*2021/11/24 13:59:28.58 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/06/14 20:15:25.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 5BBC20EC NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 477 495 2 Bottle_Number n/a 1 19 3 Pressure decibar 2.2 201.2 4 Temperature:Primary 'deg C (ITS90)' 4.4339 9.474 5 Transmissivity %/metre 39 61.9 6 Fluorescence:URU:Seapoint mg/m^3 0.132 1.411 7 PAR uE/m^2/sec 0 777.6 8 Salinity:T0:C0 PSS-78 32.5533 33.7535 9 Oxygen:Dissolved:SBE mL/L 3.32 7.4 10 Oxygen:Dissolved:SBE umol/kg 144.4 322.2 11 Number_of_bin_records n/a 56 241 12 Nitrate_plus_Nitrite umol/L 10 33.3 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 16.4 63.9 15 Flag:Silicate n/a 16 Phosphate umol/L 1.09 2.51 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 3.17 19 Flag:Dimethyl_Sulphide n/a 20 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 21 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 22 Dimethylsulfoniopropionate_Total nmol/L -99 -99 23 Flag:Dimethylsulfoniopropionate_Total ' ' 24 Chlorophyll:Extracted mg/m^3 0.9E-01 0.44 25 Flag:Chlorophyll:Extracted n/a 26 HPLC:Chl-c3 mg/m^3 0.8E-02 0.31E-01 27 HPLC:Chlide-a mg/m^3 0 0.4E-02 28 HPLC:MgDVP mg/m^3 0 0.3E-02 29 HPLC:Chl-c2 mg/m^3 0.17E-01 0.39E-01 30 HPLC:Chl-c1 mg/m^3 0 0.2E-02 31 HPLC:Me-chlide mg/m^3 0 0.5E-02 32 HPLC:Peri mg/m^3 0 0 33 HPLC:Pheide-a mg/m^3 0 0 34 HPLC:But-fuco mg/m^3 0.21E-01 0.48E-01 35 HPLC:Fuco mg/m^3 0.33E-01 0.67E-01 36 HPLC:Neo mg/m^3 0 0.3E-02 37 HPLC:Pras mg/m^3 0 0.4E-02 38 HPLC:Viola mg/m^3 0.2E-02 0.6E-02 39 HPLC:Hex-fuco mg/m^3 0.59E-01 0.113 40 HPLC:Diadino mg/m^3 0.26E-01 0.37E-01 41 HPLC:Allo mg/m^3 0 0.4E-02 42 HPLC:Diato mg/m^3 0.5E-02 0.6E-02 43 HPLC:Zea mg/m^3 0.16E-01 0.24E-01 44 HPLC:Lut mg/m^3 0 0 45 HPLC:Chl-b mg/m^3 0.2E-01 0.41E-01 46 HPLC:DVChl-a mg/m^3 0 0 47 HPLC:Chl-a mg/m^3 0.187 0.296 48 HPLC:Phe mg/m^3 0 0 49 HPLC:B-Car mg/m^3 0 0.5E-02 50 HPLC:TChl-a mg/m^3 0.187 0.296 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0075.sort -------------------------------------------------------------------------------------- This file converted from Sea-Bird file: Q:\Cruise_Data_Processing\2009-09\Pro $END *ADMINISTRATION MISSION : 2009-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P26 EVENT NUMBER : 75 LATITUDE : 49 59.93000 N ! (deg min) LONGITUDE : 145 0.04000 W ! (deg min) WATER DEPTH : 4251 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2038 conductivity:primary ' ' 2128 pressure ' ' 63507 temperature:secondary ' ' 2449 conductivity:secondary ' ' 2424 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1005 Oxygen:SBE ' ' 0997 altimeter: ' ' ' ' irradiance:primary ' ' 4601 pH ' ' 0692 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.16 Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0075.sort -------------------------------------------------------------------- SOFTWARE VERSION SEASAVE V 7.16 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/08/01 11:15:44 3774 3774 CLEAN 5.0.2 2009/08/01 12:49:35 ? ? ADDSAMP 3.4 2009/08/01 14:25:04 3774 3774 BINAVE 4.1.1 2009/08/01 14:35:35 3774 19 MERGE 3.3 2009/09/11 13:39:06 19 19 CLEAN 5.0.2 2009/09/11 13:39:15 ? ? CALIB 11.7 2009/09/11 13:43:33 19 19 SORT 3.5 2009/09/11 13:53:37 19 19 REMOVECH 8.0 2009/09/11 14:08:11 19 19 CHGUNITS 3.0 2009/09/11 14:11:24 19 19 REORDER 1.2.1 2009/09/11 14:11:57 ? ? HDREDIT2 2.5.1 2009/09/11 14:13:00 ? ? REMOVECH 8.0 2009/11/16 10:50:40 19 19 MERGE 3.3 2009/11/16 10:54:15 19 19 HDREDIT2 