*2021/11/24 13:59:28.36 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/06/09 18:22:48.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : FCF99886 NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 176 198 2 Bottle_Number n/a 1 23 3 Pressure decibar 2 601.2 4 Temperature:Primary 'deg C (ITS90)' 4.0084 11.3433 5 Transmissivity %/metre 50.6 62.7 6 Fluorescence:URU:Seapoint mg/m^3 0.126 2.102 7 PAR uE/m^2/sec 0 306.3 8 Salinity:T0:C0 PSS-78 32.409 34.1298 9 Oxygen:Dissolved:SBE mL/L 0.54 7.23 10 Oxygen:Dissolved:SBE umol/kg 23.6 314.9 11 Number_of_bin_records n/a 52 241 12 Nitrate_plus_Nitrite umol/L 6 27.2 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 10.3 43.4 15 Flag:Silicate n/a 16 Phosphate umol/L 0.84 2 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 1.11 19 Flag:Dimethyl_Sulphide n/a 20 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 21 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 22 Dimethylsulfoniopropionate_Total nmol/L -99 -99 23 Flag:Dimethylsulfoniopropionate_Total ' ' 24 Chlorophyll:Extracted mg/m^3 0.4E-01 0.5 25 Flag:Chlorophyll:Extracted n/a 26 HPLC:Chl-c3 mg/m^3 0.17E-01 0.35E-01 27 HPLC:Chlide-a mg/m^3 0 0 28 HPLC:MgDVP mg/m^3 0 0 29 HPLC:Chl-c2 mg/m^3 0.26E-01 0.37E-01 30 HPLC:Chl-c1 mg/m^3 0 0 31 HPLC:Me-chlide mg/m^3 0 0 32 HPLC:Peri mg/m^3 0 0 33 HPLC:Pheide-a mg/m^3 0 0 34 HPLC:But-fuco mg/m^3 0.22E-01 0.35E-01 35 HPLC:Fuco mg/m^3 0.37E-01 0.42E-01 36 HPLC:Neo mg/m^3 0.3E-02 0.6E-02 37 HPLC:Pras mg/m^3 0 0 38 HPLC:Viola mg/m^3 0.3E-02 0.8E-02 39 HPLC:Hex-fuco mg/m^3 0.125 0.167 40 HPLC:Diadino mg/m^3 0.24E-01 0.59E-01 41 HPLC:Allo mg/m^3 0.3E-02 0.6E-02 42 HPLC:Diato mg/m^3 0.5E-02 0.14E-01 43 HPLC:Zea mg/m^3 0.15E-01 0.19E-01 44 HPLC:Lut mg/m^3 0.1E-01 0.13E-01 45 HPLC:Chl-b mg/m^3 0.38E-01 0.62E-01 46 HPLC:DVChl-a mg/m^3 0 0 47 HPLC:Chl-a mg/m^3 0.255 0.298 48 HPLC:Phe mg/m^3 0 0 49 HPLC:B-Car mg/m^3 0 0.6E-02 50 HPLC:TChl-a mg/m^3 0.255 0.298 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0031.sort -------------------------------------------------------------------------------------- This file converted from Sea-Bird file: Q:\Cruise_Data_Processing\2009-09\Pro $END *ADMINISTRATION MISSION : 2009-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P12 EVENT NUMBER : 31 LATITUDE : 48 58.29000 N ! (deg min) LONGITUDE : 130 39.85000 W ! (deg min) WATER DEPTH : 3287 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2038 conductivity:primary ' ' 2128 pressure ' ' 63507 temperature:secondary ' ' 2449 conductivity:secondary ' ' 2424 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1005 Oxygen:SBE ' ' 0997 altimeter: ' ' ' ' irradiance:primary ' ' 4615 pH ' ' 0692 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.16 Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0031.sort -------------------------------------------------------------------- SOFTWARE VERSION SEASAVE V 7.16 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/08/01 11:14:49 5076 5076 CLEAN 5.0.2 2009/08/01 12:48:50 ? ? ADDSAMP 3.4 2009/08/01 14:24:16 5076 5076 BINAVE 4.1.1 2009/08/01 14:35:06 5076 23 MERGE 3.3 2009/09/11 13:39:02 23 23 CLEAN 5.0.2 2009/09/11 13:39:13 ? ? CALIB 11.7 2009/09/11 13:43:29 23 23 SORT 3.5 2009/09/11 13:53:35 23 23 REMOVECH 8.0 2009/09/11 14:08:11 23 23 CHGUNITS 3.0 2009/09/11 14:11:23 23 23 REORDER 1.2.1 2009/09/11 14:11:54 ? ? HDREDIT2 2.5.1 2009/09/11 14:12:58 ? ? REMOVECH 8.0 2009/11/16 10:50:38 23 23 MERGE 3.3 2009/11/16 10:54:11 23 23 HDREDIT2 2.5.1 2010/01/07 09:14:45 ? ? CALIB 11.7 2010/08/18 13:47:57 23 23 HDREDIT2 2.5.1 2010/08/18 14:29:05 ? ? HDREDIT2 2.5.1 2010/09/02 14:08:51 ? ? CALIB 11.7 2013/06/04 13:12:29 23 23 HDREDIT2 2.6 2013/07/08 08:49:06 