*2021/11/24 14:12:27.33 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/08/22 11:17:22.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 65807A45 NUMBER OF CHANNELS : 48 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 139 158 2 Bottle_Number n/a 1 20 3 Pressure decibar 5.4 2003.6 4 Temperature:Secondary 'deg C (ITS90)' 1.9549 15.5632 5 Transmissivity %/metre 43.7 50.3 6 Fluorescence:URU:Seapoint mg/m^3 0.91E-01 0.892 7 Salinity:T1:C1 PSS-78 32.172 34.5894 8 Oxygen:Dissolved:SBE mL/L 0.23 6.5 9 Oxygen:Dissolved:SBE umol/kg 10.1 283.1 10 Number_of_bin_records n/a 67 241 11 Salinity:Bottle PSS-78 32.1744 34.5889 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 0.246 6.391 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 0.2 44.9 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 4.3 173.2 18 Flag:Silicate n/a 19 Phosphate umol/L 0.37 3.3 20 Flag:Phosphate n/a 21 Chlorophyll:Extracted mg/m^3 0.2E-01 0.42 22 Flag:Chlorophyll:Extracted n/a 23 HPLC:Chl-c3 mg/m^3 0.15E-01 0.23E-01 24 HPLC:Chlide-a mg/m^3 0 0 25 HPLC:MgDVP mg/m^3 0.6E-02 0.8E-02 26 HPLC:Chl-c2 mg/m^3 0.28E-01 0.32E-01 27 HPLC:Chl-c1 mg/m^3 0 0.25E-01 28 HPLC:Me-chlide mg/m^3 0 0.9E-02 29 HPLC:Peri mg/m^3 0.11E-01 0.16E-01 30 HPLC:Pheide-a mg/m^3 0 0 31 HPLC:But-fuco mg/m^3 0.1E-01 0.16E-01 32 HPLC:Fuco mg/m^3 0.95E-01 0.107 33 HPLC:Neo mg/m^3 0.3E-02 0.6E-02 34 HPLC:Pras mg/m^3 0.11E-01 0.14E-01 35 HPLC:Viola mg/m^3 0.6E-02 0.11E-01 36 HPLC:Hex-fuco mg/m^3 0.35E-01 0.45E-01 37 HPLC:Diadino mg/m^3 0.16E-01 0.26E-01 38 HPLC:Allo mg/m^3 0 0.4E-02 39 HPLC:Diato mg/m^3 0 0 40 HPLC:Zea mg/m^3 0.74E-01 0.102 41 HPLC:Lut mg/m^3 0 0 42 HPLC:Chl-b mg/m^3 0.58E-01 0.68E-01 43 HPLC:DVChl-a mg/m^3 0 0 44 HPLC:Chl-a mg/m^3 0.349 0.413 45 HPLC:Phe mg/m^3 0 0 46 HPLC:B-Car mg/m^3 0.12E-01 0.17E-01 47 HPLC:TChl-a mg/m^3 0.349 0.417 48 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F R4 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2009-10 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P8 EVENT NUMBER : 20 LATITUDE : 48 48.98000 N ! (deg min) LONGITUDE : 128 39.95000 W ! (deg min) WATER DEPTH : 2517 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 4054 conductivity:primary ' ' 3321 pressure ' ' 77511 temperature:secondary ' ' 4700 conductivity:secondary ' ' 1766 Oxygen:SBE ' ' 1176 transmissometer:primary ' ' 983DR Fluorometer ' ' Seapoint irradiance:primary ' ' 4615 altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.18C $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/10/05 11:33:42 4645 4645 CLEAN 5.0.2 2009/10/05 11:36:50 ? ? ADDSAMP 3.4 2009/10/05 16:37:28 4645 4645 BINAVE 4.1.1 2009/10/05 16:38:58 4645 20 MERGE 3.3 2009/10/08 17:10:36 20 20 CLEAN 5.0.2 2009/10/08 17:10:47 ? ? CALIB 11.7 2009/10/09 09:01:55 20 20 SORT 3.5 2009/10/09 09:15:47 20 20 REMOVECH 8.0 2009/10/22 14:21:56 20 20 CHGUNITS 3.0 2009/10/22 14:23:30 20 20 REORDER 1.2.1 2009/10/22 14:24:02 ? ? HDREDIT2 2.5.1 2009/10/22 15:04:20 ? ? CALIB 11.7 2010/03/09 14:32:21 20 20 HDREDIT2 2.5.1 2010/05/07 09:39:18 ? ? CALIB 11.7 2013/06/04 13:12:43 20 20 HDREDIT2 2.6 2013/07/08 08:49:22 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:31:12 20 20 CHANGE_FLAGS 2.0 2014/11/20 09:56:38 20 20 SORT 3.6 2020/11/25 14:48:30 20 20 REORDER 1.3.1 2021/11/24 14:11:14 ? ? MERGE 3.5.1 2021/11/24 14:11:27 20 20 SORT 3.6 2021/11/24 14:11:35 20 20 CLEAN 5.2.4 2021/11/24 14:11:41 20 20 HDREDIT2 3.2 2021/11/24 14:12:10 ? ? HDREDIT2 3.2 2021/11/24 14:12:27 ? ? $END $REMARKS -CLEAN functions: 2009/10/05 11:36:22 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-10\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2009/10/08 17:10:34 2009/10/08 17:10:34 2009/10/08 17:10: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle [ ], Flag:Salinity:Bottle [ ], Chlorophyll:Extracted [ ], Flag:Chlorophyll:Extracted [ ], Oxygen:Dissolved [ ], Flag:Oxygen:Dissolved [ ], Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ], Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : Q:\Cruise_Data_Processing\2009-10\Processing\hydro\2009-10-0020.samavg Secondary file: Q:\Cruise_Data_Processing\2009-10\Processing\hydro\2009-10-0020.mrgcln1 -CLEAN functions: 2009/10/08 17:10:46 