2.5.1 2010/01/07 09:14:48 ? ? CALIB 11.7 2010/08/18 13:47:58 19 19 HDREDIT2 2.5.1 2010/08/18 14:29:06 ? ? HDREDIT2 2.5.1 2010/09/02 14:08:54 ? ? CALIB 11.7 2013/06/04 13:12:30 19 19 HDREDIT2 2.6 2013/07/08 08:49:08 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:31:10 19 19 CHANGE_FLAGS 2.0 2014/11/20 09:56:36 19 19 SORT 3.6 2020/07/24 13:14:03 19 19 HDREDIT2 3.2 2020/07/24 14:49:53 ? ? MERGE 3.5.1 2020/07/24 15:05:52 19 19 SORT 3.6 2020/07/24 15:06:52 19 19 CLEAN 5.2.4 2020/07/24 15:07:10 19 19 HDREDIT2 3.2 2020/07/24 15:07:39 ? ? SORT 3.6 2020/11/25 14:17:57 19 19 REORDER 1.3.1 2021/11/24 13:58:17 ? ? $END $REMARKS -CLEAN functions: 2009/08/01 12:48:19 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2009/09/11 13:38:59 2009/09/11 13:38:59 2009/09/11 13:38: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle [ ], Flag:Salinity:Bottle [ ], Chlorophyll:Extracted [ ], Flag:Chlorophyll:Extracted [ ], Oxygen:Dissolved [ ], Flag:Oxygen:Dissolved [ ], Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ], Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0075.samavg Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0075.mrgcln1 -CLEAN functions: 2009/09/11 13:39:11 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2009/09/11 13:43:33 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.3000000E+00 0.1000000E+01 15 Oxygen:Dissolved:SBE mL/L 10 -0.3050000E-01 0.1052800E+01 16 Salinity:T0:C0 PSS-78 10 0.2000000E-01 0.1000000E+01 -SORT parameters: 2009/09/11 13:53:37 Sorted in ascending order of channel Pressure -REMOVECH 2009/09/11 14:08:11 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2009/09/11 14:13:00 Applied edit header: Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 10: Firing_Number [n/a] Name: Bottle_Number ==> Firing_Number Channel 12: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 13: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 17: Flag:Silicate [n/a] Units: ==> n/a Channel 19: Flag:Phosphate [n/a] Units: ==> n/a Channel 21: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -REMOVECH 2009/11/16 10:50:40 1 channels removed. -The following MERGE parameters were used: 2009/11/16 10:54:09 2009/11/16 10:54:09 2009/11/16 10:54: Merge Channel: Pressure Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Transmissivity Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0075.remb Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0075.sort Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0075.sort -------------------------------------------------------------------- -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -SORT parameters: 2009/11/16 10:53:59 Sorted in ascending order of channel Pressure -HEADER EDITS: 2010/01/07 09:14:48 Channel 9: Bottle_Number [n/a] Name: Firing_Number ==> Bottle_Number -CALIB parameters: 2010/08/18 13:47:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\2009-09-recal-tr.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 21 Transmissivity %/metre 10 0.0000000E+00 0.1265000E+01 -HEADER EDITS: 2010/08/18 14:29:06 Applied edit header: Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\Trans_Correction1.TXT -HEADER EDITS: 2010/09/02 14:08:54 Channel 21: Transmissivity [%/metre] Format: F7.2 ==> F6.1 -CALIB parameters: 2013/06/04 13:12:30 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 17 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:49:08 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/07/24 13:14:03 