*2021/11/24 14:12:27.59 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/08/27 22:16:56.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 18 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 5DF7B0E NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 405 422 2 Bottle_Number n/a 1 19 3 Pressure decibar 3 198.3 4 Temperature:Secondary 'deg C (ITS90)' 4.7898 12.64 5 Transmissivity %/metre 26 49.6 6 Fluorescence:URU:Seapoint mg/m^3 0.102 1.247 7 PAR uE/m^2/sec 0 220.1 8 Salinity:T1:C1 PSS-78 32.4537 33.7208 9 Oxygen:Dissolved:SBE mL/L 4.04 6.89 10 Oxygen:Dissolved:SBE umol/kg 175.9 299.8 11 Number_of_bin_records n/a 39 241 12 Nitrate_plus_Nitrite umol/L 6.1 29.4 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 11.4 51.7 15 Flag:Silicate n/a 16 Phosphate umol/L 0.8 2.26 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 11.21 19 Flag:Dimethyl_Sulphide n/a 20 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 21 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 22 Dimethylsulfoniopropionate_Total nmol/L -99 -99 23 Flag:Dimethylsulfoniopropionate_Total ' ' 24 Chlorophyll:Extracted mg/m^3 0.9E-01 0.37 25 Flag:Chlorophyll:Extracted n/a 26 HPLC:Chl-c3 mg/m^3 0.18E-01 0.28E-01 27 HPLC:Chlide-a mg/m^3 0 0 28 HPLC:MgDVP mg/m^3 0 0 29 HPLC:Chl-c2 mg/m^3 0.26E-01 0.34E-01 30 HPLC:Chl-c1 mg/m^3 0 0 31 HPLC:Me-chlide mg/m^3 0 0 32 HPLC:Peri mg/m^3 0.16E-01 0.17E-01 33 HPLC:Pheide-a mg/m^3 0 0 34 HPLC:But-fuco mg/m^3 0.39E-01 0.39E-01 35 HPLC:Fuco mg/m^3 0.3E-01 0.46E-01 36 HPLC:Neo mg/m^3 0.2E-02 0.5E-02 37 HPLC:Pras mg/m^3 0 0 38 HPLC:Viola mg/m^3 0 0 39 HPLC:Hex-fuco mg/m^3 0.98E-01 0.128 40 HPLC:Diadino mg/m^3 0.24E-01 0.32E-01 41 HPLC:Allo mg/m^3 0 0 42 HPLC:Diato mg/m^3 0.4E-02 0.7E-02 43 HPLC:Zea mg/m^3 0.3E-02 0.4E-02 44 HPLC:Lut mg/m^3 0.4E-02 0.7E-02 45 HPLC:Chl-b mg/m^3 0.52E-01 0.66E-01 46 HPLC:DVChl-a mg/m^3 0 0 47 HPLC:Chl-a mg/m^3 0.231 0.276 48 HPLC:Phe mg/m^3 0 0 49 HPLC:B-Car mg/m^3 0 0.2E-02 50 HPLC:TChl-a mg/m^3 0.231 0.276 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2009-10 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P26 EVENT NUMBER : 48 LATITUDE : 50 0.00000 N ! (deg min) LONGITUDE : 144 59.90000 W ! (deg min) WATER DEPTH : 4275 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Aft-deck ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 4054 conductivity:primary ' ' 3321 pressure ' ' 77511 temperature:secondary ' ' 4700 conductivity:secondary ' ' 1766 Oxygen:SBE ' ' 1176 transmissometer:primary ' ' 983DR Fluorometer ' ' Seapoint irradiance:primary ' ' 4615 altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/10/05 11:34:47 3825 3825 CLEAN 5.0.2 2009/10/05 11:37:39 ? ? ADDSAMP 3.4 2009/10/05 16:38:04 3825 3825 BINAVE 4.1.1 2009/10/05 16:39:16 3825 19 MERGE 3.3 2009/10/08 17:10:40 19 19 CLEAN 5.0.2 2009/10/08 17:10:49 ? ? CALIB 11.7 2009/10/09 09:02:02 19 19 SORT 3.5 2009/10/09 09:15:51 19 19 REMOVECH 8.0 2009/10/22 14:21:14 19 19 CHGUNITS 3.0 2009/10/22 14:23:31 19 19 REORDER 1.2.1 2009/10/22 14:24:04 ? ? HDREDIT2 2.5.1 2009/10/22 15:04:21 ? ? CLEAN 5.0.2 2009/10/22 15:41:58 18 18 CALIB 11.7 2010/03/09 14:32:23 18 18 HDREDIT2 2.5.1 2010/05/07 09:40:02 ? ? CALIB 11.7 2013/06/04 13:12:44 18 18 HDREDIT2 2.6 2013/07/08 08:49:24 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:31:13 18 18 CHANGE_FLAGS 2.0 2014/11/20 09:56:39 18 18 SORT 3.6 2020/07/24 13:50:16 18 18 HDREDIT2 3.2 2020/07/24 14:51:20 ? ? MERGE 3.5.1 2020/07/24 14:57:05 18 18 SORT 3.6 2020/07/24 14:57:51 18 18 CLEAN 5.2.4 2020/07/24 14:59:49 18 18 HDREDIT2 3.2 2020/07/24 15:00:47 ? ? SORT 3.6 