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:31:09 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:56:35 23 23 SORT 3.6 2020/07/24 13:13:44 23 23 HDREDIT2 3.2 2020/07/24 14:49:45 ? ? MERGE 3.5.1 2020/07/24 15:05:41 23 23 SORT 3.6 2020/07/24 15:06:44 23 23 CLEAN 5.2.4 2020/07/24 15:07:02 23 23 HDREDIT2 3.2 2020/07/24 15:07:30 ? ? SORT 3.6 2020/11/25 14:17:57 23 23 REORDER 1.3.1 2021/11/24 13:58:16 ? ? $END $REMARKS -CLEAN functions: 2009/08/01 12:48:19 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2009/09/11 13:38:59 2009/09/11 13:38:59 2009/09/11 13:38: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle [ ], Flag:Salinity:Bottle [ ], Chlorophyll:Extracted [ ], Flag:Chlorophyll:Extracted [ ], Oxygen:Dissolved [ ], Flag:Oxygen:Dissolved [ ], Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ], Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0031.samavg Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0031.mrgcln1 -CLEAN functions: 2009/09/11 13:39:11 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2009/09/11 13:43:29 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.3000000E+00 0.1000000E+01 15 Oxygen:Dissolved:SBE mL/L 10 -0.3050000E-01 0.1052800E+01 16 Salinity:T0:C0 PSS-78 10 0.2000000E-01 0.1000000E+01 -SORT parameters: 2009/09/11 13:53:35 Sorted in ascending order of channel Pressure -REMOVECH 2009/09/11 14:08:11 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2009/09/11 14:12:58 Applied edit header: Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 10: Firing_Number [n/a] Name: Bottle_Number ==> Firing_Number Channel 12: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 13: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 17: Flag:Silicate [n/a] Units: ==> n/a Channel 19: Flag:Phosphate [n/a] Units: ==> n/a Channel 21: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -REMOVECH 2009/11/16 10:50:38 1 channels removed. -The following MERGE parameters were used: 2009/11/16 10:54:09 2009/11/16 10:54:09 2009/11/16 10:54: Merge Channel: Pressure Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Transmissivity Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0031.remb Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0031.sort Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0031.sort -------------------------------------------------------------------- -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -SORT parameters: 2009/11/16 10:53:56 Sorted in ascending order of channel Pressure -HEADER EDITS: 2010/01/07 09:14:45 Channel 9: Bottle_Number [n/a] Name: Firing_Number ==> Bottle_Number -CALIB parameters: 2010/08/18 13:47:57 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\2009-09-recal-tr.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 21 Transmissivity %/metre 10 0.0000000E+00 0.1265000E+01 -HEADER EDITS: 2010/08/18 14:29:05 Applied edit header: Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\Trans_Correction1.TXT -HEADER EDITS: 2010/09/02 14:08:51 Channel 21: Transmissivity [%/metre] Format: F7.2 ==> F6.1 -CALIB parameters: 2013/06/04 13:12:29 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 17 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:49:06 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/07/24 13:13:44 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2020/07/24 14:49:45 Channel 10: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 12: Flag:Chlorophyll:Extracted [n/a] Pad: 0 ==> -99 Channel 14: Flag:Nitrate_plus_Nitrite [n/a] Pad: 0 ==> -99 Channel 16: Flag:Silicate [n/a] Pad: 0 ==> -99 Channel 18: Flag:Phosphate [n/a] Pad: 0 ==> -99 Channel 20: Flag:Dimethyl_Sulphide [n/a] Pad: 0 ==> -99 -The following MERGE parameters were used: 