*2021/11/24 13:59:28.28 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2009/06/08 23:38:19.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 21 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : B7E5A184 NUMBER OF CHANNELS : 48 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 129 149 2 Bottle_Number n/a 1 21 3 Pressure decibar 5.2 2002 4 Temperature:Primary 'deg C (ITS90)' 1.9085 12.2281 5 Transmissivity %/metre 34.3 63 6 Fluorescence:URU:Seapoint mg/m^3 0.128 1.809 7 Salinity:T0:C0 PSS-78 32.3797 34.5963 8 Oxygen:Dissolved:SBE mL/L 0.2 7.11 9 Oxygen:Dissolved:SBE umol/kg 8.7 309.6 10 Number_of_bin_records n/a 42 241 11 Salinity:Bottle PSS-78 32.3786 34.6037 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 0.211 6.891 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 4.2 46.9 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 8.2 183 18 Flag:Silicate n/a 19 Phosphate umol/L 0.75 3.33 20 Flag:Phosphate n/a 21 Chlorophyll:Extracted mg/m^3 0.6E-01 0.53 22 Flag:Chlorophyll:Extracted n/a 23 HPLC:Chl-c3 mg/m^3 0.21E-01 0.44E-01 24 HPLC:Chlide-a mg/m^3 0 0 25 HPLC:MgDVP mg/m^3 0 0 26 HPLC:Chl-c2 mg/m^3 0.32E-01 0.57E-01 27 HPLC:Chl-c1 mg/m^3 0 0 28 HPLC:Me-chlide mg/m^3 0 0 29 HPLC:Peri mg/m^3 0 0.7E-02 30 HPLC:Pheide-a mg/m^3 0 0 31 HPLC:But-fuco mg/m^3 0.31E-01 0.47E-01 32 HPLC:Fuco mg/m^3 0.47E-01 0.75E-01 33 HPLC:Neo mg/m^3 0 0.6E-02 34 HPLC:Pras mg/m^3 0 0 35 HPLC:Viola mg/m^3 0 0 36 HPLC:Hex-fuco mg/m^3 0.138 0.214 37 HPLC:Diadino mg/m^3 0.34E-01 0.65E-01 38 HPLC:Allo mg/m^3 0.6E-02 0.15E-01 39 HPLC:Diato mg/m^3 0.9E-02 0.11E-01 40 HPLC:Zea mg/m^3 0.9E-02 0.11E-01 41 HPLC:Lut mg/m^3 0.5E-02 0.5E-02 42 HPLC:Chl-b mg/m^3 0.21E-01 0.48E-01 43 HPLC:DVChl-a mg/m^3 0 0 44 HPLC:Chl-a mg/m^3 0.298 0.361 45 HPLC:Phe mg/m^3 0 0 46 HPLC:B-Car mg/m^3 0.2E-02 0.5E-02 47 HPLC:TChl-a mg/m^3 0.298 0.361 48 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F R4 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0020.sort -------------------------------------------------------------------------------------- This file converted from Sea-Bird file: Q:\Cruise_Data_Processing\2009-09\Pro $END *ADMINISTRATION MISSION : 2009-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P8 EVENT NUMBER : 20 LATITUDE : 48 48.99000 N ! (deg min) LONGITUDE : 128 39.97000 W ! (deg min) WATER DEPTH : 2517 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2038 conductivity:primary ' ' 2128 pressure ' ' 63507 temperature:secondary ' ' 2449 conductivity:secondary ' ' 2424 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1005 Oxygen:SBE ' ' 0997 altimeter: ' ' ' ' irradiance:primary ' ' 4615 pH ' ' 0692 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.16 Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0020.sort -------------------------------------------------------------------- SOFTWARE VERSION SEASAVE V 7.16 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2009/08/01 11:14:37 4669 4669 CLEAN 5.0.2 2009/08/01 12:48:41 ? ? ADDSAMP 3.4 2009/08/01 14:24:07 4669 4669 BINAVE 4.1.1 2009/08/01 14:35:02 4669 21 MERGE 3.3 2009/09/11 13:39:01 21 21 CLEAN 5.0.2 2009/09/11 13:39:13 ? ? CALIB 11.7 2009/09/11 13:43:28 21 21 SORT 3.5 2009/09/11 13:53:35 21 21 REMOVECH 8.0 2009/09/11 14:07:59 21 21 CHGUNITS 3.0 2009/09/11 14:11:22 21 21 REORDER 1.2.1 2009/09/11 14:11:53 ? ? HDREDIT2 2.5.1 2009/09/11 14:12:57 ? ? REMOVECH 8.0 2009/11/16 10:50:37 21 21 MERGE 3.3 2009/11/16 10:54:11 21 21 HDREDIT2 2.5.1 2010/01/07 09:14:44 ? ? REMOVECH 8.0 2010/01/18 10:22:44 21 21 SORT 3.5 2010/01/18 10:27:00 21 21 MERGE 3.3 2010/01/18 10:42:30 21 21 SORT 3.5 2010/01/18 10:44:07 21 21 CALIB 11.7 2010/08/18 13:47:56 21 21 HDREDIT2 2.5.1 2010/08/18 14:29:05 ? ? HDREDIT2 2.5.1 2010/09/02 14:08:50 ? ? CALIB 11.7 2013/06/04 13:12:29 21 21 HDREDIT2 2.6 2013/07/08 08:49:05 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:31:09 21 21 CHANGE_FLAGS 2.0 2014/11/20 09:56:34 21 21 SORT 3.6 2020/11/25 14:17:57 21 21 REORDER 1.3.1 2021/11/24 13:58:16 ? ? MERGE 3.5.1 2021/11/24 13:58:25 21 21 SORT 3.6 2021/11/24 13:58:33 21 21 $END $REMARKS -CLEAN functions: 2009/08/01 12:48:19 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2009/09/11 13:38:59 2009/09/11 13:38:59 2009/09/11 13:38: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle [ ], Flag:Salinity:Bottle [ ], Chlorophyll:Extracted [ ], Flag:Chlorophyll:Extracted [ ], Oxygen:Dissolved [ ], Flag:Oxygen:Dissolved [ ], Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ], Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0020.samavg Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\hydro\NEW CHL\2009-09-0020.mrgcln1 -CLEAN functions: 2009/09/11 13:39:11 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2009/09/11 13:43:28 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.3000000E+00 0.1000000E+01 15 Oxygen:Dissolved:SBE mL/L 10 -0.3050000E-01 0.1052800E+01 16 Salinity:T0:C0 PSS-78 10 0.2000000E-01 0.1000000E+01 -SORT parameters: 2009/09/11 13:53:35 Sorted in ascending order of channel Pressure -REMOVECH 2009/09/11 14:07:59 11 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2009/09/11 14:12:57 Applied edit header: Q:\Cruise_Data_Processing\2009-09\Processing\doc\2009-09-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 9: Firing_Number [n/a] Name: Bottle_Number ==> Firing_Number Channel 11: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 12: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Oxygen:Dissolved [mL/L] Units: ==> mL/L Format: f8.3 ==> F8.3 Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 18: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 20: Flag:Silicate [n/a] Units: ==> n/a Channel 22: Flag:Phosphate [n/a] Units: ==> n/a -REMOVECH 2009/11/16 10:50:37 1 channels removed. -The following MERGE parameters were used: 2009/11/16 10:54:09 2009/11/16 10:54:09 2009/11/16 10:54: Merge Channel: Pressure Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Transmissivity Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0020.remb Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0020.sort Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0020.sort -------------------------------------------------------------------- -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -SORT parameters: 2009/11/16 10:53:56 Sorted in ascending order of channel Pressure -HEADER EDITS: 2010/01/07 09:14:44 Channel 8: Bottle_Number [n/a] Name: Firing_Number ==> Bottle_Number -REMOVECH 2010/01/18 10:22:44 2 channels removed. -SORT parameters: 2010/01/18 10:27:00 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2010/01/18 10:42:30 2010/01/18 10:42:30 2010/01/18 10:42: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data_Processing\2009-09\Processing\test\2009-09-0020.sort1 Secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\test\2009-09-0020.add -SORT parameters: 2010/01/18 10:44:07 Sorted in ascending order of channel Pressure -CALIB parameters: 2010/08/18 13:47:56 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\2009-09-recal-tr.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Transmissivity %/metre 10 0.0000000E+00 0.1265000E+01 -HEADER EDITS: 2010/08/18 14:29:05 Applied edit header: Q:\Cruise_Data_Processing\Trans Cor\2009-09\DOC\Trans_Correction1.TXT -HEADER EDITS: 2010/09/02 14:08:50 Channel 20: Transmissivity [%/metre] Format: F7.2 ==> F6.1 -CALIB parameters: 2013/06/04 13:12:29 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = C:\DATA\Nutrients\doc\Nutrients-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Nitrate_plus_Nitrite umol/L 10 0.1709000E+00 0.9812000E+00 18 Phosphate umol/L 10 0.4530000E-01 0.1011500E+01 -HEADER EDITS: 2013/07/08 08:49:05 Applied edit header: C:\DATA\Nutrients\doc\headedit-correction.txt -SORT parameters: 2020/11/25 14:17:57 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/24 13:58:25 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0020.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\ IOS\2009-009-0020.hplc -SORT parameters: 2021/11/24 13:58:33 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/24 13:58:40 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/24 13:59:08 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 13: Oxygen:Dissolved [mL/L] Format: f8.3 ==> F8.3 Channel 23: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/24 13:59:28 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009\Processing\Doc\ 2009-009-bot-hdr2.txt $END *COMMENTS Sample_Number 129: Salinity: Sample bottle leaking Sample_Number 131: Salinity:Duplicates differ by >0.01 Sample_Number 129: Dissolved Oxygen: Outlier in comparison with CTD DO. But CTD dissolved oxygen data was noisy and rising during the bottle stop, so bottle may be fine. Sample_Number 130: Dissolved Oxygen: Outlier in comparison with CTD DO, but CTD dissolved oxygen data was still falling as the bottle was fired. Sample_Number 141: Dissolved Oxygen: Outlier in comparison with CTD DO, and in profile and in plot of DO vs Salinity. Sample_Number 145: Dissolved Oxygen: Outlier in comparison with CTD DO, and in profile and in plot of DO vs Salinity. Sample_Number 146: Dissolved Oxygen: Outlier in comparison with CTD DO, and in profile and in plot of DO vs Salinity. Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs 10AU fluorometer which was calibrated on May 12, 2009 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2009-09CHL.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2009-009_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 950 Colorimeter. For information on precision see file 2009-09_oxy_duplicates.xls. Salinity samples were collected in glass bottles and analyzed at IOS on a Guildline model 8400B Autosal standardized with IAPSO standard seawater. Samples from some casts were analyzed at sea on a Guildline Portasal; there are comments attached to those samples and all were flagged "d". See file 2009-09-salinity-duplicates.xls for information on AUtosal precision. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using an Astoria autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2009-09nutsrev1jebc.xls. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2009-09 DMS Report.doc. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ----------------------------------------------------------------------------------- Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\trans\2009-09-0020.sort -------------------------------------------------------------------- SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\Data\2009-09\2009-09-0020.hex Software Version Seasave V 7.16 Temperature SN = 2038 Conductivity SN = 2128 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jun 07 2009 02:14:50 NMEA Latitude = 48 48.99 N NMEA Longitude = 128 39.97 W NMEA UTC (Time) = Jun 08 2009 23:38:19 Store Lat/Lon Data = Append to Every Scan Tully Cruise: 2009-08 Station: P8 Latitude: Longitude: Depth (m): 2517 # nquan = 5 # nvalues = 4669 # units = specified # name 0 = scan: Scan Count # name 1 = prDM: Pressure, Digiquartz [db] # name 2 = xmiss: Beam Transmission, Chelsea/Seatech/Wetlab CStar [%] # name 3 = nbf: number of bottles fired # name 4 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jun 07 2009 02:14:50 # sensor 0 = Frequency 0 temperature, primary, 2038, 06 May 08 # sensor 1 = Frequency 1 conductivity, primary, 2128, 30-Jan-09, cpcor = -9.57 00e-08 # sensor 2 = Frequency 2 pressure, 63507, 25-Oct-04 # sensor 3 = Frequency 3 temperature, secondary, 2449, 06 May 08 # sensor 4 = Frequency 4 conductivity, secondary, 2424, 07 May 08, cpcor = -9. 5700e-08 # sensor 5 = Extrnl Volt 0 Fluorometer, Seapoint, primary # sensor 6 = Extrnl Volt 2 transmissometer, primary, 1005, 15-Mar-08 # sensor 7 = Extrnl Volt 3 Oxygen, SBE, primary, 0997, 01-Mar-08p # sensor 8 = Extrnl Volt 4 altimeter # sensor 9 = Extrnl Volt 6 irradiance (PAR), primary, 4615, 15-Dec-00 # sensor 10 = Extrnl Volt 7 pH, 0692, 06-feb-09 # sensor 11 = Extrnl Volt 9 surface irradiance (SPAR), degrees = 0.0 # datcnv_date = Nov 16 2009 10:45:01, 7.18c # datcnv_in = Q:\Cruise_Data_Processing\2009-09\RAW\CTD\2009-09-0020.hex Q:\Crui se_Data_Processing\2009-09\Processing\doc\2009-09-ctd3.con # datcnv_bottle_scan_range_source = BL file END* Comments from secondary file: Q:\Cruise_Data_Processing\2009-09\Processing\test\2009-09-0020.add ------------------------------------------------------------------ Sample_Number 141: 2 curves, added titers Sample_Number 145: Outlier in comparison of CTD and Bottle DO, and in profile plots. Sample_Number 146: Outlier in comparison of CTD and Bottle DO, and in profile plots. ********************************************************************************* Transmissometer #1005DR was calibrated in March 2008, and drifted significantly but steadily until July 2009; then a sudden shift occurred, so that maximum values between September 2009 and July 2010 were very low, ~25%/m. In August 2010 a study was made of transmissivity that led to a decision to apply post-processing corrections to all cruises between March 2008 and June 2010. Transmissivity data from this cruise were corrected by multiplying the original values by a correction