*2021/11/24 14:26:02.29 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/04/14 22:41:13.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : CA41CA19 NUMBER OF CHANNELS : 47 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 240 256 2 Bottle_Number n/a 1 17 3 Pressure decibar 1.8 348.6 4 Temperature:Secondary 'deg C (ITS90)' 7.7133 8.6325 5 Transmissivity %/metre 25.3 58.3 6 Fluorescence:URU:Seapoint mg/m^3 0.11 3.619 7 PAR uE/m^2/sec 0 1266.4 8 PAR:Reference uE/m^2/sec 2224.6 2263.9 9 Salinity:T1:C1 PSS-78 29.8262 30.8092 10 Oxygen:Dissolved:SBE mL/L 3.32 8.56 11 Oxygen:Dissolved:SBE umol/kg 144.8 373.4 12 Number_of_bin_records n/a 241 241 13 Salinity:Bottle PSS-78 30.8069 30.8069 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 3.373 7.399 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 9.2 30.9 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 39 69.7 20 Flag:Silicate n/a 21 Phosphate umol/L 1.42 2.7 22 Flag:Phosphate n/a 23 Chlorophyll:Extracted mg/m^3 7.89 16.74 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0.75E-01 26 HPLC:Chlide-a mg/m^3 0 0.402 27 HPLC:Chl-c2 mg/m^3 0.444 1.348 28 HPLC:Peri mg/m^3 0 0.62E-01 29 HPLC:Pheide-a mg/m^3 0 0 30 HPLC:But-fuco mg/m^3 0 0.71E-01 31 HPLC:Fuco mg/m^3 1.936 7.552 32 HPLC:Neo mg/m^3 0 0 33 HPLC:Pras mg/m^3 0 0 34 HPLC:Viola mg/m^3 0 0 35 HPLC:Hex-fuco mg/m^3 0 0 36 HPLC:Diadino mg/m^3 0.122 0.861 37 HPLC:Allo mg/m^3 0.115 0.269 38 HPLC:Diato mg/m^3 0.5E-02 0.77E-01 39 HPLC:Zea mg/m^3 0 0 40 HPLC:Lut mg/m^3 0 0 41 HPLC:Chl-b mg/m^3 0 0.72E-01 42 HPLC:DVChl-a mg/m^3 0 0 43 HPLC:Chl-a mg/m^3 5.033 14.718 44 HPLC:Phe mg/m^3 0 0.505 45 HPLC:B-Car mg/m^3 0.61E-01 0.202 46 HPLC:TChl-a mg/m^3 5.033 15.12 47 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2009-26 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Strait of Georgia/Juan de Fuca SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 12 EVENT NUMBER : 64 LATITUDE : 49 43.59000 N ! (deg min) LONGITUDE : 124 40.85000 W ! (deg min) WATER DEPTH : 353 ALTIMETER (M) : 4.98 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 4883 conductivity:primary ' ' 1763 pressure ' ' 75636 temperature:secondary ' ' 2095 conductivity:secondary ' ' 2754 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1005dr Oxygen:SBE ' ' 1119 altimeter: ' ' ' ' irradiance:primary ' ' 4565 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.16 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/06/23 10:51:28 4097 4097 CLEAN 5.0.2 2009/06/23 11:23:20 ? ? CTDEDIT 4.61 2009/06/23 12:06:30 4097 4097 ADDSAMP 3.4 2009/06/24 11:59:16 4097 4097 BINAVE 4.1.1 2009/06/24 11:59:59 4097 17 MERGE 3.3 2009/06/26 10:48:53 17 17 CLEAN 5.0.2 2009/06/26 10:48:58 ? ? CALIB 11.7 2009/06/30 10:53:16 17 17 SORT 3.5 2009/06/30 13:29:24 17 17 REMOVECH 8.0 2009/06/30 13:29:56 17 17 CHGUNITS 3.0 2009/06/30 13:30:51 17 17 REORDER 1.2.1 2009/06/30 13:46:14 ? ? HDREDIT2 2.5.1 2009/06/30 13:50:30 ? ? SORT 3.5 2009/12/18 13:19:18 17 17 MERGE 3.3 2009/12/18 13:23:55 17 17 SORT 3.5 2009/12/18 13:31:08 17 17 HDREDIT2 2.5.1 2009/12/18 13:32:01 ? ? CALIB 11.7 2010/08/18 15:31:11 17 17 HDREDIT2 2.5.1 2010/08/18 15:33:45 ? ? HDREDIT2 2.5.1 2010/09/02 14:13:00 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:49:35 17 17 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:34:22 17 17 CHANGE_FLAGS 2.0 2014/11/20 09:56:47 17 17 SORT 3.6 2020/12/18 09:56:07 17 17 REORDER 1.3.1 2021/11/24 14:24:47 ? ? MERGE 3.5.1 2021/11/24 14:24:56 17 17 SORT 3.6 2021/11/24 14:25:13 17 17 CLEAN 5.2.4 2021/11/24 14:25:20 17 17 HDREDIT2 3.2 2021/11/24 14:25:44 ? ? HDREDIT2 3.2 2021/11/24 14:26:02 ? ? $END $REMARKS -CLEAN functions: 2009/06/23 11:21:37 20 Set event to last 4 characters of file name -CTDEDIT 2009/06/23 12:06:30 3 changes in channel Salinity:T1:C1 -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-26\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2009/06/26 