*2021/11/24 16:39:03.17 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2010/08/23 21:39:04.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 695D6AA1 NUMBER OF CHANNELS : 55 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 234 252 2 Bottle_Number n/a 1 19 3 Bottle:Firing_Sequence n/a 1 19 4 Pressure decibar 2 300.9 5 Temperature:Secondary 'deg C (ITS90)' 4.7638 15.1267 6 Transmissivity %/metre 47.4 61.5 7 Fluorescence:URU:Seapoint mg/m^3 0.18E-01 3.076 8 PAR uE/m^2/sec 0 383 9 Salinity:T1:C1 PSS-78 32.4439 33.8523 10 Oxygen:Dissolved:SBE mL/L 2.56 6.81 11 Oxygen:Dissolved:SBE umol/kg 111.4 296.5 12 Number_of_bin_records n/a 80 241 13 Salinity:Bottle PSS-78 32.4782 32.4782 14 Flag:Salinity:Bottle n/a 15 Nitrate_plus_Nitrite umol/L 2.1 35.4 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 4.3 66.8 18 Flag:Silicate n/a 19 Phosphate umol/L 0.58 2.55 20 Flag:Phosphate n/a 21 Dimethyl_Sulphide nmol/L 0 21.83 22 Flag:Dimethyl_Sulphide n/a 23 Dimethylsulfoniopropionate_Dissolved nmol/L 0 1.9 24 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 25 Dimethylsulfoniopropionate_Total nmol/L 0 114 26 Flag:Dimethylsulfoniopropionate_Total ' ' 27 Chlorophyll:Extracted mg/m^3 0.12 0.58 28 Flag:Chlorophyll:Extracted n/a 29 Phaeo-Pigment:Extracted mg/m^3 0.1 0.32 30 HPLC:Chl-c3 mg/m^3 0.31E-01 0.112 31 HPLC:Chlide-a mg/m^3 0 0 32 HPLC:MgDVP mg/m^3 0 0.4E-02 33 HPLC:Chl-c2 mg/m^3 0.52E-01 0.92E-01 34 HPLC:Chl-c1 mg/m^3 0 0 35 HPLC:Me-chlide mg/m^3 0 0 36 HPLC:Peri mg/m^3 0.17E-01 0.37E-01 37 HPLC:Pheide-a mg/m^3 0 0 38 HPLC:But-fuco mg/m^3 0.54E-01 0.67E-01 39 HPLC:Fuco mg/m^3 0.44E-01 0.79E-01 40 HPLC:Neo mg/m^3 0.3E-02 0.17E-01 41 HPLC:Pras mg/m^3 0 0 42 HPLC:Viola mg/m^3 0.3E-02 0.7E-02 43 HPLC:Hex-fuco mg/m^3 0.139 0.333 44 HPLC:Diadino mg/m^3 0.2E-01 0.57E-01 45 HPLC:Allo mg/m^3 0 0 46 HPLC:Diato mg/m^3 0.1E-02 0.1E-01 47 HPLC:Zea mg/m^3 0 0.2E-02 48 HPLC:Lut mg/m^3 0.3E-02 0.5E-02 49 HPLC:Chl-b mg/m^3 0.38E-01 0.132 50 HPLC:DVChl-a mg/m^3 0 0 51 HPLC:Chl-a mg/m^3 0.326 0.525 52 HPLC:Phe mg/m^3 0 0 53 HPLC:B-Car mg/m^3 0.2E-02 0.5E-02 54 HPLC:TChl-a mg/m^3 0.326 0.525 55 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- Comments from secondary file: P:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.che2 -------------------------------------------------------------------------------------- This file converted from Sea-Bird file: Q:\Cruise_Data_Processing\2010-14\Rep $END *ADMINISTRATION MISSION : 2010-14 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P16 EVENT NUMBER : 48 LATITUDE : 49 17.01000 N ! (deg min) LONGITUDE : 134 39.97000 W ! (deg min) WATER DEPTH : 3636 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.18C Comments from secondary file: P:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.che2 --------------------------------------------------------------------------- SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2011/03/22 13:20:07 4276 4276 CLEAN 5.0.2 2011/03/22 18:00:42 4276 4276 ADDSAMP 3.4 2011/03/24 14:07:27 4276 4276 BINAVE 4.1.1 2011/03/24 14:08:16 4276 19 MERGE 3.4 2011/05/07 15:20:15 19 19 CLEAN 5.0.2 2011/05/07 15:32:59 19 19 CALIB 11.7 2011/05/07 15:33:13 19 19 SORT 3.5 2011/05/07 15:33:48 19 19 REMOVECH 8.0 2011/05/07 15:35:56 19 19 CHGUNITS 3.0 2011/05/07 15:36:13 19 19 REORDER 1.3 2011/05/07 15:36:20 ? ? CLEAN 5.0.2 2011/05/13 15:30:13 19 19 HDREDIT2 2.5.1 2011/05/13 15:40:59 ? ? SORT 3.5 2011/07/07 15:35:27 19 19 MERGE 3.4 2011/10/18 14:10:30 19 19 REORDER 1.3 2011/10/18 14:17:36 ? ? SORT 3.5 2011/10/18 14:22:04 19 19 CALIB 11.7 2013/06/04 13:14:45 19 19 HDREDIT2 2.6 2013/07/08 08:50:32 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:34:50 19 19 CHANGE_FLAGS 2.0 2014/11/20 09:57:08 19 19 SORT 3.6 2015/07/16 09:07:16 19 19 MERGE 3.5 2015/07/16 09:16:41 19 19 SORT 3.6 2015/07/16 09:16:53 19 19 REMOVECH 8.2 2020/07/24 16:26:36 19 19 SORT 3.6 2020/07/24 16:26:56 19 19 MERGE 3.5.1 2020/07/24 16:40:02 19 19 SORT 3.6 2020/07/24 16:40:29 19 19 CLEAN 5.2.4 2020/07/24 16:43:14 19 19 SORT 3.6 2020/11/25 09:23:55 19 19 $END $REMARKS -CLEAN functions: 2011/03/22 18:00:25 20 Reset #RECS, MIN & MAX values in header. Insert Pad Values in Channel: Fluorescence:Seapoint [mg/m^3] where channel Fluorescence:Seapoint [mg/m^3] is in the range 21 to 1000 0 data records in pad range. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2010-14\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/05/07 15:20:13 2011/05/07 15:20:13 2011/05/07 15:20: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2010-14\Processing\hydro\2010-14-0048.samavg Secondary file: Q:\Cruise_Data_Processing\2010-14\Processing\hydro\2010-14-0048.mrgcln1s Comments from secondary file: Q:\Cruise_Data_Processing\2010-14\Processing\hydro\2010-14-0048.