*2021/11/24 13:59:28.50 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/06/12 01:12:48.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 720EDA63 NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 342 364 2 Bottle_Number n/a 1 23 3 Pressure decibar 2.2 600.3 4 Temperature:Primary 'deg C (ITS90)' 3.8077 10.8543 5 Transmissivity %/metre 44 62.6 6 Fluorescence:URU:Seapoint mg/m^3 0.131 3.273 7 PAR uE/m^2/sec 0 129.2 8 Salinity:T0:C0 PSS-78 32.4914 34.1772 9 Oxygen:Dissolved:SBE mL/L 0.43 7.66 10 Oxygen:Dissolved:SBE umol/kg 18.8 333.7 11 Number_of_bin_records n/a 62 241 12 Nitrate_plus_Nitrite umol/L 8 34.2 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 15.4 62.7 15 Flag:Silicate n/a 16 Phosphate umol/L 1.04 2.51 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 3.05 19 Flag:Dimethyl_Sulphide n/a 20 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 21 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 22 Dimethylsulfoniopropionate_Total nmol/L -99 -99 23 Flag:Dimethylsulfoniopropionate_Total ' ' 24 Chlorophyll:Extracted mg/m^3 0.8E-01 0.97 25 Flag:Chlorophyll:Extracted n/a 26 HPLC:Chl-c3 mg/m^3 0.13E-01 0.43E-01 27 HPLC:Chlide-a mg/m^3 0 0.11E-01 28 HPLC:MgDVP mg/m^3 0 0.2E-02 29 HPLC:Chl-c2 mg/m^3 0.29E-01 0.98E-01 30 HPLC:Chl-c1 mg/m^3 0 0 31 HPLC:Me-chlide mg/m^3 0 0.8E-02 32 HPLC:Peri mg/m^3 0 0.3E-02 33 HPLC:Pheide-a mg/m^3 0 0 34 HPLC:But-fuco mg/m^3 0.24E-01 0.62E-01 35 HPLC:Fuco mg/m^3 0.89E-01 0.234 36 HPLC:Neo mg/m^3 0 0.4E-02 37 HPLC:Pras mg/m^3 0 0.4E-02 38 HPLC:Viola mg/m^3 0 0.7E-02 39 HPLC:Hex-fuco mg/m^3 0.75E-01 0.162 40 HPLC:Diadino mg/m^3 0.38E-01 0.53E-01 41 HPLC:Allo mg/m^3 0.5E-02 0.8E-02 42 HPLC:Diato mg/m^3 0.5E-02 0.6E-02 43 HPLC:Zea mg/m^3 0 0 44 HPLC:Lut mg/m^3 0 0 45 HPLC:Chl-b mg/m^3 0.23E-01 0.4E-01 46 HPLC:DVChl-a mg/m^3 0 0 47 HPLC:Chl-a mg/m^3 0.242 0.49 48 HPLC:Phe mg/m^3 0 0 49 HPLC:B-Car mg/m^3 0.2E-02 0.8E-02 50 HPLC:TChl-a mg/m^3 0.242 0.509 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0056.sort -------------------------------------------------------------------------------------- This file converted from Sea-Bird file: Q:\Cruise_Data_Processing\2009-09\Pro $END *ADMINISTRATION MISSION : 2009-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P20 EVENT NUMBER : 56 LATITUDE : 49 34.02000 N ! (deg min) LONGITUDE : 138 39.98000 W ! (deg min) WATER DEPTH : 3971 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2038 conductivity:primary ' ' 2128 pressure ' ' 63507 temperature:secondary ' ' 2449 conductivity:secondary ' ' 2424 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1005 Oxygen:SBE ' ' 0997 altimeter: ' ' ' ' irradiance:primary ' ' 4615 pH ' ' 0692 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.16 Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0056.sort -------------------------------------------------------------------- SOFTWARE VERSION SEASAVE V 7.16 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/08/01 11:15:18 5053 5053 CLEAN 5.0.2 2009/08/01 12:49:14 ? ? ADDSAMP 3.4 2009/08/01 14:24:41 5053 5053 BINAVE 4.1.1 2009/08/01 14:35:16 5053 23 MERGE 3.3 2009/09/11 13:39:05 23 23 CLEAN 5.0.2 2009/09/11 13:39:14 ? ? CALIB 11.7 2009/09/11 13:43:31 23 23 SORT 3.5 2009/09/11 13:53:36 23 23 REMOVECH 8.0 2009/09/11 14:08:11 23 23 CHGUNITS 3.0 2009/09/11 14:11:23 23 23 REORDER 1.2.1 2009/09/11 14:11:56 ? ? HDREDIT2 2.5.1 2009/09/11 14:12:59 ? ? REMOVECH 8.0 2009/11/16 10:50:39 23 23 MERGE 3.3 2009/11/16 10:54:14 23 23 HDREDIT2 2.5.1 2010/01/07 09:14:47 ? ? CALIB 11.7 2010/08/18 13:47:58 23 23 HDREDIT2 2.5.1 2010/08/18 14:29:05 ? ? HDREDIT2 2.5.1 2010/09/02 14:08:53 ? ? CALIB 11.7 2013/06/04 