC:Zea mg/m^3 0.94E-01 0.97E-01 42 HPLC:Lut mg/m^3 0.14E-01 0.19E-01 43 HPLC:Chl-b mg/m^3 0.251 0.26 44 HPLC:DVChl-a mg/m^3 0 0 45 HPLC:Chl-a mg/m^3 1.656 2.305 46 HPLC:Phe mg/m^3 0 0 47 HPLC:B-Car mg/m^3 0.38E-01 0.48E-01 48 HPLC:TChl-a mg/m^3 1.663 2.321 49 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 8 F R4 3 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2010-36 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Ocean Acidification SCIENTIST : Ianson D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : QCS7 EVENT NUMBER : 17 LATITUDE : 51 37.19000 N ! (deg min) LONGITUDE : 130 46.17000 W ! (deg min) WATER DEPTH : 1039 ALTIMETER (M) : 12.55 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/01/03 15:43:36 2853 2853 CLEAN 5.0.2 2011/01/03 15:44:56 ? ? ADDSAMP 3.4 2011/01/10 13:10:50 2853 2853 BINAVE 4.1.1 2011/01/10 13:12:21 2853 24 MERGE 3.4 2011/01/14 15:31:31 24 24 CLEAN 5.0.2 2011/01/14 17:23:07 ? ? CALIB 11.7 2011/02/07 09:15:36 24 24 SORT 3.5 2011/02/08 13:09:33 24 24 REMOVECH 8.0 2011/02/08 17:06:43 24 24 REMOVECH 8.0 2011/02/08 17:10:28 24 24 CHGUNITS 3.0 2011/02/08 17:18:36 24 24 REORDER 1.3 2011/02/09 14:56:45 ? ? HDREDIT2 2.5.1 2011/02/09 14:56:53 ? ? CALIB 11.7 2013/07/11 15:09:57 24 24 HDREDIT2 2.6 2013/07/11 15:17:35 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:35:08 24 24 CHANGE_FLAGS 2.0 2014/11/20 09:57:22 24 24 SORT 3.6 2020/11/30 13:15:07 24 24 REORDER 1.3.1 2021/11/24 16:53:51 ? ? MERGE 3.5.1 2021/11/24 16:54:17 24 24 SORT 3.6 2021/11/24 16:54:25 24 24 CLEAN 5.2.4 2021/11/24 16:54:34 24 24 HDREDIT2 3.2 2021/11/24 16:55:02 ? ? HDREDIT2 3.2 2021/11/24 16:55:26 ? ? $END $REMARKS -CLEAN functions: 2011/01/03 15:44:50 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\addsamp3.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/01/14 15:31:30 2011/01/14 15:31:30 2011/01/14 15:31: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Flag:Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0017.samavg Secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0017.mrgx Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0017.mrgx -------------------------------------------------------------------- -SORT parameters: 2011/01/14 15:31:10 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/01/14 17:23:07 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2011/02/07 09:15:36 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-recal-fit1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 -0.2370000E-01 0.1049200E+01 -SORT parameters: 2011/02/08 13:09:33 Sorted in ascending order of channel Pressure -REMOVECH 2011/02/08 17:06:43 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Status:Pump Altimeter [metres] Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -REMOVECH 2011/02/08 17:10:28 The following CHANNEL(S) were removed: pH:SBE [pH Units] -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2011/02/09 14:56:53 Applied edit header: Q:\Cruise_Data_Processing\2010-36\Processing\doc\2010-36-bot-hdr.txt Channel 10: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 4: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 9: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 16: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 7: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 -CALIB parameters: 2013/07/11 15:09:57 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 23 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/11 15:17:35 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/11/30 13:15:07 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 16:54:17 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\ IOS\2010-036-0017.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036_Nov2021\Processing\ IOS\2010-036-0017.hplc -SORT parameters: 2021/11/24 16:54:25 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 16:54:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 16:55:02 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 16:55:26 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-036-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0017.mrgx -------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2010-36\Processing\hydro\2010-36-0017.add ------------------------------------------------------------------- Sample_Number 155: OXY: bad curve; looks ok in COMPARE Sample_Number 156: OXY: stopper popped, large bubble in sample Analysis methods: - ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone for 24 hours in the lab immediately following the cruise and analyzed on a Turner 10AU flourometer calibrated with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen 1978). For details including information on precision see file 2010-36CHL.xls HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~7-10 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2010-036_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). The titration system consists of a Brinkmann 665 Dosimat, a UV light source and a UV detector with a 365nm filter custom built by Scripps Institution of Oceanography. For details including details on precision, see document 2010-36oxy.xls. Salinity samples were collected in glass bottles and analyzed at sea using a Guildline Portasal (#58879) or at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. See file 2010-36-salinity.xls for data for information on precision see 2010-36-salinity-duplicates.csv. Nutrient samples were collected in plastic tubes. Most samples were analyzed at sea on an Astoria-Pacific analyzer following methods described in Barwell-Clarke and Whitney (1996). Samples from Event #225 at station JF2 were frozen and analyzed after 2 weeks. For full data and details on nutrient duplicates and precision see file QF2010-36nuts.xls. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson, C. H., and R. T. Williams. 1991. A comparison of methods for the determination of dissolved oxygen in seawater. Report No. WHPO 91-2. WOCE Hydrographic Programme Office. Woods Hole Oceanographic Institution, Woods Hole, Mass. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 4. Holm-Hansen, O. (1978). Chlorophyll a determination: improvement in methodology. Oikos 30:438-447. ----------------------------------------------------------------------------------- Transmissivity, fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The pH:SBE channel was removed from the files because sensor performance and recalibration are being studied and are not yet considered ready for the archive. The SBE Dissolved Oxygen sensor behaved poorly for all or part of some casts with concentration values offset by approximately 0.24mL/L from the normal looking casts. Data were recalibrated by applying an offset where appropriate before applying a general recalibration. The DO data must be considered of lower quality than usual. July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers 8. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.237E-01 1.0492) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- ---12--- 13 ---14-- 15 --16- 17 --18- 19 --20-- 21 --22-- 23 --24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- 49 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le ed te te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 174 20 24 3.0 12.6869 41.4 1.445 31.7467 6.47 282.0 121 -99.0000 0 6.442 0 2.5 0 9.2 0 0.63 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 177 23 22 6.1 12.6951 41.5 1.719 31.7455 6.48 282.7 70 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 2.37 6 0.70 0.115 0.012 0.027 0.308 0.005 0.208 0.174 0.052 0.457 0.026 0.037 0.027 0.200 0.138 0.169 0.012 0.097 0.019 0.257 0.000 2.305 0.000 0.048 2.321 6 173 19 21 6.2 12.6763 41.6 1.792 31.7475 6.46 281.6 121 31.7469 0 6.440 0 2.4 0 9.2 0 0.63 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 178 24 23 6.2 12.6941 41.5 1.719 31.7463 6.48 282.4 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 176 22 20 7.9 12.6754 41.6 1.793 31.7478 6.47 282.1 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 2.50 6 0.77 0.100 0.020 0.025 0.294 0.000 0.197 0.000 0.040 0.426 0.020 0.031 0.025 0.182 0.120 0.141 0.012 0.096 0.015 0.251 0.000 2.122 0.000 0.042 2.142 6 172 18 19 11.5 12.6453 42.2 1.880 31.7520 6.46 281.6 121 -99.0000 0 6.416 0 2.6 0 9.3 0 0.62 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 171 17 17 21.8 12.2201 49.5 1.481 31.8265 6.30 274.5 121 -99.0000 0 6.260 0 3.4 0 10.1 0 0.66 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 175 21 18 21.8 12.2048 49.6 1.473 31.8270 6.28 273.8 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 1.52 6 0.81 0.144 0.007 0.021 0.192 0.000 0.083 0.000 0.030 0.383 0.025 0.035 0.012 0.188 0.046 0.061 0.002 0.094 0.014 0.260 0.000 1.656 0.000 0.038 1.663 6 170 16 16 31.3 11.9160 53.3 1.029 31.8760 6.15 268.2 121 -99.0000 0 6.117 0 4.3 0 10.7 0 0.72 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 169 15 15 41.6 11.2669 57.6 0.637 31.9411 5.92 258.1 121 -99.0000 0 5.899 0 6.2 0 12.4 0 0.85 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 168 14 14 51.3 10.5253 61.0 0.325 32.0654 5.83 254.0 121 -99.0000 0 5.789 0 8.0 6 13.9 6 0.99 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 167 13 13 71.5 9.2845 63.2 0.152 32.2723 5.74 249.8 121 -99.0000 0 5.649 0 11.3 0 17.5 0 1.17 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 166 12 12 92.0 7.7394 65.0 0.068 32.5178 6.09 265.3 121 -99.0000 0 6.068 6 12.0 0 16.4 0 1.21 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 165 11 11 101.1 7.3997 65.0 0.038 32.7951 5.35 233.1 121 -99.0000 0 5.378 0 16.7 0 22.0 0 1.46 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 164 10 10 125.9 6.9788 64.7 0.029 33.1283 4.54 197.6 121 -99.0000 0 4.516 0 22.1 0 30.3 0 1.77 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 163 9 9 152.2 6.7036 64.5 0.025 33.4680 3.76 163.5 121 -99.0000 0 3.778 0 26.4 0 37.3 0 2.01 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 162 8 8 176.7 6.4291 64.8 0.025 33.6937 3.45 150.1 121 -99.0000 0 3.478 0 28.8 0 41.8 0 2.12 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 161 7 7 202.0 6.1236 64.8 0.027 33.8398 2.81 122.3 121 -99.0000 0 2.811 0 32.2 0 50.0 0 2.32 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 160 6 6 251.0 5.6595 64.7 0.028 33.8757 2.44 106.1 121 -99.0000 0 2.429 6 34.8 0 57.4 0 2.49 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 159 5 5 301.6 5.2397 65.1 0.030 33.9271 1.77 76.9 121 -99.0000 0 1.785 0 38.3 0 67.4 0 2.73 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 158 4 4 401.2 4.9011 65.3 0.033 34.0517 0.89 38.7 121 -99.0000 0 0.902 0 41.8 0 82.6 0 3.02 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 157 3 3 601.3 4.4331 64.7 0.035 34.1737 0.43 18.9 121 -99.0000 0 0.441 0 44.0 0 100.3 0 3.17 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 156 2 2 802.0 3.8041 64.7 0.036 34.2965 0.28 12.0 121 34.2853 0 0.592 4 45.4 0 120.6 0 3.27 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 155 1 1 1065.1 3.1762 64.2 0.037 34.3931 0.36 15.5 121 -99.0000 0 0.380 0 45.8 0 138.4 0 3.27 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0