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2011/05/06 14:05:17 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/05/07 15:32:58 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2011/05/07 15:33:13 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-14\Processing\doc\2010-14-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 15 Salinity:T0:C0 PSS-78 10 0.6000000E-02 0.1000000E+01 16 Salinity:T1:C1 PSS-78 10 0.1500000E-02 0.1000000E+01 17 Oxygen:Dissolved:SBE mL/L 10 -0.1600000E-02 0.1127300E+01 -SORT parameters: 2011/05/07 15:33:48 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2011/05/07 15:35:56 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Status:Pump Descent_Rate [m/s] Altimeter [metres] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -CLEAN functions: 2011/05/13 15:30:13 20 Reset #RECS, MIN & MAX values in header. -HEADER EDITS: 2011/05/13 15:40:59 Applied edit header: Q:\Cruise_Data_Processing\2010-14\Processing\doc\2010-14-bot-hdr2.txt Channel 11: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 4: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 5: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 8: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 Channel 24: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L -SORT parameters: 2011/07/07 15:35:27 Sorted in ascending order of channel Bottle_Number [n/a] -The following MERGE parameters were used: 2011/10/18 14:10:30 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Secondary, Transmissivity, Fluorescence:URU:Seapoint, PAR, Salinity:T1:C1, Sample_Number, Bottle_Number, Bottle:Firing_Sequence, Number_of_bin_records, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Secondary Channels to Include: Oxygen:Dissolved:SBE [mL/L], Oxygen:Dissolved:SBE [umol/kg] Primary file : P:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.che1 Secondary file: P:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.che2 Comments from secondary file: P:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.che2 --------------------------------------------------------------------------- -CLEAN functions: 2011/07/02 14:19:35 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number [n/a] -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2011/07/07 16:29:23 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Bottle:Position Primary file : Q:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.samavg Secondary file: Q:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.mrgsort1 Comments from secondary file: Q:\Cruise_Data_Processing\2010-14\Reprocess\Processing\hydro\2010-14-0048.mrgsort1 --------------------------------------------------------------------------- -SORT parameters: 2011/07/03 15:49:09 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2011/07/07 17:36:19 Insert Pad Values in Channel: Oxygen:Dissolved:SBE [mL/L] where channel Pressure [dbars] is in the range 2200 to 10000 0 data records in pad range. Remove Sea-Bird comments from the header. -CALIB parameters: 2011/07/07 17:36:38 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-14\Reprocess\Processing\doc\2010-14-1483-recal1.C Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Oxygen:Dissolved:SBE mL/L 10 -0.1150000E-01 0.1033500E+01 -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2011/07/07 17:52:27 Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 14: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 20: Bottle_Number [] Name: Bottle:Position ==> Bottle_Number Channel 21: Oxygen:Dissolved:SBE [umol/kg] Format: F6.2 ==> F6.1 -SORT parameters: 2011/07/07 17:53:16 Sorted in ascending order of channel Bottle_Number -SORT parameters: 2011/10/18 14:22:04 Sorted in ascending order of channel Pressure -CALIB parameters: 2013/06/04 13:14:45 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 22 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:50:32 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2015/07/16 09:07:16 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2015/07/16 09:16:41 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : P:\Cruise_Data_Processing\DMSP\2010-14\Bottle\2010-14-0048.che1 Secondary file: P:\Cruise_Data_Processing\DMSP\2010-14\Bottle\2010-14-0048.dmsp -SORT parameters: 2015/07/16 09:16:53 Sorted in ascending order of channel Pressure -REMOVECH 2020/07/24 16:26:36 The following CHANNEL(S) were removed: Dimethylsulfoniopropionate_Dissolved [nmol/L] Flag:Dimethylsulfoniopropionate_Dissolve Dimethylsulfoniopropionate_Total [nmol/L] Flag:Dimethylsulfoniopropionate_Total -SORT parameters: 2020/07/24 16:26:56 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2020/07/24 16:40:02 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2010-014\Processing\2010-014- 0048.chesort Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2010-014\Processing\2010-014- 0048.dmsp -SORT parameters: 2020/07/24 16:40:29 Sorted in ascending order of channel Pressure -CLEAN functions: 2020/07/24 16:43:05 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* -SORT parameters: 2020/11/25 09:23:55 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 16:37:58 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-014_Nov2021\Processing\ IOS\2010-014-0048.