10:48:51 2009/06/26 10:48:51 2009/06/26 10:48: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data_Processing\2009-26\Processing\hydro\2009-26-0064.samavg Secondary file: Q:\Cruise_Data_Processing\2009-26\Processing\hydro\2009-26-0064.mrgcln1 -CLEAN functions: 2009/06/26 10:48:57 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2009/06/30 10:53:16 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-26\Processing\doc\2009-26-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.8800000E-02 0.1038800E+01 -SORT parameters: 2009/06/30 13:29:24 Sorted in ascending order of channel Pressure -REMOVECH 2009/06/30 13:29:56 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2009/06/30 13:50:30 Applied edit header: Q:\Cruise_Data_Processing\2009-26\Processing\doc\2009-26-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 7: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 17: Oxygen:Dissolved [mL/L] Units: ==> mL/L Format: f8.3 ==> F8.3 Channel 18: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 20: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 22: Flag:Silicate [n/a] Units: ==> n/a Channel 24: Flag:Phosphate [n/a] Units: ==> n/a -SORT parameters: 2009/12/18 13:19:18 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2009/12/18 13:23:52 2009/12/18 13:23:53 2009/12/18 13:23: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Sample_Number [n/a], Pressure [decibar], Temperature:Secondary [deg C (ITS90)], Transmissivity [%/metre], Fluorescence:URU:Seapoint [mg/m^3], PAR [uE/m^2/sec], PAR:Reference [uE/m^2/sec], Salinity:T1:C1 [PSS-78], Oxygen:Dissolved:SBE [mL/L], Oxygen:Dissolved:SBE [umol/kg], Bottle_Number [n/a], Number_of_bin_records [n/a], Salinity:Bottle [PSS-78], Flag:Salinity:Bottle [n/a], Chlorophyll:Extracted [mg/m^3], Flag:Chlorophyll:Extracted [n/a], Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [n/a], Silicate [umol/L], Flag:Silicate [n/a], Phosphate [umol/L], Flag:Phosphate [n/a] Secondary Channels to Include: Oxygen:Dissolved [ ], Flag:Oxygen:Dissolved [ ] Primary file : Q:\Cruise_Data_Processing\2009-26\New doc\2009-26-0064.chesort Secondary file: Q:\Cruise_Data_Processing\2009-26\New doc\2009-26-0064.add -SORT parameters: 2009/12/18 13:31:08 Sorted in ascending order of channel Pressure [decibar] -HEADER EDITS: 2009/12/18 13:32:01 Applied edit header: Q:\Cruise_Data_Processing\2009-26\New Doc\2009-26-bot-hdr-corrections.txt Channel 23: Oxygen:Dissolved [mL/L] Units: ==> mL/L Format: f8.3 ==> F8.3 -CALIB parameters: 2010/08/18 15:31:11 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\Trans Cor\2009-26\DOC\2009-26-recal-tr.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Transmissivity %/metre 10 0.0000000E+00 0.1230000E+01 -HEADER EDITS: 2010/08/18 15:33:45 Applied edit header: Q:\Cruise_Data_Processing\Trans Cor\2009-26\DOC\Trans_Correction1.TXT -HEADER EDITS: 2010/09/02 14:13:00 Channel 4: Transmissivity [%/metre] Format: F7.2 ==> F6.1 -SORT parameters: 2020/12/18 09:56:07 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 14:24:56 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-026_Nov2021\Processing\ IOS\2009-026-0064.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-026_Nov2021\Processing\ IOS\2009-026-0064.hplc -SORT parameters: 2021/11/24 14:25:13 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 14:25:20 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 14:25:44 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-026\Processing\Doc\ 2009-026-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 14:26:02 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-026\Processing\Doc\ 2009-026-bot-hdr2.txt $END *COMMENTS CTDEDIT was used to clean a few records in secondary salinity around 40db. Sample_Number 240: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 