2020/11/25 14:48:30 18 18 REORDER 1.3.1 2021/11/24 14:11:14 ? ? MERGE 3.5.1 2021/11/24 14:11:27 18 18 SORT 3.6 2021/11/24 14:11:35 18 18 CLEAN 5.2.4 2021/11/24 14:11:41 18 18 $END $REMARKS -CLEAN functions: 2009/10/05 11:36:22 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-10\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2009/10/08 17:10:34 2009/10/08 17:10:34 2009/10/08 17:10: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle [ ], Flag:Salinity:Bottle [ ], Chlorophyll:Extracted [ ], Flag:Chlorophyll:Extracted [ ], Oxygen:Dissolved [ ], Flag:Oxygen:Dissolved [ ], Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ], Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : Q:\Cruise_Data_Processing\2009-10\Processing\hydro\2009-10-0048.samavg Secondary file: Q:\Cruise_Data_Processing\2009-10\Processing\hydro\2009-10-0048.mrgcln1 -CLEAN functions: 2009/10/08 17:10:46 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2009/10/09 09:02:02 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-10\Processing\doc\2009-10-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.1000000E-01 0.1072700E+01 -SORT parameters: 2009/10/09 09:15:51 Sorted in ascending order of channel Pressure -REMOVECH 2009/10/22 14:21:14 11 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2009/10/22 15:04:21 Applied edit header: Q:\Cruise_Data_Processing\2009-10\Processing\doc\2009-10-bot-hdr.txt Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 13: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 17: Flag:Silicate [n/a] Units: ==> n/a Channel 19: Flag:Phosphate [n/a] Units: ==> n/a Channel 21: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 -CLEAN functions: 2009/10/22 15:41:58 Reset #RECS, MIN & MAX values in header. -CALIB parameters: 2010/03/09 14:32:23 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-10\Processing\doc\2009-10-do-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Oxygen:Dissolved:SBE [mL/L] mL/L 10 0.0000000E+00 0.9853000E+00 9 Oxygen:Dissolved:SBE [umol/kg umol/kg 10 0.0000000E+00 0.9853000E+00 -HEADER EDITS: 2010/05/07 09:40:02 Applied edit header: C:\DATA\2009-10-HDRlars.TXT -CALIB parameters: 2013/06/04 13:12:44 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 18 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:49:24 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/07/24 13:50:16 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2020/07/24 14:51:20 -The following MERGE parameters were used: 2020/07/24 14:57:05 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-010\Processing\2009-010- 0048.che1 Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-010\Processing\2009-010- 0048.dmsp -SORT parameters: 2020/07/24 14:57:51 Sorted in ascending order of channel Pressure -CLEAN functions: 2020/07/24 14:59:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* -HEADER EDITS: 2020/07/24 15:00:47 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-010\Processing\2009- 010-bot-hdr1.txt Channel 11: Number_of_bin_records [n/a] Pad: -99 ==> blank Channel 13: Flag:Chlorophyll:Extracted [n/a] Pad: -99 ==> 0 Channel 15: Flag:Nitrate_plus_Nitrite [n/a] Pad: -99 ==> 0 Channel 17: Flag:Silicate [n/a] Pad: -99 ==> 0 Channel 19: Flag:Phosphate [n/a] Pad: -99 ==> 0 Channel 21: Flag:Dimethyl_Sulphide [n/a] Pad: -99 ==> 0 -SORT parameters: 2020/11/25 14:48:30 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 14:11:27 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010_Nov2021\Processing\ IOS\2009-010-0048.