factor, which was based on assumptions that deep offshore transmissivity from a June 2009 cruise should be about 62%/m and that drift was linear with time between March 2008 and July 2009. The corrections produced reasonable results for all cruises in that time period. For details on how the correction factor was derived see: OSD_Data_Archive:\Cruise_Data\DOCUMENTS\Transmissometer 1005DR Corrections.doc These data should be considered estimates. ********************************************************************************* July 2013: A correction has been applied to Nitrate_plus_Nitrite and Phosphate data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the following report: Corrections to Nitrate and Phosphate for Deep-Water Cruises from 2009 to 2012.pdf which is stored in folder: \\Cruise_Data\DOCUMENTS\Analysis Reference Papers Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2009\2009-009_Nov2021\Processing\IOS\2009-009-0020. hplc --------------------------------------------------------------------------- Sample_Number 146: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure dbars 10 -99 () (0.3 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.305E-01 1.0528) Salinity:T0:C0 PSS-78 10 -99 () (0.2E-01 1) Transmissivity %/metre 10 -99 () (0 1.265) Nitrate_plus_Nitrite umol/L 10 -99 () (0.1709 0.9812) Phosphate umol/L 10 -99 () (0.453E-01 1.0115) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- ---7---- --8--- --9-- -10- ---11--- 12 ---13-- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- 48 !Samp Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T0:C0 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a chlide a fuco fuco : !er er Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 148 20 5.2 12.2281 -99.0 0.912 32.3882 6.82 297.3 42 32.3900 0 6.845 0 4.2 0 8.2 0 0.75 0 0.51 0 0.024 0.000 0.000 0.032 0.000 0.000 0.000 0.000 0.031 0.047 0.000 0.000 0.000 0.138 0.065 0.015 0.011 0.009 0.005 0.021 0.000 0.313 0.000 0.005 0.313 6 149 21 5.2 12.1976 34.3 0.916 32.3895 6.82 297.4 240 32.3888 0 6.842 0 4.2 0 8.2 0 0.75 0 0.52 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 147 19 10.2 11.7208 50.5 0.979 32.3797 6.87 299.4 241 32.3786 0 6.891 0 4.2 0 8.2 0 0.75 0 0.45 6 0.021 0.000 0.000 0.039 0.000 0.000 0.003 0.000 0.035 0.048 0.005 0.000 0.000 0.141 0.055 0.015 0.011 0.009 0.005 0.029 0.000 0.298 0.000 0.002 0.298 6 146 18 25.1 11.1246 49.6 1.809 32.4155 7.02 306.0 241 32.4140 0 5.423 4 4.3 0 8.4 0 0.75 0 0.53 0 0.044 0.000 0.000 0.057 0.000 0.000 0.007 0.000 0.047 0.075 0.006 0.000 0.000 0.214 0.034 0.006 0.009 0.011 0.005 0.048 0.000 0.361 0.000 0.002 0.361 36 145 17 49.9 8.0717 56.2 1.522 32.3999 7.11 309.6 241 32.4009 0 6.187 4 7.9 0 11.5 0 0.98 0 0.49 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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-99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 141 13 150.4 6.8985 61.5 0.137 33.7284 3.83 166.5 241 33.7252 0 3.288 4 27.7 0 37.4 0 2.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 140 12 176.7 6.7087 61.6 0.132 33.8582 3.30 143.3 241 33.8555 0 3.372 0 30.3 0 43.6 0 2.15 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 139 11 200.0 6.4645 61.7 0.130 33.8805 3.15 136.9 241 33.8821 0 3.150 0 31.8 6 47.7 6 2.23 6 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 138 10 249.1 6.0093 61.9 0.131 33.9062 2.62 113.8 241 33.9053 0 2.685 0 34.3 0 56.0 0 2.41 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 137 9 301.1 5.8046 62.1 0.131 33.9814 1.49 64.7 241 33.9827 0 1.433 0 39.2 0 66.8 0 2.77 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 136 8 400.3 5.2597 62.6 0.132 34.0492 0.92 40.1 241 34.0480 0 0.987 0 42.4 0 79.9 0 3.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 134 6 600.5 4.4808 -99.0 0.132 34.1928 0.32 14.0 50 34.1999 0 0.362 0 45.1 0 103.9 0 3.25 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 135 7 600.5 4.4806 62.7 0.132 34.1929 0.32 14.0 240 34.2041 0 0.347 0 45.0 0 104.1 0 3.24 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 133 5 800.2 3.7115 62.7 0.132 34.2987 0.21 9.2 241 34.3002 0 0.211 0 46.4 0 127.4 0 3.31 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 132 4 999.7 3.2935 62.9 0.132 34.3732 0.20 8.7 241 34.3749 0 0.249 0 46.9 0 141.3 0 3.33 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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-99.000 0