*2021/11/24 14:29:23.07 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/06/20 03:29:45.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 14 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : A0F8A0BB NUMBER OF CHANNELS : 45 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 184 197 2 Bottle_Number n/a 1 14 3 Pressure decibar 5.4 234.6 4 Temperature:Primary 'deg C (ITS90)' 8.0421 9.8333 5 Transmissivity %/metre 28.8 34.6 6 Fluorescence:URU:Seapoint mg/m^3 0.893 5.488 7 PAR uE/m^2/sec 0 10.6 8 PAR:Reference uE/m^2/sec 140.7 431.8 9 Salinity:T0:C0 PSS-78 30.8639 32.6015 10 Number_of_bin_records n/a 241 241 11 Salinity:Bottle PSS-78 32.3763 32.3763 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 3.2 5.3 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 17 29 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 28.3 46 18 Flag:Silicate n/a 19 Phosphate umol/L 1.69 2.37 20 Flag:Phosphate n/a 21 Chlorophyll:Extracted mg/m^3 5.77 6.73 22 Flag:Chlorophyll:Extracted n/a 23 HPLC:Chl-c3 mg/m^3 0 0.49E-01 24 HPLC:Chlide-a mg/m^3 0.116 0.124 25 HPLC:Chl-c2 mg/m^3 0.453 0.519 26 HPLC:Peri mg/m^3 0 0.46E-01 27 HPLC:Pheide-a mg/m^3 0 0 28 HPLC:But-fuco mg/m^3 0 0 29 HPLC:Fuco mg/m^3 2.006 2.342 30 HPLC:Neo mg/m^3 0 0 31 HPLC:Pras mg/m^3 0 0 32 HPLC:Viola mg/m^3 0 0 33 HPLC:Hex-fuco mg/m^3 0 0.12E-01 34 HPLC:Diadino mg/m^3 0.168 0.203 35 HPLC:Allo mg/m^3 0.28E-01 0.4E-01 36 HPLC:Diato mg/m^3 0.9E-02 0.28E-01 37 HPLC:Zea mg/m^3 0 0 38 HPLC:Lut mg/m^3 0 0 39 HPLC:Chl-b mg/m^3 0 0 40 HPLC:DVChl-a mg/m^3 0 0 41 HPLC:Chl-a mg/m^3 3.99 4.671 42 HPLC:Phe mg/m^3 0 0 43 HPLC:B-Car mg/m^3 0.97E-01 0.1 44 HPLC:TChl-a mg/m^3 4.113 4.787 45 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F R4 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2009-43 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 59 EVENT NUMBER : 46 LATITUDE : 48 37.79000 N ! (deg min) LONGITUDE : 123 14.50000 W ! (deg min) WATER DEPTH : 235 ALTIMETER (M) : 6.32 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0941 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 03P5048 conductivity:primary ' ' 3579 pressure ' ' 0941 temperature:secondary ' ' 03P5073 conductivity:secondary ' ' 3581 Oxygen:SBE ' ' 1117 transmissometer:primary ' ' 983dr Fluorometer ' ' Seapoint irradiance:primary ' ' 4565 altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.18 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/08/18 13:03:36 3856 3856 CLEAN 5.0.2 2009/08/18 13:04:44 ? ? ADDSAMP 3.4 2009/08/19 09:51:52 3856 3856 BINAVE 4.1.1 2009/08/19 09:52:41 3856 16 MERGE 3.3 2010/04/25 16:21:39 16 14 CLEAN 5.0.2 2010/04/26 11:17:32 ? ? CALIB 11.7 2010/04/26 11:18:07 14 14 SORT 3.5 2010/04/26 11:18:23 14 14 REMOVECH 8.0 2010/04/26 11:18:58 14 14 CHGUNITS 3.0 2010/04/26 11:19:32 14 14 REORDER 1.2.1 2010/04/26 11:24:30 ? ? HDREDIT2 2.5.1 2010/04/26 11:34:18 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:49:40 14 14 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:34:27 14 14 CHANGE_FLAGS 2.0 2014/11/20 09:56:52 14 14 SORT 3.6 2020/12/18 10:55:36 14 14 REORDER 1.3.1 2021/11/24 14:28:08 ? ? MERGE 3.5.1 2021/11/24 14:28:20 14 14 SORT 3.6 2021/11/24 14:28:27 14 14 CLEAN 5.2.4 2021/11/24 14:28:37 14 14 HDREDIT2 3.2 2021/11/24 14:29:05 ? ? HDREDIT2 3.2 2021/11/24 14:29:23 ? ? $END $REMARKS -CLEAN functions: 2009/08/18 13:04:05 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2010/04/25 16:21:38 2010/04/25 16:21:38 2010/04/25 16:21: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0046.samavg Secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0046.mrgcln1 -CLEAN functions: 2010/04/26 11:17:31 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2010/04/26 11:18:07 Calibration type = Correct Mode: HEAD - calibration specs from header only. Calibration file = Q:\Cruise_Data_Processing\2009-43\Processing\doc\2009-43-recal1.ccf WARNING: No calibration done on file Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-004 -SORT parameters: 2010/04/26 11:18:23 Sorted in ascending order of channel Pressure -REMOVECH 2010/04/26 11:18:58 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Oxygen:Dissolved:SBE [mL/L] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: - No units changed -HEADER EDITS: 2010/04/26 11:34:18 Applied edit header: Q:\Cruise_Data_Processing\2009-43\Processing\doc\2009-43-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 7: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L Format: F6.1 ==> F8.3 Channel 19: Silicate [umol/L] Format: F7.2 ==> F6.1 -SORT parameters: 2020/12/18 10:55:36 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 14:28:20 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\ IOS\2009-043-0046.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\ IOS\2009-043-0046.hplc -SORT parameters: 2021/11/24 14:28:27 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 14:28:37 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 14:29:05 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043\Processing\Doc\ 2009-043-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 23: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 14:29:23 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043\Processing\Doc\ 2009-043-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0046.mrgcln1 ----------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0046.sal ------------------------------------------------------------------- Sample_Number 185: Salinity: poor comparison with CTD salinity, but CTD salinity poor. Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0046.nut ------------------------------------------------------------------- Sample_Number 188: Nutrients: Samples flagged by analyst as slightly out of line, and there is some possibility of mislabelling, but the whole profile is very complex. All Samples: These samples were originally labeled wrong so there is some possibility that errors might have been made in sample numbers. NOTE: There were 14 bottles listed on the rosette log sheet, but 16 bottles fired. It is believed the first 14 bottles were sampled but that cannot be proven. NOTE: The SBE Dissolved Oxygen sensor malfunctioned during casts 1-52. Comments on chorophyll following HPLC analysis: Sample_Number 194: Turner value clearly out of line, changed to -99. Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. Average of two samples is reported except as noted. Flags are assigned if Variability >10% which is assessed as the % (std dev/mean*100). HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a. For further information see file QF 2009-043_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 950 Colorimeter. For information on precision see file 2009-43oxy.xls. Final Dissolved Oxygen data may not match those on rosette logs. Endpoint titers were optimized in post-processing using a best fit linear regression utility. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. There were no duplicates. There are concerns about the bottle salinity values from this cruise. Many values have been flagged because they were outliers in comparison to the CTD salinity values. While there were also some problems with the CTD salinity, these do not appear to explain these values. No problem has been noted with the Autosal. The samples were in storage for 8 months and it is possible that some samples were not sealed well enough to avoid evaporation over that period. Nutrient samples were collected in plastic tubes, stored frozen and later analyzed at IOS using an Astoria autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-43nuts.xls. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\IOS\2009-043-0046. hplc --------------------------------------------------------------------------- Sample_Number 197: HPLC: >10%CV for TChl-a *CALIBRATION !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- -10- ---11--- 12 ---13-- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- 45 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er Seapoin _rec tt lv Nitri ri ca ha ted ct HP ! t ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 197 14 5.4 9.8245 29.9 4.563 10.6 140.7 30.8718 241 -99.0000 0 5.300 0 18.4 0 30.9 0 1.72 0 6.73 6 0.000 0.116 0.519 0.000 0.000 0.000 2.342 0.000 0.000 0.000 0.000 0.203 0.040 0.028 0.000 0.000 0.000 0.000 4.671 0.000 0.100 4.787 36 196 13 10.0 9.8333 29.5 5.388 2.5 172.7 30.8639 241 -99.0000 0 5.300 0 18.2 0 30.3 0 1.69 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 195 12 20.6 9.8292 29.7 5.040 0.1 201.8 30.8720 241 -99.0000 0 5.300 0 18.6 0 30.8 0 1.70 0 5.77 6 0.044 0.122 0.488 0.023 0.000 0.000 2.102 0.000 0.000 0.000 0.000 0.174 0.032 0.020 0.000 0.000 0.000 0.000 4.193 0.000 0.097 4.314 6 194 11 30.5 9.8190 29.6 5.488 0.0 221.1 30.8934 241 -99.0000 0 5.300 0 18.5 0 31.6 0 1.76 0 -99.00 5 0.049 0.124 0.453 0.046 0.000 0.000 2.006 0.000 0.000 0.000 0.012 0.168 0.028 0.009 0.000 0.000 0.000 0.000 3.990 0.000 0.098 4.113 6 193 10 40.6 9.8214 29.5 5.165 0.0 245.1 30.8880 241 -99.0000 0 5.300 0 18.4 0 31.9 0 1.73 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 192 9 50.5 9.8025 29.8 4.839 0.0 270.7 30.9275 241 -99.0000 0 5.300 0 18.5 0 30.8 0 1.82 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 191 8 75.8 9.6415 31.6 4.128 0.0 293.0 31.0955 241 -99.0000 0 5.100 0 18.7 0 31.7 0 1.72 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 190 7 101.1 9.3407 33.9 2.875 0.0 322.6 31.3887 241 -99.0000 0 4.700 0 21.2 0 35.3 0 1.88 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 189 6 125.9 9.1131 33.1 2.252 0.0 408.1 31.7007 241 -99.0000 0 4.500 0 19.9 0 33.2 0 1.85 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 188 5 126.0 9.1083 33.5 2.421 0.0 428.1 31.7058 241 -99.0000 0 4.400 0 17.0 3 28.3 3 1.71 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 187 4 151.4 8.8759 34.6 1.860 0.0 431.8 31.8234 241 -99.0000 0 4.100 0 24.5 6 40.0 6 2.06 6 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 186 3 176.7 8.8217 34.0 1.773 0.0 428.0 31.9089 241 -99.0000 0 4.000 0 24.8 0 41.6 0 2.09 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 185 2 202.5 8.2988 32.9 1.024 0.0 394.5 32.3557 241 32.3763 0 3.500 0 27.8 0 44.2 0 2.27 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 184 1 234.6 8.0421 28.8 0.893 0.0 375.0 32.6015 241 -99.0000 0 3.200 0 29.0 0 46.0 0 2.37 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0