241: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 242: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 243: Dissolved Oxygen: no DMQ on oxy flasks, critters in sample Sample_Number 244: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 245: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 246: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 247: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 248: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 249: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 250: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 251: Dissolved Oxygen: no DMQ on oxy flasks, sm. Bubble in flask Sample_Number 252: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 253: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 254: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 255: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 256: Dissolved Oxygen: no DMQ on oxy flasks, titration ended early & outlier Comments on Chlorophyll following HPLC analasys: Sample_Number 254: Turner value out of line, changed to -99, suspect dilution miscalculation Analysis methods: ----------------- Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions made from commercially prepared pure chlorophyll a. Fluorometer readings are taken before and after acidification of the extract with two drops of 1.5N HCl. Average of two samples is reported. Variability is assessed as the % (std dev/mean*100) and samples are flagged if >10%. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1 month after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a. For further information see file QF 2009-026_HPLC*.xlsx. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). Samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 900 Colorimeter. Salinity samples were collected in glass bottles and analyzed on a Guildline model 8400B Autosal at IOS. Salinometers are standardized with IAPSO standard seawater. Nutrient samples were collected in plastic tubes and stored frozen and later analysed at IOS using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). File "QF 2009-26nuts.xls" includes the raw data and an analysis of duplicates. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Comments from secondary file: Q:\Cruise_Data_Processing\2009-26\New doc\2009-26-0064.add ---------------------------------------------------------- Sample_Number 240-256: Dissolved Oxygen: no DMQ on oxy flasks Sample_Number 243: Dissolved Oxygen: critters in sample Sample_Number 250: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 251: Dissolved Oxygen: no DMQ on oxy flasks, small Bubble in flask Sample_Number 252: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 253: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 255: Dissolved Oxygen: no DMQ on oxy flasks, bubbles in flask Sample_Number 256: Dissolved Oxygen: no DMQ on oxy flasks, titration ended early. Corrections were made to the Oxygen:Dissolved channel to correct errors made in the association of flask numbers to volumes. Dec. 18, 2009. ********************************************************************************* Transmissometer #1005DR was calibrated in March 2008, and drifted significantly but steadily until July 2009; then a sudden shift occurred, so that maximum values between September 2009 and July 2010 were very low, ~25%/m. In August 2010 a study was made of transmissivity that led to a decision to apply post-processing corrections to all cruises between March 2008 and June 2010. Transmissivity data from this cruise were corrected by multiplying the original values by a correction factor, which was based on assumptions that deep offshore transmissivity from a June 2009 cruise should be about 62%/m and that drift was linear with time between March 2008 and July 2009. The corrections produced