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2020/07/24 14:49:53 Channel 10: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 12: Flag:Chlorophyll:Extracted [n/a] Pad: 0 ==> -99 Channel 14: Flag:Nitrate_plus_Nitrite [n/a] Pad: 0 ==> -99 Channel 16: Flag:Silicate [n/a] Pad: 0 ==> -99 Channel 18: Flag:Phosphate [n/a] Pad: 0 ==> -99 Channel 20: Flag:Dimethyl_Sulphide [n/a] Pad: 0 ==> -99 -The following MERGE parameters were used: 2020/07/24 15:05:52 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009- 0075.che1 Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009- 0075.dmsp -SORT parameters: 2020/07/24 15:06:52 Sorted in ascending order of channel Pressure -CLEAN functions: 2020/07/24 15:06:56 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* -HEADER EDITS: 2020/07/24 15:07:39 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-010\Processing\2009- 010-bot-hdr1.txt Channel 10: Number_of_bin_records [n/a] Pad: -99 ==> blank Channel 12: Flag:Chlorophyll:Extracted [n/a] Pad: -99 ==> 0 Channel 14: Flag:Nitrate_plus_Nitrite [n/a] Pad: -99 ==> 0 Channel 16: Flag:Silicate [n/a] Pad: -99 ==> 0 Channel 18: Flag:Phosphate [n/a] Pad: -99 ==> 0 Channel 20: Flag:Dimethyl_Sulphide [n/a] Pad: -99 ==> 0 -SORT parameters: 2020/11/25 14:17:57 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 13:58:25 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0075.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0075.hplc -SORT parameters: 2021/11/24 13:58:33 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 13:58:40 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 13:59:08 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 26: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 13:59:28 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009-0075.dmsp --------------------------------------------------------------------------- Sample_Number 477: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 478: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 481: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 490: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 493: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 495: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2009-09CHL.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2009-009_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 950 Colorimeter. For information on precision see file 2009-09_oxy_duplicates.xls. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. Samples from two casts were analyzed at sea on a Guildline Portasal; there are comments attached to those samples and all were flagged "d". See file 2009-09-salinity-duplicates.xls for information on Autosal precision. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using an Astoria Pacific autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-09nuts.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2009-09 DMS Report.doc. DMSP: All sample data discarded due to blank contamination problems. For details on analysis see documents "2009-09 dmsp QF summary.xls" and "2009-09 DMS report.doc". References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure dbars 10 -99 () (0.3 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.305E-01 1.0528) Salinity:T0:C0 PSS-78 10 -99 () (0.2E-01 1) Transmissivity %/metre 10 -99 () (0 1.265) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12- 13 --14- 15 --16-- 17 --18-- 19 --20-- 21 --22-- 23 --24-- 25 ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitra Fl Silic Fl Phosph Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T0:C0 : n: er_o te_ ag ate ag ate ag yl_ ag ylsulf ag ylsulf ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a a chlide a fuco fuco : !er er Seapoin ved: lved: _rec Nitri ri ca ha de hi te_Dis lv ionate ot ted ct HP ! t SBE SBE ords te te te te de solved ed _Total al ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -- ----- -- ------ -- ------ -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 495 19 2.2 9.4733 39.0 0.290 777.6 32.5533 6.95 302.7 241 10.0 0 16.4 0 1.10 0 3.04 0 -99.00 1 -99.00 1 0.32 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 493 17 4.8 9.4731 45.0 0.300 449.2 32.5555 6.96 303.3 129 10.1 0 16.4 0 1.09 0 3.16 0 -99.00 1 -99.00 1 0.32 0 0.008 0.000 0.000 0.017 0.000 0.000 0.000 0.000 0.021 0.033 0.000 0.000 0.005 0.059 0.033 0.000 0.005 0.016 0.000 0.020 0.000 0.187 0.000 0.004 0.187 6 494 18 5.1 9.4740 -99.0 0.293 393.9 32.5553 6.96 302.9 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 492 16 10.6 9.4447 53.1 0.418 155.2 32.5547 6.97 303.4 241 10.1 0 16.5 0 1.10 0 3.17 0 -99.00 0 -99.00 0 0.30 0 0.011 0.004 0.000 0.021 0.002 0.005 0.000 0.000 0.029 0.038 0.003 0.004 0.006 0.067 0.037 0.004 0.006 0.021 0.000 0.025 0.000 0.209 0.000 0.005 0.218 6 491 15 14.9 8.7791 52.0 0.806 119.2 32.5618 7.12 310.0 241 10.2 0 16.6 0 1.10 0 1.85 0 -99.00 0 -99.00 0 0.37 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 490 14 20.4 8.6600 51.6 0.922 80.8 32.5642 7.16 311.6 241 10.2 0 16.6 0 1.11 0 1.79 6 -99.00 1 -99.00 1 0.39 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 489 13 25.1 8.3887 51.9 1.007 59.7 32.5714 7.24 315.0 241 10.2 0 16.6 0 1.10 0 1.67 0 -99.00 0 -99.00 0 0.39 0 0.031 0.000 0.003 0.039 0.000 0.000 0.000 0.000 0.048 0.067 0.003 0.004 0.002 0.113 0.026 0.000 0.006 0.024 0.000 0.041 0.000 0.296 0.000 0.000 0.296 6 487 11 30.2 8.1755 51.7 1.107 38.7 32.5726 7.26 316.2 58 10.3 0 16.7 0 1.12 0 1.44 0 -99.00 0 -99.00 0 0.42 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 488 12 30.3 8.2295 -99.0 1.090 38.4 32.5719 7.26 316.3 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 486 10 40.5 7.2870 52.1 1.411 19.6 32.5766 7.40 322.2 241 10.7 0 17.4 0 1.15 0 1.01 0 -99.00 0 -99.00 0 0.44 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 484 8 50.7 6.6227 55.9 0.991 8.0 32.5944 7.35 320.1 69 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 485 9 50.9 6.6293 -99.0 0.982 7.9 32.5943 7.35 319.9 240 11.7 0 18.4 0 1.22 0 0.58 0 -99.00 0 -99.00 0 0.42 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 482 6 75.3 5.8927 59.3 0.541 1.2 32.6055 7.28 316.8 56 13.4 6 20.2 6 1.36 6 0.26 0 -99.00 0 -99.00 0 0.23 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 483 7 75.3 5.8933 -99.0 0.547 1.2 32.6059 7.28 317.0 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 481 5 99.8 5.1684 61.2 0.224 0.3 32.6345 7.21 313.7 240 15.0 0 21.9 0 1.41 0 0.18 0 -99.00 1 -99.00 1 0.09 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 480 4 100.1 5.1557 -99.0 0.220 0.3 32.6380 7.21 313.7 93 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 479 3 124.8 4.8286 61.7 0.146 0.1 32.8903 6.60 287.0 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 478 2 175.5 4.7673 61.7 0.132 0.0 33.6808 4.22 183.5 241 29.3 0 53.1 0 2.25 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 477 1 201.2 4.4339 61.9 0.138 0.0 33.7535 3.32 144.4 241 33.3 0 63.9 0 2.51 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0