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2009/10/09 09:01:55 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-10\Processing\doc\2009-10-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.1000000E-01 0.1051000E+01 -SORT parameters: 2009/10/09 09:15:47 Sorted in ascending order of channel Pressure -REMOVECH 2009/10/22 14:21:56 12 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2009/10/22 15:04:20 Applied edit header: Q:\Cruise_Data_Processing\2009-10\Processing\doc\2009-10-bot-hdr.txt Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 11: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 12: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L Format: f8.3 ==> F8.3 Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 18: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 20: Flag:Silicate [n/a] Units: ==> n/a Channel 22: Flag:Phosphate [n/a] Units: ==> n/a Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 -CALIB parameters: 2010/03/09 14:32:21 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-10\Processing\doc\2009-10-do-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 7 Oxygen:Dissolved:SBE [mL/L] mL/L 10 0.0000000E+00 0.9853000E+00 8 Oxygen:Dissolved:SBE [umol/kg umol/kg 10 0.0000000E+00 0.9853000E+00 -HEADER EDITS: 2010/05/07 09:39:18 Applied edit header: C:\DATA\2009-10-HDRlars.TXT -CALIB parameters: 2013/06/04 13:12:43 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 21 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:49:22 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/11/25 14:48:30 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 14:11:27 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010_Nov2021\Processing\ IOS\2009-010-0020.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010_Nov2021\Processing\ IOS\2009-010-0020.hplc -SORT parameters: 2021/11/24 14:11:35 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 14:11:41 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 14:12:10 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010\Processing\Doc\ 2009-010-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 23: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 14:12:27 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-010\Processing\Doc\ 2009-010-bot-hdr2.txt $END *COMMENTS Sample_Number 146: ALL Samples: Bottle apparently closed before firing - plots of Dissolved Oxygen, Nitrate and Silicate against Salinity:Bottle suggest all samples came from the same depth, but plots of those variables against Salinity:CTD show they are likely from around 1500db. All sample results were replaced with pad values. Sample_Number 140: Salinity: Lid loose on 1st sample but value very close to 2nd sample Sample_Number 148: Salinity:Cap broken Sample_Number 144: DO: suspiciously high and severe outlier in COMPARE and in plots against salinity. Sample_numbers 139-158: Dissolved Oxygen: Flags explained in Analysis Methods below. Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2009-10CHL.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~4 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2009-010_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 765) and a PC 950 Colorimeter. For information on precision see file 2009-10-oxy-duplicates.xls. The thiosulphate titer of 0.709 obtained during standardization was low and out of range leading to a suspected overestimate in DO value of ~2.5%. This is believed to be due to either a bad batch of standard or incorrect calibration parameters (temperature or volume dispensed). Comparison to the SBE Dissolved Oxygen sensor confirmed the likely DO overestimate using the original 0.709 titer. The data were thus recalculated using the mean thiosulfate titer for the year (0.721). Recalculated results are consistent with a post-cruise calibration of the SBE Dissolved Oxygen sensor. All samples are flagged 'd" since the data are considered to be of lower quality than usual. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. Samples from two casts were analyzed at sea on a Guildline Portasal; there are comments attached to those samples and all were flagged "d". See file 2009-10-salinity-duplicates.xls for information on AUtosal precision. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using an Astoria Pacific autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-10nuts.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2009-10 DMS Report.doc. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !-------------------------------- --------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.1E-01 1.051) 'Oxygen:Dissolved:SBE [mL/L]' mL/L 10 -99 () (0 0.9853) 'Oxygen:Dissolved:SBE [umol/kg]' umol/kg 10 -99 () (0 0.9853) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- ---7---- --8--- --9-- -10- ---11--- 12 ---13-- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- 48 !Samp Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T1:C1 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Secondar vity URU: Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a chlide a fuco fuco : !er er y Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 158 20 5.4 15.5632 44.2 0.669 32.1720 5.93 258.5 241 32.1744 0 5.881 4 0.2 0 4.3 0 0.37 0 0.38 0 0.015 0.000 0.006 0.028 0.000 0.000 0.013 0.000 0.011 0.095 0.003 0.011 0.006 0.035 0.016 0.000 0.000 0.074 0.000 0.065 0.000 0.349 0.000 0.012 0.349 6 157 19 10.3 15.5579 44.1 0.835 32.1726 5.92 258.1 241 32.1817 0 5.891 4 0.2 0 4.3 0 0.38 0 0.42 0 0.015 0.000 0.006 0.032 0.025 0.009 0.011 0.000 0.010 0.103 0.006 0.012 0.009 0.036 0.025 0.004 0.000 0.100 0.000 0.058 0.000 0.408 0.000 0.017 0.417 6 156 18 25.3 15.4013 43.7 0.892 32.1936 5.92 258.4 241 32.1997 0 5.994 64 0.2 0 4.3 0 0.40 0 0.38 0 0.023 0.000 0.008 0.032 0.000 0.000 0.016 0.000 0.016 0.107 0.004 0.014 0.011 0.045 0.026 0.003 0.000 0.102 0.000 0.068 0.000 0.413 0.000 0.017 0.413 6 155 17 49.8 8.1409 48.5 0.286 32.4329 6.50 283.1 241 32.4328 0 6.391 4 9.2 0 11.6 0 1.05 0 0.18 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 154 16 75.3 7.2668 49.8 0.107 32.5462 6.01 261.7 241 32.5301 0 6.016 4 12.8 0 15.4 0 1.25 0 0.04 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 153 15 101.5 7.4230 50.0 0.108 33.1816 4.15 180.6 241 33.1751 0 4.152 4 22.6 0 28.9 0 1.83 0 0.02 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 152 14 124.0 7.6994 50.1 0.092 33.5665 2.79 121.3 241 33.5584 0 2.811 4 28.8 0 38.6 0 2.24 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 151 13 150.7 7.7246 50.1 0.092 33.7303 2.27 98.4 241 33.7281 0 2.305 4 31.4 0 43.0 0 2.48 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 150 12 173.9 7.6156 50.1 0.091 33.8014 2.12 92.3 241 33.7988 0 2.123 4 32.5 0 44.5 0 2.43 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 149 11 200.2 7.4634 50.3 0.092 33.8574 2.04 88.6 241 33.8607 0 2.037 4 33.0 0 45.8 0 2.44 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 148 10 249.4 6.9607 50.1 0.092 33.9242 1.99 86.5 241 33.9237 3 2.012 4 33.9 0 50.0 0 2.48 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 147 9 299.8 6.4249 50.1 0.093 33.9464 1.88 81.9 241 33.9465 0 1.901 4 35.0 0 55.8 0 2.54 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 146 8 401.2 5.4492 49.9 0.094 34.0181 1.08 47.3 241 -99.0000 5 -99.000 5 -99.0 5 -99.0 5 -99.00 5 -99.00 5 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 145 7 599.9 4.6855 50.3 0.095 34.1656 0.39 17.2 241 34.1585 0 0.446 4 43.0 0 95.1 0 3.16 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 144 6 800.4 3.9582 50.2 0.095 34.2748 0.23 10.1 241 34.3261 0 -99.000 5 44.5 0 123.8 0 3.26 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 143 5 1001.6 3.5459 50.2 0.096 34.3832 0.24 10.1 241 34.3519 0 0.246 4 44.7 0 126.1 0 3.30 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 142 4 1250.2 2.9301 50.2 0.095 34.4510 0.35 15.6 241 34.4433 0 0.361 4 44.9 0 147.6 0 3.26 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 140 2 1500.4 2.5090 50.3 0.093 34.5133 0.65 28.3 67 34.5100 6 0.671 4 44.2 0 159.6 0 3.22 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 141 3 1500.7 2.5097 50.3 0.094 34.5132 0.65 28.3 240 34.5116 0 0.699 4 44.3 0 160.4 0 3.22 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 139 1 2003.6 1.9549 50.3 0.091 34.5894 1.34 58.1 241 34.5889 0 1.438 4 42.4 0 173.2 0 3.07 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0