reasonable results for all cruises in that time period. For details on how the correction factor was derived see: OSD_Data_Archive:\Cruise_Data\DOCUMENTS\Transmissometer 1005DR Corrections.doc These data should be considered estimates. ********************************************************************************* Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-026_Nov2021\Processing\IOS\2009-026-0064. hplc --------------------------------------------------------------------------- Sample_Number 256: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.88E-02 1.0388) Transmissivity %/metre 10 -99 () (0 1.23) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- 47 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T1:C1 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Secondar vity URU: nce Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er y Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 256 17 1.8 8.6325 25.3 3.265 1266.4 2224.6 29.8262 8.56 373.4 241 -99.0000 0 -99.000 5 9.2 0 39.0 0 1.42 0 16.74 6 0.075 0.402 1.348 0.062 0.000 0.071 7.552 0.000 0.000 0.000 0.000 0.861 0.269 0.077 0.000 0.000 0.072 0.000 14.718 0.505 0.202 15.120 36 255 16 5.6 8.1120 38.5 3.497 222.9 2226.1 29.9131 7.36 321.0 241 -99.0000 0 7.399 3 16.2 0 47.7 0 1.82 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 254 15 10.4 7.9125 44.9 2.915 53.5 2226.1 29.9507 6.84 298.4 241 -99.0000 0 6.842 0 19.6 0 50.0 0 1.97 0 -99.00 5 0.000 0.000 0.465 0.000 0.000 0.000 1.936 0.000 0.000 0.000 0.000 0.129 0.115 0.006 0.000 0.000 0.032 0.000 5.033 0.000 0.065 5.033 6 253 14 20.4 7.7985 44.4 3.619 4.4 2226.0 29.9500 6.70 292.5 241 -99.0000 0 6.741 3 19.7 0 49.4 0 2.03 0 7.89 6 0.000 0.000 0.444 0.000 0.000 0.026 1.991 0.000 0.000 0.000 0.000 0.122 0.129 0.005 0.000 0.000 0.000 0.000 5.066 0.000 0.061 5.066 6 252 13 30.5 7.7174 51.0 1.833 0.5 2229.2 29.9919 6.07 265.0 241 -99.0000 0 6.150 3 22.5 0 51.4 0 2.20 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 251 12 40.7 7.7133 51.8 1.422 0.1 2230.3 30.0130 5.89 256.9 241 -99.0000 0 5.890 3 23.5 0 52.9 0 2.27 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 250 11 50.4 7.7514 56.6 0.567 0.0 2234.1 30.0803 5.42 236.6 241 -99.0000 0 5.476 3 25.2 0 54.7 0 2.36 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 249 10 75.4 7.9987 58.3 0.171 0.0 2235.8 30.3082 4.32 188.6 241 -99.0000 0 4.333 0 29.6 0 60.6 0 2.54 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 248 9 100.7 8.1556 57.4 0.110 0.0 2238.6 30.5118 3.84 167.5 241 -99.0000 0 3.858 0 30.9 0 62.7 0 2.62 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 247 8 125.6 8.1541 56.7 0.116 0.0 2235.0 30.5816 3.83 167.1 241 -99.0000 0 3.847 0 30.9 0 62.8 0 2.58 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 246 7 150.7 8.1768 51.8 0.142 0.0 2231.5 30.6436 3.74 163.1 241 -99.0000 0 3.824 0 30.8 0 64.6 0 2.61 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 245 6 175.4 7.9122 55.1 0.172 0.0 2237.4 30.6135 4.15 180.8 241 -99.0000 0 4.152 0 30.3 0 60.5 0 2.54 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 244 5 200.6 8.0195 54.0 0.231 0.0 2247.7 30.6716 3.96 172.8 241 -99.0000 0 4.071 0 30.5 0 62.0 0 2.55 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 243 4 250.7 7.9845 53.5 0.135 0.0 2252.0 30.6893 4.02 175.2 241 -99.0000 0 4.018 0 30.5 0 62.3 0 2.57 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 242 3 300.6 8.2612 52.5 0.226 0.0 2257.7 30.7614 3.62 157.7 241 -99.0000 0 3.615 0 30.2 0 65.6 0 2.63 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 241 2 343.4 8.4085 48.5 0.217 0.0 2263.9 30.8066 3.35 146.1 241 30.8069 0 3.373 0 30.2 0 69.3 0 2.70 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 240 1 348.6 8.4161 47.3 0.164 0.0 2258.8 30.8092 3.32 144.8 241 -99.0000 0 3.374 0 30.6 0 69.7 0 2.70 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0