*2021/11/24 14:29:23.21 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/06/20 23:30:32.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 10 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 64619382 NUMBER OF CHANNELS : 47 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 219 228 2 Bottle_Number n/a 1 10 3 Pressure decibar 1.9 117.7 4 Temperature:Primary 'deg C (ITS90)' 7.0961 10.6695 5 Transmissivity %/metre 26.7 41.9 6 Fluorescence:URU:Seapoint mg/m^3 0.82E-01 4.349 7 PAR uE/m^2/sec 0 1122.8 8 PAR:Reference uE/m^2/sec 1800.9 2468.9 9 Salinity:T0:C0 PSS-78 30.9394 33.4732 10 Oxygen:Dissolved:SBE mL/L 2.21 6.26 11 Oxygen:Dissolved:SBE umol/kg 96 272.8 12 Number_of_bin_records n/a 192 241 13 Salinity:Bottle PSS-78 33.4735 33.4735 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 2.2 6.3 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 15.6 32.9 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 29.4 49.9 20 Flag:Silicate n/a 21 Phosphate umol/L 1.47 2.45 22 Flag:Phosphate n/a 23 Chlorophyll:Extracted mg/m^3 1.34 7.81 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0.49E-01 26 HPLC:Chlide-a mg/m^3 0 0.106 27 HPLC:Chl-c2 mg/m^3 0.85E-01 0.593 28 HPLC:Peri mg/m^3 0 0.48E-01 29 HPLC:Pheide-a mg/m^3 0 0 30 HPLC:But-fuco mg/m^3 0 0.23E-01 31 HPLC:Fuco mg/m^3 0.479 2.185 32 HPLC:Neo mg/m^3 0 0 33 HPLC:Pras mg/m^3 0 0 34 HPLC:Viola mg/m^3 0 0.21E-01 35 HPLC:Hex-fuco mg/m^3 0 0 36 HPLC:Diadino mg/m^3 0.36E-01 0.292 37 HPLC:Allo mg/m^3 0 0.55E-01 38 HPLC:Diato mg/m^3 0 0.56E-01 39 HPLC:Zea mg/m^3 0 0 40 HPLC:Lut mg/m^3 0 0 41 HPLC:Chl-b mg/m^3 0 0 42 HPLC:DVChl-a mg/m^3 0 0 43 HPLC:Chl-a mg/m^3 0.99 4.227 44 HPLC:Phe mg/m^3 0 0 45 HPLC:B-Car mg/m^3 0.23E-01 0.11 46 HPLC:TChl-a mg/m^3 0.99 4.333 47 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2009-43 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : ADCP EVENT NUMBER : 61 LATITUDE : 48 14.03000 N ! (deg min) LONGITUDE : 123 17.90000 W ! (deg min) WATER DEPTH : 122 ALTIMETER (M) : 5.05 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0941 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 03P5048 conductivity:primary ' ' 3579 pressure ' ' 0941 temperature:secondary ' ' 03P5073 conductivity:secondary ' ' 3581 Oxygen:SBE ' ' 1438 transmissometer:primary ' ' 983dr Fluorometer ' ' Seapoint irradiance:primary ' ' 4565 altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.18 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/08/18 13:03:44 2361 2361 CLEAN 5.0.2 2009/08/18 13:05:09 ? ? ADDSAMP 3.4 2009/08/19 09:52:00 2361 2361 BINAVE 4.1.1 2009/08/19 09:52:44 2361 10 MERGE 3.3 2010/04/25 16:21:39 10 10 CLEAN 5.0.2 2010/04/26 11:17:33 ? ? CALIB 11.7 2010/04/26 11:18:07 10 10 SORT 3.5 2010/04/26 11:18:23 10 10 REMOVECH 8.0 2010/04/26 11:19:17 10 10 CHGUNITS 3.0 2010/04/26 11:19:32 10 10 REORDER 1.2.1 2010/04/26 11:24:31 ? ? HDREDIT2 2.5.1 2010/04/26 11:33:14 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:49:40 10 10 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:34:27 10 10 CHANGE_FLAGS 2.0 2014/11/20 09:56:52 10 10 SORT 3.6 2020/12/18 10:55:36 10 10 REORDER 1.3.1 2021/11/24 14:28:08 ? ? MERGE 3.5.1 2021/11/24 14:28:20 10 10 SORT 3.6 2021/11/24 14:28:27 10 10 CLEAN 5.2.4 2021/11/24 14:28:37 10 10 HDREDIT2 3.2 2021/11/24 14:29:05 ? ? HDREDIT2 3.2 2021/11/24 14:29:23 ? ? $END $REMARKS -CLEAN functions: 2009/08/18 13:04:05 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2010/04/25 16:21:38 2010/04/25 16:21:38 2010/04/25 16:21: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0061.samavg Secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0061.mrgcln1 -CLEAN functions: 2010/04/26 11:17:31 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2010/04/26 11:18:07 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-43\Processing\doc\2009-43-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 16 Oxygen:Dissolved:SBE mL/L 10 0.2040000E-01 0.1055100E+01 -SORT parameters: 2010/04/26 11:18:23 Sorted in ascending order of channel Pressure -REMOVECH 2010/04/26 11:19:17 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2010/04/26 11:33:14 Applied edit header: Q:\Cruise_Data_Processing\2009-43\Processing\doc\2009-43-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 7: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Oxygen:Dissolved [mL/L] Units: ==> mL/L Format: F6.1 ==> F8.3 Channel 21: Silicate [umol/L] Format: F7.2 ==> F6.1 -SORT parameters: 2020/12/18 10:55:36 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 14:28:20 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\ IOS\2009-043-0061.