*2023/03/19 10:46:17.96 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/06/19 14:16:42.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 634E02AA NUMBER OF CHANNELS : 45 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 125 141 2 Bottle_Number n/a 1 17 3 Pressure decibar 1.4 373.4 4 Temperature:Primary 'deg C (ITS90)' 8.0076 15.7149 5 Transmissivity %/metre 2.2 45.7 6 Fluorescence:URU:Seapoint mg/m^3 0.117 3.626 7 PAR uE/m^2/sec 0 361.8 8 PAR:Reference uE/m^2/sec 584.6 664.6 9 Salinity:T0:C0 PSS-78 11.3499 30.9441 10 Number_of_bin_records n/a 209 241 11 Salinity:Bottle PSS-78 30.9372 30.9372 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 4.1 7 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 2.6 29.6 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 8.5 58.8 18 Silicate:Flag n/a 19 Phosphate umol/L 0.5 2.53 20 Flag:Phosphate n/a 21 Chlorophyll:Extracted mg/m^3 0.43 4.65 22 Flag:Chlorophyll:Extracted n/a 23 HPLC:Chl-c3 mg/m^3 0 0 24 HPLC:Chlide-a mg/m^3 0 0.113 25 HPLC:Chl-c2 mg/m^3 0.33E-01 0.388 26 HPLC:Peri mg/m^3 0 0.52E-01 27 HPLC:Pheide-a mg/m^3 0 0 28 HPLC:But-fuco mg/m^3 0.9E-02 0.35E-01 29 HPLC:Fuco mg/m^3 0.202 1.227 30 HPLC:Neo mg/m^3 0 0.37E-01 31 HPLC:Pras mg/m^3 0 0.23E-01 32 HPLC:Viola mg/m^3 0 0.43E-01 33 HPLC:Hex-fuco mg/m^3 0 0 34 HPLC:Diadino mg/m^3 0 0.463 35 HPLC:Allo mg/m^3 0.22E-01 0.222 36 HPLC:Diato mg/m^3 0 0.7E-02 37 HPLC:Zea mg/m^3 0 0.2E-01 38 HPLC:Lut mg/m^3 0 0.4E-01 39 HPLC:Chl-b mg/m^3 0 0.265 40 HPLC:DVChl-a mg/m^3 0 0 41 HPLC:Chl-a mg/m^3 0.395 4.534 42 HPLC:Phe mg/m^3 0 0 43 HPLC:B-Car mg/m^3 0 0.148 44 HPLC:TChl-a mg/m^3 0.395 4.646 45 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F R4 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2009-43 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 39 EVENT NUMBER : 30 LATITUDE : 49 9.79000 N ! (deg min) LONGITUDE : 123 32.93000 W ! (deg min) WATER DEPTH : 390 ALTIMETER (M) : 1.07 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0941 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 03P5048 conductivity:primary ' ' 3579 pressure ' ' 0941 temperature:secondary ' ' 03P5073 conductivity:secondary ' ' 3581 Oxygen:SBE ' ' 1117 transmissometer:primary ' ' 983dr Fluorometer ' ' Seapoint irradiance:primary ' ' 4565 altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.18 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/08/18 13:03:22 4065 4065 CLEAN 5.0.2 2009/08/18 13:04:31 ? ? ADDSAMP 3.4 2009/08/19 09:51:41 4065 4065 BINAVE 4.1.1 2009/08/19 09:52:36 4065 17 MERGE 3.3 2010/04/25 16:21:39 17 17 CLEAN 5.0.2 2010/04/26 11:17:32 ? ? CALIB 11.7 2010/04/26 11:18:06 17 17 SORT 3.5 2010/04/26 11:18:23 17 17 REMOVECH 8.0 2010/04/26 11:18:58 17 17 CHGUNITS 3.0 2010/04/26 11:19:32 17 17 REORDER 1.2.1 2010/04/26 11:24:30 ? ? HDREDIT2 2.5.1 2010/04/26 11:34:18 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:49:40 17 17 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:34:26 17 17 CHANGE_FLAGS 2.0 2014/11/20 09:56:52 17 17 Silicate_Correction 1.0 2018/02/20 14:42:18 17 17 SORT 3.6 2020/12/18 10:55:36 17 17 REORDER 1.3.1 2021/11/24 14:28:08 ? ? MERGE 3.5.1 2021/11/24 14:28:19 17 17 SORT 3.6 2021/11/24 14:28:27 17 17 CLEAN 5.2.4 2021/11/24 14:28:37 17 17 HDREDIT2 3.2 2021/11/24 14:29:04 ? ? HDREDIT2 3.2 2021/11/24 14:29:22 ? ? Silicate_Modification 1.2 2023/03/19 10:46:17 17 17 $END $REMARKS -CLEAN functions: 2009/08/18 13:04:05 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2010/04/25 16:21:38 2010/04/25 16:21:38 2010/04/25 16:21: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0030.samavg Secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0030.mrgcln1 -CLEAN functions: 2010/04/26 11:17:31 20 Remove Sea-Bird comments from the header. -CALIB parameters: 2010/04/26 11:18:06 Calibration type = Correct Mode: HEAD - calibration specs from header only. Calibration file = Q:\Cruise_Data_Processing\2009-43\Processing\doc\2009-43-recal1.ccf WARNING: No calibration done on file Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-003 -SORT parameters: 2010/04/26 11:18:23 Sorted in ascending order of channel Pressure -REMOVECH 2010/04/26 11:18:58 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Oxygen:Dissolved:SBE [mL/L] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: - No units changed -HEADER EDITS: 2010/04/26 11:34:18 Applied edit header: Q:\Cruise_Data_Processing\2009-43\Processing\doc\2009-43-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 7: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L Format: F6.1 ==> F8.3 Channel 19: Silicate [umol/L] Format: F7.2 ==> F6.1 -SORT parameters: 2020/12/18 10:55:36 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 14:28:19 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\ IOS\2009-043-0030.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\ IOS\2009-043-0030.hplc -SORT parameters: 2021/11/24 14:28:27 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 14:28:37 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 14:29:04 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043\Processing\Doc\ 2009-043-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 19: Silicate:Corrected [umol/L] Format: F6.1 ==> F7.2 -HEADER EDITS: 2021/11/24 14:29:22 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043\Processing\Doc\ 2009-043-bot-hdr2.txt $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 39, Sample Number: 141, Silicate corrected using CTD salinity. ===================================================================================== Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0030.mrgcln1 ----------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-43\Processing\hydro\2009-43-0030.chl ------------------------------------------------------------------- Sample_Number 139: CHL: one sample only NOTE: The SBE Dissolved Oxygen sensor malfunctioned during casts 1-52. Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. Average of two samples is reported except as noted. Flags are assigned if Variability >10% which is assessed as the % (std dev/mean*100). HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a. For further information see file QF 2009-043_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 950 Colorimeter. For information on precision see file 2009-43oxy.xls. Final Dissolved Oxygen data may not match those on rosette logs. Endpoint titers were optimized in post-processing using a best fit linear regression utility. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. There were no duplicates. There are concerns about the bottle salinity values from this cruise. Many values have been flagged because they were outliers in comparison to the CTD salinity values. While there were also some problems with the CTD salinity, these do not appear to explain these values. No problem has been noted with the Autosal. The samples were in storage for 8 months and it is possible that some samples were not sealed well enough to avoid evaporation over that period. Nutrient samples were collected in plastic tubes, stored frozen and later analyzed at IOS using an Astoria autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-43nuts.xls. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-043_Nov2021\Processing\IOS\2009-043-0030. hplc --------------------------------------------------------------------------- Sample_Number 138: HPLC: >10%CV for TChl-a *CALIBRATION !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- -10- ---11--- 12 ---13-- 14 --15- 16 --17-- 18 --19-- 20 --21-- 22 ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- 45 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Numb Salinity Fl Oxygen: Fl Nitra Fl Silica Si Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 er_o :Bottle ag Dissolv ag te_ ag te li ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce ~bin ~o ed ~o plus_ ~t ~: ~p Extrac ~a a a fuco fuco : !er er Seapoin _rec tt lv Nitri ri Fl ha ted ct HP ! t ords le ed te te ag te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ---- -------- -- ------- -- ----- -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 141 17 1.4 15.7149 2.2 3.626 361.8 593.2 11.3499 209 -99.0000 0 7.000 0 2.6 0 32.90 0 0.50 0 4.65 6 0.000 0.113 0.388 0.052 0.000 0.009 1.227 0.037 0.023 0.043 0.000 0.463 0.222 0.006 0.020 0.040 0.265 0.000 4.534 0.000 0.148 4.646 6 140 16 5.0 13.2909 37.8 1.069 25.4 587.9 27.0397 241 -99.0000 0 6.600 0 3.6 0 8.50 0 0.62 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 139 15 10.2 11.2274 41.6 1.058 5.4 586.0 29.3502 241 -99.0000 0 6.300 0 6.1 0 12.20 0 1.05 0 0.95 0 0.000 0.000 0.081 0.000 0.000 0.035 0.325 0.000 0.000 0.000 0.000 0.020 0.116 0.000 0.000 0.000 0.000 0.000 0.859 0.000 0.000 0.859 6 138 14 20.1 10.5387 44.1 0.537 1.0 584.6 29.6287 241 -99.0000 0 5.700 0 9.5 0 18.40 0 1.38 0 0.43 6 0.000 0.000 0.033 0.000 0.000 0.025 0.202 0.000 0.000 0.000 0.000 0.000 0.022 0.007 0.000 0.000 0.000 0.000 0.395 0.000 0.000 0.395 36 137 13 30.3 9.8308 44.6 0.421 0.2 587.9 29.7557 241 -99.0000 0 5.000 0 14.4 0 26.00 0 1.66 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 136 12 40.5 9.4963 45.5 0.271 0.0 591.8 29.9232 241 -99.0000 0 4.500 0 22.8 0 43.70 0 2.23 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 135 11 50.7 9.3290 45.7 0.238 0.0 595.8 29.9763 241 -99.0000 0 4.300 0 24.7 0 46.50 0 2.28 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 134 10 76.4 8.6173 45.4 0.167 0.0 601.7 30.1539 241 -99.0000 0 4.100 0 28.5 0 51.80 0 2.41 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 133 9 101.0 8.1431 44.5 0.135 0.0 609.5 30.4095 241 -99.0000 0 4.300 0 29.6 0 50.90 0 2.41 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 132 8 125.9 8.1692 42.5 0.143 0.0 615.4 30.6139 241 -99.0000 0 4.500 0 28.0 0 47.10 0 2.28 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 131 7 150.8 8.0378 44.2 0.121 0.0 615.6 30.6870 241 -99.0000 0 4.400 0 28.6 0 48.80 0 2.33 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 130 6 176.3 8.0076 43.8 0.117 0.0 608.6 30.7586 241 -99.0000 0 4.400 0 28.3 0 50.00 0 2.27 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 129 5 201.0 8.1732 41.1 0.141 0.0 603.6 30.8281 241 -99.0000 0 4.300 0 28.1 0 50.50 0 2.30 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 128 4 250.8 8.0894 36.5 0.128 0.0 599.7 30.8650 241 -99.0000 0 4.100 0 28.9 0 53.90 0 2.47 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 127 3 301.1 8.0508 40.5 0.127 0.0 619.8 30.8851 241 -99.0000 0 4.200 0 28.5 0 53.80 0 2.37 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 126 2 350.5 8.0426 41.5 0.136 0.0 664.6 30.9307 241 30.9372 0 4.100 0 28.3 0 54.70 0 2.43 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 125 1 373.4 8.0577 34.4 0.146 0.0 641.0 30.9441 241 -99.0000 0 4.100 0 28.7 0 58.80 0 2.53 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0