13:12:30 23 23 HDREDIT2 2.6 2013/07/08 08:49:07 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:31:09 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:56:36 23 23 SORT 3.6 2020/07/24 13:13:56 23 23 HDREDIT2 3.2 2020/07/24 14:49:50 ? ? MERGE 3.5.1 2020/07/24 15:05:47 23 23 SORT 3.6 2020/07/24 15:06:49 23 23 CLEAN 5.2.4 2020/07/24 15:07:07 23 23 HDREDIT2 3.2 2020/07/24 15:07:36 ? ? SORT 3.6 2020/11/25 14:17:57 23 23 REORDER 1.3.1 2021/11/24 13:58:17 ? ? $END $REMARKS -CLEAN functions: 2009/08/01 12:48:19 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2009/09/11 13:38:59 2009/09/11 13:38:59 2009/09/11 13:38: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle [ ], Flag:Salinity:Bottle [ ], Chlorophyll:Extracted [ ], Flag:Chlorophyll:Extracted [ ], Oxygen:Dissolved [ ], Flag:Oxygen:Dissolved [ ], Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ], Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0056.samavg Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0056.mrgcln1 -CLEAN functions: 2009/09/11 13:39:11 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2009/09/11 13:43:31 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.3000000E+00 0.1000000E+01 15 Oxygen:Dissolved:SBE mL/L 10 -0.3050000E-01 0.1052800E+01 16 Salinity:T0:C0 PSS-78 10 0.2000000E-01 0.1000000E+01 -SORT parameters: 2009/09/11 13:53:36 Sorted in ascending order of channel Pressure -REMOVECH 2009/09/11 14:08:11 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2009/09/11 14:12:59 Applied edit header: Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 10: Firing_Number [n/a] Name: Bottle_Number ==> Firing_Number Channel 12: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 13: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 17: Flag:Silicate [n/a] Units: ==> n/a Channel 19: Flag:Phosphate [n/a] Units: ==> n/a Channel 21: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -REMOVECH 2009/11/16 10:50:39 1 channels removed. -The following MERGE parameters were used: 2009/11/16 10:54:09 2009/11/16 10:54:09 2009/11/16 10:54: Merge Channel: Pressure Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Transmissivity Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0056.remb Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0056.sort Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0056.sort -------------------------------------------------------------------- -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -SORT parameters: 2009/11/16 10:53:59 Sorted in ascending order of channel Pressure -HEADER EDITS: 2010/01/07 09:14:47 Channel 9: Bottle_Number [n/a] Name: Firing_Number ==> Bottle_Number -CALIB parameters: 2010/08/18 13:47:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\2009-09-recal-tr.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 21 Transmissivity %/metre 10 0.0000000E+00 0.1265000E+01 -HEADER EDITS: 2010/08/18 14:29:05 Applied edit header: Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\Trans_Correction1.TXT -HEADER EDITS: 2010/09/02 14:08:53 Channel 21: Transmissivity [%/metre] Format: F7.2 ==> F6.1 -CALIB parameters: 2013/06/04 13:12:30 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 17 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:49:07 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/07/24 13:13:56 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2020/07/24 14:49:50 Channel 10: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 12: Flag:Chlorophyll:Extracted [n/a] Pad: 0 ==> -99 Channel 14: Flag:Nitrate_plus_Nitrite [n/a] Pad: 0 ==> -99 Channel 16: Flag:Silicate [n/a] Pad: 0 ==> -99 Channel 18: Flag:Phosphate [n/a] Pad: 0 ==> -99 Channel 20: Flag:Dimethyl_Sulphide [n/a] Pad: 0 ==> -99 -The following MERGE parameters were used: 2020/07/24 15:05:47 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009- 0056.che1 Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009- 0056.dmsp -SORT parameters: 2020/07/24 15:06:49 Sorted in ascending order of channel Pressure -CLEAN functions: 2020/07/24 15:06:56 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* -HEADER EDITS: 2020/07/24 15:07:36 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-010\Processing\2009- 010-bot-hdr1.txt Channel 10: Number_of_bin_records [n/a] Pad: -99 ==> blank Channel 12: Flag:Chlorophyll:Extracted [n/a] Pad: -99 ==> 0 Channel 14: Flag:Nitrate_plus_Nitrite [n/a] Pad: -99 ==> 0 Channel 16: Flag:Silicate [n/a] Pad: -99 ==> 0 Channel 18: Flag:Phosphate [n/a] Pad: -99 ==> 0 Channel 20: Flag:Dimethyl_Sulphide [n/a] Pad: -99 ==> 0 -SORT parameters: 2020/11/25 14:17:57 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 13:58:25 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0056.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0056.hplc -SORT parameters: 2021/11/24 13:58:33 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 13:58:40 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 13:59:08 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 26: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 13:59:28 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009-0056.dmsp --------------------------------------------------------------------------- Sample_Number 344: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 345: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 347: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 356: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 362: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 363: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2009-09CHL.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2009-009_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 950 Colorimeter. For information on precision see file 2009-09_oxy_duplicates.xls. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. Samples from two casts were analyzed at sea on a Guildline Portasal; there are comments attached to those samples and all were flagged "d". See file 2009-09-salinity-duplicates.xls for information on AUtosal precision. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using an Astoria Pacific autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-09nuts.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2009-09 DMS Report.doc. DMSP: All sample data discarded due to blank contamination problems. For details on analysis see documents "2009-09 dmsp QF summary.xls" and "2009-09 DMS report.doc". References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\IOS\2009-009-0056. hplc --------------------------------------------------------------------------- Sample_Number 355: HPLC: >10%CV for TChl-a Sample_Number 359: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure dbars 10 -99 () (0.3 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.305E-01 1.0528) Salinity:T0:C0 PSS-78 10 -99 () (0.2E-01 1) Transmissivity %/metre 10 -99 () (0 1.265) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12- 13 --14- 15 --16-- 17 --18-- 19 --20-- 21 --22-- 23 --24-- 25 ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitra Fl Silic Fl Phosph Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T0:C0 : n: er_o te_ ag ate ag ate ag yl_ ag ylsulf ag ylsulf ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a a chlide a fuco fuco : !er er Seapoin ved: lved: _rec Nitri