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\ IOS\2009-043-0061.hplc -SORT parameters: 2021/11/24 14:28:27 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 14:28:37 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 14:29:05 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043\Processing\Doc\ 2009-043-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 14:29:23 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043\Processing\Doc\ 2009-043-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0061.mrgcln1 ----------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0061.add ------------------------------------------------------------------- Sample_Number 222: DO: bubble in duplicate, not averaged Sample_Number 225: DO: small bubble in flask Sample_Number 228: DO: F184small bubble in flask Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0061.nut ------------------------------------------------------------------- Sample_Number 228: "Nutrients: Samples labelled wrong as 218-227, changed to match original rosette sheet Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. Average of two samples is reported except as noted. Flags are assigned if Variability >10% which is assessed as the % (std dev/mean*100). HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a. For further information see file QF 2009-043_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 950 Colorimeter. For information on precision see file 2009-43oxy.xls. Final Dissolved Oxygen data may not match those on rosette logs. Endpoint titers were optimized in post-processing using a best fit linear regression utility. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. There were no duplicates. There are concerns about the bottle salinity values from this cruise. Many values have been flagged because they were outliers in comparison to the CTD salinity values. While there were also some problems with the CTD salinity, these do not appear to explain these values. No problem has been noted with the Autosal. The samples were in storage for 8 months and it is possible that some samples were not sealed well enough to avoid evaporation over that period. Nutrient samples were collected in plastic tubes, stored frozen and later analyzed at IOS using an Astoria autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-43nuts.xls. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\IOS\2009-043-0061. hplc --------------------------------------------------------------------------- Sample_Number 225: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.204E-01 1.0551) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- 47 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 228 10 1.9 10.6695 26.7 2.421 1122.8 2463.2 30.9394 6.26 272.8 192 -99.0000 0 6.300 4 15.6 0 29.4 0 1.47 0 7.81 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 227 9 5.1 10.4761 27.7 4.349 219.1 2286.2 30.9517 6.12 266.7 241 -99.0000 0 6.000 0 17.3 0 32.7 0 1.64 0 -99.00 0 0.049 0.106 0.593 0.048 0.000 0.023 2.185 0.000 0.000 0.021 0.000 0.292 0.055 0.056 0.000 0.000 0.000 0.000 4.227 0.000 0.110 4.333 6 226 8 10.4 8.5324 41.9 0.961 59.6 2306.0 32.2262 3.78 164.6 241 -99.0000 0 3.700 0 24.7 0 40.1 0 2.02 0 1.75 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 225 7 20.4 8.2800 41.4 0.113 14.3 2032.6 32.4543 3.49 151.8 241 -99.0000 0 3.500 4 27.9 0 44.2 0 2.06 0 1.34 6 0.000 0.000 0.100 0.000 0.000 0.000 0.571 0.000 0.000 0.000 0.000 0.043 0.000 0.000 0.000 0.000 0.000 0.000 1.170 0.000 0.028 1.170 36 224 6 30.4 8.0000 41.4 0.899 4.2 2123.1 32.6942 3.19 139.0 241 -99.0000 0 3.200 0 28.6 0 45.0 0 2.23 0 -99.00 0 0.000 0.000 0.085 0.000 0.000 0.000 0.479 0.000 0.000 0.000 0.000 0.036 0.000 0.029 0.000 0.000 0.000 0.000 0.990 0.000 0.023 0.990 6 223 5 40.9 7.8676 40.9 0.754 0.9 2111.5 32.8108 3.04 132.2 241 -99.0000 0 3.100 0 31.6 0 48.3 0 2.34 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 222 4 51.5 7.5177 38.7 0.730 0.2 2158.7 33.1166 2.68 116.6 241 -99.0000 0 2.700 0 31.3 0 48.1 0 2.41 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 221 3 76.7 7.1444 34.5 0.675 0.0 2343.9 33.4324 2.26 98.5 241 -99.0000 0 2.200 0 32.8 6 49.6 6 2.45 6 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 220 2 100.2 7.1100 33.7 0.082 0.0 2468.9 33.4620 2.22 96.4 241 -99.0000 0 2.200 0 32.5 0 49.5 0 2.36 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 219 1 117.7 7.0961 32.0 0.675 0.0 1800.9 33.4732 2.21 96.0 241 33.4735 0 2.200 0 32.9 0 49.9 0 2.36 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0