*2014/11/20 09:57:06.23 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2010/06/16 22:03:46.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 5 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 36E326D6 NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 444 448 2 Pressure decibar 2 30.2 3 Temperature:Secondary 'deg C (ITS90)' 7.3233 7.6439 4 Transmissivity %/metre 49.2 49.8 5 Fluorescence:URU:Seapoint mg/m^3 0.187 1.353 6 PAR uE/m^2/sec 329.6 7070.9 7 Oxygen:Dissolved:SBE mL/L 6.78 6.81 8 Oxygen:Dissolved:SBE umol/kg 295 296.6 9 Salinity:T1:C1 PSS-78 32.707 32.7112 10 Number_of_bin_records n/a 121 121 11 Bottle_Number n/a 1 5 12 Bottle:Firing_Sequence n/a 1 5 13 Salinity:Bottle PSS-78 32.7085 32.7113 14 Flag:Salinity:Bottle n/a 15 Nitrate_plus_Nitrite umol/L 11.84718 12.4359 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 16.9 17.3 18 Flag:Silicate n/a 19 Phosphate umol/L 1.07703 1.15795 20 Flag:Phosphate n/a 21 pH n/a 7.7888 7.792 22 Flag:pH n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 7 F ' ' 1 7 -99 ' ' 7 F ' ' 2 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 ' ' ' ' 5 I I 0 11 -99 ' ' 3 I I 0 12 -99 ' ' 3 I I 0 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' ' ' F9.4 R4 ' ' 22 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2010-13 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : PA004 EVENT NUMBER : 63 LATITUDE : 50 2.82000 N ! (deg min) LONGITUDE : 144 52.69000 W ! (deg min) WATER DEPTH : 4229 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $REMARKS SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2010/08/24 16:15:34 605 605 CLEAN 5.0.2 2010/08/24 16:16:08 ? ? ADDSAMP 3.4 2010/08/27 11:52:52 605 605 BINAVE 4.1.1 2010/08/27 11:53:12 605 5 CALIB 11.7 2010/09/03 11:34:51 5 5 MERGE 3.4 2010/10/20 16:06:03 5 5 CLEAN 5.0.2 2010/10/20 16:06:11 ? ? CALIB 11.7 2010/11/09 11:43:03 5 5 SORT 3.5 2010/11/09 11:43:14 5 5 REMOVECH 8.0 2010/11/09 11:45:10 5 5 CHGUNITS 3.0 2010/11/09 11:45:46 5 5 REORDER 1.2.1 2010/11/09 11:45:53 ? ? HDREDIT2 2.5.1 2010/11/10 15:51:31 ? ? HDREDIT2 2.5.1 2010/11/15 17:37:05 ? ? SORT 3.5 2011/07/20 14:27:50 5 5 MERGE 3.4 2011/07/20 14:34:20 5 5 HDREDIT2 2.5.1 2011/07/20 14:42:33 ? ? SORT 3.5 2011/07/20 14:44:05 5 5 CALIB 11.7 2013/06/04 13:14:16 5 5 HDREDIT2 2.6 2013/07/08 08:50:23 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:31:31 5 5 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:34:49 5 5 CHANGE_FLAGS 2.0 2014/11/20 09:57:06 5 5 $END $REMARKS -CLEAN functions: 2010/08/24 16:15:49 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2010-13\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -CALIB parameters: 2010/09/03 11:34:51 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-13\Processing\doc\2010-13-recal-press.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 2 Pressure dbars 10 0.0000000E+00 0.9998800E+00 -The following MERGE parameters were used: 2010/10/20 16:06:01 2010/10/20 16:06:01 2010/10/20 16:06: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Flag:Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2010-13\Processing\hydro\2010-13-0063.samavg Secondary file: Q:\Cruise_Data_Processing\2010-13\Processing\hydro\2010-13-0063.mrgcln1 -CLEAN functions: 2010/10/20 16:06:09 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2010/11/09 11:43:03 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2010-13\Processing\doc\2010-13-recal-bottle.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Transmissivity %/metre 10 0.0000000E+00 0.2500000E+01 17 Salinity:T1:C1 PSS-78 10 -0.2500000E-02 0.1000000E+01 18 Oxygen:Dissolved:SBE mL/L 10 0.5700000E-02 0.1041400E+01 -SORT parameters: 2010/11/09 11:43:14 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2010/11/09 11:45:10 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] pH:SBE [pH Units] Status:Pump Descent_Rate [m/s] Altimeter [metres] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2010/11/10 15:51:31 Applied edit header: Q:\Cruise_Data_Processing\2010-13\Processing\doc\2010-13-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a -HEADER EDITS: 2010/11/15 17:37:05 Channel 12: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 11: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number -SORT parameters: 2011/07/20 14:27:50 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2011/07/20 14:34:20 2011/07/20 14:34:20 2011/07/20 14:34: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Average Primary Channels to Include: ALL Secondary Channels to Include: pH, Flag:pH Primary file : H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\2010-13\2010-13-0063.chesrt Secondary file: H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\2010-13\2010-13-0063.iossrt Comments from secondary file: H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\2010-13\2010-13-0063.iossrt --------------------------------------------------------------------------- -SORT parameters: 2011/07/20 14:27:16 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2011/07/20 14:42:33 Applied edit header: H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\DIC_ALK_pH.txt -SORT parameters: 2011/07/20 14:44:05 Sorted in ascending order of channel Pressure -CALIB parameters: 2013/06/04 13:14:16 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 15 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 19 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:50:23 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt $END *COMMENTS Analysis methods: - ----------------- Chlorophyll and Phaeo-Pigments samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 12, 2009 using pure chlorophyll a. Chlorophyll and Phaeo-Pigments precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2010-13 CHLChauv.xls. Oxygen samples were analyzed at sea using an automated Winkler titration system with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). The titration system consists of a Brinkmann 665 Dosimat, a UV light source and a UV detector with a 365nm filter custom built by Scripps Institution of Oceanography. For details including a duplicate analysis, see document 2010-13oxy.xls. Salinity samples were collected in glass bottles and analyzed at sea using a Guildline Portasal (#58879) or at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. See file 2010-13sal.xls for Autosal data and 2010-13 P8 Sal.txt and 2010-13-P16.txt for Portasal data. For information on precision see 2010-13-sal-duplicates.xls. Nutrient samples were collected in plastic tubes. Most samples were analyzed frozen at IOS using an Astoria autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Deep silicate samples (400m and below) were analyzed cool at IOS. For full data and details on nutrient duplicates and precision see file QF2010-13nuts.xls. NOTE: FROZEN SAMPLES WERE ACCIDENTALLY THAWED FOR 2 DAYS AT ROOM TEMPERATURE THEN STORED COOL UNTIL ANALYZED. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2010-13 DMS Report.doc and for data see DMS 2010-13 summary.xls. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. pH on the total hydrogren ion concentration scale was determined photometrically and is reported at 25C and surface pressure. Complete documentation on DIC, ALK and pH sampling, analysis and precision estimates can be found in the Carbon Excel file from the cruise located in the cruise "DOC" directory. . References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. Culberson C.H. (1991) Dissolved oxygen. In WOCE Operations Manual. Volume 3: The Observational Program. Section 3.1: WOCE Hydrographic Program. Part 3.1.3: WHP Operations and Methods. WHP Office Report WHPO 91-1 / WOCE Report No. 68/91. 3. Barwell-Clarke, J. and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. ----------------------------------------------------------------------------------- ********************************************************************************** Transmissometer #1005DR was calibrated in March 2008, and drifted significantly but steadily until July 2009; then a sudden shift occurred, so that maximum values between September 2009 and July 2010 were very low, ~25%/m. In August 2010 a study was made of transmissivity that led to a decision to apply post-processing corrections to all cruises between March 2008 and June 2010. Transmissivity data from this cruise were corrected by multiplying the original values by correction factor 2.5, which was based on the assumption that deep offshore transmissivity should be about 62%/m. For details on the transmissometer post-processing see: OSD_Data_Archive:\Cruise_Data\DOCUMENTS\Transmissometer 1005DR Corrections.doc These data should still be considered nominal. ********************************************************************************** July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure dbars 10 -99 () (0 0.99988) Transmissivity %/metre 10 -99 () (0 2.5) Salinity:T1:C1 PSS-78 10 -99 () (-0.25E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.57E-02 1.0414) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- --2--- ---3---- --4-- ---5--- --6--- --7--- --8-- ---9---- -10- 11 12 ---13--- 14 --15- 16 --17- 18 --19-- 20 ---21--- 22 !Samp Pressu Temperat Trans Fluores PAR Oxygen Oxyge Salinity Numb Bo Bo Salinity Fl Nitra Fl Silic Fl Phosph Fl pH Fl !le_ re ure: missi cence: : n: :T1:C1 er_o tt tt :Bottle ag te_ ag ate ag ate ag ag !Numb Secondar vity URU: Dissol Disso ~bin ~u ~u ~o plus_ ~t ~i ~p : !er y Seapoin ved: lved: _rec mb en tt Nitri ri ca ha pH ! t SBE SBE ords er ce le te te te te !---- ------ -------- ----- ------- ------ ------ ----- -------- ---- -- -- -------- -- ----- -- ----- -- ------ -- -------- -- *END OF HEADER 448 2.0 7.6418 49.8 0.187 7070.9 6.81 296.6 32.7072 121 5 5 32.7085 0 11.8 0 16.9 0 1.11 0 7.7911 6 447 5.7 7.6439 49.8 0.190 2884.1 6.81 296.5 32.7077 121 4 4 32.7113 0 12.2 0 17.0 0 1.08 0 7.7916 6 446 10.0 7.6089 49.5 0.313 2033.1 6.81 296.4 32.7070 121 3 3 -99.0000 0 12.0 0 16.9 0 1.09 0 7.7920 6 445 19.9 7.5145 49.2 0.904 931.2 6.80 296.0 32.7092 121 2 2 -99.0000 0 12.1 0 17.1 0 1.16 0 7.7910 6 444 30.2 7.3233 49.2 1.353 329.6 6.78 295.0 32.7112 121 1 1 -99.0000 0 12.4 0 17.3 0 1.11 0 7.7888 6