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-014_Nov2021\Processing\ IOS\2010-014-0048.hplc -SORT parameters: 2021/11/24 16:38:08 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 16:38:15 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 16:38:41 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-014-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 30: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 16:39:03 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-014-bot-hdr2.txt $END *COMMENTS Analysis methods: - ----------------- Chlorophyll and Phaeo-Pigments samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 12, 2010 using pure chlorophyll a. Chlorophyll and Phaeo-Pigments precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF2010-14CHL*.xls. Oxygen samples were analyzed at sea using an automated Winkler titration system with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). The titration system consists of a Brinkmann 665 Dosimat, a UV light source and a UV detector with a 365nm filter custom built by Scripps Institution of Oceanography. For details including a duplicate analysis, see document 2010-14oxy*.xls. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. See file 2010-14-sal.xls for analysis output. For information on precision see 2010-14-sal-duplicates.xls. Nutrient samples were collected in plastic tubes. Most samples were analyzed frozen at IOS using an Astoria autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Deep silicate samples (400m and below) were analyzed cool at IOS. For full data and details on nutrient duplicates and precision see file QF2010-14nuts*.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2010-14 DMS Report.doc and for data see DMS 2010-14 summary.xls. The minimum detectable level for DMSP is 0.10 nM, so “0” values should be interpreted as <0.10. For details on analysis and raw data, see document "2010-14 dmsp QF summary.xls. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson, C. H., and R. T. Williams. 1991. A comparison of methods for the determination of dissolved oxygen in seawater. Report No. WHPO 91-2. WOCE Hydrographic Programme Office. Woods Hole Oceanographic Institution, Woods Hole, Mass. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. ----------------------------------------------------------------------------------- Fluorescence, Transmissivity and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The quality of the SBE Dissolved Oxygen data is lower than usual for both sensors because recalibration was based on observations from very few casts, and the fits of bottles against CTD produced significantly different fits for some casts from others. Similar problems were found in sensor #1176 (CTD#0506) on some other 2010 cruises and appear to be associated with CTD communication problems. For Dissolved Oxygen Sensor #1438 there is evidence of hysteresis, so data from below 2200db have been replaced with pad values. For details see the processing report 2010-14-proc.doc. ************************************************************************** In June 2011 it was discovered that the wrong information was used for recalibration of the SBE Dissolved Oxygen sensor. Sensor #1483 was actually used for this cruise, rather than sensor #1438 as originally recorded. The SBE Dissolved Oxygen channel was reprocessed after an initial study determined that the differences were significant. A new recalibration scheme was found by rerunning the bottle comparison. The files were then merged with all the other channels from the original processing. The hysteresis noted in the original processing remains, and the quality of the data is still considered of lower quality than usual. For details see the notes at the end of the processing report 2010-14-proc.doc. ************************************************************************** July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2010-014\Processing\2010-014-0048.dmsp --------------------------------------------------------------------------- Sample_Number 243: DMSP-D & DMSP-T: Second duplicate lost. Result is not an average Sample_Number 246: DMSP-D: Sample lost Sample_Number 247: DMSP-D: Sample lost Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2010\2010-014_Nov2021\Processing\IOS\2010-014-0048. hplc --------------------------------------------------------------------------- Sample_Number 249: HPLC: >10%CV for TChl-a HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~4 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2010-014_HPLC*.xlsx. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.6E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (0.15E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.16E-02 1.1273) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 --23-- 24 --25-- 26 --27-- 28 --29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- 55 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Salinity Fl Nitra Fl Silic Fl Phosph Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o :Bottle ag te_ ag ate ag ate ag yl_ ag ylsulf ag ylsulf ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin ~o plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec tt Nitri ri ca ha de hi te_Dis lv ionate ot ted ct Extrac HP ! ence t SBE SBE ords le te te te te de solved ed _Total al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- -------- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 247 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