ri ca ha de hi te_Dis lv ionate ot ted ct HP ! t SBE SBE ords te te te te de solved ed _Total al ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -- ----- -- ------ -- ------ -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 363 22 2.2 10.8470 47.4 0.730 129.2 32.5049 6.88 299.7 64 8.3 0 15.6 0 1.04 0 2.68 0 -99.00 1 -99.00 1 0.48 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 364 23 2.5 10.8543 -99.0 0.727 119.6 32.5051 6.87 299.3 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 360 19 4.4 10.7581 50.6 0.726 76.2 32.5050 6.89 300.3 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 361 20 5.3 10.7593 50.1 0.741 62.6 32.5057 6.89 300.2 110 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 362 21 5.5 10.7590 -99.0 0.741 60.4 32.5056 6.89 300.1 240 8.3 0 15.5 0 1.04 0 2.93 0 -99.00 1 -99.00 1 0.42 0 0.015 0.000 0.000 0.031 0.000 0.000 0.000 0.000 0.032 0.089 0.002 0.000 0.007 0.092 0.053 0.006 0.005 0.000 0.000 0.023 0.000 0.309 0.000 0.006 0.309 6 358 17 8.3 10.2411 50.6 0.897 47.3 32.4989 7.01 305.3 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 359 18 10.8 10.2938 50.7 0.871 34.1 32.5019 7.00 304.8 241 8.2 0 15.4 0 1.05 0 3.05 0 -99.00 0 -99.00 0 0.39 0 0.013 0.000 0.000 0.029 0.000 0.000 0.000 0.000 0.024 0.093 0.000 0.000 0.005 0.075 0.038 0.005 0.005 0.000 0.000 0.024 0.000 0.242 0.000 0.002 0.242 36 357 16 15.6 9.4011 48.5 1.419 26.2 32.4982 7.30 318.0 241 8.2 0 15.5 0 1.04 0 2.52 0 -99.00 0 -99.00 0 0.54 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 356 15 20.4 8.9387 47.4 1.829 20.0 32.4974 7.50 326.4 241 8.0 0 15.6 0 1.04 0 2.11 6 -99.00 1 -99.00 1 0.65 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 354 13 22.8 9.0854 47.3 1.721 19.3 32.4963 7.41 322.5 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 355 14 25.4 8.7309 45.9 2.278 14.5 32.4946 7.58 330.1 241 8.0 0 15.5 0 1.04 0 2.16 0 -99.00 0 -99.00 0 0.68 6 0.043 0.011 0.002 0.098 0.000 0.008 0.003 0.000 0.062 0.234 0.004 0.004 0.000 0.162 0.052 0.008 0.006 0.000 0.000 0.040 0.000 0.490 0.000 0.008 0.509 36 353 12 30.5 8.0507 44.0 3.273 9.7 32.4914 7.66 333.7 241 8.4 0 15.8 0 1.07 0 2.25 0 -99.00 0 -99.00 0 0.97 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 352 11 40.3 7.1353 52.8 1.822 3.6 32.5124 7.43 323.6 241 10.6 0 16.8 0 1.23 0 0.99 0 -99.00 0 -99.00 0 0.69 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 350 9 45.8 6.4002 56.2 1.074 2.1 32.5304 7.38 321.2 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 351 10 50.9 6.2593 57.0 0.920 1.5 32.5380 7.39 321.5 241 12.3 0 17.7 0 1.28 0 0.58 0 -99.00 0 -99.00 0 0.44 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 349 8 76.0 5.4808 61.1 0.307 0.3 32.5553 7.22 314.2 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 348 7 76.2 5.4817 -99.0 0.300 0.3 32.5552 7.22 314.4 62 14.2 6 18.2 6 1.34 6 0.41 0 -99.00 0 -99.00 0 0.15 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 347 6 99.7 5.1970 61.6 0.196 0.1 32.6138 7.05 306.8 241 15.7 0 20.1 0 1.42 0 0.27 0 -99.00 1 -99.00 1 0.08 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 346 5 149.8 5.2328 61.9 0.143 0.0 33.5513 4.28 186.2 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 345 4 174.6 5.1355 61.6 0.132 0.0 33.7644 3.40 147.8 241 32.0 0 56.4 0 2.36 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 344 3 200.4 4.9102 61.7 0.131 0.0 33.8098 2.86 124.1 241 34.2 0 62.7 0 2.51 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 343 2 300.2 4.2953 62.4 0.134 0.0 33.8960 1.77 77.0 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 342 1 600.3 3.8077 62.6 0.139 0.0 34.1772 0.43 18.8 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0