2020/07/24 15:05:41 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009- 0031.che1 Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009- 0031.dmsp -SORT parameters: 2020/07/24 15:06:44 Sorted in ascending order of channel Pressure -CLEAN functions: 2020/07/24 15:06:56 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* -HEADER EDITS: 2020/07/24 15:07:30 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-010\Processing\2009- 010-bot-hdr1.txt Channel 10: Number_of_bin_records [n/a] Pad: -99 ==> blank Channel 12: Flag:Chlorophyll:Extracted [n/a] Pad: -99 ==> 0 Channel 14: Flag:Nitrate_plus_Nitrite [n/a] Pad: -99 ==> 0 Channel 16: Flag:Silicate [n/a] Pad: -99 ==> 0 Channel 18: Flag:Phosphate [n/a] Pad: -99 ==> 0 Channel 20: Flag:Dimethyl_Sulphide [n/a] Pad: -99 ==> 0 -SORT parameters: 2020/11/25 14:17:57 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 13:58:25 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0031.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0031.hplc -SORT parameters: 2021/11/24 13:58:33 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 13:58:40 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 13:59:08 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 26: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 13:59:28 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr2.txt $END *COMMENTS Sample_Numbers 186-197: DMS: Instrument problems; data not reliable Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2009-009\Processing\2009-009-0031.dmsp --------------------------------------------------------------------------- Sample_Number 178: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 179: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 181: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 189: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 196: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 197: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 13, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2009-09CHL.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2009-009_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 950 Colorimeter. For information on precision see file 2009-09_oxy_duplicates.xls. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. Samples from two casts were analyzed at sea on a Guildline Portasal; there are comments attached to those samples and all were flagged "d". See file 2009-09-salinity-duplicates.xls for information on AUtosal precision. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using an Astoria Pacific autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-09nuts.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2009-09 DMS Report.doc. DMSP: All sample data discarded due to blank contamination problems. For details on analysis see documents "2009-09 dmsp QF summary.xls" and "2009-09 DMS report.doc". References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\IOS\2009-009-0031. hplc --------------------------------------------------------------------------- Sample_Number 192: HPLC: >30%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure dbars 10 -99 () (0.3 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.305E-01 1.0528) Salinity:T0:C0 PSS-78 10 -99 () (0.2E-01 1) Transmissivity %/metre 10 -99 () (0 1.265) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12- 13 --14- 15 --16-- 17 --18-- 19 --20-- 21 --22-- 23 --24-- 25 ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitra Fl Silic Fl Phosph Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T0:C0 : n: er_o te_ ag ate ag ate ag yl_ ag ylsulf ag ylsulf ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a a chlide a fuco fuco : !er er