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010_Nov2021\Processing\ IOS\2009-010-0048.hplc -SORT parameters: 2021/11/24 14:11:35 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 14:11:41 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 14:12:10 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010\Processing\Doc\ 2009-010-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 26: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 14:12:27 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010\Processing\Doc\ 2009-010-bot-hdr2.txt $END *COMMENTS Sample_Number 417: : The sample labelled as #417 did not come from Niskin #13 as indicated on the rosette log sheet. It really came from Niskin #19. The firing of Niskin #13 was at the wrong level, so a final bottle was fired to gather 10m samples. The CTD data from Niskin #19 were then substituted for the CTD data of Niskin #13. The samples and CTD data both come from Niskin #19. The line for Niskin #13 was removed to avoid confusion. Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-010\Processing\2009-010-0048.dmsp --------------------------------------------------------------------------- Sample_Number 405: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 406: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 407: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 414: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 420: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 421: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2009-10CHL.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~4 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2009-010_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 765) and a PC 950 Colorimeter. For information on precision see file 2009-10-oxy-duplicates.xls. The thiosulphate titer of 0.709 obtained during standardization was low and out of range leading to a suspected overestimate in DO value of ~2.5%. This is believed to be due to either a bad batch of standard or incorrect calibration parameters (temperature or volume dispensed). Comparison to the SBE Dissolved Oxygen sensor confirmed the likely DO overestimate using the original 0.709 titer. The data were thus recalculated using the mean thiosulfate titer for the year (0.721). Recalculated results are consistent with a post-cruise calibration of the SBE Dissolved Oxygen sensor. All samples are flagged 'd" since the data are considered to be of lower quality than usual. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. Samples from two casts were analyzed at sea on a Guildline Portasal; there are comments attached to those samples and all were flagged "d". See file 2009-10-salinity-duplicates.xls for information on AUtosal precision. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using an Astoria Pacific autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-10nuts.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2009-10 DMS Report.doc. DMSP: All sample data discarded due to blank contamination problems. For details on analysis see documents "2009-10 dmsp QF summary.xls" and "2009-10 DMS report.doc". References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010_Nov2021\Processing\IOS\2009-010-0048. hplc --------------------------------------------------------------------------- Sample_Number 413: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !-------------------------------- --------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.1E-01 1.0727) 'Oxygen:Dissolved:SBE [mL/L]' mL/L 10 -99 () (0 0.9853) 'Oxygen:Dissolved:SBE [umol/kg]' umol/kg 10 -99 () (0 0.9853) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12- 13 --14- 15 --16-- 17 --18-- 19 --20-- 21 --22-- 23 --24-- 25 ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitra Fl Silic Fl Phosph Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T1:C1 : n: er_o te_ ag ate ag ate ag yl_ ag ylsulf ag ylsulf ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Secondar vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a a chlide a fuco fuco : !er er y Seapoin ved: lved: _rec Nitri ri ca ha de hi te_Dis lv ionate ot ted ct HP ! t SBE SBE ords te te te te de solved ed _Total al ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -- ----- -- ------ -- ------ -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 421 17 3.0 12.6301 40.5 0.513 220.1 32.4610 6.17 268.9 63 6.3 0 11.4 0 0.80 0 7.19 0 -99.00 1 -99.00 1 0.30 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 422 18 3.3 12.6169 30.7 0.578 181.0 32.4597 6.14 267.6 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 419 15 4.9 12.6383 26.0 0.453 96.0 32.4537 6.20 270.0 161 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 420 16 5.0 12.6400 33.6 0.460 110.1 32.4576 6.15 267.8 240 6.2 0 11.4 0 0.81 0 7.60 0 -99.00 1 -99.00 1 0.29 0 0.019 0.000 0.000 0.027 0.000 0.000 0.016 0.000 0.039 0.032 0.002 0.000 0.000 0.098 0.032 0.000 0.007 0.004 0.004 0.052 0.000 0.231 0.000 0.002 0.231 6 418 14 10.1 12.5630 44.0 0.684 56.9 32.4604 6.11 266.2 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 417 19 10.4 12.5558 44.0 0.778 44.5 32.4604 6.17 268.9 241 6.3 0 11.5 0 0.80 0 8.46 0 -99.00 0 -99.00 0 0.28 0 0.018 0.000 0.000 0.026 0.000 0.000 0.016 0.000 0.039 0.030 0.004 0.000 0.000 0.099 0.028 0.000 0.005 0.003 0.005 0.055 0.000 0.231 0.000 0.000 0.231 6 416 12 15.1 12.5533 44.1 0.777 38.8 32.4597 6.13 267.1 122 6.2 0 11.4 0 0.81 0 9.07 0 -99.00 0 -99.00 0 0.28 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 414 10 18.5 12.4538 43.8 0.919 35.4 32.4637 6.16 268.2 71 6.1 0 11.5 0 0.81 0 10.39 6 -99.00 1 -99.00 1 0.34 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 415 11 19.7 12.4540 43.9 0.927 31.5 32.4636 6.15 267.9 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 413 9 26.1 12.4428 44.3 1.199 22.1 32.4637 6.13 266.9 241 6.1 0 11.5 0 0.81 0 11.08 0 -99.00 0 -99.00 0 0.34 0 0.028 0.000 0.000 0.034 0.000 0.000 0.017 0.000 0.039 0.046 0.005 0.000 0.000 0.128 0.024 0.000 0.004 0.003 0.007 0.066 0.000 0.276 0.000 0.000 0.276 36 411 7 30.6 12.4250 44.7 1.036 17.9 32.4619 6.12 266.5 39 6.2 0 11.5 0 0.81 0 11.21 0 -99.00 0 -99.00 0 0.30 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 412 8 30.7 12.4313 44.8 1.072 17.4 32.4619 6.19 269.5 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 410 6 39.6 11.0400 45.0 1.214 9.9 32.5053 6.40 279.0 241 7.2 0 12.6 0 0.92 0 7.69 0 -99.00 0 -99.00 0 0.33 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 409 5 49.3 7.8906 46.1 1.247 5.3 32.6209 6.80 295.9 241 10.1 0 15.2 0 1.20 0 1.36 0 -99.00 0 -99.00 0 0.37 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 408 4 75.7 6.2534 48.7 0.474 1.1 32.6455 6.88 299.1 241 12.4 0 17.9 0 1.31 0 0.36 0 -99.00 0 -99.00 0 0.24 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 407 3 100.6 5.6073 49.1 0.220 0.3 32.6323 6.89 299.8 241 14.7 6 20.5 6 1.38 6 0.45 0 -99.00 1 -99.00 1 0.09 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 406 2 175.5 5.1637 49.5 0.106 0.0 33.6274 4.76 207.1 241 25.4 0 42.0 0 2.00 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 405 1 198.3 4.7898 49.6 0.102 0.0 33.7208 4.04 175.9 241 29.4 0 51.7 0 2.26 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0