Seapoin ved: lved: _rec Nitri ri ca ha de hi te_Dis lv ionate ot ted ct HP ! t SBE SBE ords te te te te de solved ed _Total al ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -- ----- -- ------ -- ------ -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 197 22 2.0 11.3385 50.8 0.390 304.7 32.4269 6.79 295.9 76 6.5 0 12.0 0 0.89 0 -99.00 5 -99.00 1 -99.00 1 0.44 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 198 23 2.1 11.3433 -99.0 0.395 306.3 32.4268 6.78 295.2 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 195 20 5.7 11.3228 51.4 0.492 177.0 32.4252 6.77 295.0 131 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 196 21 5.7 11.3155 50.6 0.447 179.3 32.4250 6.77 295.0 240 6.5 0 11.9 0 0.89 0 -99.00 5 -99.00 1 -99.00 1 0.49 0 0.025 0.000 0.000 0.029 0.000 0.000 0.000 0.000 0.022 0.041 0.005 0.000 0.008 0.149 0.059 0.006 0.014 0.019 0.013 0.046 0.000 0.298 0.000 0.006 0.298 6 194 19 6.3 11.3064 -99.0 0.512 159.7 32.4248 6.78 295.4 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 192 17 10.2 11.2803 51.2 0.701 104.8 32.4248 6.78 295.3 241 6.5 0 12.0 0 0.89 0 -99.00 5 -99.00 0 -99.00 0 0.45 0 0.017 0.000 0.000 0.026 0.000 0.000 0.000 0.000 0.023 0.037 0.003 0.000 0.005 0.125 0.048 0.003 0.008 0.016 0.010 0.038 0.000 0.255 0.000 0.003 0.255 46 193 18 11.3 11.2803 51.2 0.738 99.2 32.4246 6.77 295.1 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 190 15 15.7 10.9306 52.9 0.814 69.4 32.4090 6.81 296.6 241 6.7 0 12.2 0 0.92 0 -99.00 5 -99.00 0 -99.00 0 0.38 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 189 14 20.2 10.5971 52.2 1.085 50.4 32.4285 6.92 301.3 241 6.5 0 11.7 0 0.91 0 -99.00 5 -99.00 1 -99.00 1 0.41 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 188 13 24.7 10.4088 51.5 1.433 36.4 32.4523 6.97 303.6 241 6.0 0 11.1 0 0.85 0 -99.00 5 -99.00 0 -99.00 0 0.45 0 0.035 0.000 0.000 0.037 0.000 0.000 0.000 0.000 0.035 0.042 0.006 0.000 0.003 0.167 0.024 0.004 0.005 0.015 0.011 0.062 0.000 0.281 0.000 0.000 0.281 6 191 16 27.3 9.9904 50.7 1.692 30.4 32.4920 7.09 308.6 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 186 11 30.4 9.2977 51.5 2.102 21.9 32.5019 7.23 314.9 241 6.0 0 10.5 0 0.84 0 -99.00 5 -99.00 0 -99.00 0 0.50 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 185 10 41.0 8.3497 55.5 1.848 9.1 32.5430 7.09 308.7 241 7.0 0 10.3 0 0.91 0 1.11 0 -99.00 0 -99.00 0 0.43 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 184 9 50.5 8.0703 57.9 1.260 4.5 32.5488 7.01 305.0 241 7.4 0 10.3 0 0.95 0 0.81 0 -99.00 0 -99.00 0 0.38 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 187 12 57.5 7.8661 58.8 0.893 2.9 32.5408 6.96 303.0 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 183 8 75.0 7.7386 60.1 0.587 1.0 32.5420 6.91 301.0 240 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 182 7 75.3 7.7376 -99.0 0.585 0.9 32.5420 6.92 301.2 52 8.4 0 11.1 0 1.01 0 0.48 0 -99.00 0 -99.00 0 0.27 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 181 6 100.9 6.9567 61.7 0.156 0.3 32.8851 6.29 273.6 241 14.4 6 17.1 6 1.31 6 0.00 0 -99.00 1 -99.00 1 0.04 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 180 5 150.7 6.6414 61.6 0.135 0.0 33.6567 5.02 218.2 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 179 4 176.9 6.5014 61.7 0.129 0.0 33.7966 4.58 199.1 241 24.6 0 37.1 0 1.84 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 178 3 200.5 6.2396 61.7 0.126 0.0 33.8475 4.10 178.2 241 27.2 0 43.4 0 2.00 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 177 2 300.3 5.2411 62.1 0.129 0.0 33.8959 2.49 108.5 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 176 1 601.2 4.0084 62.7 0.135 0.0 34.1298 0.54 23.6 241 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0